CN108658361A - The integrated livestock and poultry cultivating system of biomass cogeneration of heat and power - Google Patents
The integrated livestock and poultry cultivating system of biomass cogeneration of heat and power Download PDFInfo
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- CN108658361A CN108658361A CN201710207418.3A CN201710207418A CN108658361A CN 108658361 A CN108658361 A CN 108658361A CN 201710207418 A CN201710207418 A CN 201710207418A CN 108658361 A CN108658361 A CN 108658361A
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- Prior art keywords
- methanol
- marsh gas
- pool
- biogas
- gas fermentation
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- 244000144977 poultry Species 0.000 title claims abstract description 42
- 244000144972 livestock Species 0.000 title claims abstract description 40
- 239000002028 Biomass Substances 0.000 title claims abstract description 28
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 202
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 198
- 238000000855 fermentation Methods 0.000 claims abstract description 91
- 230000004151 fermentation Effects 0.000 claims abstract description 87
- 239000001257 hydrogen Substances 0.000 claims abstract description 56
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 56
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 55
- 239000002002 slurry Substances 0.000 claims abstract description 54
- 238000004519 manufacturing process Methods 0.000 claims abstract description 45
- 238000010438 heat treatment Methods 0.000 claims abstract description 44
- GBMDVOWEEQVZKZ-UHFFFAOYSA-N methanol;hydrate Chemical compound O.OC GBMDVOWEEQVZKZ-UHFFFAOYSA-N 0.000 claims abstract description 32
- 238000012545 processing Methods 0.000 claims abstract description 23
- 239000000446 fuel Substances 0.000 claims abstract description 16
- 210000003608 fece Anatomy 0.000 claims abstract description 14
- 238000009395 breeding Methods 0.000 claims abstract description 11
- 230000001488 breeding effect Effects 0.000 claims abstract description 11
- 238000000605 extraction Methods 0.000 claims abstract description 11
- 239000007788 liquid Substances 0.000 claims description 70
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 49
- 239000007789 gas Substances 0.000 claims description 36
- 239000000243 solution Substances 0.000 claims description 28
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 24
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 22
- 238000000926 separation method Methods 0.000 claims description 18
- 238000010521 absorption reaction Methods 0.000 claims description 16
- 230000001105 regulatory effect Effects 0.000 claims description 16
- 239000007864 aqueous solution Substances 0.000 claims description 15
- 229910021529 ammonia Inorganic materials 0.000 claims description 12
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 11
- 239000001569 carbon dioxide Substances 0.000 claims description 11
- 239000012528 membrane Substances 0.000 claims description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
- 239000010865 sewage Substances 0.000 claims description 9
- 239000007858 starting material Substances 0.000 claims description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 8
- 239000001301 oxygen Substances 0.000 claims description 8
- 229910052760 oxygen Inorganic materials 0.000 claims description 8
- 239000011229 interlayer Substances 0.000 claims description 6
- 238000011010 flushing procedure Methods 0.000 claims description 5
- 210000002700 urine Anatomy 0.000 claims description 5
- 230000003009 desulfurizing effect Effects 0.000 claims description 4
- 238000004080 punching Methods 0.000 claims description 4
- 238000004062 sedimentation Methods 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- 238000012546 transfer Methods 0.000 claims description 3
- 238000004140 cleaning Methods 0.000 claims description 2
- 238000001816 cooling Methods 0.000 claims description 2
- 230000001476 alcoholic effect Effects 0.000 claims 1
- 238000005374 membrane filtration Methods 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 abstract description 23
- 239000010828 animal waste Substances 0.000 abstract description 12
- 238000000034 method Methods 0.000 abstract description 8
- 230000005611 electricity Effects 0.000 description 10
- 230000008569 process Effects 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 238000004064 recycling Methods 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- 238000004364 calculation method Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 238000009434 installation Methods 0.000 description 2
- 239000013067 intermediate product Substances 0.000 description 2
- 239000003895 organic fertilizer Substances 0.000 description 2
- 238000010248 power generation Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 238000009360 aquaculture Methods 0.000 description 1
- 244000144974 aquaculture Species 0.000 description 1
- 238000013475 authorization Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000002921 fermentation waste Substances 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000002737 fuel gas Substances 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000003808 methanol extraction Methods 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000009897 systematic effect Effects 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01K—ANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
- A01K1/00—Housing animals; Equipment therefor
- A01K1/0047—Air-conditioning, e.g. ventilation, of animal housings
- A01K1/0076—Arrangement of heaters or heat exchangers
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01K—ANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
- A01K1/00—Housing animals; Equipment therefor
- A01K1/0047—Air-conditioning, e.g. ventilation, of animal housings
- A01K1/0082—Water misting or cooling systems
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01K—ANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
- A01K1/00—Housing animals; Equipment therefor
- A01K1/01—Removal of dung or urine, e.g. from stables
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01K—ANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
- A01K1/00—Housing animals; Equipment therefor
- A01K1/02—Pigsties; Dog-kennels; Rabbit-hutches or the like
- A01K1/03—Housing for domestic or laboratory animals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01K—ANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
- A01K31/00—Housing birds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01K—ANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
- A01K31/00—Housing birds
- A01K31/04—Dropping-boards; Devices for removing excrement
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
- C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
- C10L3/10—Working-up natural gas or synthetic natural gas
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
- C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
- C10L3/10—Working-up natural gas or synthetic natural gas
- C10L3/101—Removal of contaminants
- C10L3/102—Removal of contaminants of acid contaminants
- C10L3/103—Sulfur containing contaminants
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
- C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
- C10L3/10—Working-up natural gas or synthetic natural gas
- C10L3/101—Removal of contaminants
- C10L3/102—Removal of contaminants of acid contaminants
- C10L3/104—Carbon dioxide
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
- C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
- C10L3/10—Working-up natural gas or synthetic natural gas
- C10L3/101—Removal of contaminants
- C10L3/105—Removal of contaminants of nitrogen
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
- H01M8/04089—Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
- H01M8/04097—Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants with recycling of the reactants
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F2001/007—Processes including a sedimentation step
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/20—Nature of the water, waste water, sewage or sludge to be treated from animal husbandry
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/28—Anaerobic digestion processes
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/20—Capture or disposal of greenhouse gases of methane
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Environmental Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Zoology (AREA)
- Animal Husbandry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Biodiversity & Conservation Biology (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Sustainable Development (AREA)
- Birds (AREA)
- Animal Behavior & Ethology (AREA)
- Health & Medical Sciences (AREA)
- Clinical Laboratory Science (AREA)
- General Health & Medical Sciences (AREA)
- Sustainable Energy (AREA)
- Manufacturing & Machinery (AREA)
- Water Supply & Treatment (AREA)
- Environmental & Geological Engineering (AREA)
- Hydrology & Water Resources (AREA)
- Electrochemistry (AREA)
- Processing Of Solid Wastes (AREA)
- Treatment Of Sludge (AREA)
Abstract
The present invention relates to cultivation and technical field of resource comprehensive utilization, more particularly to the integrated livestock and poultry cultivating system of biomass cogeneration of heat and power, including breeding room, it is provided with heating device, refrigerating plant, flusher, lighting device and collecting dung pond in breeding room, further includes excrement preparing pool, detention tank, the first marsh gas fermentation pool, the second marsh gas fermentation pool, methane extraction element, methanol solution synthesizer, biogas slurry and biogas residue processing unit, methanol-water hydrogen manufacturing reformer, fuel cell and control device.The present invention generates thermal energy and electric energy using animal waste conversion, realize the intelligentized control method of whole system, so that biomass energy is efficiently converted and is comprehensively utilized, form the livestock and poultry cultivation system of ecological integrated, with wide commercial application foreground.
