JPH01113311A - Hair treating agent - Google Patents
Hair treating agentInfo
- Publication number
- JPH01113311A JPH01113311A JP26875187A JP26875187A JPH01113311A JP H01113311 A JPH01113311 A JP H01113311A JP 26875187 A JP26875187 A JP 26875187A JP 26875187 A JP26875187 A JP 26875187A JP H01113311 A JPH01113311 A JP H01113311A
- Authority
- JP
- Japan
- Prior art keywords
- hair
- formula
- treating agent
- integer
- component
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000011282 treatment Methods 0.000 claims abstract description 26
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 21
- 229920002545 silicone oil Polymers 0.000 claims abstract description 11
- 150000001875 compounds Chemical class 0.000 claims abstract description 7
- 229920001296 polysiloxane Polymers 0.000 claims description 20
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 14
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 5
- 239000010703 silicon Substances 0.000 claims description 5
- 229910052710 silicon Inorganic materials 0.000 claims description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims 3
- 239000004615 ingredient Substances 0.000 abstract description 9
- 230000001680 brushing effect Effects 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 3
- 239000008267 milk Substances 0.000 abstract description 3
- 210000004080 milk Anatomy 0.000 abstract description 3
- 235000013336 milk Nutrition 0.000 abstract description 3
- 238000002156 mixing Methods 0.000 abstract description 3
- 239000004604 Blowing Agent Substances 0.000 abstract description 2
- 239000007921 spray Substances 0.000 abstract description 2
- 230000003766 combability Effects 0.000 description 8
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 238000001816 cooling Methods 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 239000003205 fragrance Substances 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 229920006317 cationic polymer Polymers 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 229940057995 liquid paraffin Drugs 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 230000002335 preservative effect Effects 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- 229920003169 water-soluble polymer Polymers 0.000 description 2
- FFJCNSLCJOQHKM-CLFAGFIQSA-N (z)-1-[(z)-octadec-9-enoxy]octadec-9-ene Chemical compound CCCCCCCC\C=C/CCCCCCCCOCCCCCCCC\C=C/CCCCCCCC FFJCNSLCJOQHKM-CLFAGFIQSA-N 0.000 description 1
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
- ODHCTXKNWHHXJC-VKHMYHEASA-M 5-oxo-L-prolinate Chemical compound [O-]C(=O)[C@@H]1CCC(=O)N1 ODHCTXKNWHHXJC-VKHMYHEASA-M 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- 229920002385 Sodium hyaluronate Polymers 0.000 description 1
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 1
- 206010044625 Trichorrhexis Diseases 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 description 1
- 238000000861 blow drying Methods 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000002274 desiccant Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000010696 ester oil Substances 0.000 description 1
- -1 etc.) Substances 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 125000005456 glyceride group Chemical group 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 230000003699 hair surface Effects 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 1
- 229920000053 polysorbate 80 Polymers 0.000 description 1
- 229940071139 pyrrolidone carboxylate Drugs 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 229940010747 sodium hyaluronate Drugs 0.000 description 1
- YWIVKILSMZOHHF-QJZPQSOGSA-N sodium;(2s,3s,4s,5r,6r)-6-[(2s,3r,4r,5s,6r)-3-acetamido-2-[(2s,3s,4r,5r,6r)-6-[(2r,3r,4r,5s,6r)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2- Chemical compound [Na+].CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 YWIVKILSMZOHHF-QJZPQSOGSA-N 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
- A61K8/585—Organosilicon compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
灸墓五Δ秤１分肚
本発明は毛髪に対し優れたクシ通り性および、なめらか
な感触を付与し、また熱やブラッシングなどから毛髪を
保護する毛髪処理剤に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a hair treatment agent that imparts excellent combability and smooth feel to the hair, and protects the hair from heat, brushing, etc.
