CN106396608B - 具有耐磨橡胶面层的陶瓷及其制作方法 - Google Patents
具有耐磨橡胶面层的陶瓷及其制作方法 Download PDFInfo
- Publication number
- CN106396608B CN106396608B CN201610760866.1A CN201610760866A CN106396608B CN 106396608 B CN106396608 B CN 106396608B CN 201610760866 A CN201610760866 A CN 201610760866A CN 106396608 B CN106396608 B CN 106396608B
- Authority
- CN
- China
- Prior art keywords
- surface layer
- ceramics
- rubber
- rubber coating
- ceramic body
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000919 ceramic Substances 0.000 title claims abstract description 84
- 239000002344 surface layer Substances 0.000 title claims abstract description 49
- 238000002360 preparation method Methods 0.000 title abstract description 7
- 238000010073 coating (rubber) Methods 0.000 claims abstract description 31
- 239000000463 material Substances 0.000 claims abstract description 13
- 239000002904 solvent Substances 0.000 claims abstract description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 25
- 238000004519 manufacturing process Methods 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 8
- 235000015895 biscuits Nutrition 0.000 claims description 7
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims description 7
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 6
- 238000000498 ball milling Methods 0.000 claims description 6
- 230000018044 dehydration Effects 0.000 claims description 6
- 238000006297 dehydration reaction Methods 0.000 claims description 6
- 238000000465 moulding Methods 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 238000007873 sieving Methods 0.000 claims description 6
- 239000004927 clay Substances 0.000 claims description 5
- 238000010304 firing Methods 0.000 claims description 5
- 239000006210 lotion Substances 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 5
- 239000011347 resin Substances 0.000 claims description 5
- 229920005989 resin Polymers 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 239000002699 waste material Substances 0.000 claims description 5
- 239000005995 Aluminium silicate Substances 0.000 claims description 4
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims description 4
- 235000012211 aluminium silicate Nutrition 0.000 claims description 4
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 claims description 4
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 4
- 229910052573 porcelain Inorganic materials 0.000 claims description 4
- 239000000454 talc Substances 0.000 claims description 4
- 235000012222 talc Nutrition 0.000 claims description 4
- 229910052623 talc Inorganic materials 0.000 claims description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 229910052626 biotite Inorganic materials 0.000 claims description 3
