JPH01139522A - Hair treating agent - Google Patents
Hair treating agentInfo
- Publication number
- JPH01139522A JPH01139522A JP62297121A JP29712187A JPH01139522A JP H01139522 A JPH01139522 A JP H01139522A JP 62297121 A JP62297121 A JP 62297121A JP 29712187 A JP29712187 A JP 29712187A JP H01139522 A JPH01139522 A JP H01139522A
- Authority
- JP
- Japan
- Prior art keywords
- hair
- formula
- component
- silicone oil
- silicone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 26
- 229920002545 silicone oil Polymers 0.000 claims abstract description 17
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract 2
- 238000011282 treatment Methods 0.000 claims description 25
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 5
- 230000001680 brushing effect Effects 0.000 abstract description 5
- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 abstract description 2
- 239000003795 chemical substances by application Substances 0.000 description 15
- 239000000203 mixture Substances 0.000 description 9
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 239000004615 ingredient Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 238000001816 cooling Methods 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 239000003205 fragrance Substances 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 2
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 229920006317 cationic polymer Polymers 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- 230000003766 combability Effects 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000010696 ester oil Substances 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- 229940057995 liquid paraffin Drugs 0.000 description 2
- 239000008267 milk Substances 0.000 description 2
- 210000004080 milk Anatomy 0.000 description 2
- 235000013336 milk Nutrition 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 230000002335 preservative effect Effects 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- 229920003169 water-soluble polymer Polymers 0.000 description 2
- FFJCNSLCJOQHKM-CLFAGFIQSA-N (z)-1-[(z)-octadec-9-enoxy]octadec-9-ene Chemical compound CCCCCCCC\C=C/CCCCCCCCOCCCCCCCC\C=C/CCCCCCCC FFJCNSLCJOQHKM-CLFAGFIQSA-N 0.000 description 1
- 239000004604 Blowing Agent Substances 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 1
- IUMSDRXLFWAGNT-UHFFFAOYSA-N Dodecamethylcyclohexasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 IUMSDRXLFWAGNT-UHFFFAOYSA-N 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- 229920002385 Sodium hyaluronate Polymers 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 125000005456 glyceride group Chemical group 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 229940075507 glyceryl monostearate Drugs 0.000 description 1
- 230000003699 hair surface Effects 0.000 description 1
- HTDJPCNNEPUOOQ-UHFFFAOYSA-N hexamethylcyclotrisiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O1 HTDJPCNNEPUOOQ-UHFFFAOYSA-N 0.000 description 1
- 210000003127 knee Anatomy 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 1
- 229920000053 polysorbate 80 Polymers 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 229940010747 sodium hyaluronate Drugs 0.000 description 1
- YWIVKILSMZOHHF-QJZPQSOGSA-N sodium;(2s,3s,4s,5r,6r)-6-[(2s,3r,4r,5s,6r)-3-acetamido-2-[(2s,3s,4r,5r,6r)-6-[(2r,3r,4r,5s,6r)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2- Chemical compound [Na+].CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 YWIVKILSMZOHHF-QJZPQSOGSA-N 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
- A61K8/585—Organosilicon compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/24—Thermal properties
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
炙１直Δ帆星立吐
本発明は毛髪に対し優れたすべり感および光沢を付与し
、またドライヤー等の熱やブラッシングなどから毛髪を
保護する毛髪処理剤に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a hair treatment agent that imparts excellent smoothness and gloss to hair and protects the hair from heat from a hair dryer and from brushing.