Description
Technical field
The present invention relates to cultivation and technical field of resource comprehensive utilization, and in particular to a kind of one of biomass cogeneration of heat and power
Change livestock and poultry cultivation system.
Background technology
Environmental pollution and energy shortage are global two principal themes, develop environmental improvement and the regenerative resource life of green
The technology of production is extremely urgent.According to statistics, the animal waste that China's scale animal and poultry cultivation generates every year（Excrement）It reaches
To about 3,800,000,000 tons, if being fully converted into biogas is equivalent to 1.62 hundred million tons of standard coals, and wherein only has about 15% and be equipped with biogas engineering
Processing equipment.Feces of livestock and poultry has become one of major source of agricultural non-point source pollution, and a large amount of feces of livestock and poultry is unprocessed, without authorization
Discharge, serious to polluted living environment and underground water source, waste, the pollution of foul smell are sustainable to agricultural, the health of aquaculture
Development causes grave danger.However, animal waste can both become pollution sources, it is also possible to become good biomass energy.
In the prior art, biomass producing methane has been popularized for many years.In order to efficiently use the animal dung generated in livestock and poultry cultivation
Just, some areas start with feces of livestock and poultry manufacture biogas.Biogas be organic substance under anaerobic, by the hair of microorganism
Ferment acts on and a kind of fuel gas of generation.But the method that excrement is handled during existing livestock and poultry cultivation, it is existing main
Problem is：（1）Feces of livestock and poultry does not make full use of, converts, and the processing method of feces of livestock and poultry is single, without integrated treatment,
Treatment effeciency is low, and occupation area of equipment is big, runs, maintenance cost height, influences large-scale promotion use；（2）Utilize livestock and poultry
Biogas prepared by excrement, which is transported and efficiently used in storage, annoyings always people.On the one hand, biogas contains hydrogen sulfide, an oxygen
Change the toxic gases such as carbon, also contains there are many miscellaneous gas, foul smell, easy firing explodes；On the other hand, people utilize master to biogas at present
If directly make its burn by way of obtain energy, such as cooked using biogas, heating, illumination, the energy of this mode
Utilization rate is relatively low；It is generated electricity using biogas in addition, the prior art also has, but existing methane power generating system is fired by biogas
The mode of burning carries out heat energy power-generating, i.e., is first converted into mechanical energy from thermal energy, then be converted into electric energy, secondary conversion efficiency from mechanical energy
It is too low, therefore fail to be used widely.
Therefore, it develops efficient animal waste processing and comprehensive utilization of resources new technology is imperative.
Invention content
For the prior art, there are above-mentioned technical problems, and the purpose of the present invention is to provide a kind of biomass cogenerations of heat and power
Integrated livestock and poultry cultivating system, the livestock and poultry cultivation system realize biomass and thermal energy on the spot using the animal waste of itself
With the Efficient Conversion of electric energy, recycle and automation control, and biogas need not be stored as intermediate product, transport and
Burning, has the advantages that safe, energy saving and environmentally friendly.
