CN109810615A - A kind of environmental protection coating material and preparation method thereof containing plant additive - Google Patents
A kind of environmental protection coating material and preparation method thereof containing plant additive Download PDFInfo
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- CN109810615A CN109810615A CN201811633664.6A CN201811633664A CN109810615A CN 109810615 A CN109810615 A CN 109810615A CN 201811633664 A CN201811633664 A CN 201811633664A CN 109810615 A CN109810615 A CN 109810615A
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- environmental protection
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- 238000000576 coating method Methods 0.000 title claims abstract description 51
- 239000011248 coating agent Substances 0.000 title claims abstract description 46
- 239000000654 additive Substances 0.000 title claims abstract description 45
- 230000000996 additive effect Effects 0.000 title claims abstract description 45
- 230000007613 environmental effect Effects 0.000 title claims abstract description 26
- 239000000463 material Substances 0.000 title claims abstract description 23
- 238000002360 preparation method Methods 0.000 title claims abstract description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 30
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000003822 epoxy resin Substances 0.000 claims abstract description 16
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 16
- 239000002562 thickening agent Substances 0.000 claims abstract description 12
- 229960001124 trientine Drugs 0.000 claims abstract description 12
- 239000002994 raw material Substances 0.000 claims abstract description 8
- 241000196324 Embryophyta Species 0.000 claims description 45
- 238000003756 stirring Methods 0.000 claims description 38
- 239000003795 chemical substances by application Substances 0.000 claims description 17
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 15
- 238000006243 chemical reaction Methods 0.000 claims description 13
- 241001116389 Aloe Species 0.000 claims description 12
- 235000004760 Pistacia weinmaniifolia Nutrition 0.000 claims description 12
- 241000115499 Pistacia weinmaniifolia Species 0.000 claims description 12
- 241001165494 Rhodiola Species 0.000 claims description 12
- 241000219784 Sophora Species 0.000 claims description 12
- 244000269722 Thea sinensis Species 0.000 claims description 12
- 235000011399 aloe vera Nutrition 0.000 claims description 12
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 12
- 239000010931 gold Substances 0.000 claims description 12
- 229910052737 gold Inorganic materials 0.000 claims description 12
- 235000009569 green tea Nutrition 0.000 claims description 12
- 235000011201 Ginkgo Nutrition 0.000 claims description 11
- 235000008100 Ginkgo biloba Nutrition 0.000 claims description 11
- 244000246386 Mentha pulegium Species 0.000 claims description 11
- 235000016257 Mentha pulegium Nutrition 0.000 claims description 11
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- 229920000914 Metallic fiber Polymers 0.000 claims description 11
- 235000001050 hortel pimenta Nutrition 0.000 claims description 11
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- 238000010790 dilution Methods 0.000 claims description 10
- 239000012895 dilution Substances 0.000 claims description 10
- 238000010438 heat treatment Methods 0.000 claims description 10
- 238000009413 insulation Methods 0.000 claims description 10
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 claims description 8
- 244000046146 Pueraria lobata Species 0.000 claims description 7
- 235000010575 Pueraria lobata Nutrition 0.000 claims description 7
- 229920002472 Starch Polymers 0.000 claims description 7
- 239000000243 solution Substances 0.000 claims description 7
- 235000019698 starch Nutrition 0.000 claims description 7
- 239000008107 starch Substances 0.000 claims description 7
- 230000004048 modification Effects 0.000 claims description 6
- 238000012986 modification Methods 0.000 claims description 6
- 241000168517 Haematococcus lacustris Species 0.000 claims description 5
- 241000219780 Pueraria Species 0.000 claims description 5
- 238000009833 condensation Methods 0.000 claims description 5
- 230000005494 condensation Effects 0.000 claims description 5
- 230000018044 dehydration Effects 0.000 claims description 5
- 238000006297 dehydration reaction Methods 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 241000195493 Cryptophyta Species 0.000 claims description 4