従来の技術およびその問題点
従来より、髪につやと弾力を与え、あるいは傷んだ髪の
手入れを行うため、ヘアートリートメント、ヘアリンス
など様々な毛髪処理剤が用いられている。例えば、毛髪
に光沢やなめらかさを与えるためには、シリコーン油、
高級アルコール、流動パラフィン、エステル油などの油
分を配合したものが用いられている。また、毛髪に柔軟
性や帯電防止効果を与えるためには、カチオン性界面活
性剤やカチオン性高分子化合物を配合したものが用いら
れている。さらに、ドライア−の熱などから毛髪を保護
するためには水溶性高分子化合物を配合したものなども
ある。BACKGROUND ART Conventionally, various hair treatment agents such as hair treatments and hair rinses have been used to give luster and elasticity to hair or to care for damaged hair. For example, silicone oil,
A blend of oils such as higher alcohol, liquid paraffin, and ester oil is used. Furthermore, in order to impart flexibility and antistatic effect to the hair, products containing a cationic surfactant or a cationic polymer compound are used. Furthermore, in order to protect the hair from the heat of a hair dryer, there are products that contain water-soluble polymer compounds.
しかしながら、前記の油分を配合した毛髪処理剤はベタ
ツキなど、毛髪に適用した場合に違和感を与える欠点が
あり、またそれ自体粘着性を有しているためクシ通りや
ブラッシングに対する物理的抵抗値も大きくなる。また
、カチオン性界面活性剤、カチオン性高分子化合物を配
合した毛髪処理剤は毛髪表面の負に帯電した部分にのみ
電気的に吸着するものであって吸着力が不充分で、均一
性にも劣り、またクシ通り性も良好ではない。さらに水
溶性高分子を配合した毛髪処理剤はそれ自体の粘着性、
接着性が大きく処理後の毛髪がゴワプッとして違和感が
あり、クシ通り性が悪いなどの欠点を有する。However, hair treatment agents containing oil have the disadvantage of being sticky and causing a feeling of discomfort when applied to the hair, and because they are sticky themselves, they have a high physical resistance to combing and brushing. Become. Additionally, hair treatment agents containing cationic surfactants and cationic polymer compounds electrically adsorb only to negatively charged areas on the hair surface, resulting in insufficient adsorption power and poor uniformity. It is inferior, and the combability is also not good. Furthermore, hair treatment agents containing water-soluble polymers have their own adhesive properties,
It has disadvantages such as high adhesiveness, which makes the hair after treatment feel stiff and uncomfortable, and poor combability.
本発明は、毛髪に対して優れたすべり感および光沢を付
与し、またドライヤー等の熱やブラッシングから髪を保
護する毛髪処理剤を得ることを目的とする。An object of the present invention is to obtain a hair treatment agent that imparts excellent smoothness and gloss to hair and protects hair from heat from a dryer or the like and from brushing.
問題点を解決するための手段
すなわち、本発明は後記の式［１１で示されるジメチル
シリコーンガム、後記の式［１］で示されるシリコーン
油、および後記式［１１１］で表される揮発性シリコー
ン油からなり、かつ［Ｉ］および［１］の重量配合比［
■コ／［Ｉ］が１／３〜３／Ｉであることを特徴とする
毛髪処理剤を提供するものである。Means for solving the problems, that is, the present invention provides a dimethyl silicone gum represented by the formula [11] below, a silicone oil represented by the formula [1] below, and a volatile silicone represented by the formula [111] below. consists of oil, and has a weight blending ratio of [I] and [1] [
(2) To provide a hair treatment agent characterized in that ⅓/[I] is 1/3 to 3/I.
本発明の毛髪処理剤に配合されるジメチルシリコーンガ
ムは、下記の構造式［Ｉ］で示される。The dimethyl silicone gum blended into the hair treatment agent of the present invention is represented by the following structural formula [I].
