CN104087183A - Aqueous wax emulsion for improving brightness of leather - Google Patents
Aqueous wax emulsion for improving brightness of leather Download PDFInfo
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- CN104087183A CN104087183A CN201410311950.6A CN201410311950A CN104087183A CN 104087183 A CN104087183 A CN 104087183A CN 201410311950 A CN201410311950 A CN 201410311950A CN 104087183 A CN104087183 A CN 104087183A
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- Prior art keywords
- water
- wax emulsion
- emulsification
- emulsion
- wax
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Links
- 239000000839 emulsion Substances 0.000 title claims abstract description 25
- 239000010985 leather Substances 0.000 title claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 32
- 238000004945 emulsification Methods 0.000 claims abstract description 14
- 238000003756 stirring Methods 0.000 claims abstract description 8
- 230000001804 emulsifying effect Effects 0.000 claims abstract description 6
- -1 perfluoroalkyl trimethyl-glycine Chemical compound 0.000 claims description 21
- HKUFIYBZNQSHQS-UHFFFAOYSA-N n-octadecyloctadecan-1-amine Chemical compound CCCCCCCCCCCCCCCCCCNCCCCCCCCCCCCCCCCCC HKUFIYBZNQSHQS-UHFFFAOYSA-N 0.000 claims description 10
- 238000005498 polishing Methods 0.000 claims description 9
- 238000001816 cooling Methods 0.000 claims description 6
- 239000013530 defoamer Substances 0.000 claims description 6
- 239000003995 emulsifying agent Substances 0.000 claims description 6
- 238000002844 melting Methods 0.000 claims description 6
- 230000008018 melting Effects 0.000 claims description 6
- 238000007599 discharging Methods 0.000 claims description 5
- 238000009775 high-speed stirring Methods 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 5
- 239000000155 melt Substances 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 5
- 239000012747 synergistic agent Substances 0.000 claims description 5
- 238000000034 method Methods 0.000 abstract description 6
- 239000000654 additive Substances 0.000 abstract description 4
- 238000010438 heat treatment Methods 0.000 abstract description 3
- 239000004530 micro-emulsion Substances 0.000 abstract description 3
- 239000006185 dispersion Substances 0.000 abstract description 2
- 239000004094 surface-active agent Substances 0.000 abstract description 2
- 238000010411 cooking Methods 0.000 abstract 1
- 238000007789 sealing Methods 0.000 abstract 1
- 239000001993 wax Substances 0.000 description 27
- 229940051841 polyoxyethylene ether Drugs 0.000 description 7
- 229920000056 polyoxyethylene ether Polymers 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 5
- 239000007788 liquid Substances 0.000 description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 125000002467 phosphate group Chemical class [H]OP(=O)(O[H])O[*] 0.000 description 2
- 239000000600 sorbitol Substances 0.000 description 2
- ATVJXMYDOSMEPO-UHFFFAOYSA-N 3-prop-2-enoxyprop-1-ene Polymers C=CCOCC=C ATVJXMYDOSMEPO-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- 241000719239 Oligoplites altus Species 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 229920013701 VORANOL™ Polymers 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 238000013016 damping Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000012875 nonionic emulsifier Substances 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- 239000004209 oxidized polyethylene wax Substances 0.000 description 1
- 235000013873 oxidized polyethylene wax Nutrition 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Landscapes
- Treatment And Processing Of Natural Fur Or Leather (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses aqueous wax emulsion for improving the brightness of leather. The aqueous wax emulsion is prepared by using a direct high temperature sealed emulsification method, that is, adding water, a surfactant, an emulsification synergist, oxidized polyethlene wax and other additives into a reaction kettle, sealing, heating and stirring, emulsifying for a while, and subsequently cooking, thereby obtaining the polyethlene wax superfine microemulsion. Due to adoption of the emulsification synergist, the dispersion stability of the wax emulsion is improved.
Description
Technical field
The present invention relates to a kind of preparation method of polymer-wax, particularly a kind of water-based wax emulsion that increases leather polishing degree.
Background technology
Oxidized polyethylene wax emulsion is applied to the fields such as water color ink, water lustering oil, agricultural, leather, shoe polish, forestry, wooden industry, gardens industry, water-borne coatings, water-miscible paint, paper product tamanori, yarn fabric softening agent and water-fast arrangement.Have that particle diameter is tiny, good waterproof performance, hardness of film are high, tack-free, be coating, leather, weaving, the good additive of ink.It can also be for ink, lustering agent, polishing wax, liquid shoe cream, liquid automobile polish, liquid floor wax and liquid leather jacket wet goods field.
CN102030996 relates to a kind of water-soluble OP wax emulsion and preparation method thereof, this OP wax emulsion is formed with wt% and is calculated and comprise following component OP wax 19.5-32 part by OP wax, fatty alcohol-polyoxyethylene ether, aliphatic alcohol polyoxyvinethene phosphate salt, the deionized water of certainweight umber, fatty alcohol-polyoxyethylene ether 2.54-9.25 part, aliphatic alcohol polyoxyvinethene phosphate salt 0.45-1.58 part, deionized water 65-70 part, by reactor heating and melting, select agent-in-oil method technique, add and stir successively.
CN101503517 relates to a kind of preparation method of cationic-nonionic modified oxidated polyethylene wax emulsion, first low-molecular-weight oxidized polyethlene wax is carried out to esterification modification with organic bases, then use sun-nonionic compound emulsifier to carry out emulsification, then carry out the composite cationic-nonionic modified oxidated polyethylene wax emulsion that makes.This product can be applied to the fields such as process hides covering with paint, fruit freshness preserving.Be characterized in the emulsion institute of modified waxes electrically charged be positively charged ion, the wax emulsion-stabilizing of the more single cationic emulsifier emulsification of shelf characteric.
Existing known technology mostly adopts fatty alcohol-polyoxyethylene ether series of surfactants as main emulsifying agent, and wherein oleophilic group is connected with ehter bond with hydrophilic group part, and stability is not high, has influence on the stability that emulsion is used yet.
Summary of the invention
For the deficiencies in the prior art, the invention provides a kind of water-based wax emulsion that increases leather polishing degree.
Adopt the preparation of direct high-temperature closed emulsion process, be about to water, tensio-active agent, emulsification synergistic agent, oxidized polyethlene wax and other additives add in reactor, start heating and stir after airtight.After emulsification for some time, cooling, i.e. available polyethylene wax super microemulsion.Emulsification synergistic agent can improve the dispersion stabilization of wax emulsion.
The invention provides a kind of water-based wax emulsion that increases leather polishing degree, by following steps, realize:
Mark by weight, by oxidized polyethlene wax 5-40 part, emulsifying agent 1-10 part, perfluoroalkyl trimethyl-glycine 0.1-0.5 part, Dioctadecyl Amine 0.1-0.5 part, defoamer 0.1-0.5 part etc. joins in emulsifying kettle, heated mixt 100-150 ℃, makes all material meltings, and melts is cooled to 80-100 ℃, the isothermal hot water that slowly adds water 30-60 part, high-speed stirring, is incubated 0.5-3 hour simultaneously, cooling rapidly, the cold water of 10-30 part is added to discharging after stirring.
Described emulsifying agent is nonionic emulsifier, is any one in Voranol EP 2001, polyoxyethylene alkyl phenyl ether, polyxyethylated allyl ether, polyoxyethylene shrink Sorbitol Powder fatty acid ester, polyoxyethylene sorbitol fatty acid ester, glycerol fatty acid ester, fatty alcohol-polyoxyethylene ether.Preferred fat polyoxyethylenated alcohol.For commercially available prod, as the product of Tianjin Hong Mei Chemical Co., Ltd. production.
The preferred polysiloxane defoamers of described defoamer, as kinds such as HX-5040, HX-5041, HX-5042, HX-5050, HX-5051, preferably HX-5041, is commercially available prod, as the product of Fanyu, Guangzhou China auxiliary agent company limited production.
Described emulsification synergistic agent perfluoroalkyl trimethyl-glycine is commercially available prod, as the product of Wuhan Sai Woer Chemical Co., Ltd. production.Molecular formula is: C
15h
15f
17n
2o
4s.
Described emulsification synergistic agent Dioctadecyl Amine is commercially available prod, as added the product that many foodstuff additive company limited produces in Suzhou.Molecular formula is: C
37h
77n.
Beneficial effect of the present invention:
Oxidized polyethlene wax superfine emulsion, through perfluoroalkyl trimethyl-glycine and Dioctadecyl Amine synergy emulsification, can significantly obviously be improved the performances such as microemulsion damping, diffusion, film forming, levelling.Improve the stability that emulsion is used.
Embodiment
Following examples are only to further illustrate the present invention, are not restriction the scope of protection of the invention.
The invention provides a kind of water-based wax emulsion that increases leather polishing degree, by following steps, realize:
Embodiment 1
In 500L emulsifying kettle, add oxidized polyethlene wax 20Kg, fatty alcohol-polyoxyethylene ether 4Kg, perfluoroalkyl trimethyl-glycine 0.2Kg, Dioctadecyl Amine 0.3Kg, HX-5041 defoamer 0.2Kg, 120 ℃ of heated mixt, make all material meltings, and melts is cooled to 90 ℃, the isothermal hot water that slowly adds water 50Kg, high-speed stirring, is incubated 1 hour simultaneously, cooling rapidly, the cold water of 20Kg is added to discharging after stirring.Obtain product, be numbered SX-1.
Embodiment 2
In 200L emulsifying kettle, add oxidized polyethlene wax 5Kg, fatty alcohol-polyoxyethylene ether 1Kg, perfluoroalkyl trimethyl-glycine 0.1Kg, Dioctadecyl Amine 0.1Kg, HX-5041 defoamer 0.1Kg, 100 ℃ of heated mixt, make all material meltings, and melts is cooled to 80 ℃, the isothermal hot water that slowly adds water 30Kg, high-speed stirring, is incubated 0.5 hour simultaneously, cooling rapidly, the cold water of 10Kg is added to discharging after stirring.Obtain product, be numbered SX-2.
Embodiment 3
In 500L emulsifying kettle, add oxidized polyethlene wax 40Kg, fatty alcohol-polyoxyethylene ether 10Kg, perfluoroalkyl trimethyl-glycine 0.5Kg, Dioctadecyl Amine 0.5Kg, HX-5041 defoamer 0.5Kg, 150 ℃ of heated mixt, make all material meltings, and melts is cooled to 100 ℃, the isothermal hot water that slowly adds water 60Kg, high-speed stirring, is incubated 3 hours simultaneously, cooling rapidly, the cold water of 30Kg is added to discharging after stirring.Obtain product, be numbered SX-3.
Comparative example 1
Do not add perfluoroalkyl trimethyl-glycine, the other the same as in Example 1.Products obtained therefrom is numbered SX-4.
Comparative example 2
Do not add Dioctadecyl Amine, the other the same as in Example 1.Products obtained therefrom is numbered SX-5.
Comparative example 2
Do not add perfluoroalkyl trimethyl-glycine, Dioctadecyl Amine, the other the same as in Example 1.Products obtained therefrom is numbered SX-6.
Embodiment 4
The water-based wax emulsion that embodiment 1-3 and comparative example 1-3 make, for leather finish technique, detects feel and the gloss of coating.Method is referring to Wei Shilin work " Wei Shilin, tanning technology, China Light Industry Press, 2005 ".
Detection of Stability: get water-based wax emulsion that embodiment 1-3 and comparative example 1-2 make with static after 10 times of volumes of hot water dilution, observe emulsion and change.
Sample | Feel | Color and luster | Stability |
SX-1 | Smooth plentiful | Light homogeneous | Not stratified |
SX-2 | Smooth plentiful | Light homogeneous | Not stratified |
SX-3 | Smooth plentiful | Light homogeneous | Not stratified |
SX-4 | Moisture feeling is strong | Light homogeneous | Not stratified |
SX-5 | Moisture feeling is strong | Light homogeneous | Not stratified |
SX-6 | Moisture feeling is stronger | Light homogeneous | Layering after 1 week |
Claims (3)
1. a water-based wax emulsion that increases leather polishing degree, is characterized in that comprising the following steps:
Mark by weight, by oxidized polyethlene wax 5-40 part, emulsifying agent 1-10 part, perfluoroalkyl trimethyl-glycine 0.1-0.5 part, Dioctadecyl Amine 0.1-0.5 part, defoamer 0.1-0.5 part etc. joins in emulsifying kettle, heated mixt 100-150 ℃, makes all material meltings, and melts is cooled to 80-100 ℃, the isothermal hot water that slowly adds water 30-60 part, high-speed stirring, is incubated 0.5-3 hour simultaneously, cooling rapidly, the cold water of 10-30 part is added, and after stirring, discharging obtains product.
2. a kind of water-based wax emulsion that increases leather polishing degree according to claim 1, is characterized in that, uses perfluoroalkyl trimethyl-glycine, and Dioctadecyl Amine is as emulsification synergistic agent.
3. a kind of water-based wax emulsion that increases leather polishing degree obtaining according to the described preparation method of one of claim 1-2.
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CN201410311950.6A CN104087183B (en) | 2014-06-26 | 2014-06-26 | A kind of water-borne wax emulsion increasing leather polishing degree |
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CN201410311950.6A CN104087183B (en) | 2014-06-26 | 2014-06-26 | A kind of water-borne wax emulsion increasing leather polishing degree |
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CN104087183B CN104087183B (en) | 2016-01-20 |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105838263A (en) * | 2016-04-10 | 2016-08-10 | 张耀忠 | Compound wax emulsion |
CN106244025A (en) * | 2016-08-02 | 2016-12-21 | 鄢海军 | A kind of wax of preventing coating protection Automobile paint |
CN106752419A (en) * | 2016-11-28 | 2017-05-31 | 德阳力久云智知识产权运营有限公司 | A kind of wax Emulsion for Leather containing OPE and preparation method thereof |
CN107325652A (en) * | 2016-11-28 | 2017-11-07 | 德阳力久云智知识产权运营有限公司 | A kind of wax Emulsion for Leather containing Tissuemat E and preparation method thereof |
CN111979802A (en) * | 2020-07-24 | 2020-11-24 | 江苏海云花新材料有限公司 | Wax emulsion for yarn dyeing |
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Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105838263A (en) * | 2016-04-10 | 2016-08-10 | 张耀忠 | Compound wax emulsion |
CN106244025A (en) * | 2016-08-02 | 2016-12-21 | 鄢海军 | A kind of wax of preventing coating protection Automobile paint |
CN106752419A (en) * | 2016-11-28 | 2017-05-31 | 德阳力久云智知识产权运营有限公司 | A kind of wax Emulsion for Leather containing OPE and preparation method thereof |
CN107325652A (en) * | 2016-11-28 | 2017-11-07 | 德阳力久云智知识产权运营有限公司 | A kind of wax Emulsion for Leather containing Tissuemat E and preparation method thereof |
CN111979802A (en) * | 2020-07-24 | 2020-11-24 | 江苏海云花新材料有限公司 | Wax emulsion for yarn dyeing |
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