従来の技術およびその問題点
従来より、髪につやと弾力を与え、あるいは傷んだ髪の
手入れを行うため、ヘアートリートメント、ヘアリンス
などの様々な毛髪処理剤が用いられている。例えば、毛
髪に光沢やなめらかさを与えるためには、シリコン浦、
高級アルコール、流動パラフィン、エステル油などの油
分を配合したものが用いられている。また、毛髪に柔軟
性や帯電防止効果を与えるためには、カチオン性界面活
性剤やカチオン性高分子化合物を配合したものが用いら
れている。さらに、ドライア−の熱などから毛髪を保護
するためには水溶性高分子化合物を配合したものなども
ある。BACKGROUND ART Conventionally, various hair treatment agents such as hair treatments and hair rinses have been used to give luster and elasticity to hair or to care for damaged hair. For example, to give gloss and smoothness to your hair, use silicone,
A blend of oils such as higher alcohol, liquid paraffin, and ester oil is used. Furthermore, in order to impart flexibility and antistatic effect to hair, products containing a cationic surfactant or a cationic polymer compound are used. Furthermore, in order to protect the hair from the heat of a hair dryer, there are products that contain water-soluble polymer compounds.
しかしながら、前記の油分を配合した毛髪処理剤はベタ
つきなど、毛髪に適用した場合に異物感を与える欠点が
あり、またそれ自体粘着性を有しているためクシ通りや
ブラッシングに対する物理的抵抗値も大きくなる。また
、カチオン性界面活性剤、カチオン性高分子化合物を配
合した毛髪処理剤は毛髪表面の負に帯電した部分にのみ
電気的に吸着するものであって吸着力が不充分で、均一
性にも劣り、またクシ通りも良好ではない。さらに水溶
性高分子を配合した毛髪処理剤はそれ自体の粘着性、接
着性が大きく処理後の毛髪がゴワゴワとして異物感があ
り、クシ通りが悪いなどの欠点を有する。However, hair treatment agents containing oil have the disadvantage of being sticky and giving a foreign body feeling when applied to the hair, and are also sticky and have low physical resistance to combing and brushing. growing. Additionally, hair treatment agents containing cationic surfactants and cationic polymer compounds electrically adsorb only to negatively charged areas on the hair surface, resulting in insufficient adsorption power and poor uniformity. It is inferior, and the combability is also not good. Furthermore, hair treatment agents containing water-soluble polymers have drawbacks such as their high tackiness and adhesion, making the hair after treatment feel stiff and foreign, and difficult to comb.
また、シリコンガムを用いたヘアケア製品、さらにはジ
メチルシリコンガムを配合した耐水性、永続性のあるス
キンケア組成物（特開昭６１−２２９８１０号参照）も
提案されているが、クシ通り性などの物理的抵抗が大き
く、またべとつき感がある。In addition, hair care products using silicone gum and water-resistant and long-lasting skin care compositions containing dimethyl silicone gum (see Japanese Patent Application Laid-Open No. 61-229810) have been proposed, but they have problems such as combability. It has a large physical resistance and feels sticky.
本発明は、毛髪に対して優れたクシ通り性となめらかな
感触を付与し、熱やブラッシングなどから髪を保護する
毛髪処理剤を得ることを目的とする。The object of the present invention is to obtain a hair treatment agent that imparts excellent combability and smooth feel to the hair and protects the hair from heat, brushing, etc.
問題点を解決するための手段
すなわち、本発明は後記の式［ＩＩで示されるジメチル
シリコンガム、並びに後記の式［Ｉ［］で示される揮発
性シリコン油および後記式［ＩＩ［］で表される揮発性
シリコン油からなる群より選ばれた少なくとも１種の化
合物を含有し、かつ［１］の配合量が［ＩＩ］および［
ＩＩ［］の配合量の和を上回らないことを特徴とする毛
髪処理剤を提供するものである。Means for solving the problems, that is, the present invention provides a dimethyl silicone gum represented by the formula [II] below, a volatile silicone oil represented by the formula [I[] below, and a volatile silicone oil represented by the formula [II[] below. contains at least one compound selected from the group consisting of volatile silicone oils, and the amount of [1] is [II] and [
The present invention provides a hair treatment agent characterized in that the blending amount does not exceed the sum of the amounts of II[].
