CN109735400B - Special wet lotion for cashmere woolen clothes - Google Patents
Special wet lotion for cashmere woolen clothes Download PDFInfo
- Publication number
- CN109735400B CN109735400B CN201910025958.9A CN201910025958A CN109735400B CN 109735400 B CN109735400 B CN 109735400B CN 201910025958 A CN201910025958 A CN 201910025958A CN 109735400 B CN109735400 B CN 109735400B
- Authority
- CN
- China
- Prior art keywords
- percent
- sodium
- salt
- surfactant
- anionic surfactant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Detergent Compositions (AREA)
Abstract
The invention discloses a special wet lotion for cashmere woolen clothes, which comprises the following raw materials in percentage by mass: 2.3 to 2.7 percent of anionic surfactant, 0.7 to 0.8 percent of alkylphenol polyoxyethylene, 0.2 to 0.3 percent of cationic surfactant, 0.1 to 0.2 percent of organic sodium salt and 0.08 to 0.10 percent of sodium hydroxide. The invention organically combines the dirt-removing power of the anionic surfactant, the oil-removing power of the nonionic surfactant and the softening function of the cationic surfactant together, and adopts a reasonable proportion to exert the functions of the anionic surfactant, the nonionic surfactant and the cationic surfactant to the maximum extent. The woolen fabric is always in a soft and fluffy state in the whole washing process, so that the phenomenon of tightness of the fabric is avoided, and stains are favorably stripped in the washing process. The invention simplifies the washing process, improves the washing efficiency, achieves the effect that the washing is finished in one step and is smooth without rinsing.
Description
Technical Field
The invention relates to the technical field of daily chemical articles, in particular to a special wet cleaning agent for cashmere woolen clothes.
Background
Clothes made of wool fiber fabrics are easy to shrink and deform after being washed by water, so the clothes are generally washed in a dry cleaning mode; most of dry cleaning agents adopted in the current market are tetrachloroethylene, petroleum solvents and the like, the solvents belong to volatile nonrenewable resources, particularly tetrachloroethylene, the solvents have a destructive effect on the atmosphere, and the residual liquid of the solvents also has serious pollution on underground water resources, so that the environmental protection department requires that each laundry must use a fifth generation of totally-closed dry cleaning equipment, which undoubtedly increases the cost of the laundry, and finally, the customers buy the list.
In order to solve the problems, the prior art discloses a detergent for washing woolen clothes, which is designed according to the principle that a neutral detergent is firstly adopted for washing, and then cation is used for softening and recovering to be soft, so that the problem of washing the woolen clothes is solved in principle, but from the practical application effect, the phenomenon that the fabric is tight after washing and the washing process is complicated still exists.
Therefore, through the improvement of the formula and the process, the special wet cleaning agent for the cashmere woolen clothes, which has the advantages of simple cleaning process and high cleaning efficiency and can effectively avoid the shrinkage deformation of the washed fabric of the woolen clothes, is very necessary.
Disclosure of Invention
In order to solve the technical problem, the invention provides a special wet cleaning agent for cashmere woolen clothes, which comprises the following raw materials in percentage by mass: 2.3 to 2.7 percent of anionic surfactant, 0.7 to 0.8 percent of alkylphenol polyoxyethylene, 0.2 to 0.3 percent of cationic surfactant, 0.1 to 0.2 percent of organic sodium salt and 0.08 to 0.10 percent of sodium hydroxide.
As a preferable technical scheme, the anionic surfactant is selected from one or more of alkyl benzene sulfonic acid, alkyl diphenyl ether disulfonate, fatty alcohol polyoxyethylene ether sulfosuccinic acid half-ester disodium salt, fatty alcohol polyoxyethylene ether sodium sulfate and alkyl ether sulfonated sodium succinate.
As a preferable technical scheme, the anionic surfactant is a composition of alkyl benzene sulfonic acid and fatty alcohol-polyoxyethylene ether sodium sulfate, and the corresponding weight parts are (1-5): (1-3).
As a preferable technical scheme, the cationic surfactant is a quaternary ammonium salt surfactant.
As a preferable technical scheme, the organic sodium salt is selected from one or more of sodium formate, sodium acetate, sodium oxalate, sodium citrate and sodium ethylene diamine tetracetate.
As a preferable technical scheme, the method also comprises the following raw materials: 0.01-0.1% of inorganic salt, 0.01-0.5% of preservative, 0.01-0.1% of fluorescent whitening agent, 0.01-0.1% of biological enzyme and the balance of water.
As a preferable technical scheme, the inorganic salt is selected from one or more of chloride salt, carbonate salt, nitrate salt and fluoride salt.
As a preferable technical scheme, the weight ratio of the inorganic salt to the organic sodium salt is (0.05-3): 10.
as a preferable technical scheme, the preservative is selected from one or more of inorganic sulfides, cason, DMDM hydantoin, iodopropynyl n-butyl carbamate, methylparaben, ethylparaben, propylparaben, cetylpyridinium chloride, benzalkonium chloride, chlorphenesin, poly (aminopropyl) biguanide, chlorhexidine digluconate, benzethonium chloride, phenoxyethanol, benzoic acid, sodium benzoate, caprylyl hydroximic acid, sodium dehydroacetate, gluconolactone, pentanediol, hexanediol and p-hydroxyacetophenone.