To achieve the above object, the present invention provides following technical scheme：
The integrated livestock and poultry cultivating system of biomass cogeneration of heat and power is provided, including breeding room, be provided in breeding room heating device,
Refrigerating plant, flusher, lighting device and collecting dung pond further include excrement preparing pool, detention tank, the first biogas hair
Ferment pond, the second marsh gas fermentation pool, methane extraction element, methanol solution synthesizer, biogas slurry and biogas residue processing unit, methanol-water hydrogen manufacturing
Reformer, fuel cell and control device, the methanol-water hydrogen manufacturing reformer include reformer chamber, separation chamber and are carried for reformer chamber
The electric heater of required temperature is reacted for reformation hydrogen production, the control device includes controller and the electricity for exporting electric energy outward
Power output port, wherein：
The excrement that collecting dung pond is collected is delivered to excrement preparing pool, the sewage such as the livestock and poultry urine generated in breeding room and flushing water
By pipeline to detention tank, the dope outlet of the detention tank is connected to the excrement preparing pool, the dirt
The purified liquor outlet in water sedimentation pond is connected to the first marsh gas fermentation pool, and the excrement preparing pool passes through the first delivery pump and described second
Marsh gas fermentation pool is connected to, the methane outlet of first marsh gas fermentation pool and the second marsh gas fermentation pool by first pipe successively with
Methane extraction element, the connection of methanol solution synthesizer, the liquid outlet of the methanol solution synthesizer pass through the second delivery pump
It is connect with the methanol-water hydrogen manufacturing reformer；The methanol aqueous solution prepared by the methanol solution synthesizer is in the methanol-water
It is reacted in hydrogen manufacturing reformer through the reformation hydrogen production of first alcohol and water occurs, the mixed gas based on carbon dioxide and hydrogen is made,
The mixed gas isolates hydrogen and high temperature residual air through separation chamber, which is delivered to fuel cell and produces electricl energy, and the electric energy is logical
It is first delivery pump, the second delivery pump, refrigerating plant, flusher, lighting device, electric heater to cross power output end mouth
And other power supply for electrical equipment；
The temperature for the high temperature residual air isolated by the separation chamber is 300 ~ 600 DEG C, and the high temperature residual air is collected to high temperature residual air
Collection device, the high temperature residual air collection device are connect by the first heating pipeline with the heating device, the high temperature residual air
Collection device is connect by the second heating pipeline with first marsh gas fermentation pool and the second marsh gas fermentation pool, first heating
Pipeline and the second heating pipeline are both provided with regulating valve and the first temperature sensor, the regulating valve, the first temperature sensor, the
One delivery pump and the second delivery pump are electrically connected with the controller respectively；
The biogas slurry and biogas residue of first marsh gas fermentation pool and the second marsh gas fermentation pool is exported to be connected with the biogas slurry and biogas residue processing unit
It connects, the biogas slurry and biogas residue generated by first marsh gas fermentation pool and the second marsh gas fermentation pool passes through the biogas slurry and biogas residue processing unit
The clear liquid obtained after processing is connect by clear liquid manifold with the flusher.
Wherein, the methanol extraction element includes sequentially connected first solid-liquid separator, desulfurizing tower, carbon dioxide absorption
The methane outlet of tower and ammonia absorption tower, first marsh gas fermentation pool and the second marsh gas fermentation pool respectively with first solid-liquid
The air inlet of separator is connected to, and the gas outlet of the ammonia absorption tower is connected to the methanol solution synthesizer.
Wherein, the methanol solution synthesizer include sequentially connected compressor, methyl alcohol synthetic reactor, gas-liquid separator and
Methanol aqueous solution memory, the methane gas and oxygen exported by the gas outlet of the ammonia absorption tower is respectively by the second pipe
Road is connected to the air inlet of compressor, and the liquid outlet of the gas-liquid separator is connect with the methanol aqueous solution memory, described
The gas outlet of gas-liquid separator is connected to by circulation line with the air inlet of compressor；It the first pipe, second pipe and follows
Endless tube road is both provided with gas flow control valve, and the gas flow control valve is electrically connected with the controller, the compressor
By power output end confession electricity.
Wherein, the methyl alcohol synthetic reactor is provided with third heating pipeline, the third heating pipeline and the high temperature residual air
Collection device connects, and the third heating tube road is provided with regulating valve, and the methyl alcohol synthetic reactor is provided with second temperature sensing
Device and pressure sensor, the regulating valve, the second temperature sensor and the pressure sensor respectively with the controller
Electrical connection.
Wherein, the biogas slurry and biogas residue processing unit includes for storing the buffer pool of biogas slurry and biogas residue, for detaching biogas slurry
The biogas slurry generated with the second solid-liquid separator, biogas residue pond, biogas slurry pond, the membrane filter of biogas residue, second marsh gas fermentation pool
Slag is connect with the buffer pool, second solid-liquid separator successively, the outlet of the biogas residue of second solid-liquid separator with it is described
Biogas residue pond connects, the biogas slurry outlet of the outlet of the biogas slurry of second solid-liquid separator and first marsh gas fermentation pool successively with
The biogas slurry pond, membrane filter connection, the purified liquor outlet of the membrane filter pass through clear liquid manifold and the flusher
Connection.
Wherein, the flusher includes cold water pipeline and hot water line, the cold water pipeline and hot water line respectively with
The clear liquid manifold connections, the clear liquid manifold are provided with reversal valve；First Heat Exchanger is provided on the hot water line, it is described
Clear liquid in hot water line carries out hot friendship with the high temperature residual air in the high temperature residual air collection device by the First Heat Exchanger
It changes, high temperature residual air, which is led to, is provided with regulating valve on the pipeline of First Heat Exchanger, the hot water line is additionally provided with fluid flow control
Valve processed and third temperature sensor, the reversal valve, regulating valve, liquid flow control valve and third temperature sensor respectively with institute
State controller electrical connection.
Wherein, the pool wall and/or bottom of pond of first marsh gas fermentation pool and the second marsh gas fermentation pool are provided with adds for being passed through
The interlayer of thermal medium, the heat medium are high temperature residual air, and the air inlet of the interlayer heats pipeline and institute by described second
The connection of high temperature residual air collection device is stated, the 4th temperature sensing is provided in first marsh gas fermentation pool and the second marsh gas fermentation pool
Device, the 4th temperature sensor are electrically connected with the controller.
Wherein, second is provided on transfer pipeline between the methanol aqueous solution memory and the methanol-water reformer to change
Hot device, the high-temperature hydrogen that methanol aqueous solution and the separation chamber of low temperature isolate carry out heat exchange through second heat exchanger.
Wherein, the methanol-water hydrogen manufacturing reformer is provided with starter, and the starter is reformed in methanol-water hydrogen manufacturing
It is that second delivery pump and electric heater are powered in device start-up course.
Wherein, the starter is accumulator.
