CN105018246B - A kind of mold-proof oxidation-resistant liquid detergent - Google Patents
A kind of mold-proof oxidation-resistant liquid detergent Download PDFInfo
- Publication number
- CN105018246B CN105018246B CN201510402749.3A CN201510402749A CN105018246B CN 105018246 B CN105018246 B CN 105018246B CN 201510402749 A CN201510402749 A CN 201510402749A CN 105018246 B CN105018246 B CN 105018246B
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- Prior art keywords
- mass fraction
- mold
- liquid detergent
- proof
- resistant liquid
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 239000003599 detergent Substances 0.000 title claims abstract description 29
- 239000007788 liquid Substances 0.000 title claims abstract description 26
- 230000003647 oxidation Effects 0.000 title claims abstract description 24
- 238000007254 oxidation reaction Methods 0.000 title claims abstract description 24
- UILPJVPSNHJFIK-UHFFFAOYSA-N Paeonol Chemical compound COC1=CC=C(C(C)=O)C(O)=C1 UILPJVPSNHJFIK-UHFFFAOYSA-N 0.000 claims abstract description 48
- YLTGFGDODHXMFB-UHFFFAOYSA-N isoacetovanillon Natural products COC1=CC=C(C(C)=O)C=C1O YLTGFGDODHXMFB-UHFFFAOYSA-N 0.000 claims abstract description 24
- MLIBGOFSXXWRIY-UHFFFAOYSA-N paeonol Natural products COC1=CC=C(O)C(C(C)=O)=C1 MLIBGOFSXXWRIY-UHFFFAOYSA-N 0.000 claims abstract description 24
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 14
- 239000011734 sodium Substances 0.000 claims abstract description 14
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 13
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims abstract description 12
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 11
- AGBQKNBQESQNJD-UHFFFAOYSA-M lipoate Chemical compound [O-]C(=O)CCCCC1CCSS1 AGBQKNBQESQNJD-UHFFFAOYSA-M 0.000 claims abstract description 11
- 235000019136 lipoic acid Nutrition 0.000 claims abstract description 11
- 229960002663 thioctic acid Drugs 0.000 claims abstract description 11
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 10
- 235000006708 antioxidants Nutrition 0.000 claims abstract description 10
- 239000000203 mixture Substances 0.000 claims abstract description 10
- 239000002689 soil Substances 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000002270 dispersing agent Substances 0.000 claims abstract description 9
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 20
- 150000002191 fatty alcohols Chemical class 0.000 claims description 20
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 11
- 235000019864 coconut oil Nutrition 0.000 claims description 11
- 239000003240 coconut oil Substances 0.000 claims description 11
- 229940072033 potash Drugs 0.000 claims description 11
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 11
- 235000015320 potassium carbonate Nutrition 0.000 claims description 11
- 239000000344 soap Substances 0.000 claims description 11
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 10
- 150000001408 amides Chemical class 0.000 claims description 10
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 10
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 10
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 10
- 235000011152 sodium sulphate Nutrition 0.000 claims description 10
- SGHZXLIDFTYFHQ-UHFFFAOYSA-L Brilliant Blue Chemical group [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 SGHZXLIDFTYFHQ-UHFFFAOYSA-L 0.000 claims description 9
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 9
- 239000001055 blue pigment Substances 0.000 claims description 9
- 239000000171 lavandula angustifolia l. flower oil Substances 0.000 claims description 9
- 239000001509 sodium citrate Substances 0.000 claims description 9
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 9
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 claims description 8
- 241000723346 Cinnamomum camphora Species 0.000 claims description 8
- 229960000846 camphor Drugs 0.000 claims description 8
- 229930008380 camphor Natural products 0.000 claims description 8
- 239000000049 pigment Substances 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 239000011976 maleic acid Substances 0.000 claims description 2
- 239000000686 essence Substances 0.000 claims 3
- -1 acyl Amine Chemical class 0.000 claims 1
- 238000005202 decontamination Methods 0.000 claims 1
- 230000003588 decontaminative effect Effects 0.000 claims 1
- 239000006185 dispersion Substances 0.000 claims 1
- 239000002518 antifoaming agent Substances 0.000 abstract description 3
- 238000000034 method Methods 0.000 abstract description 2
- 239000004094 surface-active agent Substances 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 description 7
- 238000005406 washing Methods 0.000 description 7
- 239000008367 deionised water Substances 0.000 description 6
- 229910021641 deionized water Inorganic materials 0.000 description 6
- 239000004744 fabric Substances 0.000 description 6
- 241001674044 Blattodea Species 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 244000131522 Citrus pyriformis Species 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 235000013601 eggs Nutrition 0.000 description 1
- 230000029142 excretion Effects 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000011814 protection agent Substances 0.000 description 1
- 238000013442 quality metrics Methods 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
The invention discloses a kind of mold-proof oxidation-resistant liquid detergents, belong to consumer goods industries.Mold-proof oxidation-resistant liquid detergent of the present invention, including water, effective soil release component and auxiliary agent, further include antioxidant composition and mould proof component；The antioxidant composition is the mixture of paeonol, sodium paeonol sulfonate and lipoic acid.The liquid detergent of mold-proof oxidation-resistant of the present invention is compounded with antioxidant, dirt dispersant, antifoaming agent and some other surfactant（Effective soil release component）, laundry processes not only high-effective cleansing also solves the problems, such as to store mouldy flavescence when season clothing is long.