As a preferable technical scheme, the preservative is a combination of inorganic sulfide and cason, and the weight ratio of the preservative to the organic sulfide is 10: (0.05-3).
Compared with the prior art, the invention has the beneficial effects that: the invention organically combines the dirt-removing power of the anionic surfactant, the oil-removing power of the nonionic surfactant and the softening function of the cationic surfactant together, and adopts a reasonable proportion to exert the functions of the anionic surfactant, the nonionic surfactant and the cationic surfactant to the maximum extent. The woolen fabric is in a soft and fluffy state all the time in the whole washing process, so that the phenomenon of tightness of the fabric is avoided, and the woolen fabric is more beneficial to stripping stains in the washing process. In order to simplify the washing process, improve the washing efficiency and achieve the purposes of completing the washing in one step and not rinsing, the invention reduces the content of the surfactant, so that the detergent residue on the clothes can be ignored after the clothes are dried. Meanwhile, the organic sodium salt is added in the formula, so that stain ions in the washing process are suspended to the maximum extent in the washing liquid with low surface active agent content, and are removed to the maximum extent in the spin-drying and liquid-removing process.
Detailed Description
The disclosure may be understood more readily by reference to the following detailed description of preferred embodiments of the invention and the examples included therein. Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. In case of conflict, the present specification, including definitions, will control.
For purposes of the following detailed description, it is to be understood that the invention may assume various alternative variations and step sequences, except where expressly specified to the contrary. Moreover, other than in any operating examples, or where otherwise indicated, all numbers expressing, for example, quantities of ingredients used in the specification and claims are to be understood as being modified in all instances by the term "about". Accordingly, unless indicated to the contrary, the numerical parameters set forth in the following specification and attached claims are approximations that may vary depending upon the desired properties to be obtained by the present invention. At the very least, and not as an attempt to limit the application of the doctrine of equivalents to the scope of the claims, each numerical parameter should at least be construed in light of the number of reported significant digits and by applying ordinary rounding techniques.
Notwithstanding that the numerical ranges and parameters setting forth the broad scope of the invention are approximations, the numerical values set forth in the specific examples are reported as precisely as possible. Any numerical value, however, inherently contains certain errors necessarily resulting from the standard deviation found in their respective testing measurements.
When a range of values is disclosed herein, the range is considered to be continuous and includes both the minimum and maximum values of the range, as well as each value between such minimum and maximum values. Further, when a range refers to an integer, each integer between the minimum and maximum values of the range is included. Further, when multiple range-describing features or characteristics are provided, the ranges may be combined. In other words, unless otherwise indicated, all ranges disclosed herein are to be understood to encompass any and all subranges subsumed therein. For example, a stated range from "1 to 10" should be considered to include any and all subranges between the minimum value of 1 and the maximum value of 10. Exemplary subranges of the range 1 to 10 include, but are not limited to, 1 to 6.1, 3.5 to 7.8, 5.5 to 10, and the like.
The invention provides a special wet lotion for cashmere woolen clothes, which comprises the following raw materials in percentage by mass: 2.3 to 2.7 percent of anionic surfactant, 0.7 to 0.8 percent of alkylphenol polyoxyethylene, 0.2 to 0.3 percent of cationic surfactant, 0.1 to 0.2 percent of organic sodium salt and 0.08 to 0.10 percent of sodium hydroxide.
Anionic surfactants
As a preferable technical scheme, the anionic surfactant is selected from one or more of alkyl benzene sulfonic acid, alkyl diphenyl ether disulfonate, fatty alcohol polyoxyethylene ether sulfosuccinic acid half-ester disodium salt, fatty alcohol polyoxyethylene ether sodium sulfate and alkyl ether sulfonated sodium succinate.
As a preferable technical scheme, the anionic surfactant is a composition of alkyl benzene sulfonic acid and sodium fatty alcohol polyoxyethylene ether sulfate; preferably a composition of dodecyl benzene sulfonic acid and sodium laureth sulfate, and the corresponding weight ratio is (1-5): (1-3); the weight ratio is preferably (1.3-1.5): (1-1.2), more preferably 1.4: 1.1.
alkylphenol ethoxylates
In the application, alkylphenol polyoxyethylene is a polyoxyethylene type nonionic surfactant and has the characteristics of stable property, acid and alkali resistance, low cost and the like.
As a preferred technical solution, the alkylphenol polyoxyethylene ether in the present application is nonylphenol polyoxyethylene ether.
Cationic surfactant
As a preferred technical scheme, the cationic surfactant is a quaternary ammonium salt surfactant;
as a preferred technical scheme, the quaternary ammonium salt surfactant is selected from one or more of alkyl trimethyl ammonium salt, dialkyl dimethyl ammonium salt and alkyl dimethyl benzyl ammonium salt; preferably dodecyl trimethyl ammonium chloride.