［式中、Ｒ１，Ｒ２はメヂル基または水酸基；ｎは４０
００〜９０００の整数を意味する］式［１］のジメチル
シリコーンガムの代表的なものとしては、例えば東芝シ
リコーンＴＳＥ−２００、ＴＳＥ−２００Ａ（東芝シリ
コーン（株）製）などが挙げられ、それらの１種または
２種以上を処理剤全量に対して１〜２０重量％、好まし
くは５〜１５重量％配合する。配合量がこれより少ない
と、毛髪へのクシ通り性、およびなめらかな感触が充分
ではない。一方、この範囲を越えるとジメチルシリコー
ンガム自体の粘性が強くなり使用感が低下する。[In the formula, R1 and R2 are medyl group or hydroxyl group; n is 40
An integer from 00 to 9,000] Typical dimethyl silicone gums of formula [1] include Toshiba Silicone TSE-200 and TSE-200A (manufactured by Toshiba Silicone Co., Ltd.); One or more types are blended in an amount of 1 to 20% by weight, preferably 5 to 15% by weight, based on the total amount of the processing agent. If the amount is less than this, the ability to comb through the hair and the smooth feel will not be sufficient. On the other hand, if it exceeds this range, the viscosity of the dimethyl silicone gum itself becomes strong and the usability deteriorates.
また、本発明毛髪処理剤の他の配合成分であるシリコー
ン油は下記の構造式［Ｉ［］で示される。Further, silicone oil, which is another component of the hair treatment agent of the present invention, is represented by the following structural formula [I[].
［式中、ｎは３０〜３００の整数を意味するコ式［■］
のシリコーン油の代表的なものとしては、例えば東芝シ
リコーン（株）製ＴＳＦ４５１−５０、Ｔ Ｓ Ｆ４５
１−３００、東しシリコーン（株）製５Ｈ−２００−１
００ｃｓ、５Ｈ−２００−５００ＯＳ、信越シリコーン
（株）製ＫＦ’−９６−１ｏｏ、 ＫＦ−９６−１００
０などが挙げられる。[In the formula, n means an integer from 30 to 300 [■]
Typical silicone oils include, for example, TSF451-50 and TSF45 manufactured by Toshiba Silicone Co., Ltd.
1-300, 5H-200-1 manufactured by Toshi Silicone Co., Ltd.
00cs, 5H-200-500OS, Shin-Etsu Silicone Co., Ltd. KF'-96-1oo, KF-96-100
Examples include 0.
さらに、本発明にて用いられる揮発性シリコーン油は下
記の構造式［１’［］で示される。Furthermore, the volatile silicone oil used in the present invention is represented by the following structural formula [1'[].
［式中、ｎは３〜７の整数を意味する］かかる式［ＩＩ
Ｉ］の揮発性シリコーン油の代表的なものとしては、例
えば、オクタメチルシクロテトラシロキサン、デカメチ
ルシクロペンタシロキサン、ヘキサメチルシクロトリシ
ロキサン、ドデカメチルシクロヘキサシロキサンどが挙
げられる。[In the formula, n means an integer of 3 to 7] Such a formula [II
Typical volatile silicone oils (I) include, for example, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, hexamethylcyclotrisiloxane, dodecamethylcyclohexasiloxane, and the like.
これら式［Ｉ］のジメチルシリコーンガムと式Ｕｎ］の
シリコーン油の配合重量比［ＩＩ］／［Ｉ］は１／３〜
３／１、好ましくは１．／２〜２／ｌで、・ケ・る。か
かる配合比が１／３未満であると、毛髪のすべり感およ
び光沢が充分でない。一方、３／ｌを越えると、すべり
感が充分でなく、ベタツキが強く、使用感を損なう。The blending weight ratio [II]/[I] of the dimethyl silicone gum of formula [I] and the silicone oil of formula Un] is from 1/3 to
3/1, preferably 1. /2~2/l, ・ke・ru. If the blending ratio is less than 1/3, the smoothness and gloss of the hair will not be sufficient. On the other hand, if it exceeds 3/l, the slippery feeling will not be sufficient and the stickiness will be strong, impairing the feeling of use.
本発明の毛髪処理剤は水系又は非水系とすることができ
るが、剤型安定性の面から非水系にすることが望ましい
。The hair treatment agent of the present invention can be aqueous or non-aqueous, but from the viewpoint of formulation stability, it is preferably non-aqueous.
