CN110029043A - Raising kitchen garbage energy system based on fuel cell and alloy hydrogen storage technology - Google Patents
Raising kitchen garbage energy system based on fuel cell and alloy hydrogen storage technology Download PDFInfo
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- CN110029043A CN110029043A CN201910356670.XA CN201910356670A CN110029043A CN 110029043 A CN110029043 A CN 110029043A CN 201910356670 A CN201910356670 A CN 201910356670A CN 110029043 A CN110029043 A CN 110029043A
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
- C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
- C10L3/08—Production of synthetic natural gas
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B13/00—Recovery of fats, fatty oils or fatty acids from waste materials
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- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
- C12M21/00—Bioreactors or fermenters specially adapted for specific uses
- C12M21/04—Bioreactors or fermenters specially adapted for specific uses for producing gas, e.g. biogas
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- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
- C12M23/00—Constructional details, e.g. recesses, hinges
- C12M23/36—Means for collection or storage of gas; Gas holders
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- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
- C12M43/00—Combinations of bioreactors or fermenters with other apparatus
- C12M43/04—Bioreactors or fermenters combined with combustion devices or plants, e.g. for carbon dioxide removal
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- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
- C12M43/00—Combinations of bioreactors or fermenters with other apparatus
- C12M43/08—Bioreactors or fermenters combined with devices or plants for production of electricity
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- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
- C12M45/00—Means for pre-treatment of biological substances
- C12M45/02—Means for pre-treatment of biological substances by mechanical forces; Stirring; Trituration; Comminuting
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- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
- C12M47/00—Means for after-treatment of the produced biomass or of the fermentation or metabolic products, e.g. storage of biomass
- C12M47/18—Gas cleaning, e.g. scrubbers; Separation of different gases
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
- H01M8/04201—Reactant storage and supply, e.g. means for feeding, pipes
- H01M8/04216—Reactant storage and supply, e.g. means for feeding, pipes characterised by the choice for a specific material, e.g. carbon, hydride, absorbent
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
- H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
- H01M8/0618—Reforming processes, e.g. autothermal, partial oxidation or steam reforming
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0662—Treatment of gaseous reactants or gaseous residues, e.g. cleaning
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1007—Fuel cells with solid electrolytes with both reactants being gaseous or vaporised
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/74—Recovery of fats, fatty oils, fatty acids or other fatty substances, e.g. lanolin or waxes
Abstract
This application discloses a kind of raising kitchen garbage energy system based on fuel cell and alloy hydrogen storage technology, including the kitchen garbage processing integrated apparatus being connected and biodiesel pretreatment unit, homogeneous pond is connect with kitchen garbage processing integrated apparatus, anaerobic digestor is connect with homogeneous pond, separator is connect with anaerobic digestor, tank for sewage gas is connect with anaerobic digestor, desulfurization and decarburization device is connect with tank for sewage gas, reformer is connect with desulfurization and decarburization device, purifier apparatus is connect with reformer, hydrogen gas tank is connect with purifier apparatus, alloy hydrogen container is connect with hydrogen gas tank, fuel cell power generating system is connect with alloy hydrogen container, kitchen garbage recovery vehicle is connect with alloy hydrogen container, it is connect by alloy hydrogen container with hydrogen gas tank, high-purity hydrogen is stored in alloy hydrogen storag powder, fuel cell power generating system connect power generation with alloy hydrogen container , total energy approach is high-efficient, energy storage capacity is strong.
Description
Technical field
This application involves energy resource system technical fields, more particularly to the raising based on fuel cell and alloy hydrogen storage technology
Kitchen garbage energy system.
Background technique
Kitchen garbage contains large amount of organic, grease, nutrient, has very big recycle value.The following kitchen rubbish
Rubbish treatment plant is the high-quality factory of energy and substance recycling, and the development of Hydrogen Technology is a great contract of kitchen garbage processing
Machine.
