CN106752419A - A kind of wax Emulsion for Leather containing OPE and preparation method thereof - Google Patents
A kind of wax Emulsion for Leather containing OPE and preparation method thereof Download PDFInfo
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- CN106752419A CN106752419A CN201611093154.5A CN201611093154A CN106752419A CN 106752419 A CN106752419 A CN 106752419A CN 201611093154 A CN201611093154 A CN 201611093154A CN 106752419 A CN106752419 A CN 106752419A
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- wax emulsion
- wax
- ope
- fatty acid
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
- C09D123/26—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers modified by chemical after-treatment
- C09D123/30—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers modified by chemical after-treatment by oxidation
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of wax Emulsion for Leather containing OPE, belong to wax emulsion preparing technical field, the wax emulsion is made up of the raw material of following weight portion:90~200 parts of 20~25 parts of OPE, 1~4 part of beeswax, 0.9~1.6 part of sorbitan monooleate, 5~8 parts of film-forming resin, 2~5 parts of montanin wax, 1~2 part of dibutyl phthalate, 0.5~1 part of diisopropyl sodium naphthalene sulfonate, 1~2 part of Polyoxyethylene fatty acid amides fatty acid ester, 0.1~0.3 part of isotridecyloxypropylpolyoxyethylene polyoxyethylene base propyl group amine, 0.5~0.8 part of octadecane alcohol radical APEO, 1~3 part of hydroxyethyl cellulose and water.The present invention additionally provides the preparation method of the wax emulsion simultaneously, and the wax emulsion that the present invention is provided can improve the feel of leather finishing agent, real leather products feel can be made more excellent.Wax emulsion of the invention has more excellent than like product antiacid, alkali resistant and stability in hard water, and its emulsion-stabilizing, arbitrary proportion water dilution is not stratified, is not demulsified during storage, not lumpd, long shelf-life.
Description
Technical field
The present invention relates to a kind of preparation method of wax emulsion, more particularly to a kind of leather wax containing OPE
Emulsion and preparation method thereof.
Background technology
Wax emulsion in leather industry mainly as leather finish auxiliary agent, for bottom, in, top coat, with preferable performance.
Wax had both had a general character of water proofing property and lubricity, but with such as oiliness, viscosity, fragility, toughness, fusibleness and gloss in terms of
Characteristic, is very different to each other.In actual applications, a kind of wax can not possibly have the institute required for meeting a certain special-purpose
There is property.Therefore, when the raw material of leather finish wax emulsion is selected, to consider the performance of wax, improve leather and apply
The Spraying technique of decorations.Wax emulsion is favored by researcher and user more and more in recent years, the external research and development to it
Have for many years, and form tandem product numerous in variety.Its covering with paint defensive position of the wax Emulsion for Leather of appearance in existing market
Sense is very puckery, and wax sense is not strong, and on the other hand as the wax emulsion of underseal, the permeability of its emulsion is too strong, after covering with paint leather easily
Moist feeling is caused, the quality of leather is have impact on, while the chemical stability and poor storage stability of wax emulsion.
The content of the invention
It is an object of the invention to overcome the wax sense existing for leather finish wax emulsion in the prior art not strong, chemical steady
The above-mentioned deficiency of qualitative and poor storage stability, there is provided a kind of wax Emulsion for Leather containing OPE, the feel wax
Can be used in improving the feel and chemistry, storage stability of leather finishing agent, real leather products feel can be made more excellent.
In order to realize foregoing invention purpose, the invention provides following technical scheme:
A kind of wax Emulsion for Leather containing OPE, is prepared from the following raw materials in parts by weight:Aoxidize poly- second
20~25 parts of alkene wax, 1~4 part of beeswax, 0.9~1.6 part of sorbitan monooleate, 5~8 parts of film-forming resin, montanin wax 2~5
Part, 1~2 part of dibutyl phthalate, 0.5~1 part of diisopropyl sodium naphthalene sulfonate, 1~2 part of Polyoxyethylene fatty acid amides fatty acid ester, it is different
0.1~0.3 part of tridecane epoxide propyl group amine, 0.5~0.8 part of octadecane alcohol radical APEO, 1~3 part of hydroxyethyl cellulose
With 90~200 parts of water.
