CN109980031A - A kind of texturing slot and monocrystalline silicon process for etching for crystal silicon solar energy battery - Google Patents

A kind of texturing slot and monocrystalline silicon process for etching for crystal silicon solar energy battery Download PDF

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Publication number
CN109980031A
CN109980031A CN201910331455.4A CN201910331455A CN109980031A CN 109980031 A CN109980031 A CN 109980031A CN 201910331455 A CN201910331455 A CN 201910331455A CN 109980031 A CN109980031 A CN 109980031A
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groove body
solar energy
texturing slot
energy battery
crystal silicon
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CN201910331455.4A
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周公庆
王璞
王岚
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Tongwei Solar Chengdu Co Ltd
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Tongwei Solar Chengdu Co Ltd
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Priority to CN201910331455.4A priority Critical patent/CN109980031A/en
Publication of CN109980031A publication Critical patent/CN109980031A/en
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    • CCHEMISTRY; METALLURGY
    • C30CRYSTAL GROWTH
    • C30BSINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
    • C30B33/00After-treatment of single crystals or homogeneous polycrystalline material with defined structure
    • C30B33/08Etching
    • C30B33/10Etching in solutions or melts
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/02Details
    • H01L31/0236Special surface textures
    • H01L31/02363Special surface textures of the semiconductor body itself, e.g. textured active layers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/18Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
    • H01L31/1876Particular processes or apparatus for batch treatment of the devices
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Engineering & Computer Science (AREA)
  • Computer Hardware Design (AREA)
  • Power Engineering (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Electromagnetism (AREA)
  • General Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Photovoltaic Devices (AREA)

Abstract

The invention discloses a kind of texturing slot for crystal silicon solar energy battery and monocrystalline silicon process for etching, it is related to solar cell preparation technology, the present invention for crystal silicon solar energy battery texturing slot include upper end opening groove body, groove body is cylindrical shape, groove body internal diameter is 40-60cm, bottom is the arcwall face toward evagination in groove body, arcwall face depth is h, h=4-6cm, bottom is provided with rabbling mechanism in groove body, groove body bottom is provided with heating element, monocrystalline silicon process for etching uses the above-mentioned texturing slot for crystal silicon solar energy battery, the present invention has structure simple, it can guarantee the temperature and uniform concentration distribution of Woolen-making liquid, the good advantage of the uniformity of monocrystalline silicon battery making herbs into wool flannelette obtained.