It is grid-connected that the biogas that anaerobic digester system generates at present is mainly used for biogas dragging air blower, marsh gas power generation, natural gas
With the several ways such as methane boiler.Wherein, biogas dragging air blower is that the thermal energy of biogas fuel is converted into kinetic energy, simultaneously
Export waste heat；The thermal energy of biogas fuel is converted electric energy and thermal energy by marsh gas power generation；Natural gas is grid-connected be will be after purifying
Natural gas is incorporated to city planting ductwork, uses for production and living；Methane boiler is the biogas that directly burnt using boiler, exports thermal energy.On
It is lower to state biogas utilization mode total energy approach efficiency, and does not have energy storage capacity.
Summary of the invention
Aiming to overcome that the above problem or at least being partially solved or extenuate for the application solves the above problems.
According to the one aspect of the application, a kind of raising kitchen rubbish based on fuel cell and alloy hydrogen storage technology is provided
Rubbish energy system, comprising: kitchen garbage handles integrated apparatus, is used to generate waste oil and fluidised form rubbish；Biodiesel is pre-
Processing unit is connect with kitchen garbage processing integrated apparatus, raw for forming byproduct to the waste oil processing
Object diesel oil；Homogeneous pond is connect, for the fluidised form rubbish homogenization with kitchen garbage processing integrated apparatus；
Anaerobic digestor is connect with the homogeneous pond, generates biogas residue and biogas for carrying out anaerobic reaction to the fluidised form rubbish；Point
It from device, is connect with the anaerobic digestor, generates compost and sewage for separating the biogas residue；Tank for sewage gas, and it is described
Anaerobic digestor connection, for storing the biogas；Desulfurization and decarburization device is connect with the tank for sewage gas, for the natural pond
Gas carries out desulfurization and decarburization processing purification process and forms natural gas；Reformer is connect with the desulfurization and decarburization device, for the
A part of gas renormalizing reaction generates hydrogen and carbon monoxide；Purifier apparatus is connect with the reformer, for pair
The hydrogen filtration purification obtains high-purity hydrogen；Hydrogen gas tank is connect with the purifier apparatus, for storing the High Purity Hydrogen
Gas；Alloy hydrogen container is connect with the hydrogen gas tank, for the high-purity hydrogen to be stored in the alloy hydrogen storag powder；Combustion
Expect power plant, is connect with the alloy hydrogen container, for generating electricity；Kitchen garbage recovery vehicle is stored up with the alloy
Hydrogen tank connection, for transporting the high-purity hydrogen.
In one embodiment, further includes: boiler is used with the desulfurization and decarburization device by the 14th piping connection
The combustion of natural gas described in another part generates thermal energy；Wherein, the boiler is also connected with the reformer by the 15th pipeline
It connects, enters the reformer for thermal energy described in first part, the temperature of thermal energy described in first part is 300 DEG C -800 DEG C.
In one embodiment, the boiler is used for second also with the alloy hydrogen container by the 16th piping connection
The part thermal energy enters the alloy hydrogen container and discharges hydrogen, and the temperature of thermal energy described in second part is 50 DEG C -60 DEG C.
In one embodiment, the boiler also handles integrated apparatus and the anaerobic digestor with the kitchen garbage
By the 13rd piping connection, enters kitchen garbage processing integrated apparatus for thermal energy described in Part III and described detest
Oxygen digester, the temperature of thermal energy described in Part III are 30 DEG C -50 DEG C.