- 150000001735 carboxylic acids Chemical class 0.000 claims description 4
- 238000012856 packing Methods 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 3
- 238000007873 sieving Methods 0.000 claims description 3
- 239000004615 ingredient Substances 0.000 claims description 2
- 239000004814 polyurethane Substances 0.000 claims description 2
- 229920002635 polyurethane Polymers 0.000 claims description 2
- 239000000376 reactant Substances 0.000 claims description 2
- 230000001360 synchronised effect Effects 0.000 claims description 2
- 244000194101 Ginkgo biloba Species 0.000 claims 3
- 240000007058 Halophila ovalis Species 0.000 claims 3
- VOZKAJLKRJDJLL-UHFFFAOYSA-N 2,4-diaminotoluene Chemical compound CC1=CC=C(N)C=C1N VOZKAJLKRJDJLL-UHFFFAOYSA-N 0.000 claims 1
- 240000002853 Nelumbo nucifera Species 0.000 claims 1
- 235000006508 Nelumbo nucifera Nutrition 0.000 claims 1
- 235000006510 Nelumbo pentapetala Nutrition 0.000 claims 1
- 150000001412 amines Chemical class 0.000 claims 1
- 230000007794 irritation Effects 0.000 abstract description 2
- 230000002035 prolonged effect Effects 0.000 abstract 1
- 241000218628 Ginkgo Species 0.000 description 8
- 241000544058 Halophila Species 0.000 description 5
- 238000000034 method Methods 0.000 description 4
- 238000010792 warming Methods 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 230000036541 health Effects 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
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- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 229920002101 Chitin Polymers 0.000 description 1
- 241000790917 Dioxys <bee> Species 0.000 description 1
- 241000168525 Haematococcus Species 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 244000018633 Prunus armeniaca Species 0.000 description 1
- 235000009827 Prunus armeniaca Nutrition 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
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- 150000001336 alkenes Chemical class 0.000 description 1
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- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
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- 125000003700 epoxy group Chemical group 0.000 description 1
- 235000019441 ethanol Nutrition 0.000 description 1
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 230000000505 pernicious effect Effects 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- AGGKEGLBGGJEBZ-UHFFFAOYSA-N tetramethylenedisulfotetramine Chemical compound C1N(S2(=O)=O)CN3S(=O)(=O)N1CN2C3 AGGKEGLBGGJEBZ-UHFFFAOYSA-N 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229910052613 tourmaline Inorganic materials 0.000 description 1
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Abstract
The present invention provides a kind of environmental protection coating material and preparation method thereof containing plant additive, belong to technical field of coatings, coating includes the raw material of following mass fraction: 35-40 parts of epoxy resin, triethylene tetramine 10-15 parts modified, 5-7 parts of thickener, 10-20 parts of plant additive and 50-80 parts of water, and preparation method includes preparing plant additive, the modified triethylene tetramine of preparation and being mixed to obtain environmental protection coating material.It is added with plant additive in coating provided by the invention, coating irritation can be reduced, prolonged the service life, environment friendly and pollution-free, preparation process is simple.
Description
Technical field
The invention belongs to technical field of coatings, and in particular to a kind of to contain the environmental protection coating material of plant additive and its preparation side
Method.
Background technique
It is decorated currently, architecture indoor generallys use coating, by improving wall in one coating of surface of wall brushing
Intensity, beautify indoor environment, some functional coatings have the functions such as waterproof, corrosion resistant, but due to existing mostly using of coating
It learns raw material to be prepared, when coating is dry, a variety of chemical component volatilizations, spread indoors, influence human health, bring environment
Pollution.Existing some green coatings have mainly reduced the generation of internal escaping gas to the greatest extent during the preparation process, are passing through
Can quickly be excluded after crossing short-term ventilation, avoid the accumulation of pernicious gas, but its can not further improve it is indoor
Air.