Description

A kind of texturing slot and monocrystalline silicon process for etching for crystal silicon solar energy battery
Technical field
The present invention relates to solar cell preparation technologies, more particularly to one kind for crystal silicon solar electricity The texturing slot and monocrystalline silicon process for etching in pond.
Background technique
With the development of China's economic, we increasingly have found our air quality worse and worse, and the root of everything This reason is exactly that Chinese energy resource structure is unreasonable, and the ratio of fossil fuel is excessively high, for long-range angle, fossil energy It is non-renewable, sooner or later can be exhausted, from the point of view of at present, the pollution of fossil energy is huge, has generated to national health tight The influence of weight, so all there is an urgent need to reform energy resource structure for China either from long-range angle and current angle.Common In several clean energy resourcies, water energy is kind of an inborn energy, is difficult to obtain in water resource region not abundant, wind energy is unstable, core There can be the danger of leakage, so only distribution of solar energy is extensive, become China and solve to improve the important outlet of clean energy resource ratio. Crystal-silicon solar cell can be directly changed into solar energy electric energy, and will not generate any pollution in use, at present very Multinational family will all help solar cell generation technology including China, and fundamentally reduce the dependence to fossil fuel.At present The monocrystalline process for etching of conventional batteries, most commonly seen is the method for alkali formula making herbs into wool, but the raising mesh of the uniformity of its flannelette It is preceding to become bottleneck.The uniformity of flannelette will affect silion cell to the reflectivity and transmissivity of spectrum, and then influence the electricity of silion cell Performance, on the other hand, uniform flannelette is for diffuseing to form uniform PN junction, and the hydrophobicity for increasing silicon wafer also has an impact.Through Our experiment discovery is crossed, the color distinction of silicon wafer, illustrates flannelette to silicon wafer after the silicon wafer PECVD that uniform flannelette is effectively reduced The uniform silicon nitride film of formation also have a significant impact.
In the making herbs into wool process of conventional N-type or p type single crystal silicon battery, usually using NaOH, isopropanol, tri- kinds of IPA it is molten Liquid is formed making herbs into wool flannelette using NaOH after anisotropy caustic corrosion, corrosion, but this chemical reaction by it is many because The influence of the conditions such as the influence, such as temperature, reactant concentration, product concentration of element, so the flannelette ultimately generated has not Together, and then it will affect the uniformity of flannelette and generally pass through special texturing slot system in the process for etching of monocrystalline silicon battery Suede technique, the texturing slot structural design for being currently used for monocrystalline silicon battery is unreasonable, leads to the concentration of Woolen-making liquid in texturing slot And non-uniform temperature, and it is effectively relatively low using the amount of Woolen-making liquid, the uniformity of monocrystalline silicon battery making herbs into wool flannelette is poor.
Therefore above-mentioned technical problem how is solved, there is very much realistic meaning to those skilled in the art.
Summary of the invention
It is an object of the invention to: do not conform to solve to be currently used for the texturing slot structural design of monocrystalline silicon battery Reason leads to the concentration and non-uniform temperature of Woolen-making liquid in texturing slot, and effectively relatively low using the amount of Woolen-making liquid, monocrystalline silicon battery system The technical problem of the uniformity difference of suede flannelette, the present invention provide a kind of texturing slot and monocrystalline silicon for crystal silicon solar energy battery Process for etching.
The present invention specifically uses following technical scheme to achieve the goals above:
A kind of texturing slot for crystal silicon solar energy battery, the groove body including upper end opening, groove body are cylindrical shape, groove body Internal diameter is 40-60cm, and bottom is the arcwall face toward evagination in groove body, and arcwall face depth is h, h=4-6cm, and bottom is set in groove body It is equipped with rabbling mechanism, groove body bottom is provided with heating element.
Further, groove body internal diameter is 50cm, arcwall face depth h=5cm.
Further, rabbling mechanism is magnetic control rotor.
Further, heating element is resistive heater.
Further, the grid being provided in groove body above rabbling mechanism is provided with the flower equipped with silicon wafer in grid Basket.
A kind of monocrystalline silicon process for etching, comprising the following steps:
S1: first removing silicon wafer damaging layer, with the spot on NaOH solution cleaning silicon chip surface, then with deionized water to silicon wafer into Row rinsing;
S2: the obtained silicon wafer of above-mentioned steps S1 being put into the gaily decorated basket, then the gaily decorated basket is put into the texturing slot for filling Woolen-making liquid, Texturing slot uses a kind of above-mentioned texturing slot for crystal silicon solar energy battery, then starts rabbling mechanism, and pass through heating Element heats up to Woolen-making liquid, so that Woolen-making liquid temperature is maintained 80 DEG C, silicon wafer soaking time is 20min;
S3: taking out the silicon wafer that above-mentioned steps S2 is obtained, and first passes through deionized water rinsing to the silicon wafer, then carry out pickling, then It is rinsed by deionized water, then carries out pickling, then rinsed by deionized water, then carry out pickling, floated finally by deionized water It washes.
Further, the proportion of the Woolen-making liquid used in step s 2 includes the component of following content: 39% concentration NaOH solution 6L, IPA solution 7L, flocking additive 500mL, deionized water 112.5L.
Beneficial effects of the present invention are as follows:
1, by groove body it is first cylindrical shape, guarantees that the rotation of Woolen-making liquid is uniform, and groove body internal diameter is 40-60cm, is added Thermal element can be transferred heat to quickly in Woolen-making liquid in making herbs into wool trench bottom, and since there is the rotation of rabbling mechanism in lower section Effect, quickly can reach the consistent of upper and lower surface temperature for solution, to reduce the temperature difference of silicon chip edge and central area Not, it under the mating reaction of heating element and rabbling mechanism, so that the concentration and Temperature Distribution of Woolen-making liquid are relatively uniform, improves The uniformity of silicon wafer suede, while bottom in groove body is arranged to arcwall face, increase groove body inner space, effectively uses Woolen-making liquid Amount up to 126L or so, arcwall face depth is excessive, be unfavorable for transmit heat, arcwall face depth is too small, and inner space is small, therefore Arcwall face depth is arranged to 4-6cm, maximumlly improves groove body inner space under conditions of guaranteeing and quickly transmitting heat, Guarantee the amount for effectively using Woolen-making liquid.
2, making herbs into wool is carried out for the texturing slot of crystal silicon solar energy battery using the present invention in process for etching, and stringent Woolen-making liquid temperature is controlled at 80 DEG C, soaking time 20min, then rational technology is washed, altogether using deionized water rinsing acid adding In triplicate, deionized water rinsing is finally carried out again, and making herbs into wool effect is good, the uniformity of monocrystalline silicon battery making herbs into wool flannelette obtained It is good.It is matched using new Woolen-making liquid, optimizes making herbs into wool effect.
Detailed description of the invention
Fig. 1 is a kind of structural schematic diagram of the texturing slot for crystal silicon solar energy battery of the present invention.
Appended drawing reference: 1- groove body, 2- arcwall face, 3- rabbling mechanism, 4- heating element, 5- grid, the 6- gaily decorated basket.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, with reference to the accompanying drawings and embodiments, right The present invention is further elaborated.It should be appreciated that described herein, specific examples are only used to explain the present invention, not For limiting the present invention, i.e., described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is logical The component for the embodiment of the present invention being often described and illustrated herein in the accompanying drawings can be arranged and be designed with a variety of different configurations.
Therefore, the detailed description of the embodiment of the present invention provided in the accompanying drawings is not intended to limit below claimed The scope of the present invention, but be merely representative of selected embodiment of the invention.Based on the embodiment of the present invention, those skilled in the art Member's every other embodiment obtained without making creative work, shall fall within the protection scope of the present invention.
It should be noted that the relational terms of term " first " and " second " or the like be used merely to an entity or Operation is distinguished with another entity or operation, and without necessarily requiring or implying between these entities or operation, there are any This actual relationship or sequence.Moreover, the terms "include", "comprise" or its any other variant be intended to it is non-exclusive Property include so that include a series of elements process, method, article or equipment not only include those elements, but also Further include other elements that are not explicitly listed, or further include for this process, method, article or equipment it is intrinsic Element.In the absence of more restrictions, the element limited by sentence "including a ...", it is not excluded that including described There is also other identical elements in the process, method, article or equipment of element.