The inventor finds that compounding the anionic surfactant, the nonionic surfactant and the cationic surfactant does not cause the phenomenon of 'tightness' of the fabric, and the invention achieves higher dirt-removing capacity under the condition of lower content of the surfactant, and meanwhile, stains are easier to be stripped in the washing process. The inventor also finds that when the anionic surfactant is a composition of dodecyl benzene sulfonic acid and sodium laureth sulfate, the anionic surfactant not only has the best detergency, but also does not cause the phenomenon of 'tightness' of the fabric, and meanwhile, when the corresponding weight ratio is (1-5): (1-3), particularly 1.4: 1.1, the detergent also has the best stability, does not generate layering and precipitation phenomena, and solves the problem that in the same detergent formula, an anionic surfactant meets a cationic surfactant, and the performances of the anionic surfactant and the cationic surfactant are easily counteracted to cause the detergent to lose the washing effect. The inventor speculates that the possible reasons are that the dodecylbenzene sulfonic acid has excellent detergency, the sodium laureth sulfate synergistically improves the detergency, and the large-steric-hindrance polyoxyethylene group increases the volume of the polar head of the sodium laureth sulfate, so that the polar head can be prevented from aggregating and precipitating due to too tight combination when positive ions and negative ions meet each other at a specific ratio. The compounding of the nonionic surfactant, namely the nonylphenol polyoxyethylene ether can ensure that the cleanliness is at a better level, promote the convergence of the dodecylbenzene sulfonic acid on the scale layer on the surface of the woolen product, relieve the entanglement and occlusion of wool fibers in the washing process and avoid the phenomenon of 'tightness' of the fabric.
Organic sodium salt
As a preferable technical scheme, the organic sodium salt is selected from one or more of sodium formate, sodium acetate, sodium oxalate, sodium citrate and sodium ethylene diamine tetracetate; preferably sodium edetate.
As a preferable technical scheme, the method also comprises the following raw materials: 0.01-0.1% of inorganic salt, 0.01-0.5% of preservative, 0.01-0.1% of fluorescent whitening agent, 0.01-0.1% of biological enzyme and the balance of water.
Inorganic salt
As a preferred technical scheme, the inorganic salt is selected from one or more of chloride salt, carbonate salt, nitrate salt and fluoride salt; as a preferred technical scheme, the inorganic salt is selected from one or more of chloride salt, carbonate salt, nitrate salt and fluoride salt; the chloride salt is selected from one or more of sodium chloride, magnesium chloride, calcium chloride and barium chloride; the carbonate is selected from one or more of sodium carbonate and barium carbonate; the nitrate is selected from one or more of potassium nitrate, sodium nitrate and sodium nitrite; the fluoride salt is selected from one or more of lithium fluoride, magnesium fluoride, potassium fluoride and calcium fluoride; as a preferred technical solution, the inorganic salt is calcium chloride.
As a preferable technical scheme, the weight ratio of the inorganic salt to the organic sodium salt is (0.05-3): 10, preferably 1: 10.
the inventor finds that when the organic sodium salt is sodium ethylene diamine tetracetate, stains can be removed to a large extent, and the cleaning and stain removal capacity is improved. The inventor also finds that the sodium ethylene diamine tetracetate and the inorganic salt can synergistically improve the washing capacity when being compounded, and particularly the weight ratio of the inorganic salt to the organic sodium salt is (0.05-3): 10, the detergent has the best washing and decontaminating capacity, and the inventor also unexpectedly finds that the weight ratio of the calcium chloride to the sodium ethylene diamine tetracetate is 10: (0.05-3), the detergent residue can be effectively reduced. The inventor conjectures that sodium ethylene diamine tetracetate makes the washed dirt ions in a suspended state and not attached to fabric fibers any more, so that the dirt is easily removed to the maximum extent in the liquid-removing and spin-drying process, and the aim of cleaning clothes is fulfilled; the calcium ions can increase the activity of the biological enzyme in the application, so that the cleanliness is improved, and the detergent residue is further reduced by utilizing the degradation function of the biological enzyme; however, the existence of calcium ions also reduces the washing capacity of the surfactant, and the sodium ethylene diamine tetracetate in the application can furthest relieve the influence of the calcium ions on the surfactant while ensuring the activity of the biological enzyme by capturing the calcium ions in a proper amount, so that the application has the best washing effect.
Preservative
As a preferred technical scheme, the preservative is selected from one or more of inorganic sulfides, cason, DMDM hydantoin, iodopropynyl n-butyl carbamate, methylparaben, ethylparaben, propylparaben, cetylpyridinium chloride, benzalkonium chloride, chlorphenesin, poly (aminopropyl) biguanide, chlorhexidine digluconate, benzethonium chloride, phenoxyethanol, benzoic acid, sodium benzoate, caprylyl hydroximic acid, sodium dehydroacetate, gluconolactone, pentanediol, hexanediol, and p-hydroxyacetophenone; as a preferred technical scheme, the inorganic sulfide is selected from one or more of sulfide, hydrosulfide, polysulfide, sulfite and bisulfite; preferably, the inorganic sulfide is selected from one or more of sodium hydrosulfide, sodium sulfide, sodium disulfide, sodium polysulfide, sulfite, bisulfite, sodium sulfite and sodium bisulfite; preferably, the inorganic sulfide is sodium metabisulfite.
