CN106752570A - Water-in-water multicolor coating suitable for streamline construction and preparation method thereof - Google Patents
Water-in-water multicolor coating suitable for streamline construction and preparation method thereof Download PDFInfo
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- CN106752570A CN106752570A CN201611098836.5A CN201611098836A CN106752570A CN 106752570 A CN106752570 A CN 106752570A CN 201611098836 A CN201611098836 A CN 201611098836A CN 106752570 A CN106752570 A CN 106752570A
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- water
- multicolor coating
- cellulose
- construction
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/29—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for multicolour effects
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention provides a kind of water-in-water multicolor coating suitable for streamline construction and preparation method thereof; it is made up of base paint, continuous phase emulsion compositions and Protection glue; wherein containing the complex emulsions using silicone acrylic emulsion and pure-acrylic emulsion composition, more conducively colour particles are sprawled；With the addition of the xanthans that can improve finished product paint viscosity and stability；Used with the collocation of small-molecular-weight cellulose using macromolecule, with xanthans compounding, form the All Pure Nature biogum of high intensity, improve particle intensity.And using 4000 mesh kaolin and rutile titanium dioxide as pigment.The water-in-water multicolor coating for providing the application has consumption low, cost-effective；In work progress, the stability of batch is can control；Colour particles intensity is improve, with more preferable shipping storage ability.It is applicable to streamline construction and can be constructed on production board, prior art is substantially improved because of the not good problem brought of constructing, while reducing construction cost.
Description
Technical field
The present invention relates to paint field, more specifically, it is related to a kind of many color coatings of water-water suitable for streamline construction
Material and preparation method thereof.
Background technology
Water-in-water multicolor coating rich color, paint film appearance is similar to natural granite, good decorative property, and pacifies with environmental protection
Entirely, construction technology is simple, energy-conservation, cost performance high the features such as widely favored by people, become decorating outer wall of building field
Focus product.But, the construction of multicolor finish is but limited by various conditions, such as：1st, water-in-water multicolor coating is in temperature
Cannot be constructed during less than 5 DEG C；2nd, ambient humidity is excessive, and sagging phenomenon occurs in construction；3rd, water-in-water multicolor coating construction
Effect afterwards depends on the level of workmen, and the difference of construction level, the effect for obtaining is also different, it is impossible to accomplish perfect multiple
System, and construction cost is high.
For a long time, the construction of water-in-water multicolor coating is always a difficulty, and the streamline construction of standardization is to obtain water
The inevitable approach of bag water multicolor finish high-quality effect.Therefore, it is necessary to formula to current aqueous water-in-water multicolor coating,
Component is improved, to overcome the drawbacks described above of prior art, there is provided a kind of water-water for being applicable to streamline construction is colorful
Coating.
The content of the invention
In order to solve the above problems or one of problem, the invention provides a kind of suitable streamline, can be on production board
The water-in-water multicolor coating of construction, substantially improves the not good problem brought of construction, while reducing construction cost, can overcome existing
There is the drawbacks described above of aqueous water-in-water multicolor coating.
Specifically, an aspect of of the present present invention provides a kind of water-in-water multicolor coating suitable for streamline construction, by
Base paint, continuous phase emulsion and Protection glue composition, comprising component and the mass content of each component be：
The component of base paint and the mass content of component are：
The component of continuous phase emulsion compositions and the mass content of component are：
The component of Protection glue and the mass content of component are：
Water 90-94%
Protection glue 5-10%
Xanthans 0.1-1%
Wherein, the macromolecule cellulose refers to the cellulose of molecular weight >=50,000, and the small-molecular-weight cellulose refers to
The cellulose of molecular weight ＜ 50,000.
The above-mentioned water-in-water multicolor coating suitable for streamline construction that the application is provided, using the breast of silicon third in the paint of gene basis
The complex emulsions of liquid and pure-acrylic emulsion composition, than traditional single emulsion with more compatible effect, more conducively colour particles
Sprawl, greatly reducing the proportion of goods damageds of construction, reduces cost；Xanthans is added in Protection glue, xanthans can improve finished product
The viscosity and stability of paint；Because by the way of macromolecule and the collocation of small-molecular-weight cellulose, with more preferable anti-bleeding energy
Power, macromolecule cellulose described herein refers to the cellulose of molecular weight >=5W, and small-molecular-weight cellulose refers to molecular weight
The cellulose of ＜ 5W；Small-molecular-weight cellulose is compounded with the xanthans in Protection glue, forms the All Pure Nature biogum of high intensity, is carried
Particle intensity high；Because using 4000 mesh kaolin with rutile titanium dioxide as pigment so that colour particles are full, colour
Particle intensity is more firm, solve existing water-in-water multicolor coating particle easily shrink, bleeding problem.Therefore, the application is given
Water-in-water multicolor coating has：Consumption is low, cost-effective；In work progress, the stability of batch is can control；Improve color point
Particle intensity, with more preferable shipping storage ability.So as to be applicable to streamline construction and can be constructed on production board,
Prior art is substantially improved because of the not good problem brought of constructing, while reducing construction cost, present invention is realized
Purpose.
According to one embodiment of the water-in-water multicolor coating constructed suitable for streamline of the present invention, it is preferable that institute
Small-molecular-weight cellulose is stated for microcrystalline cellulose.Microcrystalline cellulose is prepared by natural cotton fiber hydrolysis, and structure is：
And xanthans is a kind of microbial polysaccharide, also known as Xanthan Gum, also referred to as xanthan gum, it with starch is main former to be
Material, through microbial fermentation and a series of biochemical processes, a kind of biopolymer for finally giving, its main component be glucose,
Mannose, glucuronic acid etc., molecular weight reach millions of, its high viscosity and water solubility with protrusion, unique rheology spy
Property, excellent temperature stability, PH stability and gratifying compatibility.It is fine using crystallite in base paint in the program
Dimension element, can compound with the xanthans in Protection glue, form the All Pure Nature biogum of high intensity, improve particle intensity.
According to another embodiment of the water-in-water multicolor coating constructed suitable for streamline of the present invention, it is preferable that
The small-molecular-weight cellulose is cellulose of the substitution degree 2.5.
Another aspect provides the preparation method of the water-in-water multicolor coating constructed suitable for streamline, including
Following steps：
Step 101, formula as described above produces base paint, continuous phase emulsion compositions and Protection glue respectively；
Step 102, the base paint that will have been manufactured is granulated in the Protection glue, is produced preparation and is applied to streamline
Colour particles required for the water-in-water multicolor coating of construction；
Step 103, the colour particles that will have been manufactured are well mixed with the continuous phase emulsion compositions, produce
The water-in-water multicolor coating suitable for streamline construction.
The above-mentioned preparation method that the application is given, can produce the water-in-water multicolor coating suitable for streamline construction, should
Contain Protection glue, cellulose containing macromolecule and the collocation of small-molecular-weight cellulose of xanthans because of aqueous water-in-water multicolor coating,
Paint film can be made to produce synergy, it is uncontrollable so as to solve existing water-in-water multicolor coating finished product paint viscosity, particle easily shrinks,
Bleeding, coating free settling, layering, paint film is met water and is easily bleached, and paint film is water-fast intensity difference is unfavorable for asking for heat preservation production board construction
Topic.
One embodiment of the preparation method according to the water-in-water multicolor coating constructed suitable for streamline of the present invention, it is excellent
Selection of land, the small-molecular-weight cellulose suitable for the water-in-water multicolor coating of streamline construction is microcrystalline cellulose.
Another embodiment of preparation method according to novel aqueous water-in-water multicolor coating of the present invention, it is preferable that described
Small-molecular-weight cellulose suitable for the water-in-water multicolor coating of streamline construction is cellulose of the substitution degree 2.5.
Additional aspect of the invention and advantage will become obvious in following description section, or by of the invention
Practice is recognized.
Specific embodiment
In order to be more clearly understood that the above objects, features and advantages of the present invention, below to specific reality of the invention
The mode of applying is illustrated.But, in the case where not conflicting, feature in embodiments herein and embodiment can mutual group
Close.
Many details are elaborated in the following description in order to fully understand the present invention, but, the present invention may be used also
Implemented with being different from other modes described here using other, therefore, protection scope of the present invention is not by described below
Specific embodiment limitation.
Water-in-water multicolor coating suitable for streamline construction of the present invention, by base paint, continuous phase emulsion compositions
Constituted with Protection glue.Wherein, three embodiments of the mass content of the component of the base paint and component are as shown in table 1：
Table 1
The water-in-water multicolor coating constructed suitable for streamline of the present invention, the group of the continuous phase emulsion compositions
Divide as shown in table 2 with three embodiments of the mass content of component：
Table 2
It is of the present invention suitable for the water-in-water multicolor coating of streamline construction, the component of Protection glue and the quality of component
Three embodiments of content are as shown in table 3：
Table 3
The above-mentioned table 1 of the application to table 3 sets forth three according to base paint, continuous phase emulsion compositions and Protection glue respectively
Individual embodiment, according to the relation of base paint, continuous phase emulsion compositions and Protection glue, above-mentioned these embodiments can mutual group
Close, actually above-mentioned table 1- tables 3 are 27 realities for providing the herein described water-in-water multicolor coating suitable for streamline construction
Apply example.Illustrated so that one is combined as an example below：
With continuous phase in base paint embodiment one, table 2 in table 1, how Protection glue is implemented in composition embodiment one and table 3
Example one, is made the herein described water-in-water multicolor coating suitable for streamline construction：
First, the base paint, continuous phase emulsion compositions and protection are produced according to the formula of its respective embodiment one
Glue；
Secondly, the base paint that will have been manufactured is granulated in the Protection glue for having manufactured, and is produced preparation and is applied to
Colour particles required for the water-in-water multicolor coating of streamline construction；
Finally, the colour particles that will have been manufactured, manufacture with the formula according to continuous phase emulsion compositions embodiment one
Good continuous phase emulsion compositions are well mixed, and produce the herein described many color coatings of water-water suitable for streamline construction
Material.
The water-in-water multicolor coating for being applied to streamline construction is detected, the whole of prior art can be overcome to lack
Fall into, present invention purpose is realized well.
In the description of this specification, the description of term " one embodiment ", " some embodiments ", " specific embodiment " etc.
Mean that the specific features, structure, material or the feature that are described with reference to the embodiment or example are contained in of the invention at least one real
In applying example or example.In this manual, the schematic representation to above-mentioned term is not necessarily referring to identical embodiment or reality
Example.And, the specific features of description, structure, material or feature can in one or more any embodiments or example with
Suitable mode is combined.
The preferred embodiments of the present invention are the foregoing is only, is not intended to limit the invention, for the skill of this area
For art personnel, the present invention can have various modifications and variations.It is all within the spirit and principles in the present invention, made any repair
Change, equivalent, improvement etc., should be included within the scope of the present invention.
Claims (6)
1. it is a kind of suitable for streamline construction water-in-water multicolor coating, it is characterised in that by base paint, continuous phase Emulsion combination
Thing and Protection glue are constituted, comprising component and the mass content of each component be：
The component of base paint and the mass content of component are：
The component of continuous phase emulsion compositions and the mass content of component are：
The component of Protection glue and the mass content of component are：
Water 90-94%
Protection glue 5-10%
Xanthans 0.1-1%
Wherein, the macromolecule cellulose refers to the cellulose of molecular weight >=50,000, and the small-molecular-weight cellulose refers to molecule
Measure the cellulose of ＜ 50,000.
2. it is according to claim 1 suitable for streamline construction water-in-water multicolor coating, it is characterised in that described small point
Son amount cellulose is microcrystalline cellulose.
3. it is according to claim 1 suitable for streamline construction water-in-water multicolor coating, it is characterised in that described small point
Son amount cellulose is cellulose of the substitution degree 2.5.
4. the preparation method of the water-in-water multicolor coating of streamline construction is applied to, it is characterised in that comprised the following steps：
Step 101, base paint, continuous phase emulsion compositions and Protection glue are produced according to the formula described in claim 1 respectively；
Step 102, the base paint that will have been manufactured is granulated in the Protection glue, produces preparation suitable for streamline construction
Water-in-water multicolor coating required for colour particles；
Step 103, the colour particles that will have been manufactured are well mixed with the continuous phase emulsion compositions, produce described
Suitable for the water-in-water multicolor coating of streamline construction.
5. the preparation method of the water-in-water multicolor coating suitable for streamline construction according to claim 4, its feature exists
In the small-molecular-weight cellulose suitable for the water-in-water multicolor coating of streamline construction is microcrystalline cellulose.
6. the preparation method of the water-in-water multicolor coating suitable for streamline construction according to claim 4, its feature exists
In the small-molecular-weight cellulose suitable for the water-in-water multicolor coating of streamline construction is fiber of the substitution degree 2.5
Element.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611098836.5A CN106752570B (en) | 2016-12-04 | 2016-12-04 | Water-in-water multicolor coating and preparation method thereof suitable for assembly line construction |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611098836.5A CN106752570B (en) | 2016-12-04 | 2016-12-04 | Water-in-water multicolor coating and preparation method thereof suitable for assembly line construction |
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| Publication Number | Publication Date |
|---|---|
| CN106752570A true CN106752570A (en) | 2017-05-31 |
| CN106752570B CN106752570B (en) | 2019-04-26 |
Family
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| Application Number | Title | Priority Date | Filing Date |
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| CN201611098836.5A Active CN106752570B (en) | 2016-12-04 | 2016-12-04 | Water-in-water multicolor coating and preparation method thereof suitable for assembly line construction |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107488396A (en) * | 2017-10-12 | 2017-12-19 | 广东华兹卜新材料科技有限公司 | A kind of high water-whitening resistance acrylic acid water-in-water emulsion and preparation method thereof |
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| WO2008066319A1 (en) * | 2006-11-28 | 2008-06-05 | Woo-Jae Lee | Inorganic pigments composition having high hardness |
| CN102690575A (en) * | 2012-06-08 | 2012-09-26 | 仪征市通发建筑养护材料厂 | Production process for water-borne multicolor coating |
| CN103849278A (en) * | 2012-12-06 | 2014-06-11 | 天津市东鼎科技发展有限公司 | Preparation method of water-in-water multicolor paint |
| CN104263168A (en) * | 2014-07-16 | 2015-01-07 | 宿州众力融创新型建材有限公司 | Water-in-water multicolor paint and preparation method thereof |
| CN104530888A (en) * | 2015-01-26 | 2015-04-22 | 重庆索利特涂料有限公司 | Water-in-water multi-color paint and preparation method thereof |
-
2016
- 2016-12-04 CN CN201611098836.5A patent/CN106752570B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008066319A1 (en) * | 2006-11-28 | 2008-06-05 | Woo-Jae Lee | Inorganic pigments composition having high hardness |
| CN102690575A (en) * | 2012-06-08 | 2012-09-26 | 仪征市通发建筑养护材料厂 | Production process for water-borne multicolor coating |
| CN103849278A (en) * | 2012-12-06 | 2014-06-11 | 天津市东鼎科技发展有限公司 | Preparation method of water-in-water multicolor paint |
| CN104263168A (en) * | 2014-07-16 | 2015-01-07 | 宿州众力融创新型建材有限公司 | Water-in-water multicolor paint and preparation method thereof |
| CN104530888A (en) * | 2015-01-26 | 2015-04-22 | 重庆索利特涂料有限公司 | Water-in-water multi-color paint and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107488396A (en) * | 2017-10-12 | 2017-12-19 | 广东华兹卜新材料科技有限公司 | A kind of high water-whitening resistance acrylic acid water-in-water emulsion and preparation method thereof |
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|---|---|
| CN106752570B (en) | 2019-04-26 |
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