CN109713046A - A kind of trench schottky diode and its manufacturing method - Google Patents

A kind of trench schottky diode and its manufacturing method Download PDF

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Publication number
CN109713046A
CN109713046A CN201811572160.8A CN201811572160A CN109713046A CN 109713046 A CN109713046 A CN 109713046A CN 201811572160 A CN201811572160 A CN 201811572160A CN 109713046 A CN109713046 A CN 109713046A
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China
Prior art keywords
layer
groove
schottky diode
concentration
trench
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CN201811572160.8A
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黄赛琴
黄福仁
肖歩文
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FUJIAN ANTE MICROELECTRONIC Co Ltd
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FUJIAN ANTE MICROELECTRONIC Co Ltd
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Abstract

The present invention provides a kind of trench schottky diode, including a N- epitaxial layer and a N+ substrate layer, the N- epitaxial layer is set to the top of the N+ substrate layer;The concentration of dopant of the N- epitaxial layer linearly changes in vertical direction, and the concentration of dopant at N+ substrate layer is maximum;The present invention provides a kind of trench schottky diode manufacturing methods.The present invention has the advantages that improving the reverse blocking voltage of Schottky diode.

Description

A kind of trench schottky diode and its manufacturing method
Technical field
The present invention relates to semi-conductor discrete device field, a kind of trench schottky diode and its manufacturing method are referred in particular to.
Background technique
The abbreviation of Schottky diode (Schottky Barrier Diode) is SBD, be using metal and semiconductor it Between a kind of majority carrier device for working of contact berrier.Due to this diode and common P-N junction configuration diode It compares, has the characteristics that forward voltage drop is small, speed is fast, therefore collect in modern communication, ultrahigh-speed device, microwave circuit and high speed At in circuit have extensive use.
For Schottky diode, influencing most important two parameters of power consumption is forward voltage drop VF and reversed leakage respectively Electric current IR.For the Schottky diode of silicon epitaxy process, forward voltage drop VF depends on potential barrier alloy-layer, the epitaxial conditions used (epitaxy layer thickness and resistivity) and active region area.The epitaxial conditions for the Schottky diode of specific standard Optimization space it is relatively limited, and by increase active region area come reduce forward voltage drop VF and device miniaturization requirement mutually rush It is prominent, and diode capacitance can be also improved, so that increasing circuit is lost, while being also contemplated that when forward voltage reduces, reversely Leakage current can become larger.
In response to the above problems, traditional way is to be changed using trench technique and MOS structure around Schottky barrier The field distribution of drift region inhibits schottky barrier junction surface peak electric field strength between MOS structure, so that peak value electric field goes out In present device body, the optimization of the forward and reverse electrical parameter characteristic of Schottky diode may be implemented.But traditional way there are Following disadvantage: the non-uniform electric in Schottky diode causes the reverse blocking effect of Schottky diode to need to be mentioned It rises.
Summary of the invention
One of the technical problem to be solved in the present invention is to provide a kind of trench schottky diode, for promoting Xiao Te The reverse blocking voltage of based diode.
The present invention is realized in one of technical problem: a kind of trench schottky diode, including a N- epitaxial layer with And a N+ substrate layer, the N- epitaxial layer are set to the top of the N+ substrate layer;The concentration of dopant of the N- epitaxial layer is being hung down Histogram is to linear change, and the concentration of dopant at N+ substrate layer is maximum.
Further, the N- epitaxial layer is equipped with the groove of a plurality of active areas and the groove of two termination environments;Each institute The spacing stated between the groove of active area is equal, and the spacing of the groove of adjacent two active area is greater than the ditch of two termination environments The spacing of slot;The N- epitaxial layer upper surface of the trench wall and termination environment is equipped with the grid oxide layer that a thickness is greater than 50nm, and Full phosphorous doped polysilicon is filled in the groove;The trench depth is greater than 0.5um.
Further, the upper surface of the active area is equipped with a barrier metal layer, and it is blunt that the termination environment upper surface is equipped with one Change layer;The top of the barrier metal layer and passivation layer is equipped with an anode metal layer.
Further, the lower section of the N+ substrate layer is equipped with a cathode metal layer.
The second technical problem to be solved by the present invention is to provide a kind of trench schottky diode manufacturing method, be used for Promote the reverse blocking voltage of Schottky diode.
The present invention is realized in the twos' of technical problem: a kind of trench schottky diode manufacturing method, the method Include the following steps:
Step S1, N- epitaxial layer is set to the top of N+ substrate layer;N- epitaxial layer and N+ substrate layer, which mix, doping Agent;The dopant concentration of the dopant of N- epitaxial layer is less than the first concentration of setting, and linearly changes in vertical direction, more dense down It spends higher;The dopant concentration of the dopant of N+ substrate layer is greater than the first concentration of setting and is less than the second concentration of setting;
Step S2, in one oxide layer of N- epitaxial layer disposed thereon, and a plurality of trench openings are formed in oxide layer;