As a preferred technical scheme, the preservative is a combination of sodium metabisulfite and cason, and the corresponding weight ratio is 10: (0.5-3), preferably 10: 1.
the inventors have found that, in the present application, when the preservative is a combination of sodium metabisulfite and cason, the respective weight ratio is in particular 10: (0.5-3), the antiseptic and bactericidal effects can be maximized in the case of a smaller amount. In addition, the inventor surprisingly finds that when the preservative is a combination of sodium metabisulfite and kasons, the stability of the application is improved, and simultaneously the aim of counteracting the oxidation of wool fabrics in the air can be achieved, so that the washed clothes keep the original color. The inventors speculate that the possible reasons for this are that sodium metabisulfite can act synergistically with cason to improve the preservative performance and at the same time prevent the active ingredients of the present application from being converted to an unstable structure in an aqueous solution and losing the washing effect. In addition, sodium metabisulfite can counteract the oxidation of wool fabric in air.
The application also provides a preparation method of the special wet lotion for the cashmere woolen clothes, which comprises the following steps:
adding water into anionic surfactant, stirring at 40-60 deg.C, adding alkylphenol polyoxyethylene, stirring, cooling to 30-40 deg.C, and adding cationic surfactant, organic sodium salt, sodium hydroxide, inorganic salt, antiseptic, fluorescent whitening agent, and biological enzyme.
The present invention will be specifically described below by way of examples. It should be noted that the following examples are only for illustrating the present invention and should not be construed as limiting the scope of the present invention, and that the insubstantial modifications and adaptations of the present invention by those skilled in the art based on the above disclosure are still within the scope of the present invention.
In addition, the starting materials used are all commercially available, unless otherwise specified. For example: dodecyl trimethyl ammonium chloride model number is 1231; nonylphenol polyoxyethylene ether is TX-10; the specification of the dodecyl benzene sulfonic acid is 96 percent, and the dodecyl benzene sulfonic acid is purchased from the Jinan remote chemical engineering; the sodium lauryl polyoxyethylene ether sulfate with the specification of 70 percent is purchased from Luke chemical industry, Limited liability company in Shouguang city; the Kathon specification is 4 percent, and the Kathon is purchased from Jinan, China and North China Fine chemical Co., Ltd; the fluorescent brightener is ROT-C-2 and is purchased from Henan Ruizi Special chemical engineering Co., Ltd; the bio-enzyme model is CY-150, purchased from Zibobeter Bio-enzyme, Inc.
Examples
Example 1
Embodiment 1 provides a special wet lotion for cashmere woolen clothes, which comprises the following raw materials in percentage by mass: 2.5 percent of anionic surfactant, 0.75 percent of alkylphenol polyoxyethylene, 0.25 percent of cationic surfactant, 0.15 percent of organic sodium salt, 0.09 percent of sodium hydroxide, 0.015 percent of inorganic salt, 0.22 percent of preservative, 0.01 percent of fluorescent whitening agent, 0.01 percent of biological enzyme and the balance of water.
Wherein the anionic surfactant is a composition of dodecyl benzene sulfonic acid and sodium laureth sulfate, and the corresponding weight ratio is 1.4: 1.1; the alkylphenol polyoxyethylene ether is nonylphenol polyoxyethylene ether; the cationic surfactant is dodecyl trimethyl ammonium chloride; the organic sodium salt is sodium ethylene diamine tetracetate; the inorganic salt is calcium chloride, and the weight ratio of the inorganic salt to the organic sodium salt is 1: 10; the preservative is a combination of sodium metabisulfite and cason, and the corresponding weight ratio is 10: 1.
in another aspect, the present invention provides a preparation method of the special wet lotion for cashmere woolen clothes, including the following steps:
mixing dodecylbenzene sulfonic acid and lauryl alcohol polyoxyethylene ether sodium sulfate, adding water into the mixture, uniformly stirring at 50 ℃, adding nonylphenol polyoxyethylene ether, uniformly stirring, cooling to 30 ℃, and adding dodecyl trimethyl ammonium chloride, sodium ethylene diamine tetracetate, sodium hydroxide, calcium chloride, sodium metabisulfite, kasong, a fluorescent whitening agent and biological enzyme to obtain the fluorescent whitening agent.
Example 2
Embodiment 2 provides a special wet lotion for cashmere woolen clothes, which comprises the following raw materials in percentage by mass: 2.5 percent of anionic surfactant, 0.75 percent of alkylphenol polyoxyethylene, 0.25 percent of cationic surfactant, 0.01 percent of organic sodium salt, 0.09 percent of sodium hydroxide, 0.015 percent of inorganic salt, 0.01 to 0.5 percent of preservative, 0.01 to 0.1 percent of fluorescent whitening agent, 0.01 to 0.1 percent of biological enzyme and the balance of water.
Wherein the anionic surfactant is a composition of dodecyl benzene sulfonic acid and sodium laureth sulfate, and the corresponding weight ratio is 1.4: 1.1; the alkylphenol polyoxyethylene ether is nonylphenol polyoxyethylene ether; the cationic surfactant is dodecyl trimethyl ammonium chloride; the organic sodium salt is sodium ethylene diamine tetracetate; the inorganic salt is calcium chloride; the preservative is a combination of sodium metabisulfite and cason, and the corresponding weight ratio is 10: 1.
in another aspect, the present invention provides a method for preparing the wet lotion for cashmere woolen clothes, which is the same as in example 1.
Example 3
Embodiment 3 provides a special wet lotion for cashmere woolen clothes, which comprises the following raw materials in percentage by mass: 2.5 percent of anionic surfactant, 0.75 percent of alkylphenol polyoxyethylene, 0.25 percent of cationic surfactant, 1 percent of organic sodium salt, 0.09 percent of sodium hydroxide, 0.015 percent of inorganic salt, 0.22 percent of preservative, 0.01 percent of fluorescent whitening agent, 0.01 percent of biological enzyme and the balance of water.
Wherein the anionic surfactant is a composition of dodecyl benzene sulfonic acid and sodium laureth sulfate, and the corresponding weight ratio is 1.4: 1.1; the alkylphenol polyoxyethylene ether is nonylphenol polyoxyethylene ether; the cationic surfactant is dodecyl trimethyl ammonium chloride; the organic sodium salt is sodium ethylene diamine tetracetate; the inorganic salt is calcium chloride; the preservative is a combination of sodium metabisulfite and cason, and the corresponding weight ratio is 10: 8.
in another aspect, the present invention provides a method for preparing the wet lotion for cashmere woolen clothes, which is the same as in example 1.
Example 4
Embodiment 4 provides a special wet lotion for cashmere woolen clothes, which comprises the following raw materials in percentage by mass: 2.5 percent of anionic surfactant, 0.75 percent of alkylphenol polyoxyethylene, 0.25 percent of cationic surfactant, 0.15 percent of organic sodium salt, 0.09 percent of sodium hydroxide, 0.015 percent of inorganic salt, 0.22 percent of preservative, 0.01 percent of fluorescent whitening agent, 0.01 percent of biological enzyme and the balance of water.
Wherein the anionic surfactant is a composition of dodecyl benzene sulfonic acid and sodium laureth sulfate, and the corresponding weight ratio is 1.4: 1.1; the alkylphenol polyoxyethylene ether is nonylphenol polyoxyethylene ether; the cationic surfactant is dodecyl trimethyl ammonium chloride; the organic sodium salt is sodium ethylene diamine tetracetate; the inorganic salt is calcium chloride, and the weight ratio of the inorganic salt to the organic sodium salt is 1: 10; the preservative is a combination of sodium metabisulfite and cason, and the corresponding weight ratio is 10: 0.1.
in another aspect, the present invention provides a method for preparing the wet lotion for cashmere woolen clothes, which is the same as in example 1.
Example 5
Embodiment 5 provides a special wet lotion for cashmere woolen clothes, which comprises the following raw materials in percentage by mass: 2.5 percent of anionic surfactant, 0.75 percent of alkylphenol polyoxyethylene, 0.25 percent of cationic surfactant, 0.15 percent of organic sodium salt, 0.09 percent of sodium hydroxide, 0.015 percent of inorganic salt, 0.22 percent of preservative, 0.01 percent of fluorescent whitening agent, 0.01 percent of biological enzyme and the balance of water.
Wherein the anionic surfactant is a composition of dodecyl benzene sulfonic acid and sodium laureth sulfate, and the corresponding weight ratio is 1.4: 1.1; the alkylphenol polyoxyethylene ether is nonylphenol polyoxyethylene ether; the cationic surfactant is dodecyl trimethyl ammonium chloride; the organic sodium salt is sodium ethylene diamine tetracetate; the inorganic salt is calcium chloride, and the weight ratio of the inorganic salt to the organic sodium salt is 1: 10; the preservative is a combination of sodium metabisulfite and cason, and the corresponding weight ratio is 10: 8.
in another aspect, the present invention provides a method for preparing the wet lotion for cashmere woolen clothes, which is the same as in example 1.
Example 6
Embodiment 6 provides a special wet lotion for cashmere woolen clothes, which comprises the following raw materials in percentage by mass: 2.5 percent of anionic surfactant, 0.75 percent of alkylphenol polyoxyethylene, 0.25 percent of cationic surfactant, 0.15 percent of organic sodium salt, 0.09 percent of sodium hydroxide, 0.015 percent of inorganic salt, 0.22 percent of preservative, 0.01 percent of fluorescent whitening agent, 0.01 percent of biological enzyme and the balance of water.
Wherein the anionic surfactant is a composition of dodecyl benzene sulfonic acid and sodium laureth sulfate, and the corresponding weight ratio is 0.1: 1.1; the alkylphenol polyoxyethylene ether is nonylphenol polyoxyethylene ether; the cationic surfactant is dodecyl trimethyl ammonium chloride; the organic sodium salt is sodium ethylene diamine tetracetate; the inorganic salt is calcium chloride, and the weight ratio of the inorganic salt to the organic sodium salt is 1: 10; the preservative is a combination of sodium metabisulfite and cason, and the corresponding weight ratio is 10: 1.
in another aspect, the present invention provides a method for preparing the wet lotion for cashmere woolen clothes, which is the same as in example 1.
Example 7
Embodiment 7 provides a special wet lotion for cashmere woolen clothes, which comprises the following raw materials in percentage by mass: 2.5 percent of anionic surfactant, 0.75 percent of alkylphenol polyoxyethylene, 0.25 percent of cationic surfactant, 0.15 percent of organic sodium salt, 0.09 percent of sodium hydroxide, 0.015 percent of inorganic salt, 0.22 percent of preservative, 0.01 percent of fluorescent whitening agent, 0.01 percent of biological enzyme and the balance of water.
