CN109776107A - A kind of ceramic percolation glaze applied to laser air brushing - Google Patents
A kind of ceramic percolation glaze applied to laser air brushing Download PDFInfo
- Publication number
- CN109776107A CN109776107A CN201711109200.0A CN201711109200A CN109776107A CN 109776107 A CN109776107 A CN 109776107A CN 201711109200 A CN201711109200 A CN 201711109200A CN 109776107 A CN109776107 A CN 109776107A
- Authority
- CN
- China
- Prior art keywords
- glaze
- air brushing
- laser air
- ceramic
- laser
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
- Finishing Walls (AREA)
Abstract
A kind of ceramic percolation glaze applied to laser air brushing of the present invention, which is characterized in that it is the soluble inorganic metal salt of color development, solvent and can adjust the aqueous glaze with penetration property that auxiliary agent prepares；It is printed in a manner of laser air brushing in the ceramic brick body for having applied ground coat enamel and overglaze, then sprays water and help infiltration, enter roller kiln burning at firing temperature is 1080 DEG C~1200 DEG C, firing period 40~85 minutes.The present invention is suitable for laser air brushing, is coloured using chemical reaction occurs between various salts and glaze.That the more external import of cost can reduce by 20% or so using the advantages of this method, can complete import substitutes, have a vast market economic benefit；Controllability during production application and controllability improve, the more abundant diversification of product color pattern, have levels, three-dimensional sense it is strong.
Description
Technical field
The present invention relates to technical field of ceramic production, are in particular to design a kind of ceramics infiltration applied to laser air brushing
Saturating glaze.
Background technique
Laser air brushing technology is known as a kind of " direct writing technology " for having great practical value, has equipment simple, heavy
The advantages such as the thinner figure of product, environmental-friendly.With the development of digital technology with it is universal, laser air brushing technology is in ceramic industry
Field is gradually applied, and compared with silk screen roller printing, inkjet printing has many unrivaled advantages, it can be in the short period
Inside reach requirement, be suitble to that ceramic decoration is personalized, multi-color, or even completes some highly difficult can not be realized with silk screen roller flower machine
Color pattern.The Ceramic Tiles produced using this new pattern laser spray-drawing process, surface patterning, color and texture will generate
Breakthrough progress, it is the another major technological breakthrough of ceramic tile production field after roller printing equipment.High-performance, energy are suitable
The ceramic glaze ink of sharp spray printing is the basis that laser air brushing technology is applied on ceramics, at present the domestic laser air brushing glaze used
Material is surface decorating method, decoration can not be realized in polished bricks, and using external imported product, expensive.
The penetration glaze product that produces on the market is mostly by thickening into glaze soluble metallic salt now, then uses silk screen
Printing technique, equipment are printed on ceramic body surface, its shortcoming is that texture sophistication is inadequate, pattern is stereotyped, do not become
Change, pattern and color are limited at most three, four kind by printing machine.
Patent 200910311821.6 proposes a kind of ceramic laser air brushing brown and preparation method thereof.Being will be former
Material is refined and is uniformly mixed, 1100~1300 DEG C of firings, carries out micronization processing to crude pigment product using ultra-fine equipment；Using
Classifying equipoment handles micronization powder, and separation micronization powder obtains finished product.Patent 200910311976 proposes one kind
The preparation method of ceramic laser air brushing zirconium-iron pink pigment.It is to add water to be made into mixed liquor raw material and mineralizer, by mixed liquor
By spray drying granulation, powder is obtained, powder is calcined at 900~1100 DEG C；The material rinsed clean that will have been calcined dries
Dry, crushing, obtains product.This two inventions belong to monochromatic colorant, belong to incrustation colorant, and effect is different from infiltration
Glaze, cannot generate that rich in color, texture is fine and smooth, pattern is full of variety, the imitation natural stone without repeatability after polished bricks product polishing
Material effect.
Summary of the invention
The purpose of the present invention is for the deficiencies of the prior art and provide a kind of ceramic percolation applied to laser air brushing
Glaze.
It is a further object of the present invention to provide one kind can be applied to ceramic surface decoration, especially ceramic polished brick product side
Face can make complex pattern, improve production efficiency, and the use for reaching good decorative effect is suitable for the ceramics infiltration of laser air brushing
The method of saturating glaze production Ceramic Tiles.