In one embodiment, the biodiesel pretreatment unit passes through with kitchen garbage processing integrated apparatus
First piping connection；The homogeneous pond and kitchen garbage processing integrated apparatus pass through the second piping connection；The anaerobism
Digester and the homogeneous pond pass through third piping connection；The separator and the anaerobic digestor are connected by the 4th pipeline
It connects；The tank for sewage gas and the anaerobic digestor pass through the 5th piping connection；The desulfurization and decarburization device and the tank for sewage gas are logical
Cross the 6th piping connection；The reformer and the desulfurization and decarburization device pass through the 7th piping connection；The purifier apparatus and institute
It states reformer and passes through the 8th piping connection；The hydrogen gas tank and the purifier apparatus pass through the 9th piping connection；The alloy storage
Hydrogen tank and the hydrogen gas tank pass through the tenth piping connection；The fuel cell power generating system and the alloy hydrogen container pass through the tenth
One piping connection；The kitchen garbage recovery vehicle and the alloy hydrogen container pass through the 12nd piping connection.
In one embodiment, beater is installed in second pipeline, the first pump is installed in the third pipeline,
In the second pump of the 4th pipeline installation.
The raising kitchen garbage energy system based on fuel cell and alloy hydrogen storage technology of the application, passes through alloy hydrogen storage
Tank is connect with hydrogen gas tank, high-purity hydrogen is stored in alloy hydrogen storag powder, fuel cell power generating system is connect with alloy hydrogen container
Power generation, kitchen garbage recovery vehicle are connect with alloy hydrogen container, transport high-purity hydrogen.Generating efficiency is high: comparing marsh gas power generation efficiency
About 30%, the generating efficiency of fuel cell power generating system can be improved one times up to 60%.Based on fuel cell power generating system and conjunction
The kitchen garbage energy system of golden hydrogen container technology have the electric energy that total energy approach is high-efficient, energy storage capacity is strong, generates and
Thermal energy proportion adjustment is flexible, is the ideal style for realizing that kitchen garbage treatment plant energy-autarchic is self-sustaining.
According to the accompanying drawings to the detailed description of the specific embodiment of the application, those skilled in the art will be more
Above-mentioned and other purposes, the advantages and features of the application are illustrated.
Detailed description of the invention
Some specific embodiments of the application are described in detail by way of example and not limitation with reference to the accompanying drawings hereinafter.
Identical appended drawing reference denotes same or similar part or part in attached drawing.It should be appreciated by those skilled in the art that these
What attached drawing was not necessarily drawn to scale.In attached drawing:
Fig. 1 is the raising kitchen garbage energy based on fuel cell and alloy hydrogen storage technology according to the application one embodiment
The schematic block diagram of amount system.
Marked in the figure:
1, kitchen garbage handles integrated apparatus；2, biodiesel pretreatment unit；3, beater；4, homogeneous pond；5,
One pump；6, anaerobic digestor；7, the second pump；8, tank for sewage gas；9, desulfurization and decarburization device；10, reformer；11, purifier apparatus；12,
Hydrogen gas tank；13, alloy hydrogen container；14, fuel cell power generating system；15, kitchen garbage recovery vehicle；16, boiler；17, separation dress
It sets；18, the second pipeline；19, third pipeline；20, the 4th pipeline；21, the 5th pipeline；22, the 6th pipeline；23, the 7th pipeline；
24, the 8th pipeline；25, the 9th pipeline；26, the tenth pipeline；27, the 11st pipeline；28, the 12nd pipeline；29, the 13rd pipe
Road；30, the 15th pipeline；31, the 14th pipeline；32, the 16th pipeline；33, the first pipeline.
Specific embodiment
Fig. 1 is the raising kitchen garbage energy based on fuel cell and alloy hydrogen storage technology according to the application one embodiment
The schematic block diagram of amount system.Raising kitchen garbage energy system based on fuel cell and alloy hydrogen storage technology generally may be used
Integrated apparatus 1, biodiesel pretreatment unit 2, homogeneous pond 4, anaerobic digestor 6, separator are handled including kitchen garbage
17, tank for sewage gas 8, desulfurization and decarburization device 9, reformer 10, purifier apparatus 11, hydrogen gas tank 12, alloy hydrogen container 13, fuel cell hair
Electric installation 14 and kitchen garbage recovery vehicle 15.Wherein, kitchen garbage processing integrated apparatus 1 is for generating waste oil and fluidised form rubbish
Rubbish.Biodiesel pretreatment unit 2 is connect with kitchen garbage processing integrated apparatus 1, for forming by-product to waste oil processing
Product biodiesel.Homogeneous pond 4 is connect with kitchen garbage processing integrated apparatus 1, for fluidised form rubbish homogenization.Anaerobism disappears
Change tank 6 to connect with homogeneous pond 4, generates biogas residue and biogas for carrying out anaerobic reaction to fluidised form rubbish.Separator 17 and anaerobism
Digester 6 connects, and generates compost and sewage for separating biogas residue.Tank for sewage gas 8 is connect with anaerobic digestor 6, for storing biogas.
Desulfurization and decarburization device 9 is connect with tank for sewage gas 8, forms natural gas for carrying out desulfurization and decarburization processing purification process to biogas.It reforms
Device 10 is connect with desulfurization and decarburization device 9, generates hydrogen and carbon monoxide for reacting a part of gas renormalizing.Purifier apparatus
11 connect with reformer 10, obtain high-purity hydrogen for purifying to hydrogen filtration.Hydrogen gas tank 12 is connect with purifier apparatus 11, is used for
Store high-purity hydrogen.Alloy hydrogen container 13 is connect with hydrogen gas tank 12, for high-purity hydrogen to be stored in the alloy hydrogen storag powder.
Fuel cell power generating system 14 is connect with alloy hydrogen container 13, for generating electricity.Kitchen garbage recovery vehicle 15 and alloy hydrogen container 13
Connection, for transporting high-purity hydrogen.Wherein, kitchen garbage processing integrated apparatus 1 is the processing integration of existing kitchen garbage
Device, for details, reference can be made to Chinese patents: ZL201220434731.3.
The raising kitchen garbage energy system based on fuel cell and alloy hydrogen storage technology of the application, passes through alloy hydrogen storage
Tank 13 is connect with hydrogen gas tank 12, and high-purity hydrogen is stored in alloy hydrogen storag powder, fuel cell power generating system 14 and alloy hydrogen storage
The connection power generation of tank 13, kitchen garbage recovery vehicle 15 are connect with alloy hydrogen container 13, transport high-purity hydrogen.Generating efficiency is high: comparing
Marsh gas power generation efficiency about 30%, the generating efficiency of fuel cell power generating system 14 can be improved one times up to 60%.Based on fuel electricity
The kitchen garbage energy system of 13 technology of pond power generator 14 and alloy hydrogen container high-efficient, energy storage energy with total energy approach
The electric energy and thermal energy proportion adjustment that power is strong, generates are flexible, are the ideal styles for realizing that kitchen garbage treatment plant energy-autarchic is self-sustaining.
As shown in Figure 1, further including boiler 16 in embodiment, boiler 16 and desulfurization and decarburization device 9 pass through the 14th pipeline
31 connections generate thermal energy for another part combustion of natural gas.Boiler 16 is also connect with reformer 10 by the 15th pipeline 30,
The connection type can be welding or threaded connection, firm and durable.First part's thermal energy enters the reformer 10, with heat supply
Can, it improves and generation hydrogen and carbon monoxide efficiency is reacted to gas renormalizing.Optionally, the temperature of first part's thermal energy is 300
DEG C -800 DEG C, optimum temperature is 550 DEG C, promotes reforming reaction.
As shown in Figure 1, in embodiment, boiler 16 is also connect with alloy hydrogen container 13 by the 16th pipeline 32, the company
The mode of connecing can be welding or threaded connection, firm and durable.Second part thermal energy enters the alloy hydrogen container 13 and discharges hydrogen,
High-purity hydrogen is stored in alloy hydrogen storag powder for 13 heat supply of alloy hydrogen container.Optionally, the temperature of second part thermal energy is
50 DEG C -60 DEG C, promote hydrogen storage.
As shown in Figure 1, in embodiment, boiler 16 also handles integrated apparatus 1 with kitchen garbage and anaerobic digestor 6 is logical
The connection of the 13rd pipeline 29 is crossed, which can be welding or threaded connection, firm and durable.For Part III thermal energy into
Enter the kitchen garbage processing integrated apparatus 1 and anaerobic digestor 6.Optionally, the temperature of Part III thermal energy is 30 DEG C -50
DEG C, optimum temperature is 40 DEG C, and kitchen garbage processing integrated apparatus 1 is promoted to generate waste oil fluidised form rubbish and promote anaerobic reaction
It generates.