Beneficial effects of the present invention：
The integrated livestock and poultry cultivating system of the biomass cogeneration of heat and power of invention is supported using a large amount of livestock and poultry that livestock and poultry cultivation process generates
Waste is grown, includes mainly excrement and sewage（Mainly livestock and poultry urine and flushing water etc.）Two parts, excrement and sewage respectively into
Row biogas fermentation, the biogas that the two generates first pass through methane extraction element and extract methane, and then methane is synthesized through methanol solution
Device prepares methanol aqueous solution, the raw material which reacts as methanol-water reformation hydrogen production, is made more than hydrogen and high temperature
Gas, hydrogen therein are delivered to fuel cell and produce electricl energy again, which is all power supply for electrical equipment of whole system, wherein
The temperature of high temperature residual air be up to 300 ~ 600 DEG C, the thermal energy of this part high-quality is that biogas fermentation, methanol-fueled CLC are anti-in system
It answers, the temperature needed for the offers heating such as rinse water, heating device；Biogas slurry and biogas residue after biogas fermentation is using biogas slurry and biogas residue
After processing unit processing, it is recycled recycling, to form the integration cultivation system for the biomass cogeneration of heat and power that one recycles
System.Compared with prior art, the present invention has the following advantages：
（1）The present invention realizes Efficient Conversion and the utilization of animal waste-biogas-methanol-electric energy, the electric energy of conversion on the spot
Can be self-sufficient, it is not necessarily to external power supply, and the electric energy of the system output is direct current, it can be directly for direct current without conversion
Electric appliance uses, and compared to the mode that current high direct voltage centralization generates electricity, has with with sending out, be easy to distributing installation, at low cost
The characteristics of, it is not limited by the field, it is more suitable for rural culture industry；
（2）The present invention prepares methanol using the biogas that biogas fermentation generates as intermediate product, has well solved biogas storage
The problem of with transport, while the raw material as the reaction of methanol-water reformation hydrogen production, reaction process itself generate a large amount of Gao Pin to methanol again
The thermal energy of matter, this partial heat energy are fully utilized, and are directly heated for heating device, flushing hot water, biogas fermentation required
Temperature greatly reduces energy consumption, according to the yield of animal waste, the amount for being converted into methanol, each heating module in system
The thermal energy generated in power and methanol-water the reformation hydrogen production reaction of required temperature, each electricity consumption module and fuel cell output
Electric energy carry out energy perseverance calculation, so that animal waste be associated with thermal energy, electric energy, realize that the intelligence of whole system is controlled
System, makes this kind of biomass energy of animal waste efficiently be converted and be utilized, and the livestock and poultry for forming ecological integrated are supported
System is grown, with wide commercial application foreground；
（3）The present invention need not manufacture methanol using animal waste, then pass through methanol again by marsh gas power generation of burning
Water reformation hydrogen production generates electricity and powers, and a small amount of carbon dioxide, the thermal energy base itself generated in reaction process are only discharged in reaction
This meets the thermal energy needed for each heating module, and the biogas slurry and biogas residue that biogas fermentation generates are used to prepare agriculture organic fertilizer and middle water returns
With by the conversion and comprehensive utilization of the above-mentioned energy, the energy saving and environment protecting of this system is notable.
Description of the drawings
Fig. 1 is the structural schematic diagram of the integrated livestock and poultry cultivating system of the biomass cogeneration of heat and power of the present invention.
Fig. 2 is that the structure of the methane extraction element of the integrated livestock and poultry cultivating system of the biomass cogeneration of heat and power of the present invention is shown
It is intended to.
Fig. 3 is the knot of the methanol solution synthesizer of the integrated livestock and poultry cultivating system of the biomass cogeneration of heat and power of the present invention
Structure schematic diagram.
Reference numeral：
Excrement preparing pool 1, detention tank 2, the first marsh gas fermentation pool 3, the second marsh gas fermentation pool 4；
Methane extraction element 5, the first solid-liquid separator 51, desulfurizing tower 52, carbon dioxide absorption tower 53, ammonia absorption tower 54；
Methanol solution synthesizer 6, compressor 61, methyl alcohol synthetic reactor 62, gas-liquid separator 63 and methanol aqueous solution memory
64；
Biogas slurry and biogas residue processing unit 7, buffer pool 71, the second solid-liquid separator 72, biogas slurry pond 73, membrane filter 74, biogas residue pond
75.；
Methanol-water hydrogen manufacturing reformer 8, reformer chamber 81, separation chamber 82, electric heater 83；
Fuel cell 9；
First heating pipeline 10, second heats pipeline 20, third heating pipeline 30, circulation line 40, first pipe 50, second and manages
Road 60, clear liquid manifold 70；
First delivery pump 11, high temperature residual air collection device 13, First Heat Exchanger 14, the second heat exchanger 15, is adjusted second delivery pump 12
Save valve 16, reversal valve 17, gas flow control valve 18, liquid flow control valve 19；
Breeding room 100, collecting dung pond 101, heating device 200, refrigerating plant 300, flusher 400, cold water pipeline 401,
Hot water line 402, lighting device 500.
Specific implementation mode
Below in conjunction with specific embodiment and attached drawing, the present invention is described in detail.