本発明の毛髪処理剤は公知の方法により、ヘアミルク、
ブロー剤、ヘアートリートメント、ヘアリンス、トリー
トメントスプレィ、トリートメントパック等の形感に製
造される。The hair treatment agent of the present invention can be prepared by a known method such as hair milk,
Manufactured in the form of blow-dry agents, hair treatments, hair rinses, treatment sprays, treatment packs, etc.
本発明の毛髪処理剤には、その性能を損なわない範囲で
さらに油成分（流動パラフィン、トリグリセライド、エ
ステル油、ワックス類等）、着色料、香料、界面活性剤
などを配合することができる。The hair treatment agent of the present invention may further contain oil components (liquid paraffin, triglycerides, ester oils, waxes, etc.), coloring agents, fragrances, surfactants, etc. within a range that does not impair its performance.
寒皇鯉
つぎに本発明を実施例に基づきさらに具体的に説明する
。なお、実施例、比較例中の配合量は重量％で示した。Next, the present invention will be explained in more detail based on examples. In addition, the blending amounts in Examples and Comparative Examples are shown in weight %.
実施例１〜５および比較例１〜５
後記第１表に示す組成にて常法にてジメチルシリコーン
ガムおよびシリコーン等を混合した後、撹拌してヘアー
トリートメントを得た。これらを用いてつぎの項目につ
いて評価した。結果を第１表に合わせ示す。Examples 1 to 5 and Comparative Examples 1 to 5 After dimethyl silicone gum, silicone, etc. were mixed in a conventional manner with the composition shown in Table 1 below, the mixture was stirred to obtain hair treatments. Using these, the following items were evaluated. The results are also shown in Table 1.
（評価方法） 試験ザンプルの評価はつぎの方法で行なった。(Evaluation method) The test samples were evaluated in the following manner.
いずれも専門パネラ−１０名の実使用による官能評価を
行った。使用時のベタツキ、乾燥後のすべり感、しっと
り感、乾燥後の光沢について下記評価基孕にしたがって
評価し、各得点の合計を求めた。All were subjected to sensory evaluation by 10 expert panelists through actual use. Stickiness during use, smoothness after drying, moist feeling, and gloss after drying were evaluated according to the following evaluation criteria, and the sum of each score was determined.
（使用時のべたつき）
べたつきがない −１
ややべたつきがある； ０
べたつきがある ニー１
（乾燥後のすべり感、しっとり感）
使用前と比較して良好 ：２
〃 やや良好：ｌ
〃 差がない：０
（乾燥後のつや）
使用前と比較して良好 ：２
〃 やや良好：ｌ
〃 差がない二〇
実施例５（乳液タイプ）
成 分 配合量（
成分Ａ）
プロピレングリコール １．８ＰＯ
Ｅ（５）オレイルエーテル ２．５ジメヂ
ルシリコーンガム（ＴＳＥ２００） ６．０シリ
コーン浦（式（ＩＩ）、ｎ＝６０） ６．０揮
発性シリコーン（式（ＩｎＬｎ＝５） １５．０（
成分Ｂ）
カーボボール９４１ ０．３水
残
量（成分Ｃ）
トリエタノールアミン ０．３水
２．７（成分Ｄ） ゛
香料 ０・１成分
Ｂを混合して８０℃に保った。別に成分Ａを混合して７
０℃に保持し、前記成分Ｂに加え、撹拌して均一化した
後、冷却しながら成分Ｃおよび成分りを加えてヘアミル
クを製造した。(Stickiness during use) Not sticky -1 Slightly sticky; 0 Sticky Knee 1 (Slippery, moist feeling after drying) Good compared to before use: 2 Slightly good: l No difference :0 (Gloss after drying) Good compared to before use :2 〃 Slightly good: l 〃 No difference 20 Example 5 (emulsion type) Component Amount (
Component A) Propylene glycol 1.8PO
E (5) Oleyl ether 2.5 Dimedyl silicone gum (TSE200) 6.0 Silicone ura (Formula (II), n=60) 6.0 Volatile silicone (Formula (InLn=5) 15.0 (
Component B) Carboball 941 0.3 water Remaining amount (component C) Triethanolamine 0.3 water
2.7 (Component D) ゛Fragrance 0.1 Component B was mixed and kept at 80°C. Separately, mix component A and 7
The mixture was maintained at 0° C., added to the component B, stirred and homogenized, and then added with component C and ingredients while cooling to produce hair milk.