The present invention is attained in that using following technical solution
A kind of ceramic percolation glaze suitable for laser air brushing, which is characterized in that it be with can color development soluble inorganic gold
Belong to salt, solvent and adjusts the aqueous glaze with penetration property that auxiliary agent is prepared.
As a further illustration of the above scheme, it is described can color development soluble metallic salt be frerrous chloride, sodium hypochlorite,
One or more of copper carbonate, iron sulfide, silica；Solvent is deionized water, acetaldehyde, bromoethane, sodium iodide, dimethyl ether
One or more of mixed solution.
The viscosity of the aqueous glaze is 1-10mpas, and conductivity is greater than 100ms/m, pH value 7-8.5.
The adjusting is helped including surfactant, viscosity modifier, bleeding agent, pH value adjustment agent, colorant and preservative
One or more of.
The surfactant is OP-10 nonionic surfactant, SE-10 nonionic surfactant, SP3 nonionic
One of surfactant, alkyl phenol polyoxyethylene ether are a variety of；Viscosity modifier is polyphosphazene polymer bromoethane, carboxymethyl fibre
Dimension element；Bleeding agent is NP-10, NP-15, SJFC bleeding agent, lauramide alkanol sodium sulphate, one in acylamino- sulfamate
Kind or several mixing；PH value adjustment agent is diethanol amine, triethanolamine, azanol, sodium hydroxide；Colorant uses methyl orange, first
The one or more such as base indigo plant and dyestuff Huang；Preservative is phenol.
A method of the ceramic percolation glaze suitable for laser air brushing is used for ceramic tile production, which is characterized in that it includes
Following steps:
A) soluble metallic salt of color development, solvent and it will can adjust auxiliary agent and reconcile as the laser air brushing of osmotic effect can be achieved
Ink, the glaze with high temperature firing colour generation property that can be used in laser air brushing；
B) configured ink is printed on dry adobe surface in a manner of laser air brushing；
C) water spray helps infiltration, increases osmotic effect, color glaze is made to penetrate into adobe；
D) enter roller kiln burning at, 1080 DEG C~1200 DEG C of firing temperature, fire the period 40~85 minutes.
The attainable beneficial effect of this programme institute is:
The penetration glaze that the present invention uses is permeable in the green body that surface has concave-convex effect, still can be after polishing
Polished bricks surface forms decorative pattern, has started a kind of new polished bricks product decoration method, has had a vast market foreground, together
Shi Chengben more current incrustation ink-jet glaze is significantly reduced, and economic benefit is prominent；During production application can
Modulability and controllability improve, and simple production conversion process can effectively improve the raising for producing excellent rate.Product pattern figure
The more abundant diversification of case, have levels, three-dimensional sense it is strong.
Specific embodiment
Embodiment 1
1,4 parts of bromoethane, 6 parts of dimethyl ether, 9 parts of copper carbonates to be added in 100 parts of deionized water, and it is stirred obtained water
Property solution；
2, surfactant alkyl phenol polyoxyethylene ether 0.15%, SP3 nonionic table are sequentially added in mixed solution (1)
Face activating agent 0.2%, viscosity modifier carboxymethyl cellulose 0.2%, NP-15 bleeding agent 0.15%, acylamino- sulfamate
0.2%, addition triethanolamine adjusting pH value to 7.5-8.0, viscosity 4-8mpas adds 0.06% methyl blue, obtains indigo plant
Color permeates glaze solution；
3, the solution is added in ceramic laser spray drawing apparatus, surface temperature is sprayed at 45 DEG C -60 DEG C with marble grain
600mm*600mm*11mm specification adobe surface；
4, adobe is entered in roller kilns, is burnt into 65 minutes with 1210 DEG C of high temperature；
5, be burnt into after adobe struck off through surface, polish after obtain the ceramic polished brick with clear dark-brown stone pattern.
What has been described above is only a preferred embodiment of the present invention, it is noted that for those of ordinary skill in the art
For, without departing from the concept of the premise of the invention, various modifications and improvements can be made, these belong to the present invention
Protection scope.