本発明の毛髪処理剤に配合されるジメチルシリコンガム
は、下記の構造式［ＩＩで示される。The dimethyl silicone gum blended into the hair treatment agent of the present invention is represented by the following structural formula [II].
し式中、Ｒ１，Ｒ２はメチル基または水酸基；ｎは４０
００〜９０００の整数を意味する］式［ＩＩのジメチル
シリコンガムの代表的なものとしては、例えば東芝シリ
コーンＴＳＥ−２００、ＴＳＥ−２００Ａなどが挙げら
れ、それらの１種または２種以上を処理剤全景に対して
０，０１〜５０重量％、好ましくは０．５〜２０重量％
配合する。配合量がこれより少ないと、毛髪へのクシ通
り性、およびなめらかな感触が充分ではない。一方、こ
の範囲を越えると、ジメチルシリコンガム自体の粘性が
強くなり使用感が悪化する。In the formula, R1 and R2 are a methyl group or a hydroxyl group; n is 40
An integer from 00 to 9000] Typical dimethyl silicone gums of the formula [II include, for example, Toshiba Silicone TSE-200, TSE-200A, etc., and one or more of them may be treated with a processing agent. 0.01 to 50% by weight, preferably 0.5 to 20% by weight relative to the entire view
Blend. If the amount is less than this, the ability to comb through the hair and the smooth feel will not be sufficient. On the other hand, if it exceeds this range, the viscosity of the dimethyl silicone gum itself will become strong and the feeling of use will deteriorate.
一方、本発明毛髪処理剤の他の配合成分である揮発性シ
リコン油は下記の構造式［ＩＩ］で示されるシリコン油
、あるいは下記の構造式［ＩＩＩ］で示される化合物で
ある。On the other hand, the volatile silicone oil which is another component of the hair treatment agent of the present invention is a silicone oil represented by the following structural formula [II] or a compound represented by the following structural formula [III].
式［Ｉ［’］の揮発性シリコン油の代表的なものとして
は、例えば東芝シリコーン（株）製Ｔ Ｓ Ｆ ４５１
−５ ＡＳＴ Ｓ Ｐ４５Ｌ−１０Ａなどが挙げられる
。A typical volatile silicone oil of formula [I['] is, for example, TSF 451 manufactured by Toshiba Silicone Co., Ltd.
-5 AST S P45L-10A and the like.
また式［１１１］の揮発性シリコン油の代表的なものと
しては、東芝シリコーン（株）製ＴＳＦ’４０４、ＴＳ
Ｆ４０５などが挙げられる。Typical volatile silicone oils of formula [111] include TSF'404 and TS manufactured by Toshiba Silicone Corporation.
Examples include F405.
これら式［■］および式［ＩＩ］の揮発性シリコン油は
その１種または２種以上を式［ＩＩのジメチルシリコン
ガムに対して等量以上配合する。配合量がジメチルシリ
コンガムより少ないと、処理剤中におけるジメチルシリ
コンガムの溶解性が低下し、またクシ通り性が悪く切れ
毛も増加する。One or more of these volatile silicone oils of formula [■] and formula [II] are blended in equal or more amounts to the dimethyl silicone gum of formula [II]. If the amount is less than that of dimethyl silicone gum, the solubility of dimethyl silicone gum in the treatment agent will decrease, and combability will be poor and hair breakage will increase.
本発明の毛髪処理剤は公知の方法により、ヘアミルク、
ブロー剤、ヘアートリートメント、ヘアリンス、トリー
トメントスプレィ、トリートメントパック等の形態に製
造される。The hair treatment agent of the present invention can be prepared by a known method such as hair milk,
Manufactured in the form of blow-drying agents, hair treatments, hair rinses, treatment sprays, treatment packs, etc.