実施例６（ブロー剤）
成 分 配合量（
成分Ａ）
プロピレングリコール ２，０ツイー
ン８０ １．０ジメチルシリ
コーンガム（ＴＳＥ２０ＯＡ） １．５シリコーン
油（式（ｎ）、ｎ＝４０） ２．０揮発性シリ
コーン（式（ＩＩ［）、ｎ＝３） ８．０（成分Ｂ
）
水 残量
（成分Ｃ）
９５％エタノール ２０（成
分Ｄ）
香料 ｏ４６０℃
に加熱した成分Ａ中に同じく６０°Ｃに加熱した成分Ｂ
を加え撹拌混合した。ついで、冷却しながら成分Ｃおよ
びＤを加えた。Example 6 (Blowing agent) Ingredients Blend amount (
Component A) Propylene glycol 2,0 Tween 80 1.0 Dimethyl silicone gum (TSE20OA) 1.5 Silicone oil (formula (n), n=40) 2.0 Volatile silicone (formula (II[), n=3 ) 8.0 (Component B
) Water Remaining amount (Component C) 95% Ethanol 20 (Component D) Fragrance o460℃
Component A heated to 60°C and Component B heated to 60°C.
was added and mixed by stirring. Components C and D were then added while cooling.
実施例７（リンス）
成分 配合ｍ（成分Ａ
）
塩化ステアリル
トリメデルアンモニウム ２．０ジメヂ
ルシリコーンガム（ＴＳＥ２ＱＯＡ） ５．０シリコ
ーン油（式（Ｉ［）、ｎ＝４０） ２，５押発
性シリコーン（式（ＩＩＩ）、ｎ＝４） ８．０自
己乳化型
モノステアリン酸グリセリド １．０エチレ
ングリコール
モノステアレート１．０
（成分Ｂ）
グリセリン ２．０防腐剤
微量色素
水
残量（成分Ｃ）
香料
成分Ｂを混合して７５℃に保ち、これに別個に成分Ａを
混合して７５℃に保ったものを加えた。Example 7 (Rinse) Ingredients Mixture m (Component A
) Stearyl trimedelammonium chloride 2.0 Dimedyl silicone gum (TSE2QOA) 5.0 Silicone oil (Formula (I[), n=40) 2,5 Extrudable silicone (Formula (III), n=4) 8 .0 Self-emulsifying monostearic acid glyceride 1.0 Ethylene glycol monostearate 1.0 (Component B) Glycerin 2.0 Preservative Trace pigment water
Remaining amount (component C) Perfume component B was mixed and kept at 75°C, and to this was added component A that was separately mixed and kept at 75°C.
撹拌し冷却しながら成分Ｃを添加してリンスを製造した
。A rinse was prepared by adding component C with stirring and cooling.