Description
Technical field
The present invention relates to consumer goods industries, more particularly to a kind of mold-proof oxidation-resistant liquid detergent.
Background technology
Clothing, the cleaning problems of textile and people's lives level are closely bound up, and China is vast in territory, weather is various,
Especially in south, period summer in winter length, period in spring and autumn are short.It is long in washing storage time which results in season clothings, in addition south
Square humidity is big, and the generally existings such as microorganism, cockroach, these fungies, mould quasi-microorganism can make clothing mouldy, the insects meeting such as cockroach
It climbs on clothing, survival of laying eggs on clothes, and excretion metabolism product, not only damages fibre structure, but also clothing oxygen can be made
Change and turn yellow, influences beauty.
Liquid detergent is detergency ability as a kind of detergent, primary quality metric.Detergency ability includes once going
Dirty power and secondary washing power.A so-called detergency, refer to after fabric washing whiteness, Bleachability and detergent to dirt and
The detergency ability of fat；Secondary washing power refers to that the brightness after fabric is washed at the 2nd time is kept, and what liquid detergent had can prevent
The ability of dirt deposition ability and modification fabric surface color.If detergent secondary washing power energy force difference, after fabric washing not only
Meeting color graying, hardening and feel due to dirt deposition is coarse, reduces the service life of fabric, and can be because of dirt when fabric washing
Dirt is difficult to rinse and waste more water resources, to increase laundry cost.
Invention content
In order to make up the above deficiency, the present invention provides the good mould proof antioxygens of a kind of at low cost and mould proof, antioxidant effect
Change liquid detergent.
The technical scheme is that：
A kind of mold-proof oxidation-resistant liquid detergent, including water, effective soil release component and auxiliary agent further include antioxidant composition and mould proof
Component；The antioxidant composition is the mixture of paeonol, sodium paeonol sulfonate and lipoic acid.In antioxidant composition, zinc sulfate
It is the oxidation protection agent of paeonol and sodium paeonol sulfonate.
Preferably, described mould proof group is divided into camphor.At low cost and anti-mold effect is good.
Preferably, further including essence, pigment and dirt dispersant.Essence and pigment can increase the acceptance of product.
Dirt dispersant can increase the strong dirt-removing power of liquid detergent of the present invention.
Preferably, the mass fraction of effective soil release component is 15-40%, and the mass fraction of paeonol is 0.1-
0.5%, the mass fraction of sodium paeonol sulfonate is 1-5%, and the mass fraction of lipoic acid is 0.2-0.8%, the quality point of mould proof component
Number is 0.1-1%, and the mass fraction of auxiliary agent is 1.5-7%.When the content, the oxidation resistance of antioxidant composition is most strong.
Preferably, the mass fraction of essence is 0.01-0.6%, and the mass fraction of pigment is 0.0001-
0.0005%, the mass fraction of dirt dispersant is 0.1-0.8%.
Preferably, the essence is lavender oil, and the pigment is brilliant blue pigment, and the dirt dispersant is
Acid-co-maleic acid.Essence is lavender oil, and pigment is brilliant blue pigment, and dirt dispersant is acrylic acid-maleic acid
Copolymer（DS-POLYMER 542）, cost-effective.
Preferably, effectively soil release component is by sodium sulfate of polyethenoxy ether of fatty alcohol, fatty alcohol polyoxyethylene ether and 12
Sodium alkyl sulfonate forms.Effective soil release component each component cooperates, and dirt-removing power is superpower, and price is low.