本発明の毛髪処理剤には、その性能を損なわない範囲で
さらに油成分（流動パラフィン、トリグリセライド、エ
ステル浦、ワックス類等）、着色料、香料、ｐＨｊｌ整
剤（リン酸、クエン酸等）、保湿剤（ピロリドンカルボ
ン酸塩、乳酸等）などを配合することかできる。The hair treatment agent of the present invention may further contain oil components (liquid paraffin, triglyceride, esterura, waxes, etc.), coloring agents, fragrances, pH level adjusters (phosphoric acid, citric acid, etc.), within a range that does not impair its performance. Moisturizers (pyrrolidone carboxylate, lactic acid, etc.) may be added.
萩鬼鯉
つぎに本発明を実施例に基づきさらに具体的に説明する
。なお、実施例、比較例中の配合虫は重量％で示した。Next, the present invention will be explained in more detail based on examples. In addition, the compounded insects in Examples and Comparative Examples are shown in weight%.
実施例１〜５、および比較例１〜５
後記第１表に示す画成にて常法にてジメチルシリコンガ
ムおよび揮発性シリコン等を混合した後、撹拌して乳液
状の処理剤を得た。これらを用いてつぎの項目について
評価した。結果を第１表に示（評価方法）
試験サンプルの評価はつぎの方法で行なった。Examples 1 to 5 and Comparative Examples 1 to 5 Dimethyl silicone gum, volatile silicone, etc. were mixed in a conventional manner in the composition shown in Table 1 below, and then stirred to obtain a milky treatment agent. . Using these, the following items were evaluated. The results are shown in Table 1 (Evaluation Method) The test samples were evaluated in the following manner.
塗布時のべとつき：
専門パネラ−（２０代女性）５名の実使用による官能評
価
乾燥後のクシ通り抵抗：
各試験処理剤にて処理し乾燥した毛髪
２ｇをレオメータ−（不動工業
（味）製））に取り付け、クシを通した時、レオメータ
−にかかった最大の力を測
定し、次式に基づいて値を求めた。Stickiness during application: Sensory evaluation by 5 professional panelists (women in their 20s) after drying Comb-through resistance after drying: 2g of hair treated with each test treatment agent and dried was measured using a rheometer (manufactured by Fudo Kogyo (Aji)) )), and when the comb was passed through the rheometer, the maximum force applied to the rheometer was measured, and the value was determined based on the following formula.
１回洗髪乾燥後のクシ通り抵抗：
乾燥後のクシ通り抵抗に準じろ
切毛木＠：コーミング７２００回後の切毛本数（約２ｇ
の毛束：未処理毛ｔｔｃｔ本）
総合評価−〇二べとつきがなくクシ通り性良好×：べと
つきがある、又はクシ通り
性不良
実施例６（乳液タイプ）
成 分 配合量
（成分Ａ）
プロピレングリコール １．８ＰＯＥ
（５）オレイルエーテル １．２ジメチル
シリコンガム（ＴＳＥ２００） １．０揮発性
シリコン（式（ＩＩ）、ｎ＝２） １９．０（成
分Ｂ）
カーボボール９４１ ０ 、３
水 ７
３．６（成分Ｃ）
トリエタノールアミン ０．３水
２
．７（成分Ｄ）
香料 ０．１成分
Ｂを混合して８０℃に保った。別に成分Ａを混合して７
０℃に保持し、前記成分Ｂに加え、撹拌して均一化した
後、冷却しながら成分Ｃおよび成分りを加えてヘアミル
クを製造した。Combing resistance after washing and drying hair once: Same as combing resistance after drying.
