JPS59120075A - Coloring of food - Google Patents

Coloring of food

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Publication number
JPS59120075A
JPS59120075A JP57229108A JP22910882A JPS59120075A JP S59120075 A JPS59120075 A JP S59120075A JP 57229108 A JP57229108 A JP 57229108A JP 22910882 A JP22910882 A JP 22910882A JP S59120075 A JPS59120075 A JP S59120075A
Authority
JP
Japan
Prior art keywords
salts
food
anthraquinone
mixing
salt
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP57229108A
Other languages
Japanese (ja)
Inventor
Nobuyoshi Nosaka
野坂 宜嘉
Nobuo Miyano
宮野 信雄
Mikinori Asano
幹則 浅野
Hirotsugu Kato
加藤 洋次
Osamu Yamamoto
治 山本
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
TAISHO KK
Original Assignee
TAISHO KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by TAISHO KK filed Critical TAISHO KK
Priority to JP57229108A priority Critical patent/JPS59120075A/en
Publication of JPS59120075A publication Critical patent/JPS59120075A/en
Pending legal-status Critical Current

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  • Coloring Foods And Improving Nutritive Qualities (AREA)

Abstract

PURPOSE:To obtain a colored food resistant to blotting during storage, by adding and mixing an anthraquinone natural dye and a salt selected from calcium salt, magnesium salt, and aluminum salt to the food. CONSTITUTION:The objective colored food is prepared by adding an anthraquinone-type natural dye (e.g. cochineal pigment, chermes pigment, etc.) and/or an agent containing the anthraquinon-type natural dye, and mixing the colored food with one or more salts selected from calcium salts (e.g. calcium lactate), magnesium salts (e.g. magnesium chloride) and aluminum salts (e.g. aluminum chloride). As an elternative method, the salt such as calcium salt is added to the food, and then the product is colored with the anthraquinone-type natural dye.

Description

【発明の詳細な説明】 された食品において色のにじみを防止する方法に関する
。さらに詳細にけ本発明はアントラキノン系天然色素に
より着色される食品、ihに蛋白質性食品に当該色素を
添加す.る工程の前後いずれかにおいてカルシウム塩類
、マグネシウム塩類及びアルミニウム塩類のうちの7種
又は2種以上の混合物を添加、混合して色のにじみを防
止する方法に関するものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for preventing color bleeding in processed foods. More specifically, the present invention involves adding the pigment to foods colored with anthraquinone natural pigments, ih and protein foods. The present invention relates to a method for preventing color bleeding by adding and mixing seven or a mixture of two or more of calcium salts, magnesium salts, and aluminum salts either before or after the step of adding and mixing calcium salts, magnesium salts, and aluminum salts.

従来食品を着色する天然色素としてはカロチノイ)’i
色!、7ラボノイド系色素、アントシアニン糸色素、キ
ノン系色素、ポルフィリン系色素及びペタシアニン系色
素など痴使用されているが、特に赤色系の色素としては
その耐熱性及び耐光性に優れたアントラキノン系色素(
キノン系色素の7種)が広く吏用されている。アントラ
キノン系色iのケルメス色素、コチニール色素及びラッ
ク色素は耐熱性、耐光性に優れているが、一方p■によ
り色調は著しく変化し酸性側で赤橙色、中性付近で赤色
、アルカリ性側で赤紫色となる。また蛋白質、性食品に
使用すると蛋白質に吸着され、不鮮明かつ暗色の赤紫色
に変色し、食品の価値を著しく減少させる。従ってアン
トラキノン系色素のみを蛋白質性食品に添加することは
殆ど実施されていない。これらの欠点−を改良する方法
として色素安定剤と云われる焼ミョウバン、焼アンモニ
ウムミョウバン、酒石酸又はアルカリ塩類、炭酸ナトリ
ウムなどを併用するかまだはそれらの安定剤を配合した
色f製剤を使用する。これによって鮮明な色調をもつ水
溶性の安定した色素としてその用途が広くなった。しか
しながら蒲鉾、かに風蒲鉾、細工蒲鉾、なると巻及び畜
肉ソーセージなどを上記アントラキノン系天然色素又は
その色素製剤(以下色素製剤類と略す)により着色した
場合にはその保存中に色素のにじみを生じて商品価値を
著しく減少させる。例釆ば赤蒲鉾即ち蒲鉾の上表面から
側面にわたり赤色色素含有の蒲鉾層(赤色11 )を施
された蒲鉾は該赤色層と本体部の白色蒲鉾との境界にに
じみを生ぜず赤色層と白色本体とが明瞭に区画されてい
ることが必要であるから両者の境界かにじんだりぼやけ
たりすることは蒲鉾の商品価値を激減させることとなる
Traditionally, carotenoids are used as natural pigments to color foods.
color! , 7-labonoid pigments, anthocyanin thread pigments, quinone pigments, porphyrin pigments, and petacyanin pigments, among which red pigments include anthraquinone pigments (which have excellent heat resistance and light resistance).
Seven types of quinone pigments are widely used. Kermes dyes, cochineal dyes, and lac dyes of anthraquinone color I have excellent heat resistance and light resistance, but on the other hand, the color tone changes significantly with p■, becoming reddish-orange on the acidic side, red when near neutral, and red on the alkaline side. It turns purple. Furthermore, when used in protein or food products, it is adsorbed by the protein and changes color to an indistinct and dark reddish-purple color, significantly reducing the value of the food. Therefore, adding only anthraquinone pigments to protein foods is rarely practiced. As a method to improve these drawbacks, color f preparations containing dye stabilizers such as calcined alum, calcined ammonium alum, tartaric acid or alkali salts, sodium carbonate, etc. are used in combination, or else these stabilizers are blended. This has led to its use as a stable, water-soluble pigment with vivid color tones. However, when kamaboko, crab-style kamaboko, crafted kamaboko, naru-maki, meat sausage, etc. are colored with the above-mentioned anthraquinone-based natural dyes or their dye preparations (hereinafter referred to as dye preparations), the dye may bleed during storage. and significantly reduce the product value. For example, in the case of red kamaboko, that is, a kamaboko with a kamaboko layer (red color 11) containing a red dye applied from the top surface to the sides, no bleeding occurs at the boundary between the red layer and the white kamaboko of the main body, and the red layer and white kamaboko do not bleed. Since it is necessary for the kamaboko to be clearly separated from the main body, if the boundary between the two is blurred or blurred, the commercial value of the kamaboko will be drastically reduced.

本発明者らは色素製剤類によシ着色された食品の色のに
じみ防止に関し鋭意研究を重ねた結果本発明に到達した
。即ち従来の色素製剤類を使用した際の色のにじみ現象
の分析から研究に入シ、その主な原因が色素製剤類の水
溶性に起因することを解明した。さらに色素製剤類の水
溶性を減少させることにより色素の移行を少くしてにじ
みを防止することはできたが、食品に添加した除に食品
を均一に着色することが極めて困難であることが判った
。これらの経験から蓄漬された技術と各食品の製造工程
に関する知識とから各食品について幾多の試作品を製造
してその結果本発明に到達した。本発明方法において使
用するアントラキノン系天然色素及び(又は)その色素
製剤は主とし千ケルメス色素、コ゛チニール色紫及びラ
ック色素の7種又は2.a以上の混合物もしくはこれら
と色素安定剤(焼ミョウバン、:暁アンモニウムミョウ
パン、酒石酸又はアルカリ塩類及び炭酸す) +Jウム
など)との混合物又は混合溶液であシカルシウム塩類、
マグネシウム塩類及びアルミニウム塩類としては一般に
無償酸塩及び有機酸塩を使用し得る“が日本国内で食品
に使用する場合には食品添加物公定書に記載されて4る
物質でなければならない。
The present inventors have arrived at the present invention as a result of extensive research into preventing color bleeding in foods colored with colorant preparations. That is, we began research by analyzing the color bleeding phenomenon when conventional dye preparations were used, and discovered that the main cause of this was due to the water solubility of the dye preparations. Furthermore, by reducing the water solubility of pigment preparations, it was possible to reduce migration of pigments and prevent bleeding, but it was found that it was extremely difficult to uniformly color foods even when they were added to foods. Ta. Using the techniques accumulated from these experiences and the knowledge regarding the manufacturing process of each food product, we manufactured numerous prototypes of each food product, and as a result, we arrived at the present invention. The anthraquinone natural pigments and/or their pigment preparations used in the method of the present invention are mainly 7 types or 2. A mixture or mixed solution of the above or these with a pigment stabilizer (burnt alum, Akatsuki ammonium alum, tartaric acid or alkali salts and carbonic acid, etc.), calcium salts,
Generally, free acid salts and organic acid salts can be used as magnesium salts and aluminum salts, but when used in foods in Japan, they must be substances listed in the Official Food Additives Standard.

一方これらの塩類の使用量に特に制限はないが添加され
る色素製剤類の種類と量とにより異り、該儂は一般的に
は着色しようとする食品に対してθ/〜/3重景ノ々−
セントであることが望ましい。
On the other hand, there is no particular limit to the amount of these salts used, but it varies depending on the type and amount of the coloring agent added, and they are generally used at Nono-
Preferably cents.

以下に本発明方法を具体的に説明するために実施例を記
すがこれによって本発明方法は限定されるものではない
。実施例において使用したアントラキノン系色素又はそ
の色素製剤(色素製剤類)を第1表に示し、カルシウム
塩類、マグネシウム塩類及びアルミニウム塩類の7種又
は、2種以上の混合物を第2表に示しさ。
Examples are given below to specifically explain the method of the present invention, but the method of the present invention is not limited thereto. Table 1 shows anthraquinone dyes or their dye preparations (dye preparations) used in the examples, and Table 2 shows seven types or mixtures of two or more of calcium salts, magnesium salts, and aluminum salts.

実施例/ 第1表中より色素I、II及びケルメス色素を、第2表
中より塩類工、■及び■を選んで赤蒲鉾を製造した。即
ち色素製剤類7部に水コ部を添加して色素液とする。蒲
鉾の上身(色素含有層)用のすり身700部に上記色素
液を添加、混合し均一に着色したのち塩類I〜■のそれ
ぞれ7部を添加、混合しそれぞれの着色すシ身を製造し
た。これらの上身を用いて常法により赤蒲鉾を製造し、
3〜7Cで/週間保存したのち観察した結果は第3表の
ようになり、従来の方法においては色のにじみが生じた
にもかかわらず本発明方法においては色のにじみを防止
でき、商品価値の高い赤蒲鉾を製造することができた。
Example/ Red kamaboko was produced by selecting dyes I, II and Kermes dyes from Table 1 and salt dyes, ■ and ■ from Table 2. That is, one part of water is added to seven parts of the pigment preparation to prepare a pigment liquid. The above dye liquid was added to 700 parts of surimi for the upper part of kamaboko (pigment-containing layer) and mixed to uniformly color the mixture, and then 7 parts of each of salts I to ① were added and mixed to produce each colored surimi. Red kamaboko is produced using these upper fish using conventional methods.
The results observed after storage at 3 to 7C for a week are shown in Table 3. Although color bleeding occurred in the conventional method, color bleeding was prevented in the method of the present invention, and the product value increased. We were able to produce high quality red kamaboko.

第3表 実施例コ 第1表中より色素■、tV、V及びコチニール色素を、
第2表中より塩類■、塩化カルシウム、塩化マグネシウ
ム及び塩化アルミニウムを選んで実施例/と同様に赤蒲
鉾を製造した。即ち色素製剤類7部に水2部を添加して
色素液とする。藺鉾の上身用すり身700部に上記塩類
のそれぞれ3部を添加、混合したのち色素液を添加、混
合してそれぞれの着色すり身を製造した。これらの上身
を用いて常法により赤蒲鉾を製造し、10Cで5日間保
存したのち観察した結果は第7表のようになり、従来法
にくらべて本発明方法による赤蒲鉾は色のにじみが無く
商品価値の高いものであった。
Table 3 Examples From Table 1, the dyes ■, tV, V and cochineal dye were
Salts ①, calcium chloride, magnesium chloride and aluminum chloride were selected from Table 2 and red kamaboko was produced in the same manner as in Example. That is, 2 parts of water is added to 7 parts of pigment preparations to prepare a pigment liquid. Three parts of each of the above salts were added to 700 parts of surimi for the upper body of Ichiboko and mixed, and then a color liquid was added and mixed to produce each colored surimi. Red kamaboko was produced using the above-mentioned upper fish in a conventional manner and observed after storage at 10C for 5 days. The results are as shown in Table 7. Compared to the conventional method, the red kamaboko produced by the method of the present invention has less color bleeding. It was a product with high commercial value.

第り表 (注)風味においては全試験区とも正常であった実施例
3 第7表中より色素■、■、■及びラック色素を、第一表
中より塩類I、■、■及び■を選んでかに風蒲鉾を製造
した。即ちかにa蒲鉾用のすシ身/θ0部に上記塩類の
それぞれ3部を添加、混合したのち成型し15Cに約7
0時間坐りをかけた。
Table 1 (Note) All test plots were normal in flavor Example 3 Colors ■, ■, ■, and lac pigments from Table 7, and salts I, ■, ■, and ■ from Table 1. I selected and made crab-style kamaboko. That is, 3 parts of each of the above salts were added to 0 parts of sushi meat for crab a kamaboko, mixed, and molded to 15C.
I sat for 0 hours.

その後にその表面に対し上記色素製剤類7部を水コ部に
溶解させた色素液を塗布し、常法により蒸し、裁断し、
かに風蒲鉾(きざみ)を製造した。
Thereafter, a dye solution prepared by dissolving 7 parts of the above dye preparations in water is applied to the surface, steamed and cut in a conventional manner,
Manufactured crab-style kizami.

!r〜7Cに/週間保存したのち観察した結果を第3表
に示したがこれによると本発明方法によるものは色のに
じみ無く、商7品価値の高いものであつ第5表 (注)風味においては全試験区とも正常であった。
! Table 3 shows the results of observation after storage at ~7C for a week. According to the results, the products produced by the method of the present invention had no color bleeding, had high product value, and had a high flavor as shown in Table 5 (Note). The results were normal in all test plots.

実施例グ □第1表より色素■を、第1表より塩化カルシウムを選
んで次のようになると巻を製造した。なると巻の着色用
すり身/θθ部に塩化カルシウムのθ03;θ0左;θ
/;θ夕;/;3;5及び7部のそれぞれを添加混合し
たのち上記色素■の03部を水7部に溶かした色素液を
添加、混合して着色すシ身を製造した。これを用いゝて
常法によりなると巻を製造したところ「の」の字を鮮明
に着色した。/θCに3日間保存したのち観察した結)
を第6表に示した。
Example □ Dye □ was selected from Table 1, calcium chloride was selected from Table 1, and the following volumes were manufactured. Surimi for coloring of Narumaki / θ03 of calcium chloride in θθ part; θ0 left; θ
After adding and mixing 5 and 7 parts of /; θ / 3, respectively, a dye liquid prepared by dissolving 03 parts of the above dye (2) in 7 parts of water was added and mixed to produce colored shiitake. When a roll was produced using this in a conventional manner, the character ``no'' was clearly colored. Results observed after storage at /θC for 3 days)
are shown in Table 6.

第乙表 常であった 本発明方法による試験区(A2〜9)の中では應λに若
干色のにじみを生じたが他の試験区では色のにじみがな
く鮮明な「の」印が出来て商品価値の高いものであった
In the test plots (A2 to 9) using the method of the present invention, which was common in Section B, there was some color bleeding on the λ, but in the other test plots, there was no color blurring and a clear "no" mark was obtained. It had a high commercial value.

実施例S 第7表中より色素■を、第2表中より塩類■を選んで次
のようにしてなると春風ソーセージを製造した。即ちソ
ーセージ用すり身に塩類■のθ左;/;3;左;7;/
θ及び/左部を添加混合し、そののちに色素■のコ部を
水5部にとがした色素液を添加、混合して着色すり身を
製造した。この着色すり身と無着色すり身とを用いて常
法によりなると春風ソーセージを製造したところ「の」
印を鮮明に着色させ得た。これを10cに/週間保存し
たのちに観察した結果を第7表に示した。
Example S A spring breeze sausage was produced by selecting the coloring matter (2) from Table 7 and the salt (2) from Table 2 as follows. In other words, θ of salt ■ for sausage minced meat; /; 3; left; 7; /
Colored surimi was prepared by adding and mixing the θ and left portions, and then adding and mixing a dye liquid prepared by diluting the ko portion of the dye ① with 5 parts of water. Using the colored surimi and non-colored surimi, Harukaze sausage was produced using a conventional method.
The mark could be clearly colored. Table 7 shows the results observed after storing this at 10c/week.

(注)馬名の試験区で若干興味があったが他の試験区は
正常であった 実施例乙 第1表中より色素Iを、第2表中より塩化カルシウムを
選び、色素■の7部に塩化カルシウム03〜10部を配
合して色素製剤を調製した。この配合物の2部に水Ω部
を加えて色素液とし、蒲鉾の上身用すシ身10θ部に添
加、混合する。得られた着色したすり身を用いて常法に
より赤蒲鉾を製造しS〜7Cで1週間保存したのち観察
した結果は第3表のようになり、従来の方法においては
色のにじみを生じたにもかかわらず本発明方法において
は色のにじみを防止することができ、商品価値の高い赤
蒲鉾を製造し得た。
(Note) There was some interest in the horse name test group, but the other test groups were normal.Example B Select dye I from Table 1, calcium chloride from Table 2, and dye 7 A pigment preparation was prepared by adding 03 to 10 parts of calcium chloride. Add Ω parts of water to 2 parts of this mixture to obtain a coloring liquid, and add and mix with 10 θ parts of the fish meat used for the upper body of kamaboko. Using the obtained colored surimi, red kamaboko was produced by a conventional method and observed after storage at S to 7C for one week. The results were as shown in Table 3. However, in the method of the present invention, color bleeding could be prevented and red kamaboko with high commercial value could be produced.

第3表Table 3

Claims (6)

【特許請求の範囲】[Claims] (1)食品に対しアントラキノン系天然色素及び(又は
)それを含む製剤並びにカルシウム塩類、マグネシウム
塩類及びアルミニウム塩類のうちの7種または2種以上
の混合物を添加、混合することを特徴とする食品の着色
方法。
(1) A food product characterized by adding and mixing an anthraquinone natural pigment and/or a preparation containing the same, and a mixture of seven or two or more of calcium salts, magnesium salts, and aluminum salts to the food product. Coloring method.
(2)  食品に対しアントラキノン系天然色素及び(
又は)それを含む製剤を添加、混合する第1工程とカル
シウム塩類、マグネシウム塩類及びアルミニウム塩類の
1.うちの7種または2種以上の混合物を添加、混合す
る第ユニ程とから成ることを特徴とする特許請求の範囲
第1項に記載の食品の着色方法。
(2) Anthraquinone natural pigments and (
or) the first step of adding and mixing a preparation containing the same and 1. of calcium salts, magnesium salts and aluminum salts. 2. The method for coloring food according to claim 1, which comprises a first step of adding and mixing seven or a mixture of two or more of the above.
(3)  食品に対しカルシウム塩類、マグネシウム塩
類及びアルミニウム塩類のうちの7種または2種以上の
混合物を添加、混合する第1工程とアントラキノン系天
然色素及び(又は)それを含む製剤を添加、混合する第
ス工程とから成ることを特徴とする特許請求の範囲第1
項に記載の方法。
(3) The first step of adding and mixing seven types or a mixture of two or more of calcium salts, magnesium salts, and aluminum salts to food, and adding and mixing anthraquinone natural pigments and/or preparations containing them. Claim 1, characterized in that it consists of a step S.
The method described in section.
(4)  アントラキノン系天然色素及び(又は)それ
を含む製剤が溶液状であり、食品への添加、混合が該溶
液で食品の表面を処理する工程から成ることを特徴とす
る特許請求の範囲第1項に記載の方法。
(4) The anthraquinone natural pigment and/or the preparation containing it are in the form of a solution, and the addition to and mixing with the food consists of a step of treating the surface of the food with the solution. The method described in Section 1.
(5)  アントラキノン系天然色素及び(又は)それ
を含む製剤にカルシウム塩類及びマグネシウム塩類のう
ちの7種または2種以上を配合することを特徴とする特
許請求の範囲第1項に記載の方法。
(5) The method according to claim 1, characterized in that seven or more of calcium salts and magnesium salts are blended into the anthraquinone natural pigment and/or a preparation containing the same.
(6)  アントラキノン系天然色素及び(又は)それ
を含む製剤に対してカルシウム塩類、マグネシウム塩類
及びアルミニウム塩類のうちの/lまだは2種以上の混
合物を配合することを特徴とするアントラキノン系天然
色素及び(又は)それを含む製剤の食品中における色の
にじみの防止方法。
(6) An anthraquinone natural pigment and/or a mixture of two or more of calcium salts, magnesium salts, and aluminum salts is added to the anthraquinone natural pigment and/or a preparation containing the same. and/or a method for preventing color bleeding in food products containing the same.
JP57229108A 1982-12-27 1982-12-27 Coloring of food Pending JPS59120075A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP57229108A JPS59120075A (en) 1982-12-27 1982-12-27 Coloring of food

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP57229108A JPS59120075A (en) 1982-12-27 1982-12-27 Coloring of food

Publications (1)

Publication Number Publication Date
JPS59120075A true JPS59120075A (en) 1984-07-11

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
JP57229108A Pending JPS59120075A (en) 1982-12-27 1982-12-27 Coloring of food

Country Status (1)

Country Link
JP (1) JPS59120075A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0536878A2 (en) * 1991-08-23 1993-04-14 Del Monte Corporation Method for coloring fruits and vegetables
JPH08509997A (en) * 1993-02-24 1996-10-22 ワーナー−ジェンキンソン・カンパニー・インコーポレイテッド Dye composition and thin film coating method for tablets
EP1666539A1 (en) * 2003-09-03 2006-06-07 Otkrytoe Aktsionernoe Obschestvo "Lianozovsky Molochny Kombinat" Carminic acid complex compound, method for the production thereof, a food product and beverage
JP2013201949A (en) * 2012-03-28 2013-10-07 Riken Vitamin Co Ltd Cochineal pigment pharmaceutical preparation
JP2015067723A (en) * 2013-09-30 2015-04-13 理研ビタミン株式会社 Anthraquinone-based dye formulation

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5362856A (en) * 1976-11-13 1978-06-05 Shimizugen Shiyouten Kk Production of red cherry

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5362856A (en) * 1976-11-13 1978-06-05 Shimizugen Shiyouten Kk Production of red cherry

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0536878A2 (en) * 1991-08-23 1993-04-14 Del Monte Corporation Method for coloring fruits and vegetables
JPH08509997A (en) * 1993-02-24 1996-10-22 ワーナー−ジェンキンソン・カンパニー・インコーポレイテッド Dye composition and thin film coating method for tablets
EP1666539A1 (en) * 2003-09-03 2006-06-07 Otkrytoe Aktsionernoe Obschestvo "Lianozovsky Molochny Kombinat" Carminic acid complex compound, method for the production thereof, a food product and beverage
EP1666539A4 (en) * 2003-09-03 2009-11-18 Open Joint Stock Company Wimm Carminic acid complex compound, method for the production thereof, a food product and beverage
JP2013201949A (en) * 2012-03-28 2013-10-07 Riken Vitamin Co Ltd Cochineal pigment pharmaceutical preparation
JP2015067723A (en) * 2013-09-30 2015-04-13 理研ビタミン株式会社 Anthraquinone-based dye formulation

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