Wherein the anionic surfactant is a composition of dodecyl benzene sulfonic acid and sodium laureth sulfate, and the corresponding weight ratio is 1.4: 8; the alkylphenol polyoxyethylene ether is nonylphenol polyoxyethylene ether; the cationic surfactant is dodecyl trimethyl ammonium chloride; the organic sodium salt is sodium ethylene diamine tetracetate; the inorganic salt is calcium chloride, and the weight ratio of the inorganic salt to the organic sodium salt is 1: 10; the preservative is a combination of sodium metabisulfite and cason, and the corresponding weight ratio is 10: 1.
in another aspect, the present invention provides a method for preparing the wet lotion for cashmere woolen clothes, which is the same as in example 1.
Example 8
Embodiment 8 provides a special wet lotion for cashmere woolen clothes, which comprises the following raw materials in percentage by mass: 2.5 percent of anionic surfactant, 0.75 percent of alkylphenol polyoxyethylene, 0.25 percent of cationic surfactant, 0.15 percent of organic sodium salt, 0.09 percent of sodium hydroxide, 0.015 percent of inorganic salt, 0.22 percent of preservative, 0.01 percent of fluorescent whitening agent, 0.01 percent of biological enzyme and the balance of water.
Wherein the anionic surfactant is a composition of dodecyl benzene sulfonic acid and sodium n-hexadecyl sulfate, and the corresponding weight ratio is 1.4: 1.1; the alkylphenol polyoxyethylene ether is nonylphenol polyoxyethylene ether; the cationic surfactant is dodecyl trimethyl ammonium chloride; the organic sodium salt is sodium ethylene diamine tetracetate; the inorganic salt is calcium chloride, and the weight ratio of the inorganic salt to the organic sodium salt is 1: 10; the preservative is a combination of sodium metabisulfite and cason, and the corresponding weight ratio is 10: 1.
in another aspect, the present invention provides a preparation method of the special wet lotion for cashmere woolen clothes, comprising: mixing dodecyl benzene sulfonic acid and n-hexadecyl sodium sulfate, adding water into the mixture, uniformly stirring at 50 ℃, adding nonylphenol polyoxyethylene ether, uniformly stirring, cooling to 30 ℃, and adding dodecyl trimethyl ammonium chloride, sodium ethylene diamine tetracetate, sodium hydroxide, calcium chloride, sodium metabisulfite, kasong, a fluorescent whitening agent and biological enzyme to obtain the fluorescent whitening agent.
Example 9
Embodiment 9 provides a special wet lotion for cashmere woolen clothes, which comprises the following raw materials in percentage by mass: 2.5 percent of anionic surfactant, 0.1 percent of alkylphenol polyoxyethylene, 0.25 percent of cationic surfactant, 0.15 percent of organic sodium salt, 0.09 percent of sodium hydroxide, 0.015 percent of inorganic salt, 0.22 percent of preservative, 0.01 percent of fluorescent whitening agent, 0.01 percent of biological enzyme and the balance of water.
In another aspect, the present invention provides a method for preparing the wet lotion for cashmere woolen clothes, which is the same as in example 1.
Wherein the anionic surfactant is a composition of dodecyl benzene sulfonic acid and sodium laureth sulfate, and the corresponding weight ratio is 1.4: 1.1; the alkylphenol polyoxyethylene ether is nonylphenol polyoxyethylene ether; the cationic surfactant is dodecyl trimethyl ammonium chloride; the organic sodium salt is sodium ethylene diamine tetracetate; the inorganic salt is calcium chloride, and the weight ratio of the inorganic salt to the organic sodium salt is 1: 10; the preservative is a combination of sodium metabisulfite and cason, and the corresponding weight ratio is 10: 1.
in another aspect, the present invention provides a method for preparing the wet lotion for cashmere woolen clothes, which is the same as in example 1.
Example 10
Embodiment 10 provides a special wet lotion for cashmere woolen clothes, which comprises the following raw materials in percentage by mass: 2.5 percent of anionic surfactant, 0.1 percent of alkylphenol polyoxyethylene, 0.25 percent of cationic surfactant, 0.15 percent of organic sodium salt, 0.09 percent of sodium hydroxide, 0.015 percent of inorganic salt, 0.22 percent of preservative, 0.01 percent of fluorescent whitening agent, 0.01 percent of biological enzyme and the balance of water.
Wherein the anionic surfactant is a composition of dodecyl benzene sulfonic acid and sodium n-hexadecyl sulfate, and the corresponding weight ratio is 0.1: 1.1; the alkylphenol polyoxyethylene ether is nonylphenol polyoxyethylene ether; the cationic surfactant is dodecyl trimethyl ammonium chloride; the organic sodium salt is sodium ethylene diamine tetracetate; the inorganic salt is calcium chloride, and the weight ratio of the inorganic salt to the organic sodium salt is 1: 10; the preservative is a combination of sodium metabisulfite and cason, and the corresponding weight ratio is 10: 1.
in another aspect, the present invention provides a method for preparing the wet lotion for cashmere woolen clothes, which is the same as in example 1.