Hair bundle: untreated hair TTCT) Overall evaluation - No stickiness and good combability ×: Stickiness or poor combability Example 6 (emulsion type) Ingredients Amount (component A) Propylene glycol 1.8POE
(5) Oleyl ether 1.2 Dimethyl silicone gum (TSE200) 1.0 Volatile silicon (Formula (II), n=2) 19.0 (Component B) Carboball 941 0,3
water 7
3.6 (Component C) Triethanolamine 0.3 Water 2
．． 7 (Component D) Flavor 0.1 Component B was mixed and kept at 80°C. Separately, mix component A and 7
The mixture was maintained at 0° C., added to the component B, stirred and homogenized, and then added with component C and other ingredients while cooling to produce hair milk.
実施例７（ブロー剤）
成 分 配合量
（成分Ａ）
プロピレングリコール ２．０ツイ
ーン８０ １．０ジメチル
シリコンガム（ＴＳＥ２０ＯＡ） ０．８揮発性
シリコンＩ （ｎ＝３） ８．０（成分
Ｂ）
水
残量（成分Ｃ）
９５％エタノール ２０（成
分Ｄ）
香料 ０．１６０
℃に加熱した成分Ａ中に同じく６０℃に加熱した成分Ｂ
を加え撹拌混合した。ついで、冷却しながら成分Ｃおよ
びＤを加えた。Example 7 (Blowing agent) Component Amount (Component A) Propylene glycol 2.0 Tween 80 1.0 Dimethyl silicone gum (TSE20OA) 0.8 Volatile silicon I (n=3) 8.0 (Component B) water
Remaining amount (component C) 95% ethanol 20 (component D) Fragrance 0.160
Component A heated to 60°C and Component B heated to 60°C
was added and mixed by stirring. Components C and D were then added while cooling.
実施例８（リンス）
成分 配合量（成分Ａ
）
塩化ステアリル
トリメチルアンモニウム ２．０ジメチ
ルシリコンガム（ＴＳＥ２０ＯＡ） ２．０揮発
性シリコンｎ （ｎ＝４） ８．０自己
乳化型
モノステアリン酸グリセリド １．０エチレ
ングリコール
モノステアレート ｌ、０（成分
Ｂ）
グリセリン ２．０防腐剤
微量色素
水
残量（成分Ｃ）
香料
成分Ｂを混合して７５℃に保ち、これに別個に成分Ａを
混合して７５℃に保ったものを加えた。Example 8 (Rinse) Component Amount (Component A
) Stearyltrimethylammonium chloride 2.0 Dimethyl silicone gum (TSE20OA) 2.0 Volatile silicon n (n=4) 8.0 Self-emulsifying monostearic acid glyceride 1.0 Ethylene glycol monostearate l, 0 (Component B ) Glycerin 2.0 Preservative Trace amount of pigmented water
Remaining amount (component C) Perfume component B was mixed and kept at 75°C, and to this was added component A that was separately mixed and kept at 75°C.
撹拌し冷却しながら成分Ｃを添加してリンスを製造した
。A rinse was prepared by adding component C with stirring and cooling.
実施例９（ヘアトリートメント）
成 分 配合量
（成分Ａ）
塩化ジメチルベンジルアンモニウム ３．０ジメ
チルシリコンガム（ＴＳＥ２００） ５．０揮
発性シリコンＩ （ｎ＝３） ｌ Ｏ，０
ラノリン １．０スク
ワラン ２，０自己乳化型
モノステアリン酸グリセリン ３．０エチレ
ングリコール
モノステアレート ５．０セチルア
ルコール ０．５（成分Ｂ）
ヒアルロン酸ナトリウム ｏ、ｏ ｏ を
防腐剤 微量水
残量
（成分Ｃ）
香料 微量成分Ｂ
を混合して７５℃に保ち、これに別個に成分Ａを混合し
て７５°Ｃに保ったものを加えた。撹拌し冷却しながら
成分Ｃを添加してヘアートリートメントを製造した。Example 9 (Hair Treatment) Component Amount (Component A) Dimethylbenzylammonium chloride 3.0 Dimethyl silicone gum (TSE200) 5.0 Volatile silicon I (n=3) l O,0
Lanolin 1.0 Squalane 2.0 Self-emulsifying glycerin monostearate 3.0 Ethylene glycol monostearate 5.0 Cetyl alcohol 0.5 (Component B) Sodium hyaluronate o, o o as preservative Trace amount of water
Remaining amount (ingredient C) Fragrance Trace ingredient B
Component A was mixed and kept at 75°C, and Component A was separately mixed and kept at 75°C. A hair treatment was prepared by adding component C while stirring and cooling.