Further, the mass fraction of sodium sulfate of polyethenoxy ether of fatty alcohol is 8-15%, the matter of fatty alcohol polyoxyethylene ether
Amount score is 2-7%, and the mass fraction of dodecyl sodium sulfate is 5-10%.
Preferably, the auxiliary agent includes coconut oil diethanol amide, potash soap and sodium citrate.Wherein, coconut oil
As antifoaming agent, defoaming effect is good for diglycollic amide and potash soap interworking.
Further, the mass fraction of coconut oil diethanol amide is 1-3%, and the mass fraction of potash soap is 0.3-1%, lemon
The mass fraction of sour sodium is 0.5-3%.
Beneficial effects of the present invention are：
The liquid detergent of mold-proof oxidation-resistant of the present invention is compounded with antioxidant, dirt dispersant, antifoaming agent and some other table
Face activating agent（Effective soil release component）, laundry processes not only high-effective cleansing, also efficiently solve season clothing it is long when store it is mouldy
The problem of flavescence.
Specific implementation mode
Embodiment 1
The formula that the mold-proof oxidation-resistant liquid detergent of the present embodiment uses is as follows：
Paeonol 0.5%
Sodium paeonol sulfonate 4%
Lipoic acid 0.4%
Camphor 0.5%
Sodium sulfate of polyethenoxy ether of fatty alcohol 10%
Fatty alcohol polyoxyethylene ether（AEO9） 2%
Dodecyl sodium sulfate 6%
Coconut oil diethanol amide 1%
Potash soap 0.8%
DS-POLYMER 542 0.5%
Sodium citrate 1.5%
Lavender oil 0.5%
Brilliant blue pigment 0.0003%
Deionized water surplus
Embodiment 2：
The formula that the mold-proof oxidation-resistant liquid detergent of the present embodiment uses is as follows：
Paeonol 0.5%
Sodium paeonol sulfonate 3%
Lipoic acid 0.5%
Camphor 0.5%
Sodium sulfate of polyethenoxy ether of fatty alcohol 10%
Fatty alcohol polyoxyethylene ether AEO9 2%
Dodecyl sodium sulfate 6%
Coconut oil diethanol amide 1%
Potash soap 0.8%
DS-POLYMER 542 0.5%
Sodium citrate 1.5%
Lavender oil 0.5%
Brilliant blue pigment 0.0003%
Deionized water surplus
Embodiment 3：
The formula that the mold-proof oxidation-resistant liquid detergent of the present embodiment uses is as follows：
Paeonol 0.4%
Sodium paeonol sulfonate 3%
Lipoic acid 0. 5%
Camphor 0.5%
Sodium sulfate of polyethenoxy ether of fatty alcohol 10%
Fatty alcohol polyoxyethylene ether AEO9 2%
Dodecyl sodium sulfate 6%
Coconut oil diethanol amide 1%
Potash soap 0.8%
DS-POLYMER 542 0.5%
Sodium citrate 1.5%
Lavender oil 0.5%
Brilliant blue pigment 0.0003%
Deionized water surplus.
Embodiment 4：
The formula that the mold-proof oxidation-resistant liquid detergent of the present embodiment uses is as follows：
Paeonol 0.2%
Sodium paeonol sulfonate 3%
Lipoic acid 0. 7%
Camphor 0.8%
Sodium sulfate of polyethenoxy ether of fatty alcohol 13%
Fatty alcohol polyoxyethylene ether AEO9 6%
Dodecyl sodium sulfate 5%
Coconut oil diethanol amide 2%
Potash soap 0.4%
DS-POLYMER 542 0.2%
Sodium citrate 2.5%
Lavender oil 0.2%
Brilliant blue pigment 0.0001%
Deionized water surplus.
Embodiment 5：
The formula that the mold-proof oxidation-resistant liquid detergent of the present embodiment uses is as follows：
Paeonol 0.1%
Sodium paeonol sulfonate 5%
Lipoic acid 0. 8%
Camphor 0.2%
Sodium sulfate of polyethenoxy ether of fatty alcohol 15%
Fatty alcohol polyoxyethylene ether AEO9 7%
Dodecyl sodium sulfate 5%
Coconut oil diethanol amide 2.5%
Potash soap 1%
DS-POLYMER 542 0.8%
Sodium citrate 3%
Lavender oil 0.6%
Brilliant blue pigment 0.0008%
Deionized water surplus.