実施例８（ヘアーリートメント）
成 分 配合量（成
分Ａ）
塩化ジメチルベンジルアンモニウム ３．０ジメ
チルシリコーンガム（ＴＳＥ２００） ８．０シリ
コーン油（式（ＩＩ）、ｎ＝２５０） １０．０
揮発性シリコーン（式（Ｉ［Ｉ）、ｎ＝６） Ｉ Ｏ
，０ラノリン １．０
スクワラン ２．０自己乳
化型
モノステアリン酸グリセリン ３．０エチレ
ングリコール
モノステアレート５．０
セチルアルコール ０．５（成分
Ｂ）
ヒアルロン酸ナトリウム ０．００１防腐
剤 微量水
残量（成分Ｃ
）
香料 微量成分Ｂ
を混合して７５℃に保ち、これに別個に成分Ａを混合し
て７５°Ｃに保ったものを加えた。Example 8 (Hair Treatment) Component Amount (Component A) Dimethylbenzylammonium chloride 3.0 Dimethyl silicone gum (TSE200) 8.0 Silicone oil (Formula (II), n=250) 10.0
Volatile silicone (formula (I[I), n=6) I O
,0 lanolin 1.0
Squalane 2.0 Self-emulsifying glyceryl monostearate 3.0 Ethylene glycol monostearate 5.0 Cetyl alcohol 0.5 (Component B) Sodium hyaluronate 0.001 Preservative Trace amount of water
Remaining amount (component C
) Fragrance trace ingredient B
Component A was mixed and kept at 75°C, and Component A was separately mixed and kept at 75°C.
撹拌し冷却しながら成分Ｃを添加してヘアートリートメ
ントを製造した。A hair treatment was prepared by adding component C while stirring and cooling.
実施例９（非水系ヘアトリートメント）成 分
配合量ジメチルシリ
コーンゴム（ＴＳＥ２００） １５．０シリコーン
油（式〔■〕、ｎ＝１５０） ３５．０揮発性シリ
コーン（式（ＩＩＩ）、ｎ＝４） 残量香料
微量
色素 微量
上記成分を撹拌して均一化し、非水系へアートリートメ
ントを製造した。Example 9 (Non-aqueous hair treatment) Ingredients
Blend amount Dimethyl silicone rubber (TSE200) 15.0 Silicone oil (Formula [■], n = 150) 35.0 Volatile silicone (Formula (III), n = 4) Remaining amount Fragrance
Trace amount of pigment: A trace amount of the above components was stirred and homogenized to produce a non-aqueous hair treatment.
発明の効果
本発明の毛髪処理剤は、毛髪に対しで優れたすべり感お
よび光沢を付与し、熱やブラッシングなどから髪を特徴
する
特許出願人 サンスター株式会社Effects of the Invention The hair treatment agent of the present invention imparts excellent smoothness and gloss to the hair, and makes the hair resistant to heat, brushing, etc. Patent applicant: Sunstar Co., Ltd.
Claims (2)
４０００〜９０００の整数を意味する］ で示されるジメチルシリコーンガム、 （ｂ）下式［II］ ▲数式、化学式、表等があります▼［II］ ［式中、ｎは３０〜３００の整数を意味する］で示され
るシリコーン油、および （ｃ）下式［III］ ▲数式、化学式、表等があります▼［III］ ［式中、ｎは３〜７の整数を意味する］ で示される揮発性シリコーン油からなり、かつ［ I ］
と［II］との重量配合比［II］／［ I ］が１／３〜３
／１であることを特徴とする毛髪処理剤。(1) (a) The following formula: ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ [I] [In the formula, R^1 and R^2 are methyl groups or hydroxyl groups; n means an integer from 4000 to 9000] Dimethyl silicone gum represented by (b) the following formula [II] ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ [II] [In the formula, n means an integer from 30 to 300] silicone oil, and (c) The following formula [III] ▲There are mathematical formulas, chemical formulas, tables, etc.▼ [III] [In the formula, n means an integer from 3 to 7] Consists of a volatile silicone oil represented by [I]
The weight mixing ratio [II]/[I] of and [II] is 1/3 to 3
A hair treatment agent characterized in that: /1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62297121A JPH01139522A (en) | 1987-11-24 | 1987-11-24 | Hair treating agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62297121A JPH01139522A (en) | 1987-11-24 | 1987-11-24 | Hair treating agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH01139522A true JPH01139522A (en) | 1989-06-01 |