発明の効果
本発明の毛髪処理剤は、毛髪に対して優れたクシ通り性
となめらかな感触を付与し、熱やブラッシングなどから
髪を保護する
特許出願人 サンスター株式会社Effects of the Invention The hair treatment agent of the present invention provides excellent combability and smooth feel to the hair, and protects the hair from heat, brushing, etc. Patent applicant: Sunstar Co., Ltd.
Claims (1)
４０００〜９０００の整数を意味する］ で示されるジメチルシリコンガム、並びに （ｂ）下式［II］ ▲数式、化学式、表等があります▼［II］ ［式中、ｎは０〜５の整数を意味する］ で示される揮発性シリコン油、および 下式［III］ ▲数式、化学式、表等があります▼［III］ ［式中、ｎは３〜７の整数を意味する］ で示される揮発性シリコン油からなる群より選ばれた少
なくとも１種の化合物を含有し、 かつ［II］と［III］の配合量の和を［ I ］の配合量に
対して等量以上とするすることを特徴とする毛髪処理剤
。(1) (a) The following formula: ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ [I] [In the formula, R^1 and R^2 are methyl groups or hydroxyl groups; n means an integer from 4000 to 9000] dimethyl silicone gum represented by, and (b) volatile silicon represented by the following formula [II] ▲Mathematical formula, chemical formula, table, etc.▼[II] [In the formula, n means an integer from 0 to 5] selected from the group consisting of volatile silicone oils represented by the following formula [III] ▲Mathematical formulas, chemical formulas, tables, etc.▼[III] [In the formula, n means an integer from 3 to 7] A hair treatment agent containing at least one type of compound, and characterized in that the sum of the amounts of [II] and [III] is equal to or more than the amount of [I].
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP26875187A JPH01113311A (en) | 1987-10-23 | 1987-10-23 | Hair treating agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP26875187A JPH01113311A (en) | 1987-10-23 | 1987-10-23 | Hair treating agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH01113311A true JPH01113311A (en) | 1989-05-02 |
Family
ID=17462830
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP26875187A Pending JPH01113311A (en) | 1987-10-23 | 1987-10-23 | Hair treating agent |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01113311A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01175923A (en) * | 1987-12-28 | 1989-07-12 | Nonogawa Shoji:Kk | Hair cosmetic |
| US6843982B1 (en) | 1994-01-26 | 2005-01-18 | L'oreal | Anhydrous cosmetic or dermatological composition containing the combination of a silicone oil and a wax made from an ethylene homopolymer or copolymer |
| WO2005018586A1 (en) * | 2003-08-21 | 2005-03-03 | Kao Corporation | Hair care product |
-
1987
- 1987-10-23 JP JP26875187A patent/JPH01113311A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01175923A (en) * | 1987-12-28 | 1989-07-12 | Nonogawa Shoji:Kk | Hair cosmetic |
| US6843982B1 (en) | 1994-01-26 | 2005-01-18 | L'oreal | Anhydrous cosmetic or dermatological composition containing the combination of a silicone oil and a wax made from an ethylene homopolymer or copolymer |
| WO2005018586A1 (en) * | 2003-08-21 | 2005-03-03 | Kao Corporation | Hair care product |
| CN100418508C (en) * | 2003-08-21 | 2008-09-17 | 花王株式会社 | Hair care product |
| US7854921B2 (en) | 2003-08-21 | 2010-12-21 | Kao Corporation | Hair care product |
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