Nano functional ecotypic environmental protection coating material (Publication No. CN104073072A) is using tourmaline air cleaning zinc oxide
Whisker composite bactericidal, natural plants medicinal powder refreshment and tranquilization air cleaning, the long-acting fragrance of chitin natural disinfection insect prevention, borax are transparent
Put fragrant fire prevention air cleaning, diatomite nano ecological, environmental protective, bentonite nano ecological, environmental protective, medical stone dissolution element promotees health and receive
Meter Gong Neng ecotypic environmental protection coating material composition, the coating are adsorbed by adding a variety of nano materials, and cost of manufacture is high, whole to make
Make complex process.
A kind of environmental protection coating material and preparation method thereof (Publication No. CN108587444A), the raw material of the environmental protection coating material is with weight
Number meter includes: 40~45 parts of urethane acrylate, 30~35 parts of epoxy group acrylic resin, and 15~30 parts of ethyl alcohol, dioxy
10~15 parts of titanium suspension of change, 10~15 parts of silica alcoholic solution, 10~15 parts of reactive diluent, titanate coupling agent 3~5
Part, it is 2~5 parts of dispersing agent, 1~5 part of ammonium hydroxide, 2~4 parts of levelling agent, 1~3 part of initiator, 1~3 part of emulsifier, main in the invention
Will be using chemical reagent as coating composition, environmental-protecting performance is poor, seriously polluted.
Summary of the invention
In view of the deficiencies of the prior art, it is an object of the present invention to provide a kind of environmental protection coating material containing plant additive and its
Preparation method, coating is interior to be added with plant additive, can reduce coating irritation, prolong the service life, environment friendly and pollution-free, preparation
Simple process.
The present invention provides the following technical solutions:
A kind of environmental protection coating material containing plant additive, raw material include epoxy resin, modified triethylene tetramine, thickener,
Plant additive and water, the mass fraction of each raw material be respectively as follows: 35-40 parts of epoxy resin, it is triethylene tetramine 10-15 parts modified,
5-7 parts of thickener, 10-20 parts of plant additive and 50-80 parts of water.
Preferably, the plant additive includes the ingredient of following mass fraction: 10-20 parts of gold kudzuvine root starch agent, aloe powder
10-15 parts of agent, 6-8 parts of cactus pulvis, 5-8 parts of peppermint pulvis, 10-15 parts of Pistacia weinmannifolia leaf pulvis, 10-15 parts of rhizome of chuanxiong pulvis,
10-30 parts of root of kirilow rhodiola pulvis, 10-15 parts of sophora flower pulvis, 10-15 parts of ginkgo leaf pulvis, haematococcus pluvialis pulvis or sea grass pulvis
5-10 parts, 10-13 parts of green tea pulvis, 10-15 parts of wilsonii rhizome pulvis and 1-2 parts of metallic fiber.
Preferably, the thickener is made of soluble polyurethane or poly- carboxylic acid.
A kind of preparation method of the environmental protection coating material containing plant additive, comprising the following steps:
S1, plant additive is prepared；
S2, modified triethylene tetramine is prepared；
S3, the plant additive that mass fraction is 35-40 parts of epoxy resin, 5-7 parts of thickener and 10-20 parts is mixed
Merging stirs evenly, and 10-15 parts of modification triethylene tetramine stirring, mixing speed 80-105r/min, stirring is then added
It after 5min, is diluted with water, continues thereafter with stirring, it is primary every ten minutes plus water, until amount of water reaches 50-80 parts, finally will
Coating packing after dilution is stand-by.