Step S3, the groove and two terminals for generating a plurality of active areas are etched on N- epitaxial layer by trench openings The groove in area, then removes removing oxide layer;
Step S4, a grid oxide layer, and deposit polycrystalline silicon are generated in N- epitaxial layer upper surface and trench wall;
Step S5, the grid oxide layer and polysilicon of the N- epitaxial layer upper surface of active area are removed, removal termination environment is higher than N- The polysilicon of epitaxial layer upper surface;
Step S6, a passivation layer is deposited in the upper surface of termination environment;
Step S7, after the upper surface of active area sputters a barrier metal layer, sputtering one anode metal layer covering potential barrier gold Belong to layer and passivation layer;
Step S8, a cathode metal layer is generated in the lower section of N+ substrate layer.
Further, in the step S1, first concentration is 1 × 1019A/cm3, the second concentration is 1 × 1021A/ cm3
Further, in the step S3, the spacing between the groove of each active area is equal;Adjacent two is described active The spacing of the groove in area is greater than the spacing of the groove of two termination environments.
Further, in the step S3, the depth of the groove is greater than 0.5um.
Further, the step S4 specifically: use the side of thermal oxide in N- epitaxial layer upper surface and trench wall Formula generates the grid oxide layer that a thickness is not less than 50nm, and deposits phosphorous doped polysilicon.
Further, the step S5 specifically: N- epi-layer surface is deposited on by the removal of polycrystalline dry etch process Phosphorous doped polysilicon.
The present invention has the advantages that
1, linearly changed by the dopant concentration of the dopant of N- epitaxial layer in vertical direction, concentration is higher more down, makes The electric field for obtaining N- epitaxial layer is uniformly distributed in the horizontal direction, and then promotes the reverse blocking voltage of Schottky diode.
2, linearly changed by the dopant concentration of the dopant of N- epitaxial layer in vertical direction, concentration is higher more down, makes It obtains and realizes high-concentration dopant on N- epitaxial layer, and then make Schottky diode that there is lower forward conduction resistance.
3, by etching the groove of active area and termination environment simultaneously, the size of trench schottky diode is reduced, Reduce manufacturing cost.
4, by etching the groove of two termination environments, the resistance to pressure of trench schottky diode is improved, so that The reliability of trench schottky diode greatly promotes.
Detailed description of the invention
The present invention is further illustrated in conjunction with the embodiments with reference to the accompanying drawings.
Fig. 1 is oxide layer etching schematic diagram of the present invention.
Fig. 2 is groove and trench termination etching schematic diagram of the present invention.
Fig. 3 is etching polysilicon schematic diagram of the present invention.
Fig. 4 is passivation layer etching schematic diagram of the present invention.
Fig. 5 is trench schottky diode structural schematic diagram of the present invention.
Fig. 6 is N- epitaxial layer concentration of dopant schematic diagram of the present invention.
Description of symbols:
100- trench schottky diode, 1-N- epitaxial layer, 2-N+ substrate layer, 3- oxide layer, the groove of 4- active area, 5- The groove of termination environment, 6- grid oxide layer, 7- phosphorous doped polysilicon, 8- passivation layer, 9- anode metal layer, 10- cathode metal layer, 11- gesture Base metal layer, 12- active area, the termination environment 13-, 14- trench openings.
Specific embodiment
It please refers to shown in Fig. 1 to Fig. 6, a kind of preferred embodiment of trench schottky diode 100 of the present invention, including a N- Epitaxial layer 1 and a N+ substrate layer 2, the N- epitaxial layer 1 are set to the top of the N+ substrate layer 2;The N- epitaxial layer 1 is mixed Miscellaneous dose of concentration linearly changes in vertical direction, and the concentration of dopant at N+ substrate layer 2 is maximum;The dopant be phosphorus or Arsenic, the resistivity of N- epitaxial layer 1 and N+ substrate layer 2 can be changed by doping dopant, and then change electric conductivity;N+ substrate layer 2 concentration of dopant is greater than the concentration of dopant of N- epitaxial layer 1, and the concentration of dopant of N+ substrate layer 2 is greater than 1 × 1019A/ cm3, the concentration of dopant of N- epitaxial layer 1 is less than 1 × 1019A/cm3
The N- epitaxial layer 1 is equipped with the groove 4 of a plurality of active areas and (the bicyclic groove end of groove 5 of two termination environments End);Spacing between the groove 4 of each active area is equal, and the spacing of the groove 4 of adjacent two active area is greater than described in two The spacing of the groove 5 of termination environment;It is big that 1 upper surface of N- epitaxial layer of groove 4 (5) inner wall and termination environment 13 is equipped with a thickness Full phosphorous doped polysilicon 7 is filled in the grid oxide layer 6 of 50nm, and in the groove 4 (5);Groove 4 (5) depth is greater than 0.5um. By simultaneously etch the groove 4 of active area and the groove 5 of termination environment, reduce the size of trench schottky diode 100, Reduce manufacturing cost;By etching the groove 5 of two termination environments, the resistance to of trench schottky diode 100 is improved Pressure property, so that the reliability of trench schottky diode 100 greatly promotes.
The upper surface of the active area 12 is equipped with a barrier metal layer 11, and 13 upper surface of termination environment is equipped with a passivation layer 8;The top of the barrier metal layer 11 and passivation layer 8 is equipped with an anode metal layer 9.
The lower section of the N+ substrate layer 2 is equipped with a cathode metal layer 10.
The second technical problem to be solved by the present invention is to provide a kind of trench schottky diode manufacturing method, be used for Promote the reverse blocking voltage of Schottky diode.
A kind of preferred embodiment of trench schottky diode manufacturing method of the present invention, includes the following steps:
Step S1, N- epitaxial layer 1 is set to the top of N+ substrate layer 2;N- epitaxial layer 1 and N+ substrate layer 2, which mix, to be had Dopant;The dopant concentration of the dopant of N- epitaxial layer 1 is less than the first concentration of setting, and linearly changes in vertical direction, more Concentration is higher down;The dopant concentration of the dopant of N- epitaxial layer 1 linearly changes in vertical direction crosses layering production difference all Realization is merged after the N- epitaxial layer 1 of dopant concentration;The dopant concentration of the dopant of N+ substrate layer 2 is greater than the of setting One concentration and the second concentration for being less than setting;Linearly changed by the dopant concentration of the dopant of N- epitaxial layer 1 in vertical direction, Concentration is higher more down, so that the electric field of N- epitaxial layer 1 is uniformly distributed in the horizontal direction, and then promotes the trench schottky The reverse blocking voltage of diode 100;So that realizing high-concentration dopant on the N- epitaxial layer 1, and then make groove Xiao Special based diode 100 has lower forward conduction resistance;
Step S2, in 1 disposed thereon of N- epitaxial layer, one oxide layer 3, and a plurality of ditches are formed in oxide layer 3 by photoetching Slot window 14;
Step S3, using trench etch process, a plurality of active areas are generated on N- epitaxial layer 1 by trench openings 14 Groove 4 and the groove of two termination environments 5 (bicyclic trench termination), then remove removing oxide layer 3;By etching active area simultaneously And the groove 4 (5) of termination environment, the size of the trench schottky diode 100 is reduced, manufacturing cost is reduced;
Step S4, a grid oxide layer 6, and deposit polycrystalline silicon are generated in 1 upper surface of N- epitaxial layer and groove 4 (5) inner wall;
Step S5, the grid oxide layer 6 and polysilicon 7 for removing 1 upper surface of N- epitaxial layer of active area 12, remove termination environment 13 Higher than the polysilicon 7 of 1 upper surface of N- epitaxial layer;
Step S6, a passivation layer 8 is deposited in the upper surface of termination environment 13;
Step S7, after the upper surface of active area 12 sputters a barrier metal layer 11, one anode metal layer 9 of sputtering covers gesture Base metal layer 11 and passivation layer 8;
Step S8, a cathode metal layer 10 is generated in the lower section of N+ substrate layer 2, last test scribing that is, will batch production The trench schottky diode 100 be divided into and minimum use unit.
In the step S1, first concentration is 1 × 1019A/cm3, the second concentration is 1 × 1021A/cm3, i.e. N+ lining 2 high-concentration dopant phosphorus or arsenic of bottom, 1 low concentration doping phosphorus or arsenic of N- epitaxial layer;The dopant is phosphorus or arsenic, by mixing The resistivity of miscellaneous dose of changeable N- epitaxial layer 1 and N+ substrate layer 2, and then change electric conductivity;The N- epitaxial layer 1 and N+ lining Bottom 2 is manufactured by silicon.
In the step S3, the spacing between the groove 4 of each active area is equal;The groove of adjacent two active area 4 spacing is greater than the spacing of the groove 5 of two termination environments;The spacing of the groove 5 of two termination environments can be according to different rule The pressure voltage of the trench schottky diode of lattice optimizes.
In the step S3, the depth of the groove 4 (5) is greater than 0.5um.
The step S4 specifically: raw by the way of thermal oxide in 1 upper surface of N- epitaxial layer and groove 4 (5) inner wall It is not less than the grid oxide layer 6 of 50nm at a thickness, and deposits phosphorous doped polysilicon 7;The performance of MOS transistor is dependent on grid oxide layer 6 Thickness, the reduction of 6 thickness of grid oxide layer, enhances the current driving ability of transistor, improves speed and power characteristic, therefore drop Low 6 thickness of gate oxide can effectively improve transistor performance, however thin grid oxide layer 6 can aggravate electric current tunneling effect and drop Suboxides layer reliability.
The step S5 specifically: the p-doped for being deposited on 1 surface of N- epitaxial layer by the removal of polycrystalline dry etch process is more Crystal silicon 7.
The step S6 specifically: deposit silicon dioxide passivation layer 8 on N- epitaxial layer 1, covered by photoetching process removal Cover the silicon dioxide passivation layer 8 on 12 surface of active area.
The step S8 specifically: one cathode is generated by sputtering or multiple layer metal evaporation in the lower section of N+ substrate layer 2 Metal layer 10.
In conclusion the present invention has the advantages that
1, linearly changed by the dopant concentration of the dopant of N- epitaxial layer in vertical direction, concentration is higher more down, makes The electric field for obtaining N- epitaxial layer is uniformly distributed in the horizontal direction, and then promotes the reverse blocking voltage of Schottky diode.
2, linearly changed by the dopant concentration of the dopant of N- epitaxial layer in vertical direction, concentration is higher more down, makes It obtains and realizes high-concentration dopant on N- epitaxial layer, and then make Schottky diode that there is lower forward conduction resistance.
3, by etching the groove of active area and termination environment simultaneously, the size of trench schottky diode is reduced, Reduce manufacturing cost.
4, by etching the groove of two termination environments, the resistance to pressure of trench schottky diode is improved, so that The reliability of trench schottky diode greatly promotes.
Although specific embodiments of the present invention have been described above, those familiar with the art should be managed Solution, we are merely exemplary described specific embodiment, rather than for the restriction to the scope of the present invention, it is familiar with this The technical staff in field should be covered of the invention according to modification and variation equivalent made by spirit of the invention In scope of the claimed protection.