Claims (3)
1. a kind of ceramic percolation glaze suitable for laser air brushing, which is characterized in that it be with can color development soluble inorganic metal
Salt, solvent and the aqueous glaze with penetration property for adjusting auxiliary agent preparation.
2. a kind of ceramic percolation glaze suitable for laser air brushing according to claim 1, which is characterized in that it is described can color development
Soluble metallic salt be one or more of zinc sulfate, sodium hypochlorite, copper carbonate, iron sulfide, silica；Solvent is to go
One or more of ionized water, acetaldehyde, bromoethane, sodium iodide, dimethyl ether mixed solution.
3. a kind of ceramic percolation glaze suitable for laser air brushing according to claim 1, which is characterized in that the aqueous glaze
The viscosity of material is 1-10mpas, and conductivity is greater than 100ms/m, pH value 7-8.5.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711109200.0A CN109776107A (en) | 2017-11-11 | 2017-11-11 | A kind of ceramic percolation glaze applied to laser air brushing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711109200.0A CN109776107A (en) | 2017-11-11 | 2017-11-11 | A kind of ceramic percolation glaze applied to laser air brushing |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109776107A true CN109776107A (en) | 2019-05-21 |
Family
ID=66484598
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711109200.0A Pending CN109776107A (en) | 2017-11-11 | 2017-11-11 | A kind of ceramic percolation glaze applied to laser air brushing |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109776107A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110922210A (en) * | 2019-12-04 | 2020-03-27 | 山东雅美特新材料科技股份有限公司 | Permeable color-developing slurry and use method thereof in ceramic plate production |
-
2017
- 2017-11-11 CN CN201711109200.0A patent/CN109776107A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110922210A (en) * | 2019-12-04 | 2020-03-27 | 山东雅美特新材料科技股份有限公司 | Permeable color-developing slurry and use method thereof in ceramic plate production |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107235632B (en) | Preparation method of ceramic tile with high-simulation 3D digital glaze spraying three-dimensional pattern effect function | |
| CN102795892B (en) | Soluble salt ceramic tile and production method thereof | |
| CN102249741A (en) | Ceramic penetration glaze suitable for spray ink printing and method for using same to produce ceramic tiles | |
| CN106193529B (en) | Eliminate colorful Dali stone ceramic tile white border line manufacturing process and its colorful Dali stone ceramic tile | |
| CN105777089B (en) | A kind of transparent brick and preparation method thereof | |
| CN106518170B (en) | Fancy infiltration method for ceramic tile | |
| CN107685383B (en) | Production process of antique brick ceramic | |
| CN106365694B (en) | Ceramic tile with three-dimensional pattern and combined ceramic ink and production method thereof | |
| CN105086698B (en) | A kind of production method of flexible finishing material | |
| CN108996908A (en) | A kind of printing polishing glaze and preparation method thereof and the application method in tile product | |
| CN105753465B (en) | A kind of preparation method of super flat mirror face art mural of porcelain and its obtained product | |
| CN101372422A (en) | In-glaze decoration method for bright red glazed ceramic | |
| CN107417303A (en) | The manufacture method of ink-jet pattern permeating tile under a kind of glaze | |
| CN106800423B (en) | A kind of preparation method for seeping flower ceramic tile | |
| CN108238819A (en) | A kind of high texture Antique Imitation Tiles with fluorescence and preparation method thereof | |
| CN101993237B (en) | Method for manufacturing low-temperature red clay colour-painted and glazed ecological ceramic product | |
| CN102786833A (en) | Ceramic inkjet ink composition and ceramic glazed tile | |
| CN104446344A (en) | Preparation method of slim mirror-plane artistic porcelain painting and product prepared by preparation method | |
| CN107141025A (en) | A kind of marble plating metal modelled after an antique throws the preparation method of glaze Ceramic Tiles | |
| CN109776107A (en) | A kind of ceramic percolation glaze applied to laser air brushing | |
| CN105801176A (en) | Once-fired metal glaze surface deep-processing method | |
| CN105712712B (en) | A kind of manufacturing method of Scagliola ceramics | |
| CN108046603A (en) | A kind of production method of the Ceramic Tiles of formula multiclass | |
| CN106007662B (en) | A kind of ink-jet marble ceramic tile | |
| CN107500740B (en) | Environment-friendly black ceramic tile and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20190521 |