| JPH0567122B2 JPH0567122B2 (en) | 1993-09-24 |
Family
ID=17842487
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62297121A Granted JPH01139522A (en) | 1987-11-24 | 1987-11-24 | Hair treating agent |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01139522A (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01175923A (en) * | 1987-12-28 | 1989-07-12 | Nonogawa Shoji:Kk | Hair cosmetic |
| EP0837101A1 (en) * | 1996-10-21 | 1998-04-22 | Klinview Corporation | Lustering and protecting agent for rubber, vinyl, and the like |
| EP0839871A1 (en) * | 1996-10-21 | 1998-05-06 | No Touch North America | Propellant - free lustering and protecting agent for rubber, vinyl and the like |
| US6843982B1 (en) | 1994-01-26 | 2005-01-18 | L'oreal | Anhydrous cosmetic or dermatological composition containing the combination of a silicone oil and a wax made from an ethylene homopolymer or copolymer |
| WO2005018586A1 (en) * | 2003-08-21 | 2005-03-03 | Kao Corporation | Hair care product |
| JP2005206505A (en) * | 2004-01-22 | 2005-08-04 | Milbon Co Ltd | Nonaqueous hair treatment agent |
| JP2008260785A (en) * | 2008-07-17 | 2008-10-30 | Kao Corp | Aerosol spray composition |
| JP2008273902A (en) * | 2007-05-02 | 2008-11-13 | Kose Corp | Oily hair cosmetic |
| WO2009102758A1 (en) * | 2008-02-11 | 2009-08-20 | The Procter & Gamble Company | Process for reducing hair damage upon treatment of hair by heat |
| JP2009221143A (en) * | 2008-03-17 | 2009-10-01 | Shiseido Co Ltd | Hair cosmetic |
| US9427603B2 (en) | 2008-02-11 | 2016-08-30 | The Procter & Gamble Company | Process for reducing hair damage upon treatment of hair by heat |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57112319A (en) * | 1980-03-10 | 1982-07-13 | Procter & Gamble | Hair conditioning composition |
| JPS616A (en) * | 1984-03-15 | 1986-01-06 | ザ、プロクタ−、エンド、ギヤンブル、カンパニ− | Hair conditioning composition |
| JPS6248615A (en) * | 1985-06-06 | 1987-03-03 | ザ、プロクタ−、エンド、ギヤンブル、カンパニ− | Hair treatment mousse |
| JPS6277311A (en) * | 1985-07-10 | 1987-04-09 | ザ、プロクタ−、エンド、ギヤンブル、カンパニ− | Shampoo composition |
| JPS63183517A (en) * | 1986-09-03 | 1988-07-28 | Shiseido Co Ltd | Hair cosmetic |
| JPS63313714A (en) * | 1987-06-17 | 1988-12-21 | Shiseido Co Ltd | Hair cosmetic |
-
1987
- 1987-11-24 JP JP62297121A patent/JPH01139522A/en active Granted
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57112319A (en) * | 1980-03-10 | 1982-07-13 | Procter & Gamble | Hair conditioning composition |
| JPS616A (en) * | 1984-03-15 | 1986-01-06 | ザ、プロクタ−、エンド、ギヤンブル、カンパニ− | Hair conditioning composition |
| JPS6248615A (en) * | 1985-06-06 | 1987-03-03 | ザ、プロクタ−、エンド、ギヤンブル、カンパニ− | Hair treatment mousse |
| JPS6277311A (en) * | 1985-07-10 | 1987-04-09 | ザ、プロクタ−、エンド、ギヤンブル、カンパニ− | Shampoo composition |
| US4704272A (en) * | 1985-07-10 | 1987-11-03 | The Procter & Gamble Company | Shampoo compositions |
| JPS63183517A (en) * | 1986-09-03 | 1988-07-28 | Shiseido Co Ltd | Hair cosmetic |
| JPS63313714A (en) * | 1987-06-17 | 1988-12-21 | Shiseido Co Ltd | Hair cosmetic |