Embodiment 6：
The formula that the mold-proof oxidation-resistant liquid detergent of the present embodiment uses is as follows：
Paeonol 0.5%
Sodium paeonol sulfonate 1%
Lipoic acid 0. 2%
Camphor 0.9%
Sodium sulfate of polyethenoxy ether of fatty alcohol 8%
Fatty alcohol polyoxyethylene ether AEO9 6%
Dodecyl sodium sulfate 10%
Coconut oil diethanol amide 1%
Potash soap 0.3%
DS-POLYMER 542 0.1%
Sodium citrate 0.5%
Lavender oil 0.01%
Brilliant blue pigment 0.0003%
Deionized water surplus.
Claims (8)
1. a kind of mold-proof oxidation-resistant liquid detergent, including water, effective soil release component and auxiliary agent, it is characterised in that：Further include anti-oxidant
Component and mould proof component；The antioxidant composition is the mixture of paeonol, sodium paeonol sulfonate and lipoic acid；Effective decontamination group
The mass fraction divided is 15-40%, and the mass fraction of paeonol is 0.1-0.5%, and the mass fraction of sodium paeonol sulfonate is 1-5%,
The mass fraction of lipoic acid is 0.2-0.8%, and the mass fraction of mould proof component is 0.1-1%, and the mass fraction of auxiliary agent is 1.5-7%；
Effective soil release component is made of sodium sulfate of polyethenoxy ether of fatty alcohol, fatty alcohol polyoxyethylene ether and dodecyl sodium sulfate.
2. mold-proof oxidation-resistant liquid detergent as described in claim 1, it is characterised in that：Described mould proof group is divided into camphor.
3. mold-proof oxidation-resistant liquid detergent as described in claim 1, it is characterised in that：Further include essence, pigment and soil dispersion
Agent.
4. mold-proof oxidation-resistant liquid detergent as claimed in claim 3, it is characterised in that：The mass fraction of essence is 0.01-0.6%,
The mass fraction of pigment is 0.0001-0.0005%, and the mass fraction of dirt dispersant is 0.1-0.8%.
5. mold-proof oxidation-resistant liquid detergent as described in claim 3 or 4, it is characterised in that：The essence is lavender oil, institute
It is brilliant blue pigment to state pigment, and the dirt dispersant is acid-co-maleic acid.
6. mold-proof oxidation-resistant liquid detergent as described in claim 1, it is characterised in that：The auxiliary agent includes coconut oil diethanol acyl
Amine, potash soap and sodium citrate.
7. mold-proof oxidation-resistant liquid detergent as claimed in claim 6, it is characterised in that：The mass fraction of coconut oil diethanol amide
Mass fraction for 1-3%, potash soap is 0.3-1%, and the mass fraction of sodium citrate is 0.5-3%.
8. mold-proof oxidation-resistant liquid detergent as described in claim 1, it is characterised in that：The matter of sodium sulfate of polyethenoxy ether of fatty alcohol
Amount score is 8-15%, and the mass fraction of fatty alcohol polyoxyethylene ether is 2-7%, and the mass fraction of dodecyl sodium sulfate is 5-
10%。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510402749.3A CN105018246B (en) | 2015-07-10 | 2015-07-10 | A kind of mold-proof oxidation-resistant liquid detergent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510402749.3A CN105018246B (en) | 2015-07-10 | 2015-07-10 | A kind of mold-proof oxidation-resistant liquid detergent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105018246A CN105018246A (en) | 2015-11-04 |
| CN105018246B true CN105018246B (en) | 2018-11-02 |
Family
ID=54408552
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510402749.3A Expired - Fee Related CN105018246B (en) | 2015-07-10 | 2015-07-10 | A kind of mold-proof oxidation-resistant liquid detergent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105018246B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108485838B (en) * | 2018-05-30 | 2020-06-16 | 福建省梦娇兰日用化学品有限公司 | Clothes cleaning agent |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006128554A1 (en) * | 2005-06-03 | 2006-12-07 | Unilever Plc | Incorporation of antioxidant in detergent composition |
| CN104629938A (en) * | 2015-02-05 | 2015-05-20 | 江苏健客生物科技发展有限公司 | Softening color-protecting laundry detergent |
-
2015
- 2015-07-10 CN CN201510402749.3A patent/CN105018246B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006128554A1 (en) * | 2005-06-03 | 2006-12-07 | Unilever Plc | Incorporation of antioxidant in detergent composition |
| CN104629938A (en) * | 2015-02-05 | 2015-05-20 | 江苏健客生物科技发展有限公司 | Softening color-protecting laundry detergent |
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| Publication number | Publication date |
|---|---|
| CN105018246A (en) | 2015-11-04 |
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