The integrated livestock and poultry cultivating system of biomass cogeneration of heat and power, as shown in Figure 1, including breeding room 100, breeding room 100
It is inside provided with heating device 200, refrigerating plant 300, flusher 400, lighting device 500 and collecting dung pond 101, is being cultivated
Excrement preparing pool 1, detention tank 2, the first marsh gas fermentation pool 3, the second biogas fermentation is respectively set in region near room 100 is outer
Pond 4, methane extraction element 5, methanol solution synthesizer 6, biogas slurry and biogas residue processing unit 7, methanol-water hydrogen manufacturing reformer 8, fuel
Battery 9 and control device, methanol-water hydrogen manufacturing reformer 8 include reformer chamber 81, separation chamber 82 and provide reformation for reformer chamber 81
The electric heater 83 of hydrogen production reaction required temperature, control device include controller and the power output end for exporting electric energy outward
Mouthful, wherein：
A large amount of animal wastes that livestock and poultry cultivation process generates include mainly excrement and sewage（Mainly livestock and poultry urine and punching
Wash water etc.）Two parts, wherein excrement are delivered to excrement preparing pool 1, livestock and poultry urine and punching after being collected by collecting dung pond 101 is unified
By pipeline to detention tank 2, the dope outlet of detention tank 2 is connected to the sewage such as wash water with excrement preparing pool 1, dirty
The purified liquor outlet in water sedimentation pond 2 is connected to the first marsh gas fermentation pool 3, and excrement preparing pool 1 passes through the first delivery pump 11 and the second natural pond
Gas fermentation vat 4 is connected to, and biogas slurry and biogas residue outlet and the biogas slurry and biogas residue processing of the first marsh gas fermentation pool 3 and the second marsh gas fermentation pool 4 fill
Set 7 connections, the methane outlet of the first marsh gas fermentation pool 3 and the second marsh gas fermentation pool 4 is carried with methane successively by first pipe 50
Device 5, methanol solution synthesizer 6 is taken to be connected to, the liquid outlet of methanol solution synthesizer 6 passes through the second delivery pump 12 and methanol
Water hydrogen manufacturing reformer 8 connects.Sewage clear liquid during this after 2 precipitation process of detention tank enters the first marsh gas fermentation pool
3 carry out biogas fermentation, and the dope of 2 bottom of detention tank enters the second biogas fermentation together with the excrement of excrement preparing pool 1
Pond 4 carries out biogas fermentation, and since excrement is different with main component, the water content of sewage, the two is separated carry out anaerobic fermentation, can
To improve the yield of biogas.The biogas that first marsh gas fermentation pool 3 and the second marsh gas fermentation pool 4 generate first passes through methane extraction element
5 extract methane, and the methane then obtained enters back into methanol solution synthesizer 6 and prepares methanol, the first marsh gas fermentation pool 3 and
After biogas slurry and biogas residue after the fermentation of two marsh gas fermentation pools 4 are handled using biogas slurry and biogas residue processing unit 7, it is recycled recycling.
The above-mentioned methanol prepared by methanol solution synthesizer 6 and the aqueous solution raw material as hydrogen manufacturing and power generation again, in first
The reformation hydrogen production reaction that first alcohol and water occurs is reacted in alcohol water hydrogen manufacturing reformer 8 through catalysis（The reaction of methanol-water reformation hydrogen production is existing
There is technology, is no longer described in detail in the present embodiment）, the mixed gas based on carbon dioxide and hydrogen, the mixed gas is made
Hydrogen and high temperature residual air are isolated through separation chamber 82, which is delivered to fuel cell 9 and produces electricl energy, and the electric energy is defeated by electric power
Exit port is the first delivery pump 11, the second delivery pump 12, refrigerating plant 300, flusher 400, lighting device 500, electrical heating
Other power supply for electrical equipment in device 83 and system, to realize animal waste-biogas-methanol-electric energy on the spot
Efficient Conversion and utilization, it is self-sufficient, it is not necessarily to external power supply.And the electric energy of the system output is direct current, directly for direct current
Electric appliance uses, without transformer module and subsequent rectification module etc., the side to generate electricity compared to current high direct voltage centralization
Formula has the characteristics that, with with sending out, being easy to distributing installation, to be more suitable for rural culture industry.First delivery pump 11 and second conveys
Pump 12 is electrically connected with the controller, can automation control.
Meanwhile the temperature for the high temperature residual air isolated by the separation chamber 82 of methanol-water hydrogen manufacturing reformer 8 is 300 ~ 600 DEG C,
High temperature residual air is collected to high temperature residual air collection device 13, and high temperature residual air collection device 13 is filled by the first heating pipeline 10 with heating
200 connections are set, high temperature residual air collection device 13 passes through the second heating pipeline 20 and the first marsh gas fermentation pool 3 and the second biogas fermentation
Pond 4 connects, and the high-quality heat energy that high temperature residual air generates can be that biogas fermentation and heating device 200 are provided needed for heating again
Temperature.Thus the thermal energy that this system is generated in reformation hydrogen production reaction is taken full advantage of, is greatly reduced needed for system conducting self-heating
Energy consumption, have energy-efficient effect.First heating pipeline 10 and second heats pipeline 20 and is both provided with regulating valve 16 and the first temperature
Sensor is spent, regulating valve 16 and the first temperature sensor are electrically connected with the controller respectively, and this system can be realized to heating device 200
With the automation control of marsh gas fermentation pool heating temperature.It further can also be according to the production according to animal waste in system
Measure, be converted into temperature needed for the amount of methanol, each heating module, the power of each electricity consumption module and the reaction of methanol-water reformation hydrogen production
The electric energy of thermal energy and the fuel cell output of middle generation carries out energy perseverance calculation, thus by animal waste and thermal energy, electricity
It can be associated with, realize the intelligentized control method of whole system, the energy is made efficiently to be converted and be utilized, form the poultry of ecological integrated
Fowl cultivating system, with wide commercial application foreground.
Add for being passed through specifically, the pool wall and/or bottom of pond of the first marsh gas fermentation pool 3 and the second marsh gas fermentation pool 4 are provided with
The interlayer of thermal medium, heat medium are high temperature residual air, and the air inlet of interlayer is collected by the second heating pipeline 20 with high temperature residual air
Device 13 connects, and the temperature provided needed for anaerobic fermentation is heated to marsh gas fermentation pool using high temperature residual air.First marsh gas fermentation pool 3
It is provided with the 4th temperature sensor in the second marsh gas fermentation pool 4, the 4th temperature sensor is electrically connected with the controller, in order to right
The detection and regulation and control of temperature.
In the present embodiment, as shown in Fig. 2, methane extraction element 5 includes sequentially connected first solid-liquid separator 51, desulfurization
The biogas of tower 52, carbon dioxide absorption tower 53 and ammonia absorption tower 54, the first marsh gas fermentation pool 3 and the second marsh gas fermentation pool 4 goes out
Mouth is connected to the air inlet of the first solid-liquid separator 51 respectively, gas outlet and the methanol solution synthesizer 6 of ammonia absorption tower 54
Connection.Since the biogas that anaerobic fermentation generates is the mixture containing methane, sulfide and carbon dioxide etc., it is solid to first pass through first
Liquid/gas separator 51 removes solid impurity, removes sulfide then in turn through desulfurizing tower 52, is removed by carbon dioxide absorption tower 53
It removes carbon dioxide, obtain the higher methane gas of purity after ammonia absorption tower 54 removes ammonia, then be delivered to methanol solution
Synthesizer 6 prepares methanol aqueous solution.