Feature and performance of the invention are described in further detail with reference to embodiments.
Embodiment 1
As shown in Figure 1, the present embodiment provides a kind of texturing slots for crystal silicon solar energy battery, including upper end opening Groove body 1, groove body 1 are cylindrical shape, and 1 internal diameter of groove body is 40-60cm, and bottom is the arcwall face 2 toward evagination in groove body 1, and arcwall face 2 is deep Spending is h, h=4-6cm, and bottom is provided with rabbling mechanism 3 in groove body 1, and 1 bottom of groove body is provided with heating element 4.
It is first cylindrical shape by groove body in the present embodiment, guarantees that the rotation of Woolen-making liquid is uniform, and groove body internal diameter is 40-60cm, heating element can be transferred heat to quickly in Woolen-making liquid in making herbs into wool trench bottom, and since there is stirring in lower section Solution quickly can be reached the consistent of upper and lower surface temperature, to reduce silicon chip edge and center by the rotary action of mechanism The temperature difference in domain, under the mating reaction of heating element and rabbling mechanism, so that the concentration and Temperature Distribution of Woolen-making liquid compare Uniformly, the uniformity of silicon wafer suede is improved, while bottom in groove body is arranged to arcwall face, increases groove body inner space, has For effect using the amount of Woolen-making liquid up to 126L or so, arcwall face depth is excessive, is unfavorable for transmitting heat, arcwall face depth is too small, interior Portion space is small, therefore arcwall face depth is arranged to 4-6cm, maximumlly improves under conditions of guaranteeing and quickly transmitting heat Groove body inner space guarantees the amount for effectively using Woolen-making liquid.
Embodiment 2
As shown in Figure 1, the present embodiment is to be further optimized on the basis of embodiment 1, and specifically, 1 internal diameter of groove body For 50cm, 2 depth h=5cm of arcwall face, most it is able to satisfy quickly transmitting heat and guarantees the condition of groove body inner space, blender Structure 3 is magnetic control rotor, and at low cost, mixing effect is good, and heating element 4 is resistive heater, and heating rate is fast, setting in groove body 1 There is the grid 5 for being located at 3 top of rabbling mechanism, is provided with the gaily decorated basket 6 equipped with silicon wafer in grid 5.
Embodiment 3
As shown in Figure 1, the present embodiment provides a kind of monocrystalline silicon process for etching, comprising the following steps:
S1: first removing silicon wafer damaging layer, with the spot on NaOH solution cleaning silicon chip surface, then with deionized water to silicon wafer into Row rinsing;
S2: the obtained silicon wafer of above-mentioned steps S1 is put into the gaily decorated basket 6, then the gaily decorated basket 6 is put into the texturing slot for filling Woolen-making liquid Interior, texturing slot uses a kind of above-mentioned texturing slot for crystal silicon solar energy battery, then starts rabbling mechanism 3, and pass through Heating element 4 heats up to Woolen-making liquid, so that Woolen-making liquid temperature is maintained 80 DEG C, silicon wafer soaking time is 20min;
S3: taking out the silicon wafer that above-mentioned steps S2 is obtained, and first passes through deionized water rinsing to the silicon wafer, then carry out pickling, then It is rinsed by deionized water, then carries out pickling, then rinsed by deionized water, then carry out pickling, floated finally by deionized water It washes.
Further, the proportion of the Woolen-making liquid used in step s 2 includes the component of following content: 39% concentration NaOH solution 6L, IPA solution 7L, flocking additive 500mL, deionized water 112.5L.
In the present embodiment, in process for etching using the texturing slot for crystal silicon solar energy battery in embodiment 1 come Carry out making herbs into wool, and strict control Woolen-making liquid temperature is at 80 DEG C, soaking time 20min, rational technology, then using deionization Water rinsing acid adding is washed, and altogether in triplicate, finally carries out deionized water rinsing again, making herbs into wool effect is good, monocrystalline silicon battery system obtained The uniformity of suede flannelette is good.It is matched using new Woolen-making liquid, optimizes making herbs into wool effect.
Silicon wafer after making herbs into wool is diffused, wet etching, plated film, silk-screen printing and burning using conventional single silicon technology Knot, can be prepared by solar battery.
The above, only presently preferred embodiments of the present invention, are not intended to limit the invention, patent protection model of the invention It encloses and is subject to claims, it is all to change with equivalent structure made by specification and accompanying drawing content of the invention, similarly It should be included within the scope of the present invention.