Claims (10)

1. a kind of trench schottky diode, it is characterised in that: including a N- epitaxial layer and a N+ substrate layer, the N- extension Layer is set to the top of the N+ substrate layer;The concentration of dopant of the N- epitaxial layer linearly changes in vertical direction, and close to N+ Concentration of dopant at substrate layer is maximum.
2. a kind of trench schottky diode as described in claim 1, it is characterised in that: the N- epitaxial layer is equipped with a plurality of The groove of active area and the groove of two termination environments;Spacing between the groove of each active area is equal, described in adjacent two The spacing of the groove of active area is greater than the spacing of the groove of two termination environments;The N- extension of the trench wall and termination environment Layer upper surface is equipped with the grid oxide layer that a thickness is greater than 50nm, and full phosphorous doped polysilicon is filled in the groove;The trench depth Greater than 0.5um.
3. a kind of trench schottky diode as described in claim 1, it is characterised in that: the upper surface of the active area is equipped with One barrier metal layer, the termination environment upper surface are equipped with a passivation layer;The top of the barrier metal layer and passivation layer is equipped with One anode metal layer.
4. a kind of trench schottky diode as described in claim 1, it is characterised in that: the lower section of the N+ substrate layer is equipped with One cathode metal layer.
5. a kind of trench schottky diode manufacturing method, it is characterised in that: described method includes following steps:
Step S1, N- epitaxial layer is set to the top of N+ substrate layer;N- epitaxial layer and N+ substrate layer, which mix, dopant;N- The dopant concentration of the dopant of epitaxial layer is less than the first concentration of setting, and linearly changes in vertical direction, and concentration is more more down It is high;The dopant concentration of the dopant of N+ substrate layer is greater than the first concentration of setting and is less than the second concentration of setting;
Step S2, in one oxide layer of N- epitaxial layer disposed thereon, and a plurality of trench openings are formed in oxide layer;
Step S3, the groove for generating a plurality of active areas and two termination environments are etched on N- epitaxial layer by trench openings Then groove removes removing oxide layer;
Step S4, a grid oxide layer, and deposit polycrystalline silicon are generated in N- epitaxial layer upper surface and trench wall;
Step S5, the grid oxide layer and polysilicon of the N- epitaxial layer upper surface of active area are removed, removal termination environment is higher than N- extension The polysilicon of layer upper surface;
Step S6, a passivation layer is deposited in the upper surface of termination environment;
Step S7, after the upper surface of active area sputters a barrier metal layer, one anode metal layer of sputtering covers barrier metal layer And passivation layer;
Step S8, a cathode metal layer is generated in the lower section of N+ substrate layer.
6. a kind of trench schottky diode manufacturing method as claimed in claim 5, it is characterised in that: in the step S1, First concentration is 1 × 1019A/cm3, the second concentration is 1 × 1021A/cm3
7. a kind of trench schottky diode manufacturing method as claimed in claim 5, it is characterised in that: in the step S3, Spacing between the groove of each active area is equal;The spacing of the groove of adjacent two active area is greater than two termination environments Groove spacing.
8. a kind of trench schottky diode manufacturing method as claimed in claim 5, it is characterised in that: in the step S3, The depth of the groove is greater than 0.5um.
9. a kind of trench schottky diode manufacturing method as claimed in claim 5, it is characterised in that: the step S4 is specific Are as follows: the grid oxide layer that a thickness is not less than 50nm is generated by the way of thermal oxide in N- epitaxial layer upper surface and trench wall, And deposit phosphorous doped polysilicon.
10. a kind of trench schottky diode manufacturing method as claimed in claim 5, it is characterised in that: the step S5 tool Body are as follows: the phosphorous doped polysilicon of N- epi-layer surface is deposited on by the removal of polycrystalline dry etch process.
CN201811572160.8A 2018-12-21 2018-12-21 A kind of trench schottky diode and its manufacturing method Pending CN109713046A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113903813A (en) * 2021-09-30 2022-01-07 上海芯导电子科技股份有限公司 Schottky diode, manufacturing method thereof and electronic device