Preferably, in the S1 plant additive preparation method comprising steps of
D1, take gold Pueraria lobota, aloe, cactus, peppermint, Pistacia weinmannifolia leaf, rhizome of chuanxiong, root of kirilow rhodiola, sophora flower, ginkgo leaf, rain raw
Haematococcus or sea grass, green tea and wilsonii rhizome are cleaned respectively, and it is spare to be then ground into pulvis after drying, dehydration；
D2, metallic fiber is crushed after through 100-150 mesh sieve plate sieving, be then by mass fraction with pulvis each in D1
10-20 parts of gold kudzuvine root starch agent, 10-15 parts of aloe pulvis, 6-8 parts of cactus pulvis, 5-8 parts of peppermint pulvis, Pistacia weinmannifolia leaf pulvis
10-15 parts, 10-15 parts of rhizome of chuanxiong pulvis, 10-30 parts of root of kirilow rhodiola pulvis, 10-15 parts of sophora flower pulvis, 10-15 parts of ginkgo leaf pulvis,
Haematococcus pluvialis pulvis or 5-10 parts of sea grass pulvis, 10-13 parts of green tea pulvis, 10-15 parts of wilsonii rhizome pulvis and metal are fine
The ratio mixing of 1-2 parts of dimension, adds water and stirs uniformly, plant additive is made.
Preferably, in the S2 modified triethylene tetramine preparation method comprising steps of
G1, the triethylene tetramine under room temperature is added in the reactor with condensation and blender, is slowly added to modifying agent and stirs
Heating is mixed and synchronizes, agitator speed first stirs 10-15min with 15-20r/min, then raises speed to 20-30r/min, until stirring
It mixes uniformly, temperature rises to 50-60 DEG C at this time, then insulation reaction 1-3h；
G2, the reactant in G1 is cooled to room temperature, is then slowly added to epoxy resin ethereal solution along chamber wall, then again
It is secondary to be warming up to 60-70 DEG C, heating-up time 5-8min, then insulation reaction 1-2h；
G3, acetic acid is added, stops heating, and reactor temperature is waited voluntarily to be cooled to room temperature；
G4, dilution is added water and stirred, modified triethylene tetramine is made.
Preferably, the modifying agent in the G1 is thiocarbamide.
The beneficial effects of the present invention are:
(1) environmental protection coating material provided by the present invention, the plant additive in raw material can be evenly dispersed in coating, with
The coating of coating, gradually covering is indoor, so it is progressive original smell is diffused, improve indoor climate, there is sterilization
Deinsectization anti-corrosion function, it is nontoxic, facilitate human body health.
(2) preparation method provided by the present invention is simple, and production process is environment friendly and pollution-free.
(3) plant additive in the present invention is the mixing of various plants pulvis, and dispersing uniformity is good, and plant powder can be locked
Its tight internal component, the effect of improving plant duration, extend the service life of coating.
(4) revolving speed, mixing time and temperature control employed in modified triethylene tetramine preparation etc., improve three second
The stability of paint coatings can be improved so that reaction is more abundant in alkene tetramine and epoxy resin reaction efficiency.
Specific embodiment
Embodiment 1
S1, plant additive is prepared.
Take the raw red ball of gold Pueraria lobota, aloe, cactus, peppermint, Pistacia weinmannifolia leaf, rhizome of chuanxiong, root of kirilow rhodiola, sophora flower, ginkgo leaf, rain
Algae, green tea and wilsonii rhizome are cleaned respectively, and it is spare to be then ground into pulvis after drying, dehydration；It is passed through after metallic fiber is crushed
The sieve plate of 100 mesh is sieved, and is then 10 parts of gold kudzuvine root starch agent, 10 parts of aloe pulvis, celestial being by mass fraction with above-mentioned each pulvis
Slap 6 parts of pulvis, 5 parts of peppermint pulvis, 10 parts of Pistacia weinmannifolia leaf pulvis, 10 parts of rhizome of chuanxiong pulvis, 10 parts of root of kirilow rhodiola pulvis, sophora flower pulvis 10
Part, 10 parts of ginkgo leaf pulvis, 5 parts of haematococcus pluvialis pulvis, 10 parts of green tea pulvis, 10 parts of wilsonii rhizome pulvis and metallic fiber
1 part of ratio mixing, adds water and stirs uniformly, plant additive is made.
S2, modified triethylene tetramine is prepared.
Triethylene tetramine under room temperature is added in the reactor with condensation and blender, modifying agent thiocarbamide is slowly added to and stirs
Heating is mixed and synchronizes, agitator speed first stirs 10min with 15r/min, then raises speed to 20r/min, until stir evenly, this
Shi Wendu rises to 50 DEG C, then insulation reaction 1h；It then is cooled to room temperature, it is molten to be then slowly added to epoxy resin ether along chamber wall
Liquid is then warming up to 60 DEG C, heating-up time 5min, then insulation reaction 1-h again；Acetic acid is added, stops heating, and wait
Reactor temperature is voluntarily cooled to room temperature；Dilution is added water and stirred, modified triethylene tetramine is made.
S3, by mass fraction be 35 parts of epoxy resin, 5 parts of thickener (being made of poly- carboxylic acid) and 10 parts of plant
Additive is mixed and stirred for uniformly, and 10 parts of modification triethylene tetramine stirring, mixing speed 80r/min, stirring is then added
It after 5min, is diluted with water, continues thereafter with stirring, it is primary every ten minutes plus water, until amount of water reaches 50 parts, it finally will dilution
Coating packing afterwards can be obtained the environmental protection coating material containing plant additive for use.
Embodiment 2
S1, plant additive is prepared.
Take gold Pueraria lobota, aloe, cactus, peppermint, Pistacia weinmannifolia leaf, rhizome of chuanxiong, root of kirilow rhodiola, sophora flower, ginkgo leaf, sea grass, green
Tea and wilsonii rhizome are cleaned respectively, and it is spare to be then ground into pulvis after drying, dehydration；Through 100 mesh after metallic fiber is crushed
Sieve plate sieving, then with above-mentioned each pulvis by mass fraction be 10 parts of gold kudzuvine root starch agent, 10 parts of aloe pulvis, cactus pulvis
6 parts, 5 parts of peppermint pulvis, 10 parts of Pistacia weinmannifolia leaf pulvis, 10 parts of rhizome of chuanxiong pulvis, 10 parts of root of kirilow rhodiola pulvis, 10 parts of sophora flower pulvis, silver
10 parts of apricot leaf pulvis, 5 parts of sea grass pulvis, 10 parts of green tea pulvis, 10 parts of wilsonii rhizome pulvis and 1 part of metallic fiber of ratio are mixed
It closes, adds water and stirs uniformly, plant additive is made.
S2, modified triethylene tetramine is prepared.
Triethylene tetramine under room temperature is added in the reactor with condensation and blender, modifying agent thiocarbamide is slowly added to and stirs
Heating is mixed and synchronizes, agitator speed first stirs 5min with 10r/min, then raises speed and stirs 10min to 20r/min, and stirring is equal
Even, temperature rises to 50 DEG C at this time, then insulation reaction 1h；It then is cooled to room temperature, is then slowly added to asphalt mixtures modified by epoxy resin along chamber wall
Rouge ethereal solution is then warming up to 60 DEG C, heating-up time 5min, then insulation reaction 1h again；Acetic acid is added, stops heating,
And reactor temperature is waited voluntarily to be cooled to room temperature；Dilution is added water and stirred, modified triethylene tetramine is made.
S3, by mass fraction be 35 parts of epoxy resin, 5 parts of thickener (being made of poly- carboxylic acid) and 10 parts of plant
Additive is mixed and stirred for uniformly, and 10 parts of modification triethylene tetramine stirring, mixing speed 80r/min, stirring is then added
It after 5min, is diluted with water, continues thereafter with stirring, it is primary every ten minutes plus water, until amount of water reaches 50 parts, it finally will dilution
Coating packing afterwards can be obtained the environmental protection coating material containing plant additive for use.
Embodiment 3
S1, plant additive is prepared.