In the present embodiment, as shown in figure 3, methanol solution synthesizer 6 includes sequentially connected compressor 61, methanol-fueled CLC
Tower 62, gas-liquid separator 63 and methanol aqueous solution memory 64, by ammonia absorption tower 54 gas outlet export methane gas with
And oxygen is connected to by second pipe 60 with the air inlet of compressor 61 respectively, the liquid outlet and methanol of gas-liquid separator 63 are water-soluble
Liquid memory 64 connects, and the gas outlet of gas-liquid separator 63 is connected to by circulation line 40 with the air inlet of compressor 61.It is above-mentioned
In the process, methane gas and outer oxygen（As oxygen cylinder provides oxygen）It is delivered to methyl alcohol synthetic reactor after the pressurization of compressor 61
The reaction of 62 internal oxiditions generates methanol, and wherein methane and oxygen presses 8 ~ 9:1 ~ 2 volume ratio mixing, at 150 ~ 220 DEG C and 80 ~ 125
It under conditions of a atmospheric pressure, reacts and methanol is made, reaction equation is：2CH4+O2=2CH3OH.The first generated in methyl alcohol synthetic reactor 62
The methanol solution that the residual gases such as alcohol and unreacted methane obtain after 63 condensation separation of gas-liquid separator is stored in first
Alcohol solution memory 64, the residual gas after separation are back to 61 air inlet of compressor by circulation line 40 again, enter back into
Methyl alcohol synthetic reactor 62 reacts methanol processed.First pipe 50, second pipe 60 and circulation line 40 are both provided with gas flow control
Valve 18, gas flow control valve 18 are electrically connected with the controller, and gas flow in each pipeline is realized by gas flow control valve 18
Automation control, compressor 61 powered by systematic electricity output port.
Methyl alcohol synthetic reactor 62 is provided with third heating pipeline 30, and third heats pipeline 30 and connects with high temperature residual air collection device 13
It connects, i.e., the thermal energy generated by this system itself is that methyl alcohol synthetic reactor 62 provides reaction required temperature, and third heats pipeline 30
On be provided with regulating valve 16, be provided with second temperature sensor and pressure sensor in methyl alcohol synthetic reactor 62, the regulating valve 16,
Two temperature sensor and pressure sensor are electrically connected with the controller respectively, to realizing to 62 interior reaction temperature of methyl alcohol synthetic reactor and
The automation control of pressure.
In the present embodiment, the biogas slurry and biogas residue after the first marsh gas fermentation pool 3 and the fermentation of the second marsh gas fermentation pool 4 are using natural pond
After the processing of liquid biogas residue processing unit 7, it is recycled recycling.Biogas slurry and biogas residue processing unit 7 includes for storing biogas slurry and biogas residue
Buffer pool 71, the second solid-liquid separator 72, biogas residue pond 75, biogas slurry pond 73, membrane filter 74 for detaching biogas slurry and biogas residue.
The biogas slurry and biogas residue that second marsh gas fermentation pool 4 generates is connect with buffer pool 71, the second solid-liquid separator 72 successively, and second is separated by solid-liquid separation
The biogas residue outlet of device 72 connect with biogas residue pond 75, and the biogas slurry of the second solid-liquid separator 72 exports and the first marsh gas fermentation pool 3
Biogas slurry outlet is connect with biogas slurry pond 73, membrane filter 74 successively, and the purified liquor outlet of membrane filter 74 passes through clear liquid manifold 70 and punching
Cleaning device 400 connects.Since the first marsh gas fermentation pool 3 mainly ferments to sewage, product is mainly biogas slurry after fermentation, will
This part biogas slurry is stored in biogas slurry pond 73, and the second marsh gas fermentation pool 4 is mainly the anaerobic fermentation of excrement, is generated after fermentation a large amount of
Biogas residue and a small amount of biogas slurry need to first pass through the second solid-liquid separator 72 and isolate biogas residue spare, the separation that is stored in biogas residue pond 75
The biogas slurry gone out is stored in biogas slurry pond 73, and the clear liquid that then biogas slurry in biogas slurry pond 73 obtains after being filtered using membrane filter 74 is defeated
It send to flusher 400, can be used as rinse water reuse.It can be directly as liquid after 74 filtered dope of membrane filter is concentrated
Body concentration fertilizer is used for the plantation of crops.Biogas residue in biogas residue pond 75 can be further used for preparing agriculture organic fertilizer use.By
This, the biogas slurry and biogas residue of this system can also turn waste into wealth, and both avoid to the landfill of biogas fermentation waste or burning processing
Process reduces environmental pollution, and can reduce the usage amount of agrochemical, is conducive to the development of sustainable agriculture.
Flusher 400 includes cold water pipeline 401 and hot water line 402, and cold water pipeline 401 and hot water line 402 distinguish
It is connect with clear liquid manifold 70, clear liquid manifold 70 is provided with for switching between cold water pipeline 401 and hot water line 402
Reversal valve 17 selects the hot water or cold water of flushing as needed.First Heat Exchanger 14, hot water are provided on hot water line 402
Clear liquid in pipeline 402 carries out heat exchange with the high temperature residual air in high temperature residual air collection device 13 by First Heat Exchanger 14, from
And the clear liquid in hot water line 402 is heated.Hot water line 402 is additionally provided with liquid flow control valve 19 and third temperature sensing
Device, reversal valve 17, liquid flow control valve 19 and third temperature sensor are electrically connected with the controller respectively, to realize heating temperature
Automation control.