As shown in Figure 1, in embodiment, biodiesel pretreatment unit 2 passes through with kitchen garbage processing integrated apparatus 1
The connection of first pipeline 33, the connection type can be welding or threaded connection, firm and durable.Homogeneous pond 4 and kitchen garbage are handled
Integrated apparatus 1 is connected by the second pipeline 18, which can be welding or threaded connection, firm and durable.Anaerobism disappears
Change tank 6 and connect with homogeneous pond 4 by third pipeline 19, which can be welding or threaded connection, firm and durable.Separation
Device 17 is connect with anaerobic digestor 6 by the 4th pipeline 20, which can be welding or threaded connection, securely resistance to
With.Tank for sewage gas 8 is connect with anaerobic digestor 6 by the 5th pipeline 21, which can be welding or threaded connection, securely
It is durable.Desulfurization and decarburization device 9 is connect with tank for sewage gas 8 by the 6th pipeline 22, which can be welding or threaded connection,
Firm and durable.Reformer 10 is connect with desulfurization and decarburization device 9 by the 7th pipeline 23, which can be welding or screw thread
Connection, firm and durable.Purifier apparatus 11 is connect with reformer 10 by the 8th pipeline 24, which can be welding or spiral shell
Line connection, firm and durable.Hydrogen gas tank 12 and purifier apparatus 11 connects by the 9th pipeline 25, the connection type can be weld or
It is threadedly coupled, firm and durable.Alloy hydrogen container 13 is connect with hydrogen gas tank 12 by the tenth pipeline 26, which can be weldering
It connects or is threadedly coupled, firm and durable.Fuel cell power generating system 14 is connect with alloy hydrogen container 13 by the 11st pipeline 27, should
Connection type can be welding or threaded connection, firm and durable.Kitchen garbage recovery vehicle 15 and alloy hydrogen container 13 pass through the tenth
The connection of two pipelines 28, the connection type can be welding or threaded connection, firm and durable.
As shown in Figure 1, in embodiment, beater 3 is equipped in the second pipeline 18, for being beaten, in third pipeline 19
First pump 5 is installed, for conveying the fluidised form rubbish after homogenization, in the second pump 7 of the 4th pipeline 20 installation, for conveying life
Biogas residue and biogas.Specification is needed, the first pump 5 and the second pump 7 are existing pump.
As shown in Figure 1, in embodiment, by taking day handles 200 tons of kitchen garbage treatment plant as an example, kitchen garbage system is natural
Gas and natural gas are as follows for thermal sub-system process flow: by kitchen garbage processing integrated apparatus 1, (feed is broken kitchen garbage
Bag, magnetic separation, sorting, slurrying, three phase separation, water-oil separating, heating) etc. preprocessing process, wherein separate oil by into
The processing of one step is changed into biodiesel, other process products are delivered to homogeneous pond 4 by beater 3 and are stirred and filter.So
After send to anaerobic digestor 6 generate biogas, about 14000m3.By 9 desulfurization of desulfurization and decarburization device, decarburization, purification, pressurization conversion
For natural gas, about 9600m3.Wherein about 2400m3 is used for fuel, provides high-quality heat, waste heat for hydrogen making by natural gas reformation
It can be also used for being crushed/pretreatment units and the alloy hydrogen container release hydrogen such as magnetic separation/slurrying/separation.
