CN107325652A - A kind of wax Emulsion for Leather containing Tissuemat E and preparation method thereof - Google Patents
A kind of wax Emulsion for Leather containing Tissuemat E and preparation method thereof Download PDFInfo
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- CN107325652A CN107325652A CN201611065454.2A CN201611065454A CN107325652A CN 107325652 A CN107325652 A CN 107325652A CN 201611065454 A CN201611065454 A CN 201611065454A CN 107325652 A CN107325652 A CN 107325652A
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- parts
- wax
- wax emulsion
- leather
- tissuemat
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
- C09D123/02—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D123/04—Homopolymers or copolymers of ethene
- C09D123/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C11/00—Surface finishing of leather
- C14C11/003—Surface finishing of leather using macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/387—Borates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
Abstract
The invention discloses a kind of wax Emulsion for Leather containing Tissuemat E, belong to wax emulsion preparing technical field, the wax emulsion is made up of the raw material of following parts by weight：80~170 parts of 10~15 parts of Tissuemat E, 2~6 parts of Brazil wax, 1.2~3 parts of polyoxyethylene cetyl base stearyl bis ether, 4~7 parts of film-forming resin, 3~6 parts of polyester wax, 1~3 part of phosphoric acid tributyl ethoxylated ester, 0.6~0.9 part of dimethyl PABA amido propyl lauryl dimethyl ammonium toluene fulfonate, 0.3~0.5 part of triethylene diamine, 0.5~0.8 part of octadecane alcohol radical APEO, 1~3 part of Firebrake ZB and water.The present invention additionally provides the preparation method of the wax emulsion simultaneously, and the wax emulsion that the present invention is provided can improve the feel of leather finishing agent, real leather products feel can be made more excellent.The wax emulsion of the present invention has more excellent than like product antiacid, alkali resistant and stability in hard water, and its emulsion-stabilizing, arbitrary proportion water dilution is not stratified, is not demulsified, does not lump during storage, long shelf-life.
Description
Technical field
The present invention relates to a kind of preparation method of wax emulsion, more particularly to a kind of wax Emulsion for Leather containing Tissuemat E
And preparation method thereof.
Background technology
Wax emulsion in leather industry mainly as leather finish auxiliary agent, for bottom, in, top coat, with preferable performance.
Wax had both had the general character of water proofing property and lubricity, in terms of having such as oiliness, viscosity, fragility, toughness, fusibleness and gloss again
Characteristic, is very different to each other.In actual applications, a kind of wax can not possibly have the institute met required for a certain special-purpose
There is property.Therefore, when selecting the raw material of leather finish wax emulsion, to consider the performance of wax, improve leather and apply
The Spraying technique of decorations.Wax emulsion is favored by researcher and user more and more in recent years, the external research and development to it
Have for many years, and form tandem product numerous in variety.Its covering with paint defensive position of the wax Emulsion for Leather occurred in existing market
Sense is very puckery, and wax sense is not strong, on the other hand as the wax emulsion of underseal, and the permeability of its emulsion is too strong, covers with paint, lacquer, colour wash, etc. after leather easily
Moist feeling is caused, the quality of leather is have impact on, while the chemical stability and poor storage stability of wax emulsion.
The content of the invention
It is an object of the invention to overcome the wax sense present in leather finish wax emulsion in the prior art not strong, chemical steady
The above-mentioned deficiency of qualitative and poor storage stability is there is provided a kind of wax Emulsion for Leather containing Tissuemat E, and the feel wax can
Feel and chemistry, storage stability for improving leather finishing agent, can make real leather products feel more excellent.
In order to realize foregoing invention purpose, the invention provides following technical scheme：
A kind of wax Emulsion for Leather containing Tissuemat E, is prepared from the following raw materials in parts by weight：10~15 parts of Tissuemat E,
2~6 parts of Brazil wax, 1.2~3 parts of polyoxyethylene cetyl base stearyl bis ether, 4~7 parts of film-forming resin, polyester wax 3~6
Part, 1~3 part of phosphoric acid tributyl ethoxylated ester, dimethyl PABA amido propyl lauryl dimethyl ammonium toluene fulfonate 0.6~
0.9 part, 0.3~0.5 part of triethylene diamine, 0.5~0.8 part of octadecane alcohol radical APEO, 1~3 part of Firebrake ZB and water 80
~170 parts.
Preferably, a kind of wax Emulsion for Leather containing Tissuemat E, is prepared from the following raw materials in parts by weight：Polyethylene
12 parts of wax, 4 parts of Brazil wax, 1.8 parts of polyoxyethylene cetyl base stearyl bis ether, 5.5 parts of film-forming resin, 4 parts of polyester wax, phosphorus
Sour 2 parts of tributyl ethoxylated ester, 0.8 part of dimethyl PABA amido propyl lauryl dimethyl ammonium toluene fulfonate, triethylene
130 parts of 0.4 part of diamines, 0.6 part of octadecane alcohol radical APEO, 2 parts of Firebrake ZB and water.
Another object of the present invention is to provide the preparation method of the wax Emulsion for Leather containing Tissuemat E, including it is following
Step：
（1）The preparation of film-forming resin：The formula of film-forming resin is lauric acid/dodecanoic acid list PULLRONIC F68 block type polyether ester 2
~6 parts, 1~3 part of glycerine mono-propionate, 3~5 parts of stearoxyl trimethyl silane, 4~6 parts of ethoxy dodecyl alcohol, third
2~4 parts of olefin(e) acid hydroxypropyl acrylate, 0.1~0.3 part of ferrous sulfate, 3~5 parts of trimellitic anhydride, 0.2~0.3 part of potassium peroxydisulfate, 1,4-
0.3~0.5 part of butanediol；Preparation method is as follows：
A, by lauric acid/dodecanoic acid list PULLRONIC F68 block type polyether ester, glycerine mono-propionate, hydroxypropyl acrylate, hard
Fat epoxide trimethyl silane and trimellitic anhydride add stainless steel cauldron, are warming up to 80~90 DEG C, open stirring and add over cure
Sour potassium, ferrous sulfate, ethoxy dodecyl alcohol and 1,4- butanediols；
B and then it is warming up to 130~150 DEG C with 20~30 DEG C/h speed, reacts 1~2 hour and stop heating, be cooled to 60~70
DEG C stir evenly and to obtain film-forming resin；
（2）Into autoclave Tissuemat E, Brazil wax, polyester wax, polyoxyethylene cetyl base tristearin are added by proportioning
Base bis ether, phosphoric acid tributyl ethoxylated ester and film-forming resin, are heated to 100~120 DEG C of meltings, stir, obtain oil phase point
Dissipate mixture；
（3）By dimethyl PABA amido propyl lauryl dimethyl ammonium toluene fulfonate, triethylene diamine and octadecane alcohol radical
APEO is soluble in water, is heated to 90~95 DEG C, obtains Aqueous dispersions mixture；
（4）The mixing speed of autoclave is improved to 1000~2000rpm, step is added（3）The Aqueous dispersions mixing of preparation
Thing is emulsified, and emulsification times are 1~3h；Then warmed to room temperature in 200~300rpm mixing speed decline, add Firebrake ZB
Continue to stir 10~30min afterwards, be then filtrated to get wax Emulsion for Leather.
Compared with prior art, beneficial effects of the present invention：
The wax emulsion of the present invention can improve the feel of leather finishing agent, and real leather products feel can be made more excellent.The wax of the present invention
Emulsion has more excellent than like product antiacid, alkali resistant and a stability in hard water, its emulsion-stabilizing, the dilution of arbitrary proportion water regardless of
Layer, is not demulsified during storage, does not lump, long shelf-life.
Embodiment
With reference to test example and embodiment, the present invention is described in further detail.But this should not be understood
Following embodiment is only limitted to for the scope of above-mentioned theme of the invention, it is all that this is belonged to based on the technology that present invention is realized
The scope of invention.
Embodiment 1
A kind of wax Emulsion for Leather containing Tissuemat E, is prepared from the following raw materials in parts by weight：12 parts of Tissuemat E, Brazil
4 parts of palm wax, 1.8 parts of polyoxyethylene cetyl base stearyl bis ether, 5.5 parts of film-forming resin, 4 parts of polyester wax, phosphoric acid tributyl second
2 parts of epoxide ester, 0.8 part of dimethyl PABA amido propyl lauryl dimethyl ammonium toluene fulfonate, 0.4 part of triethylene diamine,
130 parts of 0.6 part of octadecane alcohol radical APEO, 2 parts of Firebrake ZB and water.
The preparation method of the above-mentioned wax Emulsion for Leather containing Tissuemat E, comprises the following steps：
（1）The preparation of film-forming resin：The formula of film-forming resin is lauric acid/dodecanoic acid list PULLRONIC F68 block type polyether ester 4
Part, 2 parts of glycerine mono-propionate, 3 parts of stearoxyl trimethyl silane, 5 parts of ethoxy dodecyl alcohol, hydroxypropyl acrylate 3
Part, 0.2 part of ferrous sulfate, 4 parts of trimellitic anhydride, 0.2 part of potassium peroxydisulfate, 0.4 part of 1,4- butanediols；Preparation method is as follows：
A, by lauric acid/dodecanoic acid list PULLRONIC F68 block type polyether ester, glycerine mono-propionate, hydroxypropyl acrylate, hard
Fat epoxide trimethyl silane and trimellitic anhydride add stainless steel cauldron, are warming up to 90 DEG C, open stirring add potassium peroxydisulfate,
Ferrous sulfate, ethoxy dodecyl alcohol and 1,4- butanediols；
B and then it is warming up to 140 DEG C with 30 DEG C/h speed, reacts 1.5 hours and stop heating, is cooled to 60 DEG C and stirs evenly and obtain film forming
Resin；
（2）Into autoclave Tissuemat E, Brazil wax, polyester wax, polyoxyethylene cetyl base tristearin are added by proportioning
Base bis ether, phosphoric acid tributyl ethoxylated ester and film-forming resin, are heated to 110 DEG C of meltings, stir, obtain oil phase dispersion mixing
Thing；
（3）By dimethyl PABA amido propyl lauryl dimethyl ammonium toluene fulfonate, triethylene diamine and octadecane alcohol radical
APEO is soluble in water, is heated to 92 DEG C, obtains Aqueous dispersions mixture；
（4）The mixing speed of autoclave is improved to 1500rpm, step is added（3）The Aqueous dispersions mixture of preparation is carried out
Emulsification, emulsification times are 1.5h；Then warmed to room temperature in 250rpm mixing speed decline, add after Firebrake ZB and continue to stir
20min, is then filtrated to get wax Emulsion for Leather.
The performance indications of wax emulsion made from above-described embodiment：
Faint yellow emulsion, solid content 12.3%, PH：10, product stability, 50 DEG C, outward appearance is unchanged within 12 months.
Wax emulsion prepared by embodiment is formulated consumption by primary coat and primary coat is deployed into slurry with resin, covers with paint, lacquer, colour wash, etc. ox-hide leather
Afterwards, leather hand feeling is full, gentle, and wax sense is strong, while having excellent water resistance.
Claims (4)
1. a kind of wax Emulsion for Leather containing Tissuemat E, it is characterised in that be prepared from the following raw materials in parts by weight：Poly- second
10~15 parts of alkene wax, 2~6 parts of Brazil wax, 1.2~3 parts of polyoxyethylene cetyl base stearyl bis ether, film-forming resin 4~7
Part, 3~6 parts of polyester wax, 1~3 part of phosphoric acid tributyl ethoxylated ester, dimethyl PABA amido propyl lauryl dimethyl ammonium first
0.6~0.9 part of benzene sulfonate, 0.3~0.5 part of triethylene diamine, 0.5~0.8 part of octadecane alcohol radical APEO, Firebrake ZB
1~3 part and 80~170 parts of water.
2. the wax Emulsion for Leather according to claim 1 containing Tissuemat E, it is characterised in that by following parts by weight
Raw material be made：12 parts of Tissuemat E, 4 parts of Brazil wax, 1.8 parts of polyoxyethylene cetyl base stearyl bis ether, film-forming resin
5.5 parts, 4 parts of polyester wax, 2 parts of phosphoric acid tributyl ethoxylated ester, dimethyl PABA amido propyl lauryl dimethyl ammonium toluene
130 parts of 0.8 part of sulfonate, 0.4 part of triethylene diamine, 0.6 part of octadecane alcohol radical APEO, 2 parts of Firebrake ZB and water.
3. the wax Emulsion for Leather according to claim 1 containing Tissuemat E, it is characterised in that described film-forming resin
Formula be 2~6 parts of lauric acid/dodecanoic acid list PULLRONIC F68 block type polyether ester, it is 1~3 part of glycerine mono-propionate, stearic
3~5 parts of epoxide trimethyl silane, 4~6 parts of ethoxy dodecyl alcohol, 2~4 parts of hydroxypropyl acrylate, ferrous sulfate 0.1~
0.3 part, 3~5 parts of trimellitic anhydride, 0.2~0.3 part of potassium peroxydisulfate, 0.3~0.5 part of 1,4- butanediols；Preparation method is as follows：
（1）By lauric acid/dodecanoic acid list PULLRONIC F68 block type polyether ester, glycerine mono-propionate, hydroxypropyl acrylate, hard
Fat epoxide trimethyl silane and trimellitic anhydride add stainless steel cauldron, are warming up to 80~90 DEG C, open stirring and add over cure
Sour potassium, ferrous sulfate, ethoxy dodecyl alcohol and 1,4- butanediols；
（2）Then 130~150 DEG C are warming up to 20~30 DEG C/h speed, react 1~2 hour and stop heating, be cooled to 60~70
DEG C stir evenly and to obtain film-forming resin.
4. a kind of preparation method of the wax Emulsion for Leather as claimed in claim 1 containing Tissuemat E, it is characterised in that bag
Include following steps：
（1）Film-forming resin is made in formula according to claim 3 and preparation method；
（2）Into autoclave Tissuemat E, Brazil wax, polyester wax, polyoxyethylene cetyl base tristearin are added by proportioning
Base bis ether, phosphoric acid tributyl ethoxylated ester and film-forming resin, are heated to 100~120 DEG C of meltings, stir, obtain oil phase point
Dissipate mixture；
（3）By dimethyl PABA amido propyl lauryl dimethyl ammonium toluene fulfonate, triethylene diamine and octadecane alcohol radical
APEO is soluble in water, is heated to 90~95 DEG C, obtains Aqueous dispersions mixture；
（4）The mixing speed of autoclave is improved to 1000~2000rpm, step is added（3）The Aqueous dispersions mixing of preparation
Thing is emulsified, and emulsification times are 1~3h；Then warmed to room temperature in 200~300rpm mixing speed decline, add Firebrake ZB
Continue to stir 10~30min afterwards, be then filtrated to get wax Emulsion for Leather.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611065454.2A CN107325652A (en) | 2016-11-28 | 2016-11-28 | A kind of wax Emulsion for Leather containing Tissuemat E and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611065454.2A CN107325652A (en) | 2016-11-28 | 2016-11-28 | A kind of wax Emulsion for Leather containing Tissuemat E and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107325652A true CN107325652A (en) | 2017-11-07 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611065454.2A Withdrawn CN107325652A (en) | 2016-11-28 | 2016-11-28 | A kind of wax Emulsion for Leather containing Tissuemat E and preparation method thereof |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1611560A (en) * | 2003-10-31 | 2005-05-04 | 中国石油化工股份有限公司 | Wax-containing composition for leather and its product surface coating |
| CN101942152A (en) * | 2009-07-06 | 2011-01-12 | 上海雅运纺织助剂有限公司 | Microemulsion composite of polyethylene wax oxide |
| CN104087183A (en) * | 2014-06-26 | 2014-10-08 | 衢州市中通化工有限公司 | Aqueous wax emulsion for improving brightness of leather |
| CN105647368A (en) * | 2016-03-04 | 2016-06-08 | 陈震烁 | Leather surface treatment agent and preparation method thereof |
| CN105779670A (en) * | 2016-04-29 | 2016-07-20 | 四川力久知识产权服务有限公司 | Wax emulsion for leather finishing and preparing method of wax emulsion |
| CN105802256A (en) * | 2016-04-14 | 2016-07-27 | 广东额图网络科技发展有限公司 | Preparation method of multifunctional leather wax emulsion |
-
2016
- 2016-11-28 CN CN201611065454.2A patent/CN107325652A/en not_active Withdrawn
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1611560A (en) * | 2003-10-31 | 2005-05-04 | 中国石油化工股份有限公司 | Wax-containing composition for leather and its product surface coating |
| CN101942152A (en) * | 2009-07-06 | 2011-01-12 | 上海雅运纺织助剂有限公司 | Microemulsion composite of polyethylene wax oxide |
| CN104087183A (en) * | 2014-06-26 | 2014-10-08 | 衢州市中通化工有限公司 | Aqueous wax emulsion for improving brightness of leather |
| CN105647368A (en) * | 2016-03-04 | 2016-06-08 | 陈震烁 | Leather surface treatment agent and preparation method thereof |
| CN105802256A (en) * | 2016-04-14 | 2016-07-27 | 广东额图网络科技发展有限公司 | Preparation method of multifunctional leather wax emulsion |
| CN105779670A (en) * | 2016-04-29 | 2016-07-20 | 四川力久知识产权服务有限公司 | Wax emulsion for leather finishing and preparing method of wax emulsion |
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Application publication date: 20171107 |
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