CN109679782A - Remaining detergent of a kind of removal cement and preparation method thereof - Google Patents

Remaining detergent of a kind of removal cement and preparation method thereof Download PDF

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Publication number
CN109679782A
CN109679782A CN201910095555.1A CN201910095555A CN109679782A CN 109679782 A CN109679782 A CN 109679782A CN 201910095555 A CN201910095555 A CN 201910095555A CN 109679782 A CN109679782 A CN 109679782A
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CN
China
Prior art keywords
agent
remaining detergent
strong acid
deionized water
preservative
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910095555.1A
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Chinese (zh)
Inventor
李勇波
张建国
杨高产
陈柔好
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ZHONGSHAN DATIAN CAR CARE INDUSTRY Inc
Original Assignee
ZHONGSHAN DATIAN CAR CARE INDUSTRY Inc
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Application filed by ZHONGSHAN DATIAN CAR CARE INDUSTRY Inc filed Critical ZHONGSHAN DATIAN CAR CARE INDUSTRY Inc
Priority to CN201910095555.1A priority Critical patent/CN109679782A/en
Publication of CN109679782A publication Critical patent/CN109679782A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/83Mixtures of non-ionic with anionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/008Polymeric surface-active agents
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/825Mixtures of compounds all of which are non-ionic
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/042Acids
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/046Salts
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/046Salts
    • C11D3/048Nitrates or nitrites
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2075Carboxylic acids-salts thereof
    • C11D3/2079Monocarboxylic acids-salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/34Organic compounds containing sulfur
    • C11D3/3409Alkyl -, alkenyl -, cycloalkyl - or terpene sulfates or sulfonates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/34Organic compounds containing sulfur
    • C11D3/349Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29Sulfates of polyoxyalkylene ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention discloses a kind of remaining detergents of removal cement, which is characterized in that including the following raw material: strong acid, surfactant, bleeding agent, preservative, deionized water.The feature that the present invention has elimination effect good, easy to use, cement residual can be dissolved and be removed in 3 minutes.

Description

Remaining detergent of a kind of removal cement and preparation method thereof
Technical field
The invention belongs to household chemicals technical fields, and in particular to a kind of remaining detergent of removal cement and its preparation Method.
Background technique
In recent years, with economic sustainable growth, there is a large amount of infrastructure in city and rural area, cement is again can not The raw material of shortcoming, inevitably had during this small amount of cement remain in Automobile paint or building surface on, and Clean that this kind of cement residual generally requires a large amount of manpower and material resources and effect is unobvious.
A kind of urgent need that market is had become for the remaining detergent of a small amount of cement is developed as a result,.
Summary of the invention
The purpose of the present invention is to provide remaining detergents of a kind of removal cement and preparation method thereof.
The technical solution used in the present invention is:
The remaining detergent of a kind of removal cement, which is characterized in that the main product made of the following raw material: strong acid, table Face activating agent, bleeding agent, preservative, deionized water.
Preferably, according to the mass fraction, including the following raw material: 5-8 parts of strong acid, 2-5 parts of surfactant, bleeding agent 3-8 Part, 1-3 parts of preservative, 75-85 parts of deionized water.
Preferably, the strong acid is concentrated hydrochloric acid.
Preferably, the surfactant is cocoanut fatty acid diethanolamide, alkyl phenol polyoxyethylene ether, fat One of alcohol polyethenoxy ether sodium sulfate, fatty alcohol polyoxyethylene ether or multiple combinations.
Preferably, the bleeding agent is the combination of one or both of penetrating agent JFC, dioctylis sulfosuccinas natricus.
Preferably, the preservative is one of sodium benzoate, sodium nitrite, sodium molybdate, Kathon CG or multiple combinations.
A kind of preparation method removing the remaining detergent of cement, which comprises the steps of: strong acid is added Diluted into deionized water, add surfactant, bleeding agent, preservative, be uniformly mixed to get.
Under product of the present invention room temperature, pH value 1-2.
Appropriate amount of essence can also be added in the present invention.
Inventive formulation design principle: the main component of cement is CaO, SiO2、Al2O3、Fe2O3.There are also MgO, K2O、 Na2O、SO3, these ingredients can react decomposition in strong acid, cooperate in the stronger surfactant of cleaning capacity, bleeding agent It is common to remove residual cement, deionized water is added and is diluted to suitable concentration, essence is added and adjusts smell, preservative is added and increases The shelf-life of product.
The beneficial effects of the present invention are:
Product of the present invention can effectively, promptly remove a small amount of residual cement and realize following index, effect:
1, a small amount of cement on automobile fender can be dissolved rapidly, and the mud that vehicle is painted can be removed in the case where not hurting vehicle paint Dirt;
2, product can be used as the cleaning agent that family spends tea stain scale after diluting 10 times;
3, pump gun spraying can be used, easy to use, no waste sufficiently uses.
The feature that the present invention has elimination effect good, easy to use, cement residual can be dissolved and be removed in 3 minutes.
Detailed description of the invention
Fig. 1 is to use picture before product of the present invention.
Fig. 2 is to use picture after product of the present invention.
Specific embodiment
Below with reference to embodiment, the present invention is further illustrated.
Embodiment 1
Remove the remaining detergent of cement
Raw material: 37% concentrated hydrochloric acid 6kg, sodium sulfate of polyethenoxy ether of fatty alcohol (AES70) 2kg, coco-nut oil fatty acid diethyl Alkylolamides (6501) 1kg, penetrating agent JFC 5kg, sodium nitrite 0.8kg, Kathon CG 1.2kg, essence 0.1kg, deionized water 83.9kg。
The preparation method is as follows:
(1) strong acid dilutes: deionized water 30kg being put into plastic barrel, placing into power is 22-35KW, frequency conversion 0-3000 Turn/the stirring dispersion machine of min, slowly start stirring, 37% concentrated hydrochloric acid 6kg of accurate measurement is put into when stirring, mixing obtains dilute Strong acid after releasing can be ready for use on subsequent configuration.
(2) agent liquid is prepared: the good strong acid 36kg of pre-dilution being added and is prepared in pot, stirring is started, fat is added when stirring Alcohol polyethenoxy ether sodium sulfate (AES70) 2kg, cocoanut fatty acid diethanolamide (6501) 1kg, penetrating agent JFC 5kg, Asia Sodium nitrate 0.8kg, Kathon CG 1.2kg, essence 0.1kg, deionized water 53.9kg.Stirring 5 minutes, is uniformly dispersed and obtains agent material.
(3) it fills tank finished product: by the production method of aqua product, corresponding pump is added by product requirement after filling dose of liquid Rifle to get.
Embodiment 2
Remove the remaining detergent of cement
Raw material: 37% concentrated hydrochloric acid 5kg, fatty alcohol polyoxyethylene ether (AEO-9) 3kg, cocoanut fatty acid diethanolamide (6501) 1kg, penetrating agent JFC 4kg, Kathon CG 2kg, essence 0.1kg, deionized water 84.9kg.
The preparation method is as follows:
(1) strong acid dilutes: deionized water 25kg being put into plastic barrel, placing into power is 22-35KW, frequency conversion 0-3000 Turn/the stirring dispersion machine of min, slowly start stirring, 37% concentrated hydrochloric acid 5kg of accurate measurement is put into when stirring, mixing obtains dilute Strong acid after releasing can be ready for use on subsequent configuration.
(2) agent liquid is prepared: the good strong acid 30kg of pre-dilution being added and is prepared in pot, stirring is started, fat is added when stirring Alcohol polyoxyethylene ether (AEO-9) 3kg, cocoanut fatty acid diethanolamide (6501) 1kg, penetrating agent JFC 4kg, Kathon CG 2kg, Essence 0.1kg, deionized water 59.9kg.Stirring 5 minutes, is uniformly dispersed and obtains agent material.
(3) it fills tank finished product: by the production method of aqua product, corresponding pump is added by product requirement after filling dose of liquid Rifle to get.
Embodiment 3
Remove the remaining detergent of cement
Raw material: 37% concentrated hydrochloric acid 5kg, fatty alcohol polyoxyethylene ether (AEO-9) 2kg, alkyl phenol polyoxyethylene ether (TX-10) 2kg, dioctylis sulfosuccinas natricus 4kg, sodium molybdate 0.5kg, Kathon CG 1.5kg, essence 0.1kg, deionized water 84.9kg.
The preparation method is as follows:
(1) strong acid dilutes: deionized water 25kg being put into plastic barrel, placing into power is 22-35KW, frequency conversion 0-3000 Turn/the stirring dispersion machine of min, slowly start stirring, 37% concentrated hydrochloric acid 5kg of accurate measurement is put into when stirring, mixing obtains dilute Strong acid after releasing can be ready for use on subsequent configuration.
(2) agent liquid is prepared: the good strong acid 30kg of pre-dilution being added and is prepared in pot, stirring is started, fat is added when stirring Alcohol polyoxyethylene ether (AEO-9) 2kg, alkyl phenol polyoxyethylene ether (TX-10) 2kg, dioctylis sulfosuccinas natricus 4kg, molybdic acid Sodium 0.5kg, Kathon CG 1.5kg, essence 0.1kg, deionized water 59.9kg.Stirring 5 minutes, is uniformly dispersed and obtains agent material.
(3) it fills tank finished product: by the production method of aqua product, corresponding pump is added by product requirement after filling dose of liquid Rifle to get.
Embodiment 4
Remove the remaining detergent of cement
Raw material: 37% concentrated hydrochloric acid 8kg, fatty alcohol polyoxyethylene ether (AEO-9) 5kg, penetrating agent JFC 3kg, sodium benzoate 1kg, deionized water 75kg.
The preparation method is as follows:
(1) strong acid dilutes: deionized water 25kg being put into plastic barrel, placing into power is 22-35KW, frequency conversion 0-3000 Turn/the stirring dispersion machine of min, slowly start stirring, 37% concentrated hydrochloric acid 8kg of accurate measurement is put into when stirring, mixing obtains dilute Strong acid after releasing can be ready for use on subsequent configuration.
(2) agent liquid is prepared: the good strong acid 33kg of pre-dilution being added and is prepared in pot, stirring is started, fat is added when stirring Alcohol polyoxyethylene ether (AEO-9) 5kg, penetrating agent JFC 3kg, sodium benzoate 1kg, deionized water 50kg.Stirring 5 minutes, dispersion Uniformly obtain agent material.
(3) it fills tank finished product: by the production method of aqua product, corresponding pump is added by product requirement after filling dose of liquid Rifle to get.
Embodiment 5
Remove the remaining detergent of cement
Raw material: 37% concentrated hydrochloric acid 5kg, fatty alcohol polyoxyethylene ether (AEO-9) 2kg, penetrating agent JFC 2kg, sulfo group fourth two Sour sodium dioctyl ester 6kg, sodium molybdate 0.5kg, Kathon CG 1.5kg, deionized water 85kg.
The preparation method is as follows:
(1) strong acid dilutes: deionized water 25kg being put into plastic barrel, placing into power is 22-35KW, frequency conversion 0-3000 Turn/the stirring dispersion machine of min, slowly start stirring, 37% concentrated hydrochloric acid 5kg of accurate measurement is put into when stirring, mixing obtains dilute Strong acid after releasing can be ready for use on subsequent configuration.
(2) agent liquid is prepared: the good strong acid 30kg of pre-dilution being added and is prepared in pot, stirring is started, fat is added when stirring Alcohol polyoxyethylene ether (AEO-9) 2kg, dioctylis sulfosuccinas natricus 4kg, penetrating agent JFC 2kg, sodium molybdate 0.5kg, Kathon CG 1.5kg, deionized water 59.9kg.Stirring 5 minutes, is uniformly dispersed and obtains agent material.
(3) it fills tank finished product: by the production method of aqua product, corresponding pump is added by product requirement after filling dose of liquid Rifle to get.
Performance test
Every physical and chemical, functional attributes method of inspection:
1. feed liquid appearance: colourless to light yellow transparent liquid, range estimation.
2. smell: product are heard.
3.pH value (1%): it is executed by the regulation in GB6920-86.
4. density: being executed by the regulation in GB/T 1884.
5. solid content: being executed by the regulation in GB/T 2793.
6. cleaning rate: being carried out by the method in QB/T 2117.
7. heat resistance: sample being placed in baking oven, temperature is maintained at (40 ± 2) DEG C, and holding is taken out afterwards for 24 hours, is restored extremely It is observed after room temperature.
8. cold tolerance: sample being placed in refrigerator, temperature is maintained at (- 5 ± 2) DEG C, and holding is taken out afterwards for 24 hours, is restored extremely It is observed after room temperature.
1-3 of the embodiment of the present invention product being prepared is tested for the property, obtained quality index is as shown in table 1.
Table 1
Index parameter Embodiment 1 Embodiment 2 Embodiment 3
Feed liquid appearance Colourless transparent liquid Colourless transparent liquid Colourless transparent liquid
Smell Free from extraneous odour Free from extraneous odour Free from extraneous odour
PH value (1%) 1 2 2
Density, g/cm3 1.086 1.102 1.098
Solid content, % 9 8.5 8.4
Cleaning rate, % 92 88 87
Heat resistance It is qualified It is qualified It is qualified
Cold tolerance It is qualified It is qualified It is qualified
As can be seen from the data in table 1: the present invention, which removes the remaining detergent of cement, to be had to the remaining cleaning energy of a small amount of cement Power can remove a small amount of cement remained on automobile fender, building surface and hard surface that Common detergents are difficult to clean off Residual meets consumer and effectively removes the remaining demand of cement rapidly.
By attached drawing 1 and the comparison of attached drawing 2 it is found that the present invention removes the remaining detergent of cement, common cleaning can be rapidly removed What agent was difficult to clean off remains in a small amount of cement residual on automobile fender, building surface and hard surface, and effect is obvious, and makes Use convenient pollution-free.
Above-described embodiment is merely illustrative of the technical solution of the present invention and is not intended to limit it, all without departing from the present invention Any modification of spirit and scope or equivalent replacement should all cover the range in technical solution of the present invention.

Claims (7)

1. a kind of remaining detergent of removal cement, which is characterized in that the main product made of the following raw material: strong acid, surface Activating agent, bleeding agent, preservative, deionized water.
2. a kind of remaining detergent of removal cement according to claim 1, which is characterized in that according to the mass fraction, packet Include the following raw material: 5-8 parts of strong acid, 2-5 parts of surfactant, 3-8 parts of bleeding agent, 1-3 parts of preservative, 75-85 parts of deionized water.
3. a kind of remaining detergent of removal cement according to claim 1 or 2, which is characterized in that the strong acid is Concentrated hydrochloric acid.
4. a kind of remaining detergent of removal cement according to claim 1 or 2, which is characterized in that the surface is living Property agent be cocoanut fatty acid diethanolamide, alkyl phenol polyoxyethylene ether, sodium sulfate of polyethenoxy ether of fatty alcohol, poly alkyl alcohol One of ethylene oxide ether or multiple combinations.
5. a kind of remaining detergent of removal cement according to claim 1 or 2, which is characterized in that the bleeding agent For the combination of one or both of penetrating agent JFC, dioctylis sulfosuccinas natricus.
6. a kind of remaining detergent of removal cement according to claim 1 or 2, which is characterized in that the preservative For one of sodium benzoate, sodium nitrite, sodium molybdate, Kathon CG or multiple combinations.
7. a kind of method for preparing the claim 1~6 any one removal cement residual cleaning agent, which is characterized in that including Following steps: being add to deionized water dilution for strong acid, add surfactant, bleeding agent, preservative, is stirred It is even to get.
CN201910095555.1A 2019-01-31 2019-01-31 Remaining detergent of a kind of removal cement and preparation method thereof Pending CN109679782A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910095555.1A CN109679782A (en) 2019-01-31 2019-01-31 Remaining detergent of a kind of removal cement and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201910095555.1A CN109679782A (en) 2019-01-31 2019-01-31 Remaining detergent of a kind of removal cement and preparation method thereof

Publications (1)

Publication Number Publication Date
CN109679782A true CN109679782A (en) 2019-04-26

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU511335A1 (en) * 1973-11-28 1976-04-25 Уральский филиал Всесоюзного научно-исследовательского и проектного института химической промышленности Solid Surface Wash
CN101679915A (en) * 2007-06-12 2010-03-24 罗迪亚公司 Method with hard surface cleaning composition and cleaning hard surfaces of hydrophilizing agent
CN101735896A (en) * 2009-12-18 2010-06-16 天津工业大学 Cleaning agent for oil well cement
CN103725465A (en) * 2013-12-20 2014-04-16 同济大学 Thin-layer cement scale chemical cleaning agent mainly composed of hydroxyacetic acid
CN103773629A (en) * 2012-10-22 2014-05-07 章健嘉 Novel efficient cement scale cleaning fluid and preparation method thereof
CN104804906A (en) * 2015-04-14 2015-07-29 同济大学 Hardened cement body dirt cleaning agent and usage method thereof
CN105132196A (en) * 2015-09-29 2015-12-09 湖北穆兰同大科技有限公司 Car cleaning nursing agent and preparation method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU511335A1 (en) * 1973-11-28 1976-04-25 Уральский филиал Всесоюзного научно-исследовательского и проектного института химической промышленности Solid Surface Wash
CN101679915A (en) * 2007-06-12 2010-03-24 罗迪亚公司 Method with hard surface cleaning composition and cleaning hard surfaces of hydrophilizing agent
CN101735896A (en) * 2009-12-18 2010-06-16 天津工业大学 Cleaning agent for oil well cement
CN103773629A (en) * 2012-10-22 2014-05-07 章健嘉 Novel efficient cement scale cleaning fluid and preparation method thereof
CN103725465A (en) * 2013-12-20 2014-04-16 同济大学 Thin-layer cement scale chemical cleaning agent mainly composed of hydroxyacetic acid
CN104804906A (en) * 2015-04-14 2015-07-29 同济大学 Hardened cement body dirt cleaning agent and usage method thereof
CN105132196A (en) * 2015-09-29 2015-12-09 湖北穆兰同大科技有限公司 Car cleaning nursing agent and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
陈珍珍: "环保型水泥清洗剂研制", 《中国洗涤用品工业》 *

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Application publication date: 20190426