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- 239000000839 emulsion Substances 0.000 claims description 3
- 229910052710 silicon Inorganic materials 0.000 claims description 3
- 239000010703 silicon Substances 0.000 claims description 3
- 239000007921 spray Substances 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 2
- 239000000049 pigment Substances 0.000 claims description 2
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical group CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 claims 1
- 239000012975 dibutyltin dilaurate Substances 0.000 claims 1
- 239000000853 adhesive Substances 0.000 abstract description 8
- 230000001070 adhesive effect Effects 0.000 abstract description 8
- 239000002994 raw material Substances 0.000 abstract description 6
- 239000002966 varnish Substances 0.000 abstract description 3
- 239000012298 atmosphere Substances 0.000 abstract description 2
- 235000013372 meat Nutrition 0.000 abstract description 2
- 238000005507 spraying Methods 0.000 abstract description 2
- 239000000047 product Substances 0.000 description 15
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000010410 layer Substances 0.000 description 3
- 230000032683 aging Effects 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 238000007790 scraping Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- 229920001800 Shellac Polymers 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 125000002243 cyclohexanonyl group Chemical group *C1(*)C(=O)C(*)(*)C(*)(*)C(*)(*)C1(*)* 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- PYBNTRWJKQJDRE-UHFFFAOYSA-L dodecanoate;tin(2+) Chemical compound [Sn+2].CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O PYBNTRWJKQJDRE-UHFFFAOYSA-L 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 description 1
- 238000003682 fluorination reaction Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000004208 shellac Substances 0.000 description 1
- ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 description 1
- 229940113147 shellac Drugs 0.000 description 1
- 235000013874 shellac Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/04—Clay; Kaolin
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
- C04B33/1324—Recycled material, e.g. tile dust, stone waste, spent refractory material
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
- C04B41/49—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes
- C04B41/4905—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes containing silicon
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/82—Coating or impregnation with organic materials
- C04B41/83—Macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