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Publication number Priority date Publication date Assignee Title
US20060118833A1 (en) * 2004-12-08 2006-06-08 Stmicroelectronics S.A. Vertical unipolar component periphery
CN101015059A (en) * 2004-07-15 2007-08-08 飞兆半导体公司 Schottky diode structure to reduce capacitance and switching losses and method of making same
CN102637595A (en) * 2011-02-15 2012-08-15 陈自雄 Trench schottky diode and manufacturing method thereof
KR101463078B1 (en) * 2013-11-08 2014-12-04 주식회사 케이이씨 Schottky barrier diode and fabricating method thereof
CN106449775A (en) * 2016-10-31 2017-02-22 复旦大学 GaN-based hybrid PIN Schottky diode and production method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101015059A (en) * 2004-07-15 2007-08-08 飞兆半导体公司 Schottky diode structure to reduce capacitance and switching losses and method of making same
US20060118833A1 (en) * 2004-12-08 2006-06-08 Stmicroelectronics S.A. Vertical unipolar component periphery
CN102637595A (en) * 2011-02-15 2012-08-15 陈自雄 Trench schottky diode and manufacturing method thereof
KR101463078B1 (en) * 2013-11-08 2014-12-04 주식회사 케이이씨 Schottky barrier diode and fabricating method thereof
CN106449775A (en) * 2016-10-31 2017-02-22 复旦大学 GaN-based hybrid PIN Schottky diode and production method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113903813A (en) * 2021-09-30 2022-01-07 上海芯导电子科技股份有限公司 Schottky diode, manufacturing method thereof and electronic device
CN113903813B (en) * 2021-09-30 2024-02-09 上海芯导电子科技股份有限公司 Schottky diode, preparation method thereof and electronic equipment

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