Take the raw red ball of gold Pueraria lobota, aloe, cactus, peppermint, Pistacia weinmannifolia leaf, rhizome of chuanxiong, root of kirilow rhodiola, sophora flower, ginkgo leaf, rain
Algae, green tea and wilsonii rhizome are cleaned respectively, and it is spare to be then ground into pulvis after drying, dehydration；It is passed through after metallic fiber is crushed
The sieve plate of 100 mesh is sieved, and is then 10 parts of gold kudzuvine root starch agent, 15 parts of aloe pulvis, celestial being by mass fraction with above-mentioned each pulvis
Slap 8 parts of pulvis, 8 parts of peppermint pulvis, 15 parts of Pistacia weinmannifolia leaf pulvis, 15 parts of rhizome of chuanxiong pulvis, 10 parts of root of kirilow rhodiola pulvis, sophora flower pulvis 10
Part, 10 parts of ginkgo leaf pulvis, 5 parts of haematococcus pluvialis pulvis, 10 parts of green tea pulvis, 10 parts of wilsonii rhizome pulvis and metallic fiber
1 part of ratio mixing, adds water and stirs uniformly, plant additive is made.
S2, modified triethylene tetramine is prepared.
Triethylene tetramine under room temperature is added in the reactor with condensation and blender, is slowly added to modifying agent stirring simultaneously
Synchronous heating, agitator speed first stirs 15min with 20r/min, then raises speed to 30r/min, until stir evenly, it is warm at this time
Degree rises to 60 DEG C, then insulation reaction 3h；It then is cooled to room temperature, is then slowly added to epoxy resin ethereal solution along chamber wall,
It is then warming up to 70 DEG C, heating-up time 8min again, then insulation reaction 1h；Acetic acid is added, stops heating, and wait reaction
Temperature is voluntarily cooled to room temperature in device；Dilution is added water and stirred, modified triethylene tetramine is made.
It S3, is that 40 parts of epoxy resin, 7 parts of thickener and 20 parts of plant additive are mixed and stirred for by mass fraction
Uniformly, 15 parts of modification triethylene tetramine stirring is then added, mixing speed 105r/min is diluted with water after stirring 5min,
Stirring is continued thereafter with, it is primary every ten minutes plus water, until amount of water reaches 80 parts, finally the coating after dilution is dispensed stand-by
It can be obtained the environmental protection coating material containing plant additive.
Correlated performance test is carried out to the coating obtained in embodiment 1-3, as a result such as the following table 1, as seen from table, coating appearance
Without agglomeration, without cavity, bubble-free, uniformity and good fluidity, impact resistance, OT bending, hardness, hue difference and bond strength
Reach prescribed requirement, and benzene, toluene, ethylbenzene, dimethylbenzene and free formaldehyde are not detected in coating, the feature of environmental protection is strong.
The performance test table of coating in 1 embodiment 1-3 of table
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, although referring to aforementioned reality
Applying example, invention is explained in detail, for those skilled in the art, still can be to aforementioned each implementation
Technical solution documented by example is modified or equivalent replacement of some of the technical features.It is all in essence of the invention
Within mind and principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.
Claims (7)
1. a kind of environmental protection coating material containing plant additive, which is characterized in that raw material includes epoxy resin, modified triethylene four
Amine, thickener, plant additive and water, the mass fraction of each raw material are respectively as follows: 35-40 parts of epoxy resin, modified triethylene four
10-15 parts of amine, 5-7 parts of thickener, 10-20 parts of plant additive and 50-80 parts of water.
2. a kind of environmental protection coating material containing plant additive according to claim 1, which is characterized in that the plant addition
Agent includes the ingredient of following mass fraction: 10-20 parts of gold kudzuvine root starch agent, 10-15 parts of aloe pulvis, 6-8 parts of cactus pulvis, thin
5-8 parts of lotus pulvis, 10-15 parts of Pistacia weinmannifolia leaf pulvis, 10-15 parts of rhizome of chuanxiong pulvis, 10-30 parts of root of kirilow rhodiola pulvis, sophora flower pulvis 10-
5-10 parts of 15 parts, 10-15 parts of ginkgo leaf pulvis, haematococcus pluvialis pulvis or sea grass pulvis, 10-13 parts of green tea pulvis, wilsonii
10-15 parts and metallic fiber 1-2 parts of rhizome pulvis.