In the present embodiment, it is provided on transfer pipeline between methanol aqueous solution memory 64 and methanol-water hydrogen manufacturing reformer 8
Second heat exchanger 15, the high-temperature hydrogen that methanol aqueous solution and the separation chamber 82 of low temperature isolate carry out hot friendship through the second heat exchanger 15
After changing, enter fuel cell 9 after hydrogen cooling, methanol-water is further heated, is then sent in methanol-water hydrogen manufacturing reformer 8
Evaporation gasification.
In the present embodiment, methanol-water hydrogen manufacturing reformer 8 is provided with starter.First, starter is in methanol-water hydrogen manufacturing
In 8 start-up course of reformer, it is that the second delivery pump 12 and electric heater 83 are powered, starts so that methanol-water reformation hydrogen production reacts,
The hydrogen of acquisition enters fuel cell 9, after the work of fuel cell 9 produces electricl energy, then is the equipment power supply of whole system, methanol-water
The high-quality heat energy that reformation hydrogen production reaction generates is system biogas fermentation, methanol synthesis reaction, rinse water and heating dress again
200 equal offer thermal energy are set, to form the integrated cultivating system for the biomass cogeneration of heat and power that one recycles.Specifically, starting
Device is accumulator；Or be combustion-type starter, it is heated for reformer chamber 81 by combustion methanol；Or be hydrogen storage bottle,
The hydrogen storage bottle can be 9 inputting hydrogen of fuel cell in 8 start-up course of methanol-water hydrogen manufacturing reformer, make the work production of fuel cell 9
Raw electric energy, and then power for the second delivery pump 12 and electric heater 83.
Finally it should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention, rather than the present invention is protected
The limitation of range is protected, although being explained in detail to the present invention with reference to preferred embodiment, those skilled in the art answer
Work as understanding, technical scheme of the present invention can be modified or replaced equivalently, without departing from the reality of technical solution of the present invention
Matter and range.
Claims (10)
1. the integrated livestock and poultry cultivating system of biomass cogeneration of heat and power, including breeding room, heating device, system are provided in breeding room
Device for cooling, flusher, lighting device and collecting dung pond, it is characterised in that：Further include excrement preparing pool, detention tank,
First marsh gas fermentation pool, the second marsh gas fermentation pool, methane extraction element, methanol solution synthesizer, biogas slurry and biogas residue processing unit,
Methanol-water hydrogen manufacturing reformer, fuel cell and control device, the methanol-water hydrogen manufacturing reformer include reformer chamber, separation chamber and
The electric heater that reformation hydrogen production reacts required temperature is provided for reformer chamber, the control device includes controller and is used for defeated outward
Go out the power output end mouth of electric energy, wherein：
The excrement that collecting dung pond is collected is delivered to excrement preparing pool, the sewage such as the livestock and poultry urine generated in breeding room and flushing water
By pipeline to detention tank, the dope outlet of the detention tank is connected to the excrement preparing pool, the dirt
The purified liquor outlet in water sedimentation pond is connected to the first marsh gas fermentation pool, and the excrement preparing pool passes through the first delivery pump and described second
Marsh gas fermentation pool is connected to, the methane outlet of first marsh gas fermentation pool and the second marsh gas fermentation pool by first pipe successively with
Methane extraction element, the connection of methanol solution synthesizer, the liquid outlet of the methanol solution synthesizer pass through the second delivery pump
It is connect with the methanol-water hydrogen manufacturing reformer；The methanol aqueous solution prepared by the methanol solution synthesizer is in the methanol-water
It is reacted in hydrogen manufacturing reformer through the reformation hydrogen production of first alcohol and water occurs, the mixed gas based on carbon dioxide and hydrogen is made,
The mixed gas isolates hydrogen and high temperature residual air through separation chamber, which is delivered to fuel cell and produces electricl energy, and the electric energy is logical
It is first delivery pump, the second delivery pump, refrigerating plant, flusher, lighting device, electric heater to cross power output end mouth
And other power supply for electrical equipment；
The temperature for the high temperature residual air isolated by the separation chamber is 300 ~ 600 DEG C, and the high temperature residual air is collected to high temperature residual air
Collection device, the high temperature residual air collection device are connect by the first heating pipeline with the heating device, the high temperature residual air
Collection device is connect by the second heating pipeline with first marsh gas fermentation pool and the second marsh gas fermentation pool, first heating
Pipeline and the second heating pipeline are both provided with regulating valve and the first temperature sensor, the regulating valve, the first temperature sensor, the
One delivery pump and the second delivery pump are electrically connected with the controller respectively；
The biogas slurry and biogas residue of first marsh gas fermentation pool and the second marsh gas fermentation pool is exported to be connected with the biogas slurry and biogas residue processing unit
It connects, the biogas slurry and biogas residue generated by first marsh gas fermentation pool and the second marsh gas fermentation pool passes through the biogas slurry and biogas residue processing unit
The clear liquid obtained after processing is connect by clear liquid manifold with the flusher.
2. the integrated livestock and poultry cultivating system of biomass cogeneration of heat and power according to claim 1, it is characterised in that：The first
Alcohol extracting device includes sequentially connected first solid-liquid separator, desulfurizing tower, carbon dioxide absorption tower and ammonia absorption tower, described
The methane outlet of first marsh gas fermentation pool and the second marsh gas fermentation pool is connected to the air inlet of first solid-liquid separator respectively,
The gas outlet of the ammonia absorption tower is connected to the methanol solution synthesizer.
3. the integrated livestock and poultry cultivating system of biomass cogeneration of heat and power according to claim 2, it is characterised in that：The first
Alcoholic solution synthesizer includes sequentially connected compressor, methyl alcohol synthetic reactor, gas-liquid separator and methanol aqueous solution memory, by
The methane gas and oxygen of the gas outlet output of the ammonia absorption tower pass through the air inlet of second pipe and compressor respectively
Connection, the liquid outlet of the gas-liquid separator are connect with the methanol aqueous solution memory, the gas outlet of the gas-liquid separator
It is connected to the air inlet of compressor by circulation line；The first pipe, second pipe and circulation line are both provided with gas
Flow control valve, the gas flow control valve are electrically connected with the controller, and the compressor is by the power output end mouth
Power supply.