- C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
- C04B2235/3472—Alkali metal alumino-silicates other than clay, e.g. spodumene, alkali feldspars such as albite or orthoclase, micas such as muscovite, zeolites such as natrolite
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Laminated Bodies (AREA)
Abstract
本发明涉及一种具有耐磨橡胶面层的陶瓷及其制作方法，属于日用陶瓷技术领域。该具有耐磨橡胶面层的陶瓷包括陶瓷坯体和橡胶涂料面层，所述陶瓷坯体表面喷涂橡胶涂料形成橡胶涂料面层，所述陶瓷坯体由坯体基料制得，本发明通过对陶瓷坯体原料与橡胶漆原料进行改进，有效提高了橡胶面层与陶瓷坯体之间的附着力，使制得的产品具有优异的耐磨抗刮性能，附着力可达0级；同时产品具有极佳的橡胶质感和滑爽性，赋予了普通陶瓷产品大气沉稳的橡胶质外观；此外，橡胶面层的肉厚感和软触感较佳，还具有良好的耐候性和耐溶剂性。
Description
技术领域
本发明属于日用陶瓷技术领域，具体涉及一种具有耐磨橡胶面层的陶瓷及其制作方法。
背景技术
陶瓷是以粘土、天然矿物等为主要原料经过粉碎球磨、过筛、压滤脱水、练泥成型、烧制施釉制得的具有优异机械性能的制品。陶瓷的传统概念是指所有以粘土等无机非金属矿物为原料制成的产品。目前，我国陶瓷产品的主要产地为景德镇、高安、丰城、萍乡、佛山、潮州及德化等地。
陶瓷的发展比较久远，因此其种类也比较丰富。为了进一步丰富陶瓷产品的种类，提高其装饰效果，在陶瓷产品表面结合橡胶材料可赋予其普通陶瓷产品无法比拟的橡胶质感。若是直接在陶瓷产品表面固定橡胶材料，两者之间容易开裂产生缝隙，因此选择在陶瓷表面喷涂橡胶类涂料，一般为了提高涂料与陶瓷坯体的附着力，选用陶瓷素坯进行喷涂效果会较好，但是如此以来陶瓷素坯缺少了釉层的保护，即使涂料层会起到保护作用，陶瓷产品整体的性能仍会下降。而目前现有的橡胶涂料存在与陶瓷坯体釉层附着力较差的不足，橡胶面层的耐磨性和抗刮性不佳，有待进一步改进。
如申请号为201010190317.8的中国专利公开了一种高耐磨弹性橡胶漆，虽然该橡胶漆具有优异的耐磨性，但是其在陶瓷产品上的应用差强人意，该橡胶漆与陶瓷釉面的附着力较差，导致其耐磨性下降。因此对具有耐磨橡胶面层的陶瓷进行研究就显得尤为重要。
发明内容
本发明的目的是为了解决现有技术的不足，而提供一种具有耐磨橡胶面层的陶瓷及其制作方法，该具有耐磨橡胶面层的陶瓷具有优异的耐磨性能，其表面的橡胶面层与陶瓷坯体的附着力佳，赋予陶瓷产品良好的抗刮性、滑爽性和极佳的橡胶质感。
本发明采用如下技术方案：
具有耐磨橡胶面层的陶瓷，包括陶瓷坯体和橡胶涂料面层，所述陶瓷坯体表面喷涂橡胶涂料形成橡胶涂料面层，所述陶瓷坯体由坯体基料制得；
所述坯体基料包括白刚玉细粉、茂名高岭土、吴县青山白泥、滑石、废旧陶瓷素坯碎料和黑云母，所述白刚玉细粉、茂名高岭土、吴县青山白泥、滑石、废旧陶瓷素坯碎料和黑云母的质量比为15.6-20：19.3-25.7：10-15：5.7-9.8：22-28.7：11.3-16.4；
所述橡胶涂料包括按照质量份数计的如下组分：A组分：弹性树脂乳液30-40份、催干剂1.5-2.5份、流平剂0.8-1.0份、手感剂0.2-0.5份、溶剂35.35-48.51份、颜料15-23份，B组分：固化剂1.2-1.5份。
更近一步地，所述的具有耐磨橡胶面层的陶瓷，其中所述白刚玉细粉的粒径为10-30μm。
更近一步地，所述的具有耐磨橡胶面层的陶瓷，其中所述弹性树脂乳液为氟化聚氨酯-丙烯酸酯乳液。
更近一步地，所述的具有耐磨橡胶面层的陶瓷，其中所述流平剂为氟改性丙烯酸流平剂。
更近一步地，所述的具有耐磨橡胶面层的陶瓷，其中所述手感剂为有机硅类手感剂。
更近一步地，所述的具有耐磨橡胶面层的陶瓷，其中所述溶剂为环己酮、二乙二醇丁醚和乙酸丁酯的混合物，所述环己酮、二乙二醇丁醚和乙酸丁酯的质量比为1：2：4。
更近一步地，所述的具有耐磨橡胶面层的陶瓷，其中所述催干剂为二月桂酸二丁基锡。
本发明还提供所述的具有耐磨橡胶面层的陶瓷的制作方法，步骤如下：陶瓷坯体制作：将所述坯体基料混合后经球磨、过筛、压滤脱水、练泥、成型、烧制及施釉，得陶瓷坯体；橡胶涂料制作：将A组分中所述各组分混合均匀，再加入B组分的固化剂搅拌均匀，即得橡胶涂料；将所得橡胶涂料喷涂于所述陶瓷坯体表面，烘干，即得具有耐磨橡胶面层的陶瓷。
更近一步地，所述的具有耐磨橡胶面层的陶瓷的制作方法，其中橡胶面层的厚度为15-18μm。
更近一步地，所述的具有耐磨橡胶面层的陶瓷的制作方法，其中橡胶涂料制作时，采用高速混合机混合各组分。
本发明与现有技术相比，其有益效果为：
本发明通过对陶瓷坯体原料与橡胶漆原料进行改进，有效提高了橡胶面层与陶瓷坯体之间的附着力，使制得的产品具有优异的耐磨抗刮性能，附着力可达0级；同时产品具有极佳的橡胶质感和滑爽性，赋予了普通陶瓷产品大气沉稳的橡胶质外观；此外，橡胶面层的肉厚感和软触感较佳，还具有良好的耐候性和耐溶剂性。
具体实施方式
下面结合实施例对本发明作进一步的详细描述。
本领域技术人员将会理解，下列实施例仅用于说明本发明，而不应视为限定本发明的范围，其中本发明使用的弹性树脂乳液为氟化聚氨酯-丙烯酸酯乳液，固含量为60％，市售产品均可以；所用流平剂为氟改性丙烯酸流平剂，购自巴斯夫，型号为EFKA3777，有效物质含量70％，为无色透明状；使用的手感剂为有机硅类手感剂，购自东莞市博诚化工有限公司，型号为SP-301弹性手感剂，固含量99％，比重1.04，淡黄色透明液体，使用的废旧陶瓷素坯碎料粒径为20-30μm。
实施例1
本实施例的具有耐磨橡胶面层的陶瓷按照下表1所示配料组成进行制作：
表1实施例1各配料组成
制备方法为：陶瓷坯体制作：将所述坯体基料混合后经球磨、过筛、压滤脱水、练泥、成型、烧制及施釉，得陶瓷坯体；橡胶涂料制作：将A组分中所述各组分用高速混合机混合均匀，再加入B组分的固化剂搅拌均匀，即得橡胶涂料；将所得橡胶涂料喷涂于所述陶瓷坯体表面，烘干，橡胶面层的厚度为16μm，即得具有耐磨橡胶面层的陶瓷。
实施例2
本实施例的具有耐磨橡胶面层的陶瓷按照下表2所示配料组成进行制作：
表2实施例2各配料组成
制备方法为：陶瓷坯体制作：将所述坯体基料混合后经球磨、过筛、压滤脱水、练泥、成型、烧制及施釉，得陶瓷坯体；橡胶涂料制作：将A组分中所述各组分用高速混合机混合均匀，再加入B组分的固化剂搅拌均匀，即得橡胶涂料；将所得橡胶涂料喷涂于所述陶瓷坯体表面，烘干，橡胶面层的厚度为15μm，即得具有耐磨橡胶面层的陶瓷。
实施例3
本实施例的具有耐磨橡胶面层的陶瓷按照下表3所示配料组成进行制作：
表3实施例3各配料组成
制备方法为：陶瓷坯体制作：将所述坯体基料混合后经球磨、过筛、压滤脱水、练泥、成型、烧制及施釉，得陶瓷坯体；橡胶涂料制作：将A组分中所述各组分用高速混合机混合均匀，再加入B组分的固化剂搅拌均匀，即得橡胶涂料；将所得橡胶涂料喷涂于所述陶瓷坯体表面，烘干，橡胶面层的厚度为18μm，即得具有耐磨橡胶面层的陶瓷。
将实施例1至3制得的产品进行性能检测，其中耐老化性能测试采用紫外线加速老化400h，后测定其外观变化和60度光测度，以评定其耐老化性能，其他性能测试按照参考标准进行，结果如下表4所示：
表4实施例1至3制得的产品的性能
由上表4可见，本发明制得的具有耐磨橡胶面层的陶瓷，其橡胶涂层与陶瓷坯体釉面附着力较好，实施例2效果最佳。
本行业的技术人员应该了解，本发明不受上述实施例的限制，上述实施例和说明书中描述的只是说明本发明的原理，在不脱离本发明精神和范围的前提下，本发明还会有各种变化和改进，这些变化和改进都落入要求保护的本发明范围内。本发明要求保护范围由所附的权利要求书及其等效物界定。
Claims (5)
1.具有耐磨橡胶面层的陶瓷，其特征在于，包括陶瓷坯体和橡胶涂料面层，所述陶瓷坯体表面喷涂橡胶涂料形成橡胶涂料面层，所述陶瓷坯体由坯体基料制得；
所述坯体基料包括白刚玉细粉、茂名高岭土、吴县青山白泥、滑石、废旧陶瓷素坯碎料和黑云母，所述白刚玉细粉、茂名高岭土、吴县青山白泥、滑石、废旧陶瓷素坯碎料和黑云母的质量比为15.6-20∶19.3-25.7∶10-15∶5.7-9.8∶22-28.7∶11.3-16.4；
所述橡胶涂料包括按照质量份数计的如下组分：A组分：弹性树脂乳液30-40份、催干剂1.5-2.5份、流平剂0.8-1.0份、手感剂0.2-0.5份、溶剂35.35-48.51份、颜料15-23份，B组分：固化剂1.2-1.5份；
所述弹性树脂乳液为氟化聚氨酯-丙烯酸酯乳液；
所述流平剂为氟改性丙烯酸流平剂；
所述手感剂为有机硅类手感剂；
所述溶剂为环己酮、二乙二醇丁醚和乙酸丁酯的混合物，所述环己酮、二乙二醇丁醚和乙酸丁酯的质量比为1∶2∶4；
所述催干剂为二月桂酸二丁基锡。
2.根据权利要求1所述的具有耐磨橡胶面层的陶瓷，其特征在于，所述白刚玉细粉的粒径为10-30μm。
3.权利要求1所述的具有耐磨橡胶面层的陶瓷的制作方法，其特征在于，步骤如下：陶瓷坯体制作：将所述坯体基料混合后经球磨、过筛、压滤脱水、练泥、成型、烧制及施釉，得陶瓷坯体；橡胶涂料制作：将A组分中所述各组分混合均匀，再加入B组分的固化剂搅拌均匀，即得橡胶涂料；将所得橡胶涂料喷涂于所述陶瓷坯体表面，烘干，即得具有耐磨橡胶面层的陶瓷。
4.根据权利要3所述的具有耐磨橡胶面层的陶瓷的制作方法，其特征在于，橡胶面层的厚度为15-18μm。
5.根据权利要求3所述的具有耐磨橡胶面层的陶瓷的制作方法，其特征在于，橡胶涂料制作时，采用高速混合机混合各组分。
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910120003.1A CN109650846B (zh) | 2016-08-30 | 2016-08-30 | 具有耐磨橡胶面层的陶瓷的制作方法 |
| CN201610760866.1A CN106396608B (zh) | 2016-08-30 | 2016-08-30 | 具有耐磨橡胶面层的陶瓷及其制作方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610760866.1A CN106396608B (zh) | 2016-08-30 | 2016-08-30 | 具有耐磨橡胶面层的陶瓷及其制作方法 |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910120003.1A Division CN109650846B (zh) | 2016-08-30 | 2016-08-30 | 具有耐磨橡胶面层的陶瓷的制作方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106396608A CN106396608A (zh) | 2017-02-15 |
| CN106396608B true CN106396608B (zh) | 2019-03-22 |
Family
ID=58002638
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910120003.1A Active CN109650846B (zh) | 2016-08-30 | 2016-08-30 | 具有耐磨橡胶面层的陶瓷的制作方法 |
| CN201610760866.1A Active CN106396608B (zh) | 2016-08-30 | 2016-08-30 | 具有耐磨橡胶面层的陶瓷及其制作方法 |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910120003.1A Active CN109650846B (zh) | 2016-08-30 | 2016-08-30 | 具有耐磨橡胶面层的陶瓷的制作方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (2) | CN109650846B (zh) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113563116B (zh) * | 2021-07-21 | 2022-12-02 | 佛山欧神诺陶瓷有限公司 | 一种复合陶瓷砖及其制备方法与应用 |
| CN114213109B (zh) * | 2021-12-30 | 2023-03-10 | 辽宁省轻工科学研究院有限公司 | 一种高精度、高强度陶瓷手模及其制备方法 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CZ113496A3 (en) * | 1993-10-20 | 1996-07-17 | Henkel Kgaa | Binding agents based on fatty chemical reaction products |
| FR2780393B1 (fr) * | 1998-06-26 | 2000-12-29 | Rhodia Chimie Sa | Preparation d'un sulfure de terre rare comprenant un element alcalin a partir d'un phosphate ou d'un borate de l'element alcalin, composition obtenue et application comme pigment colorant |
| CN1820034B (zh) * | 2002-10-15 | 2010-10-27 | 埃克森美孚化学专利公司 | 聚烯烃粘合剂组合物和由其制成的制品 |
| CN101200373A (zh) * | 2007-12-11 | 2008-06-18 | 中国科学院上海硅酸盐研究所 | 一种用于橡胶模具的碳化硅陶瓷坯体的制备方法 |
| CN101845256B (zh) * | 2010-06-03 | 2012-05-23 | 深圳市千浪化工有限公司 | 一种高耐磨弹性橡胶漆 |
| KR101207019B1 (ko) * | 2011-01-11 | 2012-11-30 | 세화엔지니어링 주식회사 | 탄성을 갖는 내마모성 및 내열성 소재의 제조방법 |
| CN103468051B (zh) * | 2013-09-17 | 2014-12-17 | 烟台全丰密封技术有限公司 | 一种橡胶涂料的制备方法 |
| CN104497830B (zh) * | 2014-12-31 | 2016-09-21 | 东莞市新威环保科技有限公司 | 一种橡胶涂料 |
| CN104877187A (zh) * | 2015-05-28 | 2015-09-02 | 芜湖风雪橡胶有限公司 | 耐磨橡胶及其制备方法 |
| CN108285322A (zh) * | 2015-09-24 | 2018-07-17 | 于洋 | 一种电力用复合陶瓷接线柱的制备方法 |
| CN105255327B (zh) * | 2015-10-08 | 2017-10-03 | 江苏科技大学 | 一种含柔性高分子固化剂的陶瓷防腐耐磨涂料及制备方法 |
-
2016
- 2016-08-30 CN CN201910120003.1A patent/CN109650846B/zh active Active
- 2016-08-30 CN CN201610760866.1A patent/CN106396608B/zh active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN106396608A (zh) | 2017-02-15 |
| CN109650846B (zh) | 2021-03-30 |
| CN109650846A (zh) | 2019-04-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103360121B (zh) | 一种高强度电瓷灰釉配方及其制备方法 | |
| CN103642344A (zh) | 一种质感多彩涂料及其制备方法 | |
| CN106045577B (zh) | 中温雪花釉陶瓷制品及其的制作方法 | |
| CN106396608B (zh) | 具有耐磨橡胶面层的陶瓷及其制作方法 | |
| CN105348976A (zh) | 一种反光性热熔标线涂料组合物 | |
| CN102585634A (zh) | 一种具有仿瓷效果的涂料及其喷涂工艺 | |
| CN103964901A (zh) | 一种抛光砖抛釉砖加工工艺 | |
| CN102674751A (zh) | 一种双组分环氧填缝剂及其制备方法 | |
| CN107699123A (zh) | 仿石涂料及生产方法 | |
| CN105348975A (zh) | 一种振动性热熔标线涂料组合物 | |
| CN106833319B (zh) | 水性聚碳酸酯改性硅溶胶复合涂料及其制备方法 | |
| CN101265391A (zh) | 多彩干粉理石墙艺漆 | |
| CN102731065B (zh) | 隔热瓷砖及其制造方法 | |
| CN101270263A (zh) | 纳米复合干粉理石墙艺漆 | |
| CN106118207A (zh) | 一种新型耐水腻子粉及其制备和使用方法 | |
| CN109898765A (zh) | 绿色环保室内墙面装修方法 | |
| CN109294294A (zh) | 一种艺术雅晶石漆及其制作方法 | |
| CN104877497A (zh) | 低光透明粉末涂料及其制备方法 | |
| JP5072473B2 (ja) | 壁面構造体 | |
| CN106830879A (zh) | 一种高强度防滑砖的砖坯及其制备方法和所制备的防滑砖 | |
| CN107268927B (zh) | 一种软体石材 | |
| US7812071B2 (en) | Decorative floor and deck finish and method for creating and applying such a finish | |
| JP2893045B2 (ja) | 複数の塗材およびこれらを用いて得られる被膜 | |
| CN109096800A (zh) | 一种利用光纤预制棒废料粉末制备的环保型内墙涂料 | |
| CN106830688A (zh) | 一种红釉浆及其制备方法和应用 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |