CN110041591A - 一种颗粒化功能化复配三聚异氰脲酸酯与制备 - Google Patents

一种颗粒化功能化复配三聚异氰脲酸酯与制备 Download PDF

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CN110041591A
CN110041591A CN201910235258.2A CN201910235258A CN110041591A CN 110041591 A CN110041591 A CN 110041591A CN 201910235258 A CN201910235258 A CN 201910235258A CN 110041591 A CN110041591 A CN 110041591A
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poly
isocyanurates
taic
plasticizer
compounds
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CN110041591B (zh
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盛钧
盛天昊
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Nanjing Sikai Rubber And Plastic Product Co Ltd
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Nanjing Sikai Rubber And Plastic Product Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02—Organic and inorganic ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/36—Silica
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/098—Metal salts of carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/101—Esters; Ether-esters of monocarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/101—Esters; Ether-esters of monocarboxylic acids
    • C08K5/103—Esters; Ether-esters of monocarboxylic acids with polyalcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3477—Six-membered rings
    • C08K5/3492—Triazines
    • C08K5/34924—Triazines containing cyanurate groups; Tautomers thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C08L71/02—Polyalkylene oxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04—Polysiloxanes

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  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
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Abstract

一种颗粒化功能化复配三聚异氰脲酸酯(TAIC)，质量份配方如下：三聚异氰脲酸酯(TAIC)60、增塑剂5‑10、聚乙烯蜡10‑19；白碳黑：5‑25。制备流程为：1)三聚异氰脲酸酯(TAIC)60、增塑剂5‑10、分散剂1共熔，2)用白碳黑吸附共熔物；3)吸附料在40‑60℃共混；4)共混后的料在40‑60℃挤出造粒。

Description

一种颗粒化功能化复配三聚异氰脲酸酯与制备
技术领域
本发明涉及橡胶助剂的制备，尤其是橡胶助剂与增塑剂等惰性载体复合共混制备方法。
背景技术
在橡塑行业，三聚异氰脲酸酯(TAIC)是性价比极高的一种助交联剂，但其熔点在23度左右，正好在常温室温范围内，用桶包装，冬天凝固取用困难。如用袋包装，夏季流淌，贮运运输也极麻烦。
如何很好的解决这个问题且不影响三聚异氰脲酸酯(TAIC)的使用性能是困扰行业的一个问题。
发明内容
本发明目的是，提出一种颗粒化复配三聚异氰脲酸酯(TAIC)方法，尤其是采用合适惰性载体与TAIC共熔再用白碳黑吸附后，再熔造粒，有效物质三聚异氰脲酸酯的含量达到60％；贮存条件呈固体，基本不受温度的影响，可以在一年四季正常使用，配用安全方便，可以用于自动化配料系统的产品。
本发明技术方案是，一种颗粒化功能化复配三聚异氰脲酸酯(TAIC)的方法，颗粒化复配的配方如下(质量份)：三聚异氰脲酸酯(TAIC)60、增塑剂5-10、聚乙烯蜡10-19；白碳黑：5-25；白碳黑规格吸浊淔3-3.6，含水率4％，pH值6.8-7.2；
另采用内脱模剂10-19、分散剂1-2；内脱模剂：脂肪酸盐、脂肪酸酯、脂肪酰胺或其混和物。
分散剂0.5-3：聚乙二醇或和脂肪酰胺；
聚乙烯蜡10-19、熔点60度左右；
增塑剂5-15：聚酯增塑剂、乙二酸乙二醇醚酯；
本发明的制备流程：
1、三聚异氰脲酸酯(TAIC)60、增塑剂5-10或再加分散剂1共熔，
2、用白碳黑吸附共熔物；
3、吸附料在40-60℃共混；
4、共混后的料在40-60℃挤出造粒。
有益效果，本发明提出一种颗粒化复配三聚异氰脲酸酯(TAIC)方法，采用合适惰性载体增塑剂与TAIC共熔再用白碳黑吸附后，再熔造粒，制造出熔程温度55-65℃，有效物质的含量达到60％的贮存条件，配用安全方便，可以自动化配料的产品。
具体实施方式
实施例1：通用型颗粒化复配三聚异氰脲酸酯(TAIC)，配方如下(质量份)：三聚异氰脲酸酯(TAIC)60、聚酯增塑剂10、聚乙烯蜡15、白炭黑15。
制备流程：
1、三聚异氰脲酸酯(TAIC)60、增塑剂10、共熔，
2、用白碳黑吸附共熔物；
3、聚乙烯蜡和吸附料在55℃共混；
4、共混后的料在55℃挤出造粒。
实施例2：一种内脱模型颗粒化复配三聚异氰脲酸酯(TAIC)方法，配方如下(质量份)：三聚异氰脲酸酯(TAIC)40、聚乙烯蜡10；硬脂酸锌15、油酸丁酯25、白炭黑10；
制备流程：
1、三聚异氰脲酸酯(TAIC)、油酸丁酯共熔，
2、用白碳黑硬脂酸锌吸附共熔物；
3、聚乙烯蜡和吸附料在50-60℃共混；
4、共混后的料在50-60℃挤出造粒。
实施例3：一种助分散型颗粒化复配三聚异氰脲酸酯(TAIC)方法，配方如下(质量份)：三聚异氰脲酸酯(TAIC)40、聚乙烯蜡5；脂肪酰胺15、聚乙二醇4000 25、白炭黑15；
制备流程：
1、三聚异氰脲酸酯(TAIC)、聚乙二醇共熔，
2、用白碳黑吸附共熔物；
3、聚乙烯蜡脂肪酰胺和吸附料在40℃共混；
4、共混后的料在60℃挤出造粒。
实施例4：一种耐磨型颗粒化复配三聚异氰脲酸酯(TAIC)方法，配方如下(质量份)：三聚异氰脲酸酯(TAIC)40、聚乙烯蜡10；高分子硅酮40、白炭黑10；
实施例5：一种通用型颗粒化复配三聚异氰脲酸酯(TAIC)方法，配方如下(质量份)：三聚异氰脲酸酯(TAIC)50、己二酸乙二醇醚酯15、聚乙烯蜡15、白炭黑20、合计100
制备流程：
1、三聚异氰脲酸酯(TAIC)50、增塑剂15、共熔，
2、用白碳黑吸附共熔物；
3、聚乙烯蜡和吸附料在60℃共混；
4、共混后的料在40℃挤出造粒。

Claims (5)

1.一种颗粒化功能化复配三聚异氰脲酸酯(TAIC)，其特征是，质量份配方如下：三聚异氰脲酸酯(TAIC)60、增塑剂5-10、聚乙烯蜡10-19；白碳黑：5-25。
2.根据权利要求1所述的功能化复配三聚异氰脲酸酯(TAIC)，其特征是，另增加内脱模剂10-19、分散剂1-2；内脱模剂：脂肪酸盐、脂肪酸酯、脂肪酰胺或其混和物。
3.根据权利要求2所述的功能化复配三聚异氰脲酸酯(TAIC)，其特征是，所述分散剂0.5-3：采用聚乙二醇或和脂肪酰胺；聚乙烯蜡10-19、熔点60度左右。
4.根据权利要求1所述的功能化复配三聚异氰脲酸酯(TAIC)，其特征是，增塑剂5-15：聚酯增塑剂、乙二酸乙二醇醚酯。
5.根据权利要求1-4之一所述的功能化复配三聚异氰脲酸酯(TAIC)制备方法，其特征是，制备流程为：
1)三聚异氰脲酸酯(TAIC)60、增塑剂5-10、分散剂1份共熔；
2)用白碳黑吸附共熔物；
3)吸附料在40-60℃共混；
4)共混后的料在40-60℃挤出造粒。
CN201910235258.2A 2019-03-27 2019-03-27 一种颗粒化功能化复配三聚异氰脲酸酯与制备 Active CN110041591B (zh)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11130958A (ja) * 1997-10-30 1999-05-18 Nippon Miractran Kk 抗菌、防かび性に優れた熱可塑性ポリウレタン樹脂組成物。
CN102731893A (zh) * 2012-07-10 2012-10-17 西安汉华橡胶科技有限公司 一种低成本耐高温橡胶材料及其制备方法
CN104725733A (zh) * 2015-03-23 2015-06-24 常熟市中联光电新材料有限责任公司 辐照型cpe电缆护套料及其制备方法
CN108410073A (zh) * 2018-04-03 2018-08-17 山东华凌电缆有限公司 一种乙丙橡胶冷缩管及其制备方法
CN108586954A (zh) * 2018-05-15 2018-09-28 山东华凌电缆有限公司 一种无卤阻燃环保型乙丙橡胶冷缩管及其制备方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11130958A (ja) * 1997-10-30 1999-05-18 Nippon Miractran Kk 抗菌、防かび性に優れた熱可塑性ポリウレタン樹脂組成物。
CN102731893A (zh) * 2012-07-10 2012-10-17 西安汉华橡胶科技有限公司 一种低成本耐高温橡胶材料及其制备方法
CN104725733A (zh) * 2015-03-23 2015-06-24 常熟市中联光电新材料有限责任公司 辐照型cpe电缆护套料及其制备方法
CN108410073A (zh) * 2018-04-03 2018-08-17 山东华凌电缆有限公司 一种乙丙橡胶冷缩管及其制备方法
CN108586954A (zh) * 2018-05-15 2018-09-28 山东华凌电缆有限公司 一种无卤阻燃环保型乙丙橡胶冷缩管及其制备方法

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