Natural gas hydrogen preparation and energy storing and electricity generating subsystem process flow are as follows: remaining about 7200m3 natural gas turns by steam
The process changeovers such as change, CO transformation, hydrogen purification are high-purity hydrogen, about 22000m3；There are two types of usages for hydrogen obtained；
First, it is used directly for the kitchen garbage recycling of the power generation of fuel cell power generating system 14, assembly High Pressure Hydrogen gas cylinder
The driving of vehicle 15, hydrogenation stations sell hydrogen.According to the heat balance of restaurant garbage treating system, producing 22000m3 daily is about 2000kg
Hydrogen in need about 1000kg for fuel cell power generating system 14 generate electricity, generate waste heat can meet kitchen garbage processing
The needs of system.This can support 14 power generator of fuel cell power generating system of 750kW to generate electricity for 24 hours daily for hydrogen amount, day power generation
Measure about 18MWh.Remaining hydrogen can meet the consumption hydrogen demand of a 1000kg grades of hydrogenation stations, can be 150 hydrogen fuel public transport
Vehicle/kitchen garbage recovery vehicle or 1800 hydrogen fuel cell cars provide hydrogen supply.All hydrogen are such as produced daily to be used to generate electricity,
The fuel cell power generating system 14 of about 1.5MW can be supported to generate electricity, daily generation about 36MWh, day is for waste heat about 54000MJ (with about
The form of 70 DEG C of warm water).
Second, hydrogen energy storage can be got up by alloy hydrogen container 13, then be used for fuel cell power generation as needed
The power generation of device 14 and kitchen garbage recovery vehicle 15 drive, and can also be sold in the form of hydrogen.
When specifically used:
First kitchen garbage processing integrated apparatus 1 be crushed, magnetic separation, slurrying and separation, generate waste oil and fluidised form
Rubbish；Wherein waste oil is further processed in biodiesel pretreatment unit 2 generates byproduct biodiesel.Fluidised form rubbish benefit
Homogeneous pond 4 is delivered to beater 3 and carries out homogeneous, caching and water quality adjustment, then fluidised form rubbish is transported to by the first pump 5 and is detested
Oxygen digester 6 carries out anaerobic reaction and generates biogas residue and biogas.Wherein biogas residue is transported to biogas residue liquid bath and separation dress by the second pump 7
17 generation compost and sewage are set, then the biogas storage of generation carries out desulfurization by desulfurization and decarburization device 9 and take off in tank for sewage gas 8
The purifying process such as carbon are changed into natural gas.Natural gas is divided into two parts, and a part passes through the reaction of reformer 10 together with vapor and produces
The gases such as raw hydrogen, carbon monoxide, are filtered purification by purification devices 11, the high-purity hydrogen of acquisition is stored in hydrogen container 12
In.According to specific needs, high-purity hydrogen obtained is used directly for the power generation of fuel cell power generating system 14, kitchen garbage recycling
Vehicle 15 is flushed with hydrogen and externally provides, and hydrogen storage can also be used for energy storage in hydrogen storing alloy powder by alloy hydrogen container 13, then
According to specific needs, alloy hydrogen container 13 absorbs heat, and dehydrogenation is directly used in the power generation of fuel cell power generating system 14, kitchen garbage recycles
Vehicle 15 is flushed with hydrogen and externally provides.
The purifying process such as desulfurization and decarburization, which are carried out, by desulfurization and decarburization device 9 is changed into another part of natural gas in boiler
Burning generates thermal energy in 16, these high-quality heat energies are first used for reformer 10, generally require and be heated to 300 DEG C~800 DEG C.Then
It is used to kitchen garbage processing integrated apparatus 1 together with the waste heat of fuel cell power generating system 14 to heat, generally requires and is heated to
90 DEG C or so.Hydrogen subsequently is discharged for alloy hydrogen container 13, generally requires and is heated to 50 DEG C~60 DEG C.It is eventually used for anaerobism
Digester 6 generally requires and is heated to 30 DEG C~50 DEG C.
The method of raising kitchen garbage capacity usage ratio based on fuel cell and alloy hydrogen storage technology has energy synthesis
The electric energy and thermal energy proportion adjustment that utilization efficiency is high, energy storage capacity is strong, generates are flexible, are to realize kitchen garbage treatment plant energy certainly
To self-sustaining ideal style.
It should be noted that unless otherwise indicated, technical term or scientific term used in this application should be this Shen
It please the ordinary meaning that is understood of one of ordinary skill in the art.
In the description of the present application, it is to be understood that term " center ", " longitudinal direction ", " transverse direction ", " length ", " width ",
" thickness ", "upper", "lower", "front", "rear", "left", "right", "vertical", "horizontal", "top", "bottom" "inner", "outside", " up time
The orientation or positional relationship of the instructions such as needle ", " counterclockwise ", " axial direction ", " radial direction ", " circumferential direction " be orientation based on the figure or
Positional relationship is merely for convenience of description the application and simplifies description, rather than the device or element of indication or suggestion meaning must
There must be specific orientation, be constructed and operated in a specific orientation, therefore should not be understood as the limitation to the application.
In addition, term " first ", " second " etc. are used for description purposes only, it is not understood to indicate or imply relatively important
Property or implicitly indicate the quantity of indicated technical characteristic.In the description of the present application, the meaning of " plurality " is two or more,
Unless otherwise specifically defined.
In this application unless specifically defined or limited otherwise, term " installation ", " connected ", " connection ", " fixation " etc.
Term shall be understood in a broad sense, for example, it may be being fixedly connected, may be a detachable connection, or integral；It can be mechanical connect
It connects, is also possible to be electrically connected；It can be directly connected, can also can be in two elements indirectly connected through an intermediary
The interaction relationship of the connection in portion or two elements.It for the ordinary skill in the art, can be according to specific feelings
Condition understands the concrete meaning of above-mentioned term in this application.
In this application unless specifically defined or limited otherwise, fisrt feature in the second feature " on " or " down " can be with
It is that the first and second features directly contact or the first and second features pass through intermediary mediate contact.Moreover, fisrt feature exists
Second feature " on ", " top " and " above " but fisrt feature be directly above or diagonally above the second feature, or be merely representative of
First feature horizontal height is higher than second feature.Fisrt feature can be under the second feature " below ", " below " and " below "
One feature is directly under or diagonally below the second feature, or is merely representative of first feature horizontal height less than second feature.
The preferable specific embodiment of the above, only the application, but the protection scope of the application is not limited thereto,
Within the technical scope of the present application, any changes or substitutions that can be easily thought of by anyone skilled in the art,
Should all it cover within the scope of protection of this application.Therefore, the protection scope of the application should be with scope of protection of the claims
Subject to.
Claims (6)
1. a kind of raising kitchen garbage energy system based on fuel cell and alloy hydrogen storage technology, comprising:
Kitchen garbage handles integrated apparatus (1), is used to generate waste oil and fluidised form rubbish；
Biodiesel pretreatment unit (2) is connect with kitchen garbage processing integrated apparatus (1), for described useless
Grease processing forms byproduct biodiesel；
Homogeneous pond (4) is connect with kitchen garbage processing integrated apparatus (1), to the fluidised form rubbish homogeneous
Reason；
Anaerobic digestor (6) is connect with the homogeneous pond (4), generates natural pond for carrying out anaerobic reaction to the fluidised form rubbish
Slag and biogas；
Separator (17) is connect with the anaerobic digestor (6), generates compost and sewage for separating the biogas residue；
Tank for sewage gas (8) is connect, for storing the biogas with the anaerobic digestor (6)；
Desulfurization and decarburization device (9) is connect with the tank for sewage gas (8), for carrying out desulfurization and decarburization processing purifying to the biogas
Processing forms natural gas；
Reformer (10) is connect with the desulfurization and decarburization device (9), for generating to a part of gas renormalizing reaction
Hydrogen and carbon monoxide；
Purifier apparatus (11) is connect with the reformer (10), obtains high-purity hydrogen for purifying to the hydrogen filtration；
Hydrogen gas tank (12) is connect, for storing the high-purity hydrogen with the purifier apparatus (11)；
Alloy hydrogen container (13) is connect with the hydrogen gas tank (12), is stored up for the high-purity hydrogen to be stored in the alloy
In hydrogen powder；
Fuel cell power generating system (14) is connect, for generating electricity with the alloy hydrogen container (13)；
Kitchen garbage recovery vehicle (15) is connect, for transporting the high-purity hydrogen with the alloy hydrogen container (13).