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01175923A (en) * | 1987-12-28 | 1989-07-12 | Nonogawa Shoji:Kk | Hair cosmetic |
| US6843982B1 (en) | 1994-01-26 | 2005-01-18 | L'oreal | Anhydrous cosmetic or dermatological composition containing the combination of a silicone oil and a wax made from an ethylene homopolymer or copolymer |
| EP0837101A1 (en) * | 1996-10-21 | 1998-04-22 | Klinview Corporation | Lustering and protecting agent for rubber, vinyl, and the like |
| EP0839871A1 (en) * | 1996-10-21 | 1998-05-06 | No Touch North America | Propellant - free lustering and protecting agent for rubber, vinyl and the like |
| CN100418508C (en) * | 2003-08-21 | 2008-09-17 | 花王株式会社 | Hair care product |
| WO2005018586A1 (en) * | 2003-08-21 | 2005-03-03 | Kao Corporation | Hair care product |
| US7854921B2 (en) | 2003-08-21 | 2010-12-21 | Kao Corporation | Hair care product |
| JP2005206505A (en) * | 2004-01-22 | 2005-08-04 | Milbon Co Ltd | Nonaqueous hair treatment agent |
| JP2008273902A (en) * | 2007-05-02 | 2008-11-13 | Kose Corp | Oily hair cosmetic |
| WO2009102758A1 (en) * | 2008-02-11 | 2009-08-20 | The Procter & Gamble Company | Process for reducing hair damage upon treatment of hair by heat |
| JP2011511842A (en) * | 2008-02-11 | 2011-04-14 | ザ プロクター アンド ギャンブル カンパニー | Method for reducing hair damage during hair treatment by heat |
| US8940282B2 (en) | 2008-02-11 | 2015-01-27 | The Procter & Gamble Company | Process for reducing hair damage upon treatment of hair by heat |
| US9427603B2 (en) | 2008-02-11 | 2016-08-30 | The Procter & Gamble Company | Process for reducing hair damage upon treatment of hair by heat |
| JP2009221143A (en) * | 2008-03-17 | 2009-10-01 | Shiseido Co Ltd | Hair cosmetic |
| JP2008260785A (en) * | 2008-07-17 | 2008-10-30 | Kao Corp | Aerosol spray composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0567122B2 (en) | 1993-09-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP3081049B2 (en) | Hair composition | |
| JPH04108719A (en) | Hair cosmetic | |
| JP2820329B2 (en) | Hair cosmetics | |
| JPS5912718B2 (en) | Hair washing composition | |
| JPH01139522A (en) | Hair treating agent | |
| JPH04108725A (en) | Hair cosmetic | |
| JPH01168609A (en) | Emulsified hair cosmetic | |
| JP3522025B2 (en) | Hair cosmetics | |
| JPS6351314A (en) | Hair cosmetic | |
| JP4136967B2 (en) | Hair cosmetics | |
| JP2001181156A (en) | Hair rinse composition | |
| JP3522024B2 (en) | Hair cosmetics | |
| JP2000086434A (en) | Cosmetic | |
| JP2530758B2 (en) | Hair cosmetics | |
| JPH0436222A (en) | Emulsified hair cosmetic | |
| JPH01175923A (en) | Hair cosmetic | |
| JPH01149707A (en) | Hair-treatment agent | |
| JP2000178141A (en) | Hair cosmetic | |
| JPH01113311A (en) | Hair treating agent | |
| JP4587094B2 (en) | Hair curing treatment | |
| JPH01168608A (en) | Hair drying composition | |
| JP3096498B2 (en) | Hair cosmetics | |
| JPH01132509A (en) | Hair cosmetic | |
| JP3465233B2 (en) | Hair cosmetics | |
| JPH07285834A (en) | Hair cosmetic |