Claims (7)

1. a kind of texturing slot for crystal silicon solar energy battery, the groove body (1) including upper end opening, which is characterized in that groove body It (1) is cylindrical shape, groove body (1) internal diameter is 40-60cm, and groove body (1) interior bottom is the arcwall face (2) toward evagination, and arcwall face (2) is deep Degree is h, h=4-6cm, and groove body (1) interior bottom is provided with rabbling mechanism (3), and groove body (1) bottom is provided with heating element (4).
2. a kind of texturing slot for crystal silicon solar energy battery according to claim 1, which is characterized in that groove body (1) Internal diameter is 50cm, arcwall face (2) depth h=5cm.
3. a kind of texturing slot for crystal silicon solar energy battery according to claim 1 or 2, which is characterized in that stirring Mechanism (3) is magnetic control rotor.
4. a kind of texturing slot for crystal silicon solar energy battery according to claim 1 or 2, which is characterized in that heating Element (4) is resistive heater.
5. a kind of texturing slot for crystal silicon solar energy battery according to claim 3, which is characterized in that groove body (1) The grid (5) being inside provided with above rabbling mechanism (3) is provided with the gaily decorated basket (6) equipped with silicon wafer in grid (5).
6. a kind of monocrystalline silicon process for etching, which comprises the following steps:
S1: first removing silicon wafer damaging layer, floats with the spot on NaOH solution cleaning silicon chip surface, then with deionized water to silicon wafer It washes;
S2: the obtained silicon wafer of above-mentioned steps S1 is put into the gaily decorated basket (6), then the gaily decorated basket (6) is put into the texturing slot for filling Woolen-making liquid Interior, then texturing slot starts blender using a kind of texturing slot for crystal silicon solar energy battery as claimed in claim 5 Structure (3), and heated up by heating element (4) to Woolen-making liquid, so that Woolen-making liquid temperature is maintained 80 DEG C, silicon wafer soaking time is 20min;
S3: taking out the silicon wafer that above-mentioned steps S2 is obtained, and first passes through deionized water rinsing to the silicon wafer, then carry out pickling, then pass through Deionized water rinsing, then pickling is carried out, then rinse by deionized water, then carry out pickling, it is rinsed finally by deionized water.
7. a kind of monocrystalline silicon process for etching according to claim 6, which is characterized in that the Woolen-making liquid used in step s 2 Proportion include following content component: NaOH solution 6L, the IPA solution 7L of 39% concentration, flocking additive 500mL, go from Sub- water 112.5L.
CN201910331455.4A 2019-04-23 2019-04-23 A kind of texturing slot and monocrystalline silicon process for etching for crystal silicon solar energy battery Withdrawn CN109980031A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111341879A (en) * 2020-01-07 2020-06-26 通威太阳能(眉山)有限公司 Method for manufacturing crystalline silicon solar cell and crystalline silicon solar cell
CN113690331A (en) * 2021-08-11 2021-11-23 浙江中晶新能源股份有限公司 Back contact type high-light-efficiency photovoltaic cell texturing device

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CN105220235A (en) * 2015-10-12 2016-01-06 常州捷佳创精密机械有限公司 A kind of single polycrystalline etching method
CN107988628A (en) * 2017-11-27 2018-05-04 乐山新天源太阳能科技有限公司 Silicon chip texture etching slot
CN108411364A (en) * 2018-04-03 2018-08-17 锦州华昌光伏科技有限公司 A kind of process for etching of antiradar reflectivity monocrystalline silicon
CN108831960A (en) * 2018-06-20 2018-11-16 通威太阳能(安徽)有限公司 A kind of novel monocrystalline silicon texturing slot and its etching method
CN209561425U (en) * 2019-04-23 2019-10-29 通威太阳能(成都)有限公司 A kind of texturing slot for crystal silicon solar energy battery

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Publication number Priority date Publication date Assignee Title
CN102437236A (en) * 2011-11-25 2012-05-02 中国科学院微电子研究所 Passivation method for surface of black silicon solar cell
CN105220235A (en) * 2015-10-12 2016-01-06 常州捷佳创精密机械有限公司 A kind of single polycrystalline etching method
US20180130922A1 (en) * 2015-10-12 2018-05-10 Changzhou S.C Exact Equipment Co., Ltd. Monocrystal and polycrystal texturing method
CN107988628A (en) * 2017-11-27 2018-05-04 乐山新天源太阳能科技有限公司 Silicon chip texture etching slot
CN108411364A (en) * 2018-04-03 2018-08-17 锦州华昌光伏科技有限公司 A kind of process for etching of antiradar reflectivity monocrystalline silicon
CN108831960A (en) * 2018-06-20 2018-11-16 通威太阳能(安徽)有限公司 A kind of novel monocrystalline silicon texturing slot and its etching method
CN209561425U (en) * 2019-04-23 2019-10-29 通威太阳能(成都)有限公司 A kind of texturing slot for crystal silicon solar energy battery

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111341879A (en) * 2020-01-07 2020-06-26 通威太阳能(眉山)有限公司 Method for manufacturing crystalline silicon solar cell and crystalline silicon solar cell
CN113690331A (en) * 2021-08-11 2021-11-23 浙江中晶新能源股份有限公司 Back contact type high-light-efficiency photovoltaic cell texturing device

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