Preferably, a kind of wax Emulsion for Leather containing OPE, is prepared from the following raw materials in parts by weight:Oxygen
Change 23 parts of Tissuemat E, 2 parts of beeswax, 1.2 parts of sorbitan monooleate, 6 parts of film-forming resin, 3 parts of montanin wax, phthalic acid
1.5 parts of dibutyl ester, 0.6 part of diisopropyl sodium naphthalene sulfonate, 1.5 parts of Polyoxyethylene fatty acid amides fatty acid ester, isotridecyloxypropylpolyoxyethylene polyoxyethylene base propyl group amine 0.2
Part, 0.6 part of octadecane alcohol radical APEO, 2 parts of hydroxyethyl cellulose and 150 parts of water.
Preparation method another object of the present invention is to provide the wax Emulsion for Leather containing OPE, including
Following steps:
(1) preparation of film-forming resin:The formula of film-forming resin is 4,4 '-[1,3- penylene is double (1- methyl ethylidene)] bis-phenols
2~6 parts, 1~3 part of diphosphorous acid distearyl pentaerythritol ester, 3~5 parts of stearoxyl trimethyl silane, ethoxy dodecane
4~6 parts of base alcohol, 2~4 parts of polybutylene glycol-bis- (4-HBA ester), 0.1~0.3 part of ferrous sulfate, 4- methoxyl groups
3~5 parts of phenyi-methylene-dimethyl esters, 0.2~0.3 part of potassium peroxydisulfate, 0.3~0.5 part of BDO;Preparation method is such as
Under:
A, by 4,4 '-it is [1,3- penylene is double (1- methyl ethylidene)] bis-phenols, diphosphorous acid distearyl pentaerythritol esters, poly-
Butylen glycol-bis- (4-HBA ester), stearoxyl trimethyl silane and 4- methoxyphenyls-methylene-dimethyl
Ester adds stainless steel cauldron, is warming up to 80~90 DEG C, opens stirring and adds potassium peroxydisulfate, ferrous sulfate, ethoxy dodecane
Base alcohol and BDO;
B and then it is warmed up to 130~150 DEG C with 20~30 DEG C/h speed, reacts 1~2 hour and stop heating, is cooled to 60
~70 DEG C stir evenly and obtain film-forming resin;
(2) in autoclave by proportioning add OPE, beeswax, montanin wax, sorbitan monooleate,
Dibutyl phthalate and film-forming resin, are heated to 100~120 DEG C of meltings, stir, and obtain oil phase dispersed mixture;
(3) by diisopropyl sodium naphthalene sulfonate, Polyoxyethylene fatty acid amides fatty acid ester, isotridecyloxypropylpolyoxyethylene polyoxyethylene base propyl group amine and octadecane alcohol radical
APEO is soluble in water, is heated to 90~95 DEG C, obtains Aqueous dispersions mixture;
(4) mixing speed of autoclave is improved to 1000~2000rpm, adds the Aqueous dispersions of step (3) preparation
Mixture is emulsified, and emulsification times are 1~3h;Then the mixing speed in 200~300rpm declines and warms to room temperature, and adds hydroxyl
Continue to stir 10~30min after ethyl cellulose, be then filtrated to get wax Emulsion for Leather.
Compared with prior art, beneficial effects of the present invention:
Wax emulsion of the invention can improve the feel of leather finishing agent, and real leather products feel can be made more excellent.The present invention
Wax emulsion there is more excellent than like product antiacid, alkali resistant and stability in hard water, its emulsion-stabilizing, arbitrary proportion water dilutes not
Layering, is not demulsified during storage, does not lump, long shelf-life.
Specific embodiment
With reference to test example and specific embodiment, the present invention is described in further detail.But this should not be understood
For the scope of above-mentioned theme of the invention is only limitted to following embodiment, all technologies realized based on present invention belong to this
The scope of invention.
Embodiment 1
A kind of wax Emulsion for Leather containing OPE, is prepared from the following raw materials in parts by weight:Aoxidize poly- second
23 parts of alkene wax, 2 parts of beeswax, 1.2 parts of sorbitan monooleate, 6 parts of film-forming resin, 3 parts of montanin wax, dibutyl phthalate
1.5 parts, 0.6 part of diisopropyl sodium naphthalene sulfonate, 1.5 parts of Polyoxyethylene fatty acid amides fatty acid ester, 0.2 part of isotridecyloxypropylpolyoxyethylene polyoxyethylene base propyl group amine, ten
150 parts of eight 0.6 part of silane alcohol base APEOs, 2 parts of hydroxyethyl cellulose and water.
The preparation method of the above-mentioned wax Emulsion for Leather containing OPE, comprises the following steps:
(1) preparation of film-forming resin:The formula of film-forming resin is 4,4 '-[1,3- penylene is double (1- methyl ethylidene)] bis-phenols
4 parts, 2 parts of diphosphorous acid distearyl pentaerythritol ester, 3 parts of stearoxyl trimethyl silane, 5 parts of ethoxy dodecyl alcohol,
3 parts of polybutylene glycol-bis- (4-HBA ester), 0.2 part of ferrous sulfate, 4- methoxyphenyls-methylene-dimethyl esters
4 parts, 0.2 part of potassium peroxydisulfate, 0.4 part of BDO;Preparation method is as follows:
A, by 4,4 '-it is [1,3- penylene is double (1- methyl ethylidene)] bis-phenols, diphosphorous acid distearyl pentaerythritol esters, poly-
Butylen glycol-bis- (4-HBA ester), stearoxyl trimethyl silane and 4- methoxyphenyls-methylene-dimethyl
Ester adds stainless steel cauldron, is warming up to 90 DEG C, opens stirring and adds potassium peroxydisulfate, ferrous sulfate, ethoxy dodecyl alcohol
And BDO;
B and then it is warmed up to 140 DEG C with 30 DEG C/h speed, reacts 1.5 hours and stop heating, is cooled to 60 DEG C and stirs evenly and obtain
Film-forming resin;
(2) in autoclave by proportioning add OPE, beeswax, montanin wax, sorbitan monooleate,
Dibutyl phthalate and film-forming resin, are heated to 110 DEG C of meltings, stir, and obtain oil phase dispersed mixture;
(3) by diisopropyl sodium naphthalene sulfonate, Polyoxyethylene fatty acid amides fatty acid ester, isotridecyloxypropylpolyoxyethylene polyoxyethylene base propyl group amine and octadecane alcohol radical
APEO is soluble in water, is heated to 92 DEG C, obtains Aqueous dispersions mixture;
(4) mixing speed of autoclave is improved to 1500rpm, adds the Aqueous dispersions mixture of step (3) preparation
Emulsified, emulsification times are 1.5h;Then the mixing speed in 250rpm declines and warms to room temperature, after adding hydroxyethyl cellulose
Continue to stir 20min, be then filtrated to get wax Emulsion for Leather.
The performance indications of wax emulsion obtained in above-described embodiment:
Faint yellow emulsion, solid content 12.3%, PH:10, product stability, 50 DEG C, outward appearance is unchanged within 12 months.
Wax emulsion prepared by embodiment is formulated consumption by primary coat and primary coat resin is deployed into slurry, covers with paint, lacquer, colour wash, etc. ox-hide leather
Afterwards, leather hand feeling is full, gentle, and wax sense is strong, while having excellent water resistance.
Claims (4)
1. a kind of wax Emulsion for Leather containing OPE, it is characterised in that be prepared from the following raw materials in parts by weight:
20~25 parts of OPE, 1~4 part of beeswax, 0.9~1.6 part of sorbitan monooleate, 5~8 parts of film-forming resin, illiteracy
2~5 parts of denier wax, 1~2 part of dibutyl phthalate, 0.5~1 part of diisopropyl sodium naphthalene sulfonate, Polyoxyethylene fatty acid amides fatty acid ester 1
~2 parts, 0.1~0.3 part of isotridecyloxypropylpolyoxyethylene polyoxyethylene base propyl group amine, 0.5~0.8 part of octadecane alcohol radical APEO, hydroxy ethyl fiber
90~200 parts of 1~3 part of element and water.
2. the wax Emulsion for Leather containing OPE according to claim 1, it is characterised in that by following weight
The raw material of number is made:23 parts of OPE, 2 parts of beeswax, 1.2 parts of sorbitan monooleate, 6 parts of film-forming resin, illiteracy
It is 3 parts of denier wax, 1.5 parts of dibutyl phthalate, 0.6 part of diisopropyl sodium naphthalene sulfonate, 1.5 parts of Polyoxyethylene fatty acid amides fatty acid ester, different
150 parts of 0.2 part of tridecane epoxide propyl group amine, 0.6 part of octadecane alcohol radical APEO, 2 parts of hydroxyethyl cellulose and water.
3. the wax Emulsion for Leather containing OPE according to claim 1, it is characterised in that described film forming
The formula of resin is 4,4 '-[1,3- penylene is double (1- methyl ethylidene)] 2~6 parts of bis-phenols, diphosphorous acid distearyl Ji Wusi
1~3 part of alcohol ester, 3~5 parts of stearoxyl trimethyl silane, 4~6 parts of ethoxy dodecyl alcohol, polybutylene glycol-bis- (4-
Hydroxybenzoate) 2~4 parts, 0.1~0.3 part of ferrous sulfate, 4- methoxyphenyl -3~5 parts of methylene-dimethyl esters, mistake
0.2~0.3 part of potassium sulfate, 0.3~0.5 part of BDO;Preparation method is as follows:
(1) by 4,4 '-[1,3- penylene is double (1- methyl ethylidene)] bis-phenols, diphosphorous acid distearyl pentaerythritol ester, poly- Asia
Butyl glycol-bis- (4-HBA ester), stearoxyl trimethyl silane and 4- methoxyphenyls-methylene-dimethyl esters
Stainless steel cauldron is added, 80~90 DEG C are warming up to, stirring is opened and is added potassium peroxydisulfate, ferrous sulfate, ethoxy dodecyl
Alcohol and BDO;
(2) 130~150 DEG C and then with 20~30 DEG C/h speed are warmed up to, are reacted 1~2 hour and is stopped heating, be cooled to 60~70
DEG C stir evenly and to obtain film-forming resin.
4. a kind of preparation method of the wax Emulsion for Leather containing OPE as claimed in claim 1, its feature exists
In comprising the following steps:
(1) formula according to claim 3 and preparation method are made film-forming resin;
(2) OPE, beeswax, montanin wax, sorbitan monooleate, adjacent benzene are added by proportioning in autoclave
Dibutyl carboxylic acid and film-forming resin, are heated to 100~120 DEG C of meltings, stir, and obtain oil phase dispersed mixture;
(3) by diisopropyl sodium naphthalene sulfonate, Polyoxyethylene fatty acid amides fatty acid ester, isotridecyloxypropylpolyoxyethylene polyoxyethylene base propyl group amine and octadecane alcohol radical polyoxy
Vinethene is soluble in water, is heated to 90~95 DEG C, obtains Aqueous dispersions mixture;
(4) mixing speed of autoclave is improved to 1000~2000rpm, adds Aqueous dispersions mixing prepared by step (3)
Thing is emulsified, and emulsification times are 1~3h;Then the mixing speed in 200~300rpm declines and warms to room temperature, and adds ethoxy
Continue to stir 10~30min after cellulose, be then filtrated to get wax Emulsion for Leather.
Priority Applications (1)
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CN201611093154.5A CN106752419A (en) | 2016-11-28 | 2016-11-28 | A kind of wax Emulsion for Leather containing OPE and preparation method thereof |
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CN201611093154.5A CN106752419A (en) | 2016-11-28 | 2016-11-28 | A kind of wax Emulsion for Leather containing OPE and preparation method thereof |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107916309A (en) * | 2017-11-27 | 2018-04-17 | 四川达威科技股份有限公司 | A kind of leather embossing Antisticking Wax emulsion, its preparation method and the method for leather embossing |
CN111979802A (en) * | 2020-07-24 | 2020-11-24 | 江苏海云花新材料有限公司 | Wax emulsion for yarn dyeing |
CN117166263A (en) * | 2023-08-16 | 2023-12-05 | 广东顺德名纤布业股份有限公司 | Wear-resistant composite flocking fabric and preparation method thereof |
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CN101503519A (en) * | 2009-03-09 | 2009-08-12 | 陕西科技大学 | Preparation of anion-nonionic wax emulsion by oxidated polyethylene wax modification |
CN103755978A (en) * | 2014-01-13 | 2014-04-30 | 广东工业大学 | Preparation method of oxidized polyethylene wax emulsion |
CN104087183A (en) * | 2014-06-26 | 2014-10-08 | 衢州市中通化工有限公司 | Aqueous wax emulsion for improving brightness of leather |
CN105779670A (en) * | 2016-04-29 | 2016-07-20 | 四川力久知识产权服务有限公司 | Wax emulsion for leather finishing and preparing method of wax emulsion |
CN105802256A (en) * | 2016-04-14 | 2016-07-27 | 广东额图网络科技发展有限公司 | Preparation method of multifunctional leather wax emulsion |
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2016
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CN101503519A (en) * | 2009-03-09 | 2009-08-12 | 陕西科技大学 | Preparation of anion-nonionic wax emulsion by oxidated polyethylene wax modification |
CN103755978A (en) * | 2014-01-13 | 2014-04-30 | 广东工业大学 | Preparation method of oxidized polyethylene wax emulsion |
CN104087183A (en) * | 2014-06-26 | 2014-10-08 | 衢州市中通化工有限公司 | Aqueous wax emulsion for improving brightness of leather |
CN105802256A (en) * | 2016-04-14 | 2016-07-27 | 广东额图网络科技发展有限公司 | Preparation method of multifunctional leather wax emulsion |
CN105779670A (en) * | 2016-04-29 | 2016-07-20 | 四川力久知识产权服务有限公司 | Wax emulsion for leather finishing and preparing method of wax emulsion |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN107916309A (en) * | 2017-11-27 | 2018-04-17 | 四川达威科技股份有限公司 | A kind of leather embossing Antisticking Wax emulsion, its preparation method and the method for leather embossing |
CN107916309B (en) * | 2017-11-27 | 2020-08-25 | 四川达威科技股份有限公司 | Leather embossing anti-sticking wax emulsion, preparation method thereof and leather embossing method |
CN111979802A (en) * | 2020-07-24 | 2020-11-24 | 江苏海云花新材料有限公司 | Wax emulsion for yarn dyeing |
CN117166263A (en) * | 2023-08-16 | 2023-12-05 | 广东顺德名纤布业股份有限公司 | Wear-resistant composite flocking fabric and preparation method thereof |
CN117166263B (en) * | 2023-08-16 | 2024-03-29 | 广东顺德名纤布业股份有限公司 | Wear-resistant composite flocking fabric and preparation method thereof |
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Application publication date: 20170531 |