CN109666404A - A kind of children's wooden toy yellow paint and production method - Google Patents

A kind of children's wooden toy yellow paint and production method Download PDF

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Publication number
CN109666404A
CN109666404A CN201811453399.3A CN201811453399A CN109666404A CN 109666404 A CN109666404 A CN 109666404A CN 201811453399 A CN201811453399 A CN 201811453399A CN 109666404 A CN109666404 A CN 109666404A
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CN
China
Prior art keywords
parts
edible
children
low
yellow
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Pending
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CN201811453399.3A
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Chinese (zh)
Inventor
杨佳意
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Individual
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Individual
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Priority to CN201811453399.3A priority Critical patent/CN109666404A/en
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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D189/00Coating compositions based on proteins; Coating compositions based on derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D105/00Coating compositions based on polysaccharides or on their derivatives, not provided for in groups C09D101/00 or C09D103/00
    • C09D105/06Pectin; Derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/41Organic pigments; Organic dyes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Toys (AREA)

Abstract

The invention discloses a kind of children's wooden toy yellow paint and production methods, including using carthamin yellow, it is the composition weight proportion of the coating are as follows: 1 part to 2 parts of carthamin yellow, 5 parts to 10 parts edible gelatins, 2 parts to 5 parts of low-ester pectin, 0.5 part to 2 parts of edible grade sodium chloride, 1 part to 10 parts food grade calcium carbonate and 100 parts of water, wherein 1 part to 2 parts of carthamin yellow, 2 parts to 5 parts of low-ester pectin and 0.5 part to 2 parts of edible grade sodium chloride and water form mill base group, 5 parts to 10 parts edible gelatins and 1 part to 10 parts food grade calcium carbonate and water composition film forming promotion group, it is sufficiently mixed for two groups when use.A kind of children's wooden toy yellow paint that the production method of this use invention obtains, with high safety, after being coated on children's wooden toy, the toy even if children bite when playing, health hazard will not be brought to the person of biting, ensured the healthy growth of children, and both ensure that after being painted on wooden toy color it is bright-coloured and also keep wooden toy much cleaner and safe.

Description

A kind of children's wooden toy yellow paint and production method
Technical field
The present invention relates to a kind of production technology of coating, especially a kind of children's wooden toy yellow paint and producer Method.
Background technique
In existing toy coating, it is especially used for the toy for children coating of woodwork, used coating to be substantially third Olefin(e) acid class coating, as disclosed in 200910193125.X " acrylic emulsion of water-borne toy coating ", disclosed in 200910038289.5 " a kind of low volatility, quick-drying aqueous toy coating and its manufacturing method ", although acrylic coating is compared to poly- ammonia Esters coating toxicity is low, but as being used for toy for children, children when playing often biting in toy posting port, institute With for children and unsafe, as the coating of articles for children, it is not only that it should be without harmful volatility object Matter, also answering entrance is also to have safety.
For the wooden toy of children, the purpose of coating is to give various colors abundant, rather than extends wooden toy The problem of holding time, thus how to obtain it is a kind of can be given on woodwork color abundant without to child skin, It is the toy for children paint development matter of utmost importance to be considered that entrance, which all brings the coating of harm, at present almost without such a true Really it is suitable for the safety dope of children's wooden toy.
Summary of the invention
One kind is provided and is had a safety feature the purpose of the present invention is to solve above-mentioned the deficiencies in the prior art, and can be obtained Bright colors and being suitble to are attached to a kind of children's wooden toy yellow paint and production method of woodwork.
To achieve the goals above, a kind of children's wooden toy yellow paint designed by the present invention, including using red Anthoxanthin, it is characterised in that the composition weight proportion of the coating are as follows: 1 part to 2 parts of carthamin yellow, 5 parts to 10 portions foods With gelatin, 2 parts to 5 parts of low-ester pectin, 0.5 part to 2 parts of edible grade sodium chloride, 1 part to 10 parts food grade calcium carbonate and 100 The water of part, wherein 1 part to 2 parts of carthamin yellow, 2 parts to 5 parts of low-ester pectin and 0.5 part to 2 parts of edible grade sodium chloride Mill base group, 5 parts to 10 parts edible gelatins and 1 part to 10 parts food grade calcium carbonate and water composition film forming promotion group are formed with water, is made Two groups of used time are sufficiently mixed.
In order to further be incorporated in pigment on wood fibre, and in the presence of calcium ion there is preferably solidification to make With, the wear-resisting property and color saturation of coating are improved, keeps color more bright-coloured beautiful, a kind of children's wooden toy yellow Coating is the cornstarch being additionally provided in every 100 parts of above-mentioned components no more than 2 parts.
The present invention provides a kind of production method of children's wooden toy yellow paint, is first by 2 parts to 5 parts of low ester fruit Glue is wet with edible ethanol, for standard, then under high velocity agitation the dosage of edible ethanol is all wet with reaching low-ester pectin Will it is wet after low-ester pectin be dissolved in 50 parts of water, be added after being uniformly dissolved 0.5 part to 2 parts edible grade sodium chloride and 1 part To 2 parts of carthamin yellow, continues stirring and be all sufficiently solubilized to edible grade sodium chloride and carthamin yellow and with SILVER REAGENT salt Acid adjusts pH value that mill base group is made to 3 to 3.5;It is molten that gelatin separately is made in 50 parts of water in 5 parts to 10 parts edible gelatins heating for dissolving Liquid, heating and temperature control is at 60 DEG C hereinafter, 1 part to 10 parts food grade calcium carbonate is added in gelatin solution again and is sufficiently stirred Mix composition film forming promotion group;When needing coating, mill base group and film forming promotion group are mixed and are stirred well to uniformly.
Here, carthamin yellow is one of carthamin yellow pigment, light resistance is good, and 100 degree or less unchanged;? In acidic aqueous solution, effect is more preferable, and dyeing capacity is strong;Pectin plays emulsification after pigment dissolves in gelatin, pigment herein Dispersion and stabilization, further stable pigment plays the role of protecting color sodium chloride, and carthamin yellow is in the environment existing for pectin It is with good stability, keep bright in color distinctness without fugitive color;The addition of food grade calcium carbonate, can be according to additional amount Control is adjusted to opacity needed for wood materials, and calcium ion also promotes the film forming of low-ester pectin, pectin film can play anti- Bacterium bacteriostasis forms antibiotic layer in wood surface, makes the much cleaner safety of wooden toy;Using reagent grade hydrochloric acid adjusting coating PH Value, ensure that guarantor's colour circle border of carthamin yellow.
When needing that cornstarch is added, it is the cornstarch being added in every 100 parts of above-mentioned components no more than 2 parts, first will Cornstarch is completely dissolved under high velocity agitation in 50 parts of water, is added the low-ester pectin with edible ethanol after wet, is worked as jade Rice starch and low-ester pectin be added in stirring again after being completely dissolved 0.5 part to 2 parts edible grade sodium chloride and 1 part to 2 parts Simultaneously mill base group is made with reagent grade hydrochloric acid tune pH value to 3 to 3.5 in carthamin yellow, this successive addition sequence, to facilitate low ester The dispersion and dissolution of pectin in water, guarantee the product quality of coating.
A kind of children's wooden toy yellow paint that the production method of this use invention obtains, it is all former using food-grade Material has high safety, and after being coated on children's wooden toy, the toy even if children bite when playing will not be gnawed The person of stinging brings health hazard, has ensured the healthy growth of children, here, low-ester pectin, cornstarch and edible gelatin are in this hair In the composition of bright offer all have film forming, and have respective effect, both ensure that after being painted on wooden toy color It is bright-coloured, also make wooden toy much cleaner and safe.
Specific embodiment
Below with reference to embodiment, the present invention is further described.
Embodiment 1:
A kind of children's wooden toy yellow paint that this implementation column provides, including carthamin yellow is used, it is the coating Composition weight proportion are as follows: 1 part of carthamin yellow, 5 parts of edible gelatins, 5 parts of low-ester pectin, 0.5 part of edible grade sodium chloride, 1 Part food grade calcium carbonate and 100 parts of water, wherein 1 part of carthamin yellow, 5 parts of low-ester pectin and 0.5 part of edible grade sodium chloride Mill base groups, 5 parts of edible gelatins and 1 part of food grade calcium carbonate and 50 parts of water composition film forming promotion groups are formed with 50 parts of water, when use Two groups are sufficiently mixed.
It is first by 5 parts of low-ester pectin the present embodiment provides a kind of production method of children's wooden toy yellow paint Wet with edible ethanol, the dosage of edible ethanol is all wet with reaching low-ester pectin as standard, then under high velocity agitation will Low-ester pectin after wet is dissolved in 50 parts of water, and 0.5 part of edible grade sodium chloride and 1 part of safflower yellow are added after being uniformly dissolved Element continues stirring and is all sufficiently solubilized to edible grade sodium chloride and carthamin yellow and with reagent grade hydrochloric acid tune pH value to 3 to 3.5 Mill base group is made;5 parts of edible gelatins heating for dissolving is separately made gelatin solution in 50 parts of water, heating and temperature control 60 DEG C with Under, 1 part of food grade calcium carbonate is added in gelatin solution and carries out that composition film forming promotion group is sufficiently stirred.When needing coating, by color Slurry group and film forming promotion group are mixed and are stirred well to uniformly.
A kind of children's wooden toy yellow paint that the present embodiment obtains, by naturally dry after being painted on wooden toy Translucent beautiful yellow is presented after film forming in dry film forming.
Embodiment 2:
A kind of children's wooden toy yellow paint that this implementation column provides, including carthamin yellow is used, it is the coating Composition weight proportion are as follows: 2 parts of carthamin yellow, 10 parts of edible gelatins, 2 parts of low-ester pectins, 2 parts of edible grade sodium chloride, 10 parts of food grade calcium carbonate and 100 parts of water, wherein 2 parts of carthamin yellow, 2 parts of low-ester pectins and 2 parts of food grade chlorination Sodium and 50 parts of water form mill base group, 10 parts of edible gelatins and 10 parts of food grade calcium carbonate and 50 parts of water composition film forming promotion groups, make Two groups of used time are sufficiently mixed.
It is first to use 2 parts of low-ester pectins the present embodiment provides a kind of production method of children's wooden toy yellow paint Edible ethanol is wet, and the dosage of edible ethanol is all wet with reaching low-ester pectin as standard, then under high velocity agitation will be wet Low-ester pectin after profit is dissolved in 50 parts of water, and 2 parts of edible grade sodium chloride and 2 parts of safflower yellow are added after being uniformly dissolved Element continues stirring and is all sufficiently solubilized to edible grade sodium chloride and carthamin yellow and with reagent grade hydrochloric acid tune pH value to 3 to 3.5 Mill base group is made;Separately 10 parts of edible gelatins are dissolved by heating, gelatin solution is made in 50 parts of water, heating and temperature control is at 60 DEG C Hereinafter, 10 parts of food grade calcium carbonate are added in gelatin solution and carry out that composition film forming promotion group is sufficiently stirred.It, will when needing coating Mill base group and film forming promotion group are mixed and are stirred well to uniformly.
A kind of children's wooden toy yellow paint that the present embodiment obtains, by naturally dry after being painted on wooden toy Opaque beautiful yellow is presented after film forming in dry film forming.
Embodiment 3:
A kind of children's wooden toy yellow paint that this implementation column provides is implemented at every 100 parts on the basis of embodiment 1 2 parts of cornstarch is added in component described in example 1.It is the jade that 2 parts are added in every 100 parts of above-mentioned components when cornstarch is added Cornstarch is first completely dissolved in 50 parts of water by rice starch under high velocity agitation, is added low after wet with edible ethanol Ester pectin, be added in stirring again after cornstarch and low-ester pectin are completely dissolved 0.5 part edible grade sodium chloride and 1 part it is red Simultaneously mill base group is made with reagent grade hydrochloric acid tune pH value to 3 to 3.5 in anthoxanthin, this successive addition sequence, to facilitate low ester fruit The dispersion and dissolution of glue in water, guarantee the product quality of coating.
Embodiment 4:
A kind of children's wooden toy yellow paint that this implementation column provides is implemented on the basis of embodiment 2 at every 100 parts 0.5 part of cornstarch is added in component described in example 2.It is that 0.5 part is added in every 100 parts of above-mentioned components when cornstarch is added Cornstarch, first cornstarch is completely dissolved under high velocity agitation in 50 parts of water, add with edible ethanol it is wet after Low-ester pectin, be added in stirring again after cornstarch and low-ester pectin are completely dissolved 2 parts edible grade sodium chloride and 2 parts Carthamin yellow and mill base group is made with reagent grade hydrochloric acid tune pH value to 3 to 3.5, this successive addition sequence is low to facilitate The dispersion and dissolution of ester pectin in water, guarantee the product quality of coating.

Claims (4)

1. a kind of children's wooden toy yellow paint, including use carthamin yellow, it is characterised in that the composition of the coating Weight proportion are as follows: 1 part to 2 parts of carthamin yellow, 5 parts to 10 parts edible gelatins, 2 parts to 5 parts of low-ester pectin, 0.5 part to 2 The edible grade sodium chloride, 1 part to 10 parts food grade calcium carbonate and 100 parts of water of part, wherein 1 part to 2 parts of carthamin yellow, 2 Part form mill base group to the edible grade sodium chloride and water of 5 parts of low-ester pectin and 0.5 part to 2 parts, 5 parts to 10 parts edible gelatins and 1 part to 10 parts food grade calcium carbonate and water composition film forming promotion group, are sufficiently mixed for two groups when use.
2. a kind of children's wooden toy yellow paint according to claim 1, it is characterized in that in every 100 parts of above-mentioned components In be additionally provided with cornstarch no more than 2 parts.
3. a kind of a kind of production method of children's wooden toy yellow paint according to claim 1, it is characterized in that first 2 parts to 5 parts of low-ester pectin is moistened with edible ethanol, the dosage of edible ethanol is all wet with reaching low-ester pectin as mark Standard, the low-ester pectin after then moistening under high velocity agitation are dissolved in 50 parts of water, and 0.5 part to 2 parts is added after being uniformly dissolved Edible grade sodium chloride and 1 part to 2 parts of carthamin yellow, continue stirring and all filled to edible grade sodium chloride and carthamin yellow Divide and dissolves and mill base group is made with reagent grade hydrochloric acid tune pH value to 3 to 3.5;Separately by 5 parts to 10 parts edible gelatins dissolve by heating in Gelatin solution is made in 50 parts of water, heating and temperature control is at 60 DEG C hereinafter, 1 part to 10 parts food grade is added in gelatin solution again Calcium carbonate simultaneously carries out that composition film forming promotion group is sufficiently stirred;When needing coating, mill base group and film forming promotion group are mixed and sufficiently stirred It mixes to uniform.
4. the production method of a kind of children's wooden toy yellow paint according to claim 3, it is characterized in that every 100 It is additionally provided with the cornstarch no more than 2 parts in the above-mentioned component of part, cornstarch is first completely dissolved in 50 parts under high velocity agitation In water, the low-ester pectin with edible ethanol after wet is added, is being stirred again after cornstarch and low-ester pectin are completely dissolved 0.5 part to 2 parts of edible grade sodium chloride of middle addition and 1 part to 2 parts of carthamin yellow and with reagent grade hydrochloric acid tune pH value to 3 to 3.5 are made mill base group.
CN201811453399.3A 2018-11-30 2018-11-30 A kind of children's wooden toy yellow paint and production method Pending CN109666404A (en)

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CN201811453399.3A CN109666404A (en) 2018-11-30 2018-11-30 A kind of children's wooden toy yellow paint and production method

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CN201811453399.3A CN109666404A (en) 2018-11-30 2018-11-30 A kind of children's wooden toy yellow paint and production method

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1050733A (en) * 1990-10-26 1991-04-17 付蓬 The method of aqueous color paste and coating wood thereof
CN101245207A (en) * 2007-02-16 2008-08-20 朱庆成 Inner wall paint
CN103725071A (en) * 2013-12-25 2014-04-16 邹珺 Method for self-making finger painting pigment from food materials
CN107641377A (en) * 2017-11-02 2018-01-30 苏州甫众塑胶有限公司 A kind of preparation method of food packaging antibiotic paint

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1050733A (en) * 1990-10-26 1991-04-17 付蓬 The method of aqueous color paste and coating wood thereof
CN101245207A (en) * 2007-02-16 2008-08-20 朱庆成 Inner wall paint
CN103725071A (en) * 2013-12-25 2014-04-16 邹珺 Method for self-making finger painting pigment from food materials
CN107641377A (en) * 2017-11-02 2018-01-30 苏州甫众塑胶有限公司 A kind of preparation method of food packaging antibiotic paint

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
曹竑: "《食品添加剂》", 31 July 2004, 甘肃民族出版社 *

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Application publication date: 20190423