Evaluation of Performance
1. Stability test
The special wet lotion for cashmere woolen clothes prepared in examples 1 to 10 is subjected to stability test, the test method refers to the test method that Q/321100AFL001-2018 is not less than Q/321100AFL and the special fine lotion for woolen fabric clothes is not less than Q/898, and the test results are shown in Table 1.
2. Detergency test
The special wet lotion for cashmere woolen clothes prepared in examples 1 to 10 was allowed to stand for 12 months under the same conditions, and then a soil-release capability test was performed.
(1) The carbon black oil stain cloth (JB01), protein stain cloth (JB02) and sebum stain cloth (JB03) are cut into pieces of 6cm × 6cm, and the test pieces are named. The whiteness values of the test pieces before washing are read one by a whiteness meter under 457nm, and numbering records are made.
(2) 1.67g of calcium chloride and 2.47g of magnesium sulfate are weighed, and deionized water is added to prepare 1L of water solution, namely 2500mg/kg of hard water. When in use, 0.1L of the water is diluted by deionized water to 1L, namely 250mg/kg of standard hard water.
(3) 1L of standard hard water (preheated to about 30 ℃ C. beforehand) and 3.0g of the detergent prepared in each example were added to a decontamination jar, and the apparatus was adjusted to maintain the wash test temperature at 30 ℃. + -. 1 ℃.
(4) Adding test pieces into the decontamination cylinder, wherein each test piece comprises 3 carbon black oil stain cloths, 3 protein stain cloths and 3 leather fat stain cloths. Starting stirring, keeping the stirring speed at 120r/min, and stopping the washing process after the washing process lasts for 20 min.
(5) And (3) taking out the test piece by using a forceps, putting the test piece into a small dish, washing the test piece by using tap water at a stable speed for about 10s, throwing water, spreading the test piece in an enamel plate in sequence, and measuring whiteness after drying in the air.
The decontamination index is the difference between the whiteness after washing and the whiteness before washing, the larger the difference is, the better the decontamination ability is, and the test results are shown in table 1.
3. Other washing effect tests.
30 pieces of woolen clothes to be washed are divided into 10 groups, the wet washing agents special for the woolen clothes prepared in the embodiments 1-10 are respectively used for washing under the same conditions and by the same method, the washing effects are compared, the washing effect test comprises whether the washed fabric shrinks and becomes tight or not and whether the washed fabric keeps the original chroma or not, and the test results are shown in table 1.
The foregoing examples are merely illustrative and serve to explain some of the features of the method of the present invention. The appended claims are intended to claim as broad a scope as is contemplated, and the examples presented herein are merely illustrative of selected implementations in accordance with all possible combinations of examples. Accordingly, it is applicants' intention that the appended claims are not to be limited by the choice of examples illustrating features of the invention. Also, where numerical ranges are used in the claims, subranges therein are included, and variations in these ranges are also to be construed as possible being covered by the appended claims.
Claims (1)
1. The special wet lotion for the cashmere woolen clothes is characterized by comprising the following raw materials in percentage by mass: 2.3 to 2.7 percent of anionic surfactant, 0.7 to 0.8 percent of alkylphenol polyoxyethylene, 0.2 to 0.3 percent of cationic surfactant, 0.1 to 0.2 percent of organic sodium salt and 0.08 to 0.10 percent of sodium hydroxide; the method also comprises the following raw materials: 0.01-0.1% of inorganic salt, 0.01-0.5% of preservative, 0.01-0.1% of fluorescent whitening agent, 0.01-0.1% of biological enzyme and the balance of water; the weight ratio of the inorganic salt to the organic sodium salt is (0.05-3): 10; wherein the anionic surfactant is a composition of dodecyl benzene sulfonic acid and sodium laureth sulfate, and the corresponding weight parts are (1-5): (1-3); the alkylphenol polyoxyethylene ether is nonylphenol polyoxyethylene ether; the cationic surfactant is dodecyl trimethyl ammonium chloride; the organic sodium salt is sodium ethylene diamine tetracetate; the inorganic salt is calcium chloride; the preservative is a combination of sodium metabisulfite and cason, and the corresponding weight ratio is 10: (0.5-3).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910025958.9A CN109735400B (en) | 2019-01-11 | 2019-01-11 | Special wet lotion for cashmere woolen clothes |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910025958.9A CN109735400B (en) | 2019-01-11 | 2019-01-11 | Special wet lotion for cashmere woolen clothes |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109735400A CN109735400A (en) | 2019-05-10 |