3. a kind of environmental protection coating material containing plant additive according to claim 1, which is characterized in that the thickener by
Soluble polyurethane or poly- carboxylic acid composition.
4. a kind of preparation method of the environmental protection coating material containing plant additive, which comprises the following steps:
S1, plant additive is prepared；
S2, modified triethylene tetramine is prepared；
S3, the plant additive that mass fraction is 35-40 parts of epoxy resin, 5-7 parts of thickener and 10-20 parts is mixed simultaneously
It stirs evenly, 10-15 parts of modification triethylene tetramine stirring is then added, mixing speed 80-105r/min stirs 5min
Afterwards, it is diluted with water, continues thereafter with stirring, it is primary every ten minutes plus water, until amount of water reaches 50-80 parts, it finally will dilution
Coating packing afterwards is stand-by.
5. a kind of preparation method of environmental protection coating material containing plant additive according to claim 4, which is characterized in that institute
State the preparation method of plant additive in S1 comprising steps of
D1, the raw red ball of gold Pueraria lobota, aloe, cactus, peppermint, Pistacia weinmannifolia leaf, rhizome of chuanxiong, root of kirilow rhodiola, sophora flower, ginkgo leaf, rain is taken
Algae or sea grass, green tea and wilsonii rhizome are cleaned respectively, and it is spare to be then ground into pulvis after drying, dehydration；
D2, metallic fiber is crushed after through 100-150 mesh sieve plate sieving, then with pulvis each in D1 by mass fraction be gold
10-20 parts of kudzuvine root starch agent, 10-15 parts of aloe pulvis, 6-8 parts of cactus pulvis, 5-8 parts of peppermint pulvis, Pistacia weinmannifolia leaf pulvis 10-15
Part, the life of 10-15 parts of rhizome of chuanxiong pulvis, 10-30 parts of root of kirilow rhodiola pulvis, 10-15 parts of sophora flower pulvis, 10-15 parts of ginkgo leaf pulvis, rain are red
Ball algae pulvis or 5-10 parts of sea grass pulvis, 10-13 parts of green tea pulvis, 10-15 parts of wilsonii rhizome pulvis and 1-2 parts of metallic fiber
Ratio mixing, add water and stir uniformly, be made plant additive.
6. a kind of preparation method of environmental protection coating material containing plant additive according to claim 4, which is characterized in that institute
State in S2 the preparation method of modified triethylene tetramine comprising steps of
G1, the triethylene tetramine under room temperature is added in the reactor with condensation and blender, is slowly added to modifying agent stirring simultaneously
Synchronous heating, agitator speed first stir 10-15min with 15-20r/min, then raise speed to 20-30r/min, until stirring is equal
Even, temperature rises to 50-60 DEG C at this time, then insulation reaction 1-3h；
G2, the reactant in G1 is cooled to room temperature, is then slowly added to epoxy resin ethereal solution along chamber wall, then rises again
Temperature is to 60-70 DEG C, heating-up time 5-8min, then insulation reaction 1-2h；
G3, acetic acid is added, stops heating, and reactor temperature is waited voluntarily to be cooled to room temperature；
G4, dilution is added water and stirred, modified triethylene tetramine is made.
7. a kind of preparation method of environmental protection coating material containing plant additive according to claim 6, which is characterized in that institute
Stating the modifying agent in G1 is thiocarbamide.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811633664.6A CN109810615A (en) | 2018-12-29 | 2018-12-29 | A kind of environmental protection coating material and preparation method thereof containing plant additive |
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| CN201811633664.6A CN109810615A (en) | 2018-12-29 | 2018-12-29 | A kind of environmental protection coating material and preparation method thereof containing plant additive |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110482987A (en) * | 2019-09-18 | 2019-11-22 | 贵州中能高新材料有限公司 | A kind of building mortar and preparation method thereof based on gypsum |
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| WO2004087820A1 (en) * | 2003-03-31 | 2004-10-14 | Matsushita Electric Industrial Co. Ltd. | Insect repellent coating and industrial product using the same |
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Application publication date: 20190528 |