CN109608967A - Electrophoresis ground decorative protection water-borne acrylic coatings and preparation method thereof - Google Patents

Electrophoresis ground decorative protection water-borne acrylic coatings and preparation method thereof Download PDF

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Publication number
CN109608967A
CN109608967A CN201811558649.XA CN201811558649A CN109608967A CN 109608967 A CN109608967 A CN 109608967A CN 201811558649 A CN201811558649 A CN 201811558649A CN 109608967 A CN109608967 A CN 109608967A
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China
Prior art keywords
parts
water
agent
preparation
borne acrylic
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Pending
Application number
CN201811558649.XA
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Chinese (zh)
Inventor
王伟东
史旭平
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Jiangsu Sifang Vtera Technology Co Ltd
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Jiangsu Sifang Vtera Technology Co Ltd
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Priority to CN201811558649.XA priority Critical patent/CN109608967A/en
Publication of CN109608967A publication Critical patent/CN109608967A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/30Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3045Sulfates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention belongs to paint fields, it is related to decorative protection water-borne acrylic coatings of a kind of electrophoresis ground and preparation method thereof, it is made of following raw material according to mass fraction: 45 ~ 55 parts of water-based acrylic resin, 11 ~ 25 parts of aqueous aliphatic polyurethane rouge, 20 ~ 35 parts of distilled water, 10 ~ 15 parts of rutile type titanium white, 8 ~ 12 parts of ultra-fine barium sulfate powder, 1 ~ 2 part of hydroxypropyl methyl cellulose, 0.5 ~ 2 part of dispersing agent, 0.5 ~ 1 part of thickener, 0.5 ~ 1 part of coalescing aid, 1, 0.5 ~ 1 part of 2- propylene glycol, 0.1 ~ 0.5 part of AMP-95 multifunction amine auxiliary agent, 0.1 ~ 0.2 part of defomaing agent, 0.1 ~ 0.2 part of preservative, further include can neutralizer it is appropriate.Electrophoresis ground provided by the invention decorative protection water-borne acrylic coatings and preparation method thereof, solve the problems, such as that the high VOC emission of paint currently used in the market is not up to standard, and response national green development is called, and promote environment-friendly products market portion.

Description

Electrophoresis ground decorative protection water-borne acrylic coatings and preparation method thereof
Technical field
The invention belongs to paint field, it is related to a kind of decorative protection water-borne acrylic coatings of electrophoresis ground and its system Preparation Method.
Background technique
Applied to the coating on electric vehicle, motorcycle electrophoresis plastics appearance member, the high VOC of oiliness is largely used currently on the market Product is unfavorable for environmental requirement.
Summary of the invention
The purpose of the present invention is to propose to a kind of electrophoresis grounds to protect water-borne acrylic coatings and preparation method thereof with decorative, Meet aqueous, environmental protective product requirement, VOC content of material reaches aqueous paint vehicle standard, solves paint currently used in the market High VOC emission problem.
To achieve the above object, the technical solution of the present invention is as follows:
The decorative protection water-borne acrylic coatings of electrophoresis ground, are made of following raw material according to mass fraction: water soluble acrylic acid 45 ~ 55 parts of resin, 20 ~ 35 parts of distilled water, 10 ~ 15 parts of rutile type titanium white, surpasses 11 ~ 25 parts of aqueous aliphatic polyurethane rouge Thin 8 ~ 12 parts of blanc fixe, 1 ~ 2 part of hydroxypropyl methyl cellulose, 0.5 ~ 2 part of dispersing agent, 0.5 ~ 1 part of thickener, coalescing aid 0.5 ~ 1 part, 0.5 ~ 1 part of 1,2- propylene glycol, 0.1 ~ 0.5 part of AMP-95 multifunction amine auxiliary agent, 0.1 ~ 0.2 part of defomaing agent, preservative 0.1 ~ 0.2 part, further include can neutralizer it is appropriate.
The preparation method of the decorative protection water-borne acrylic coatings of the electrophoresis ground, comprising the following steps: aqueous acrylamide Acid resin, aqueous aliphatic polyurethane rouge, distilled water, rutile type titanium white, ultra-fine barium sulfate powder, hydroxypropyl methyl fiber Element, dispersing agent, thickener, coalescing aid, 1,2- propylene glycol, AMP-95 multifunction amine auxiliary agent, defomaing agent, preservative are proportionally It sequentially adds in high speed disperser, with 800 ~ 1200rpm of revolving speed stirring 5 ~ 15 minutes, obtains mixed emulsion;In stirring It is middle that appropriate neutralizer is added, the pH value of mixed emulsion is adjusted, pH value is in 7.5 ~ 8.
Electrophoresis ground provided by the invention decorative protection water-borne acrylic coatings and preparation method thereof, solve at present The high VOC emission of the paint used in the market problem not up to standard, response national green development are called, and environment-friendly products city is promoted Field portion.
Specific embodiment
Technical characteristic of the invention is further illustrated combined with specific embodiments below:
Embodiment 1
The decorative protection water-borne acrylic coatings of electrophoresis ground, are made of following raw material according to mass fraction: water soluble acrylic acid 48 parts of resin, 15 parts of aqueous aliphatic polyurethane rouge, 28 parts of distilled water, 13 parts of rutile type titanium white, ultra-fine barium sulfate powder 10 Part, 2 parts of hydroxypropyl methyl cellulose, 2 parts of dispersing agent, 1 part of thickener, 0.8 part of coalescing aid, 0.5 part of 1,2- propylene glycol, 0.1 part of AMP-95 multifunction amine auxiliary agent, 0.2 part of defomaing agent, 0.2 part of preservative, further include can neutralizer it is appropriate.
The preparation method of the decorative protection water-borne acrylic coatings of the electrophoresis ground, comprising the following steps: aqueous acrylamide Acid resin, aqueous aliphatic polyurethane rouge, distilled water, rutile type titanium white, ultra-fine barium sulfate powder, hydroxypropyl methyl fiber Element, dispersing agent, thickener, coalescing aid, 1,2- propylene glycol, AMP-95 multifunction amine auxiliary agent, defomaing agent, preservative are proportionally It sequentially adds in high speed disperser, with 800 ~ 1200rpm of revolving speed stirring 5 ~ 15 minutes, obtains mixed emulsion;In stirring It is middle that appropriate neutralizer is added, the pH value of mixed emulsion is adjusted, pH value is in 7.5 ~ 8.
Embodiment 2
The decorative protection water-borne acrylic coatings of electrophoresis ground, are made of following raw material according to mass fraction: water soluble acrylic acid 45 ~ 55 parts of resin, 25 parts of aqueous aliphatic polyurethane rouge, 20 parts of distilled water, 105 parts of rutile type titanium white, ultra-fine barium sulfate 12 parts of powder, 1 part of hydroxypropyl methyl cellulose, 2 parts of dispersing agent, 1 part of thickener, 1 part of coalescing aid, 1 part of 1,2- propylene glycol, 0.1 part of AMP-95 multifunction amine auxiliary agent, 0.2 part of defomaing agent, 0.2 part of preservative, further include can neutralizer it is appropriate.
The preparation method of the decorative protection water-borne acrylic coatings of the electrophoresis ground, comprising the following steps: aqueous acrylamide Acid resin, aqueous aliphatic polyurethane rouge, distilled water, rutile type titanium white, ultra-fine barium sulfate powder, hydroxypropyl methyl fiber Element, dispersing agent, thickener, coalescing aid, 1,2- propylene glycol, AMP-95 multifunction amine auxiliary agent, defomaing agent, preservative are proportionally It sequentially adds in high speed disperser, with 800 ~ 1200rpm of revolving speed stirring 5 ~ 15 minutes, obtains mixed emulsion;In stirring It is middle that appropriate neutralizer is added, the pH value of mixed emulsion is adjusted, pH value is in 7.5 ~ 8.
Embodiment 3
The decorative protection water-borne acrylic coatings of electrophoresis ground, are made of following raw material according to mass fraction: water soluble acrylic acid 45 parts of resin, 11 parts of aqueous aliphatic polyurethane rouge, 35 parts of distilled water, 10 parts of rutile type titanium white, ultra-fine barium sulfate powder 10 Part, 2 parts of hydroxypropyl methyl cellulose, 1 part of dispersing agent, 0.6 part of thickener, 0.7 part of coalescing aid, 0.8 part of 1,2- propylene glycol, 0.4 part of AMP-95 multifunction amine auxiliary agent, 0.1 part of defomaing agent, 0.2 part of preservative, further include can neutralizer it is appropriate.
The preparation method of the decorative protection water-borne acrylic coatings of the electrophoresis ground, comprising the following steps: aqueous acrylamide Acid resin, aqueous aliphatic polyurethane rouge, distilled water, rutile type titanium white, ultra-fine barium sulfate powder, hydroxypropyl methyl fiber Element, dispersing agent, thickener, coalescing aid, 1,2- propylene glycol, AMP-95 multifunction amine auxiliary agent, defomaing agent, preservative are proportionally It sequentially adds in high speed disperser, with 800 ~ 1200rpm of revolving speed stirring 5 ~ 15 minutes, obtains mixed emulsion;In stirring It is middle that appropriate neutralizer is added, the pH value of mixed emulsion is adjusted, pH value is in 7.5 ~ 8.
The above description is merely a specific embodiment, but scope of protection of the present invention is not limited thereto, any The change or replacement expected without creative work, should be covered by the protection scope of the present invention.Therefore, of the invention Protection scope should be determined by the scope of protection defined in the claims.

Claims (2)

1. the decorative protection water-borne acrylic coatings of electrophoresis ground, which is characterized in that by following raw material according to mass parts numeral system At: 45 ~ 55 parts of water-based acrylic resin, 11 ~ 25 parts of aqueous aliphatic polyurethane rouge, 20 ~ 35 parts of distilled water, rutile titanium dioxide 10 ~ 15 parts of powder, 8 ~ 12 parts of ultra-fine barium sulfate powder, 1 ~ 2 part of hydroxypropyl methyl cellulose, 0.5 ~ 2 part of dispersing agent, thickener 0.5 ~ 1 part, 0.5 ~ 1 part of coalescing aid, 0.5 ~ 1 part of 1,2- propylene glycol, 0.1 ~ 0.5 part of AMP-95 multifunction amine auxiliary agent, defomaing agent 0.1 ~ 0.2 part, 0.1 ~ 0.2 part of preservative, further include can neutralizer it is appropriate.
2. the electrophoresis ground according to claim 1 preparation method of decorative protection water-borne acrylic coatings, feature It is, comprising the following steps: water-based acrylic resin, distilled water, rutile type titanium white, surpasses aqueous aliphatic polyurethane rouge Thin blanc fixe, hydroxypropyl methyl cellulose, dispersing agent, thickener, coalescing aid, 1,2- propylene glycol, AMP-95 multifunction amine Auxiliary agent, defomaing agent, preservative proportionally sequentially add in high speed disperser, stir 5 ~ 15 points with 800 ~ 1200rpm of revolving speed Clock obtains mixed emulsion;Appropriate neutralizer is added in stirring, adjusts the pH value of mixed emulsion, pH value is in 7.5 ~ 8.
CN201811558649.XA 2018-12-19 2018-12-19 Electrophoresis ground decorative protection water-borne acrylic coatings and preparation method thereof Pending CN109608967A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811558649.XA CN109608967A (en) 2018-12-19 2018-12-19 Electrophoresis ground decorative protection water-borne acrylic coatings and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201811558649.XA CN109608967A (en) 2018-12-19 2018-12-19 Electrophoresis ground decorative protection water-borne acrylic coatings and preparation method thereof

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Publication Number Publication Date
CN109608967A true CN109608967A (en) 2019-04-12

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1796471A (en) * 2004-12-28 2006-07-05 日本油漆株式会社 Pigment dispersion and coating
CN101747818A (en) * 2009-11-27 2010-06-23 广州擎天实业有限公司 Water-based paint for quick-drying alcohol-resistance plastics and preparation method thereof
WO2012137864A1 (en) * 2011-04-06 2012-10-11 関西ペイント株式会社 Method for forming multi-layered coating film
CN105462466A (en) * 2014-09-26 2016-04-06 立邦涂料(中国)有限公司 High-pinhole limit aqueous coating composition

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1796471A (en) * 2004-12-28 2006-07-05 日本油漆株式会社 Pigment dispersion and coating
CN101747818A (en) * 2009-11-27 2010-06-23 广州擎天实业有限公司 Water-based paint for quick-drying alcohol-resistance plastics and preparation method thereof
WO2012137864A1 (en) * 2011-04-06 2012-10-11 関西ペイント株式会社 Method for forming multi-layered coating film
CN105462466A (en) * 2014-09-26 2016-04-06 立邦涂料(中国)有限公司 High-pinhole limit aqueous coating composition

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Application publication date: 20190412