2. the raising kitchen garbage energy system according to claim 1 based on fuel cell and alloy hydrogen storage technology,
It is characterized in that, further includes:
Boiler (16) is connect, for day described in another part by the 14th pipeline (31) with the desulfurization and decarburization device (9)
Right gas burning generates thermal energy；
Wherein, the boiler (16) is also connect with the reformer (10) by the 15th pipeline (30), is used for institute, first part
It states thermal energy and enters the reformer (10), the temperature of thermal energy described in first part is 300 DEG C -800 DEG C.
3. the raising kitchen garbage energy system according to claim 2 based on fuel cell and alloy hydrogen storage technology,
It is characterized in that:
The boiler (16) is also connect with the alloy hydrogen container (13) by the 16th pipeline (32), for described in second part
Thermal energy enters the alloy hydrogen container (13) and discharges hydrogen, and the temperature of thermal energy described in second part is 50 DEG C -60 DEG C.
4. the raising kitchen garbage energy system according to claim 2 based on fuel cell and alloy hydrogen storage technology,
It is characterized in that:
The boiler (16) also passes through the tenth with kitchen garbage processing integrated apparatus (1) and the anaerobic digestor (6)
Three pipelines (29) connection enters kitchen garbage processing integrated apparatus (1) for thermal energy described in Part III and described detests
Oxygen digester (6), the temperature of thermal energy described in Part III are 30 DEG C -50 DEG C.
5. the raising kitchen garbage energy system according to claim 1 based on fuel cell and alloy hydrogen storage technology,
It is characterized in that:
The biodiesel pretreatment unit (2) and kitchen garbage processing integrated apparatus (1) pass through the first pipeline (33)
Connection；
The homogeneous pond (4) is connect with kitchen garbage processing integrated apparatus (1) by the second pipeline (18)；
The anaerobic digestor (6) is connect with the homogeneous pond (4) by third pipeline (19)；
The separator (17) is connect with the anaerobic digestor (6) by the 4th pipeline (20)；
The tank for sewage gas (8) is connect with the anaerobic digestor (6) by the 5th pipeline (21)；
The desulfurization and decarburization device (9) is connect with the tank for sewage gas (8) by the 6th pipeline (22)；
The reformer (10) is connect with the desulfurization and decarburization device (9) by the 7th pipeline (23)；
The purifier apparatus (11) is connect with the reformer (10) by the 8th pipeline (24)；
The hydrogen gas tank (12) is connect with the purifier apparatus (11) by the 9th pipeline (25)；
The alloy hydrogen container (13) is connect with the hydrogen gas tank (12) by the tenth pipeline (26)；
The fuel cell power generating system (14) is connect with the alloy hydrogen container (13) by the 11st pipeline (27)；
The kitchen garbage recovery vehicle (15) is connect with the alloy hydrogen container (13) by the 12nd pipeline (28).
6. the raising kitchen garbage energy system according to claim 1 based on fuel cell and alloy hydrogen storage technology,
It is characterized in that:
Beater (3) are installed in second pipeline (18), the first pump (5) are installed in the third pipeline (19), in institute
State the second pump (7) of the 4th pipeline (20) installation.
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