4. the integrated livestock and poultry cultivating system of biomass cogeneration of heat and power according to claim 3, it is characterised in that：The first
Alcohol synthetic tower is provided with third heating pipeline, and third heating pipeline is connect with the high temperature residual air collection device, and described the
Three heating tubes road is provided with regulating valve, and the methyl alcohol synthetic reactor is provided with second temperature sensor and pressure sensor, described
Regulating valve, the second temperature sensor and the pressure sensor are electrically connected with the controller respectively.
5. the integrated livestock and poultry cultivating system of biomass cogeneration of heat and power according to claim 1, it is characterised in that：The natural pond
Liquid biogas residue processing unit includes being separated by solid-liquid separation for storing the buffer pool of biogas slurry and biogas residue, for detaching the second of biogas slurry and biogas residue
Device, biogas residue pond, biogas slurry pond, membrane filter, the biogas slurry and biogas residue that second marsh gas fermentation pool generates successively with the buffer pool, institute
The connection of the second solid-liquid separator is stated, the biogas residue outlet of second solid-liquid separator is connect with the biogas residue pond, and described second is solid
The biogas slurry of liquid/gas separator export and the outlet of the biogas slurry of first marsh gas fermentation pool successively with the biogas slurry pond, the membrane filtration
Device connects, and the purified liquor outlet of the membrane filter is connect by clear liquid manifold with the flusher.
6. the integrated livestock and poultry cultivating system of biomass cogeneration of heat and power according to claim 5, it is characterised in that：The punching
Cleaning device includes cold water pipeline and hot water line, and the cold water pipeline and hot water line connect with the clear liquid manifold respectively, institute
It states clear liquid manifold and is provided with reversal valve；First Heat Exchanger is provided on the hot water line, the clear liquid in the hot water line with
High temperature residual air in the high temperature residual air collection device carries out heat exchange by the First Heat Exchanger, and high temperature residual air leads to first
Regulating valve is provided on the pipeline of heat exchanger, the hot water line is additionally provided with liquid flow control valve and third temperature sensing
Device, the reversal valve, regulating valve, liquid flow control valve and third temperature sensor are electrically connected with the controller respectively.
7. the integrated livestock and poultry cultivating system of biomass cogeneration of heat and power according to claim 1, it is characterised in that：Described
The pool wall and/or bottom of pond of one marsh gas fermentation pool and the second marsh gas fermentation pool are provided with the interlayer for being passed through heat medium, described to add
Thermal medium is high temperature residual air, and the air inlet of the interlayer heats pipeline by described second and connects with the high temperature residual air collection device
It connects, the 4th temperature sensor, the 4th temperature sensing is provided in first marsh gas fermentation pool and the second marsh gas fermentation pool
Device is electrically connected with the controller.
8. the integrated livestock and poultry cultivating system of biomass cogeneration of heat and power according to claim 3, it is characterised in that：The first
The second heat exchanger is provided between alcohol solution memory and the methanol-water reformer on transfer pipeline, the methanol of low temperature is water-soluble
The high-temperature hydrogen that liquid is isolated with separation chamber carries out heat exchange through second heat exchanger.
9. the integrated livestock and poultry cultivating system of biomass cogeneration of heat and power according to claim 1, it is characterised in that：The first
Alcohol water hydrogen manufacturing reformer is provided with starter, and the starter is described in methanol-water hydrogen manufacturing reformer start-up course
Second delivery pump and electric heater power supply.
10. the integrated livestock and poultry cultivating system of biomass cogeneration of heat and power according to claim 9, it is characterised in that：It is described
Starter is accumulator.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111841141A (en) * | 2020-07-31 | 2020-10-30 | 浙江天地环保科技股份有限公司 | Biogas slurry solid-liquid separation system for biogas engineering and control mode |
| CN113319109A (en) * | 2021-05-12 | 2021-08-31 | 杨西建 | Resource utilization and treatment device for agricultural and livestock wastes |
| CN114108758A (en) * | 2020-12-16 | 2022-03-01 | 浙江金字机械电器股份有限公司 | Method for treating excrement and movable clean-discharge non-sewer toilet |
| EP4060774A1 (en) * | 2021-03-19 | 2022-09-21 | Hitachi, Ltd. | Fuel cell system |
| CN115926947A (en) * | 2022-11-30 | 2023-04-07 | 东莞市巴能检测技术有限公司 | Grassland animal husbandry transformation circulation organic ecological resource recycling system |
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2017
- 2017-03-31 CN CN201710207418.3A patent/CN108658361A/en not_active Withdrawn
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| CN111841141A (en) * | 2020-07-31 | 2020-10-30 | 浙江天地环保科技股份有限公司 | Biogas slurry solid-liquid separation system for biogas engineering and control mode |
| CN111841141B (en) * | 2020-07-31 | 2023-12-01 | 浙江天地环保科技股份有限公司 | Biogas slurry solid-liquid separation system for biogas engineering and control mode |
| CN114108758A (en) * | 2020-12-16 | 2022-03-01 | 浙江金字机械电器股份有限公司 | Method for treating excrement and movable clean-discharge non-sewer toilet |
| CN114108758B (en) * | 2020-12-16 | 2024-05-14 | 浙江金字机械电器股份有限公司 | Method for treating excrement and urine and movable clean-discharge toilet without sewer |
| EP4060774A1 (en) * | 2021-03-19 | 2022-09-21 | Hitachi, Ltd. | Fuel cell system |
| CN113319109A (en) * | 2021-05-12 | 2021-08-31 | 杨西建 | Resource utilization and treatment device for agricultural and livestock wastes |
| CN113319109B (en) * | 2021-05-12 | 2023-12-26 | 杨西建 | Resource utilization treatment device for farm animal waste |
| CN115926947A (en) * | 2022-11-30 | 2023-04-07 | 东莞市巴能检测技术有限公司 | Grassland animal husbandry transformation circulation organic ecological resource recycling system |
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