| CN109735400B true CN109735400B (en) | 2021-04-27 |
Family
ID=66364527
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910025958.9A Active CN109735400B (en) | 2019-01-11 | 2019-01-11 | Special wet lotion for cashmere woolen clothes |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109735400B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111500376A (en) * | 2020-06-03 | 2020-08-07 | 永奥(上海)健康科技有限公司 | Technology for preparing laundry detergent tablets by soybean fermentation technology |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102965222A (en) * | 2012-12-04 | 2013-03-13 | 新时代健康产业（集团）有限公司 | Low-foaming anti-crease soft laundry detergent and preparation method thereof |
| CN104450279A (en) * | 2014-11-13 | 2015-03-25 | 青岛厚科信息工程有限公司 | Laundry detergent capable of preventing clothes from shrinking |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1098136A (en) * | 1993-07-24 | 1995-02-01 | 柯子勤 | Multifunctional detergent for woollen sweater |
| CN1094440A (en) * | 1994-04-14 | 1994-11-02 | 山东金泰集团股份有限公司 | Light-duty liquid detergent for washing clothes with static resistance |
| CN1086198C (en) * | 1999-02-05 | 2002-06-12 | 安徽芳草日化股份有限公司 | Multifunctional concentrated phosphorus-free liquid detergent |
| CN1354237A (en) * | 2000-11-22 | 2002-06-19 | 上海白猫有限公司 | Non-phosphate liquid detergent and its production method |
| CN1322802A (en) * | 2001-06-04 | 2001-11-21 | 贾发颂 | Phosphate-free liquid detergent and its compounding process |
| CN1418939A (en) * | 2002-12-17 | 2003-05-21 | 刘荣虎 | Shrink-resisting liquid detergent for clothes |
| CN101033434A (en) * | 2007-03-28 | 2007-09-12 | 常熟市亚德实业有限公司 | Clothes detergent |
| CN104673526A (en) * | 2013-12-03 | 2015-06-03 | 青岛惠城石化科技有限公司 | Formulation of environmental-friendly wool scouring agent |
| CN104087458A (en) * | 2014-07-16 | 2014-10-08 | 上海制皂(集团)如皋有限公司 | Low foaming washing liquid used for underwear and preparation method thereof |
| CN105754745A (en) * | 2016-05-11 | 2016-07-13 | 于文 | Total-effect clothing pre-washing agent free from organic solvent |
| CN106987466A (en) * | 2017-04-07 | 2017-07-28 | 淮北市相山区靖函洗涤用品店 | A kind of clothing washes liquid |
| CN108192760A (en) * | 2018-01-17 | 2018-06-22 | 深圳市芭格美生物科技有限公司 | A kind of anhydrous liquid detergent and preparation method thereof |
| CN108300606A (en) * | 2018-03-20 | 2018-07-20 | 深圳市零度智控科技有限公司 | Liquid detergent |
| CN109111999A (en) * | 2018-09-06 | 2019-01-01 | 顾芳 | A kind of anion flexible abstergent |
-
2019
- 2019-01-11 CN CN201910025958.9A patent/CN109735400B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102965222A (en) * | 2012-12-04 | 2013-03-13 | 新时代健康产业（集团）有限公司 | Low-foaming anti-crease soft laundry detergent and preparation method thereof |
| CN104450279A (en) * | 2014-11-13 | 2015-03-25 | 青岛厚科信息工程有限公司 | Laundry detergent capable of preventing clothes from shrinking |
Also Published As
| Publication number | Publication date |
|---|---|
| CN109735400A (en) | 2019-05-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| NO144268B (en) | DETERGENT. | |
| DE1767334A1 (en) | Foam-regulated washing active substance combination or detergent containing them | |
| US3000830A (en) | Use of polyvinylpyrrolidone as a soil-suspending agent | |
| FI82261B (en) | TVAETTMEDEL- MJUKGOERINGSMEDELKOMPOSITION FOER TVAETTCYKEL MED FOERBAETTRAD SUBSTANTIVITET MOT TEXTILIER. | |
| CN109735400B (en) | Special wet lotion for cashmere woolen clothes | |
| DE2343636A1 (en) | SOFTENING DETERGENT | |
| DE2243306A1 (en) | FOAM REGULATED DETERGENTS, ESPECIALLY FOR DRUM WASHING MACHINES | |
| CN108048236B (en) | Liquid detergent containing carboxymethyl cellulose and preparation method thereof | |
| DE2728558A1 (en) | DRY MIXED CONCENTRATED DETERGENTS AND WASHING METHODS | |
| CN111218349A (en) | Liquid laundry detergent | |
| DE2727346A1 (en) | GRILLY DETERGENT | |
| CN107418741A (en) | Color protection laundry sheet and preparation method thereof | |
| CN108441347A (en) | A kind of compound laundry sheet | |
| CN108753485A (en) | Ozone laundry composition and preparation method thereof | |
| CN114164056A (en) | Multifunctional disinfecting cleaning agent and preparation method thereof | |
| CN111021054A (en) | Application of refining oil removal agent SP-1360 | |
| CN109267400A (en) | A kind of modification laccase soaping agent and preparation method thereof soaped for cotton fabric | |
| CN1354244A (en) | Liquid detergent capable of resisting cross talk | |
| KR930000925B1 (en) | Hot water wash cycle detergent-softener compositions | |
| CN105018246B (en) | A kind of mold-proof oxidation-resistant liquid detergent | |
| CN114606071B (en) | Rinse agent composition and application thereof | |
| EP2812421A1 (en) | Washing or cleaning agent with cellulose or a cellulose derivative | |
| FI86741B (en) | COMPOSITION OF A TVAETTMEDEL OCH UPPMJUKANDE MEDEL FOER ANVAENDNING I TVAETTCYKEL. | |
| DE2539270C2 (en) | Detergents containing textile softeners | |
| JP5253712B2 (en) | Liquid detergent composition for clothing |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |