CN109650846A - 具有耐磨橡胶面层的陶瓷的制作方法 - Google Patents
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Abstract
本分案申请涉及一种具有耐磨橡胶面层的陶瓷的制作方法，属于日用陶瓷技术领域。所述具有耐磨橡胶面层的陶瓷包括陶瓷坯体和橡胶涂料面层，所述陶瓷坯体表面喷涂橡胶涂料形成橡胶涂料面层，所述陶瓷坯体由坯体基料制得，通过本发明制作方法制得的具有耐磨橡胶面层的陶瓷，橡胶面层与陶瓷坯体之间的附着力得到了有效提高，使制得的产品具有优异的耐磨抗刮性能，附着力可达0级；同时产品具有极佳的橡胶质感和滑爽性，赋予了普通陶瓷产品大气沉稳的橡胶质外观；此外，橡胶面层的肉厚感和软触感较佳，还具有良好的耐候性和耐溶剂性。
Description
本申请为申请号为201610760866.1、申请日为2016年08月30日、发明创造名称为“具有耐磨橡胶面层的陶瓷及其制作方法”的发明专利申请的分案申请。
技术领域
本发明属于日用陶瓷技术领域，具体涉及一种具有耐磨橡胶面层的陶瓷的制作方法。
背景技术
陶瓷是以粘土、天然矿物等为主要原料经过粉碎球磨、过筛、压滤脱水、练泥成型、烧制施釉制得的具有优异机械性能的制品。陶瓷的传统概念是指所有以粘土等无机非金属矿物为原料制成的产品。目前，我国陶瓷产品的主要产地为景德镇、高安、丰城、萍乡、佛山、潮州及德化等地。
陶瓷的发展比较久远，因此其种类也比较丰富。为了进一步丰富陶瓷产品的种类，提高其装饰效果，在陶瓷产品表面结合橡胶材料可赋予其普通陶瓷产品无法比拟的橡胶质感。若是直接在陶瓷产品表面固定橡胶材料，两者之间容易开裂产生缝隙，因此选择在陶瓷表面喷涂橡胶类涂料，一般为了提高涂料与陶瓷坯体的附着力，选用陶瓷素坯进行喷涂效果会较好，但是如此以来陶瓷素坯缺少了釉层的保护，即使涂料层会起到保护作用，陶瓷产品整体的性能仍会下降。而目前现有的橡胶涂料存在与陶瓷坯体釉层附着力较差的不足，橡胶面层的耐磨性和抗刮性不佳，有待进一步改进。
如申请号为201010190317.8的中国专利公开了一种高耐磨弹性橡胶漆，虽然该橡胶漆具有优异的耐磨性，但是其在陶瓷产品上的应用差强人意，该橡胶漆与陶瓷釉面的附着力较差，导致其耐磨性下降。因此对具有耐磨橡胶面层的陶瓷进行研究就显得尤为重要。
发明内容
本发明的目的是为了解决现有技术的不足，而提供一种具有耐磨橡胶面层的陶瓷的制作方法，本发明制得的具有耐磨橡胶面层的陶瓷具有优异的耐磨性能，其表面的橡胶面层与陶瓷坯体的附着力佳，赋予陶瓷产品良好的抗刮性、滑爽性和极佳的橡胶质感。
本发明采用如下技术方案：
具有耐磨橡胶面层的陶瓷的制作方法，步骤如下：
陶瓷坯体制作：将坯体基料混合后经球磨、过筛、压滤脱水、练泥、成型、烧制及施釉，得陶瓷坯体；所述坯体基料包括白刚玉细粉、茂名高岭土、吴县青山白泥、滑石、废旧陶瓷素坯碎料和黑云母，所述白刚玉细粉、茂名高岭土、吴县青山白泥、滑石、废旧陶瓷素坯碎料和黑云母的质量比为18.7：23：12：8.1：25：13；
橡胶涂料制作：将A组分中所述各组分混合均匀，再加入B组分的固化剂搅拌均匀，即得橡胶涂料；所述橡胶涂料包括按照质量份数计的如下组分：A组分：氟化聚氨酯-丙烯酸酯乳液35份、二月桂酸二丁基锡2份、氟改性丙烯酸流平剂0.9份、有机硅类手感剂0.4份、溶剂42份、颜料20份，所述溶剂为环己酮、二乙二醇丁醚和乙酸丁酯的混合物，所述环己酮、二乙二醇丁醚和乙酸丁酯的质量比为1：2：4；
B组分：固化剂1.3份；
将所得橡胶涂料喷涂于所述陶瓷坯体表面，烘干，即得具有耐磨橡胶面层的陶瓷。
更进一步地，所述白刚玉细粉的粒径为10-30μm。
更进一步地，橡胶面层的厚度为15-18μm。
更进一步地，橡胶涂料制作时，采用高速混合机混合各组分。
本发明与现有技术相比，其有益效果为：
本发明通过对陶瓷坯体原料与橡胶漆原料进行改进，有效提高了橡胶面层与陶瓷坯体之间的附着力，使制得的产品具有优异的耐磨抗刮性能，附着力可达0级；同时产品具有极佳的橡胶质感和滑爽性，赋予了普通陶瓷产品大气沉稳的橡胶质外观；此外，橡胶面层的肉厚感和软触感较佳，还具有良好的耐候性和耐溶剂性。
具体实施方式
下面结合实施例对本发明作进一步的详细描述。
本领域技术人员将会理解，下列实施例仅用于说明本发明，而不应视为限定本发明的范围，其中本发明使用的弹性树脂乳液为氟化聚氨酯-丙烯酸酯乳液，固含量为60％，市售产品均可以；所用流平剂为氟改性丙烯酸流平剂，购自巴斯夫，型号为EFKA3777，有效物质含量70％，为无色透明状；使用的手感剂为有机硅类手感剂，购自东莞市博诚化工有限公司，型号为SP-301弹性手感剂，固含量99％，比重1.04，淡黄色透明液体，使用的废旧陶瓷素坯碎料粒径为20-30μm。
实施例1
本实施例的具有耐磨橡胶面层的陶瓷按照下表1所示配料组成进行制作：
表1实施例1各配料组成
制备方法为：陶瓷坯体制作：将所述坯体基料混合后经球磨、过筛、压滤脱水、练泥、成型、烧制及施釉，得陶瓷坯体；橡胶涂料制作：将A组分中所述各组分用高速混合机混合均匀，再加入B组分的固化剂搅拌均匀，即得橡胶涂料；将所得橡胶涂料喷涂于所述陶瓷坯体表面，烘干，橡胶面层的厚度为16μm，即得具有耐磨橡胶面层的陶瓷。
实施例2
本实施例的具有耐磨橡胶面层的陶瓷按照下表2所示配料组成进行制作：
表2实施例2各配料组成
制备方法为：陶瓷坯体制作：将所述坯体基料混合后经球磨、过筛、压滤脱水、练泥、成型、烧制及施釉，得陶瓷坯体；橡胶涂料制作：将A组分中所述各组分用高速混合机混合均匀，再加入B组分的固化剂搅拌均匀，即得橡胶涂料；将所得橡胶涂料喷涂于所述陶瓷坯体表面，烘干，橡胶面层的厚度为15μm，即得具有耐磨橡胶面层的陶瓷。
实施例3
本实施例的具有耐磨橡胶面层的陶瓷按照下表3所示配料组成进行制作：
表3实施例3各配料组成
制备方法为：陶瓷坯体制作：将所述坯体基料混合后经球磨、过筛、压滤脱水、练泥、成型、烧制及施釉，得陶瓷坯体；橡胶涂料制作：将A组分中所述各组分用高速混合机混合均匀，再加入B组分的固化剂搅拌均匀，即得橡胶涂料；将所得橡胶涂料喷涂于所述陶瓷坯体表面，烘干，橡胶面层的厚度为18μm，即得具有耐磨橡胶面层的陶瓷。
将实施例1至3制得的产品进行性能检测，其中耐老化性能测试采用紫外线加速老化400h，后测定其外观变化和60度光测度，以评定其耐老化性能，其他性能测试按照参考标准进行，结果如下表4所示：
表4实施例1至3制得的产品的性能
由上表4可见，本发明制得的具有耐磨橡胶面层的陶瓷，其橡胶涂层与陶瓷坯体釉面附着力较好，实施例2效果最佳。
本行业的技术人员应该了解，本发明不受上述实施例的限制，上述实施例和说明书中描述的只是说明本发明的原理，在不脱离本发明精神和范围的前提下，本发明还会有各种变化和改进，这些变化和改进都落入要求保护的本发明范围内。本发明要求保护范围由所附的权利要求书及其等效物界定。
Claims (4)
1.具有耐磨橡胶面层的陶瓷的制作方法，其特征在于，步骤如下：
陶瓷坯体制作：将坯体基料混合后经球磨、过筛、压滤脱水、练泥、成型、烧制及施釉，得陶瓷坯体；所述坯体基料包括白刚玉细粉、茂名高岭土、吴县青山白泥、滑石、废旧陶瓷素坯碎料和黑云母，所述白刚玉细粉、茂名高岭土、吴县青山白泥、滑石、废旧陶瓷素坯碎料和黑云母的质量比为18.7：23：12：8.1：25：13；
橡胶涂料制作：将A组分中所述各组分混合均匀，再加入B组分的固化剂搅拌均匀，即得橡胶涂料；所述橡胶涂料包括按照质量份数计的如下组分：A组分：氟化聚氨酯-丙烯酸酯乳液35份、二月桂酸二丁基锡2份、氟改性丙烯酸流平剂0.9份、有机硅类手感剂0.4份、溶剂42份、颜料20份，所述溶剂为环己酮、二乙二醇丁醚和乙酸丁酯的混合物，所述环己酮、二乙二醇丁醚和乙酸丁酯的质量比为1：2：4；
B组分：固化剂1.3份；
将所得橡胶涂料喷涂于所述陶瓷坯体表面，烘干，即得具有耐磨橡胶面层的陶瓷。
2.根据权利要求1所述的具有耐磨橡胶面层的陶瓷的制作方法，其特征在于，所述白刚玉细粉的粒径为10-30μm。
3.根据权利要1所述的具有耐磨橡胶面层的陶瓷的制作方法，其特征在于，橡胶面层的厚度为15-18μm。
4.根据权利要求1所述的具有耐磨橡胶面层的陶瓷的制作方法，其特征在于，橡胶涂料制作时，采用高速混合机混合各组分。
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