CN109608967A - Electrophoresis ground decorative protection water-borne acrylic coatings and preparation method thereof - Google Patents
Electrophoresis ground decorative protection water-borne acrylic coatings and preparation method thereof Download PDFInfo
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- CN109608967A CN109608967A CN201811558649.XA CN201811558649A CN109608967A CN 109608967 A CN109608967 A CN 109608967A CN 201811558649 A CN201811558649 A CN 201811558649A CN 109608967 A CN109608967 A CN 109608967A
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- borne acrylic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention belongs to paint fields, it is related to decorative protection water-borne acrylic coatings of a kind of electrophoresis ground and preparation method thereof, it is made of following raw material according to mass fraction: 45 ~ 55 parts of water-based acrylic resin, 11 ~ 25 parts of aqueous aliphatic polyurethane rouge, 20 ~ 35 parts of distilled water, 10 ~ 15 parts of rutile type titanium white, 8 ~ 12 parts of ultra-fine barium sulfate powder, 1 ~ 2 part of hydroxypropyl methyl cellulose, 0.5 ~ 2 part of dispersing agent, 0.5 ~ 1 part of thickener, 0.5 ~ 1 part of coalescing aid, 1, 0.5 ~ 1 part of 2- propylene glycol, 0.1 ~ 0.5 part of AMP-95 multifunction amine auxiliary agent, 0.1 ~ 0.2 part of defomaing agent, 0.1 ~ 0.2 part of preservative, further include can neutralizer it is appropriate.Electrophoresis ground provided by the invention decorative protection water-borne acrylic coatings and preparation method thereof, solve the problems, such as that the high VOC emission of paint currently used in the market is not up to standard, and response national green development is called, and promote environment-friendly products market portion.
Description
Technical field
The invention belongs to paint field, it is related to a kind of decorative protection water-borne acrylic coatings of electrophoresis ground and its system
Preparation Method.
Background technique
Applied to the coating on electric vehicle, motorcycle electrophoresis plastics appearance member, the high VOC of oiliness is largely used currently on the market
Product is unfavorable for environmental requirement.
Summary of the invention
The purpose of the present invention is to propose to a kind of electrophoresis grounds to protect water-borne acrylic coatings and preparation method thereof with decorative,
Meet aqueous, environmental protective product requirement, VOC content of material reaches aqueous paint vehicle standard, solves paint currently used in the market
High VOC emission problem.
To achieve the above object, the technical solution of the present invention is as follows:
The decorative protection water-borne acrylic coatings of electrophoresis ground, are made of following raw material according to mass fraction: water soluble acrylic acid
45 ~ 55 parts of resin, 20 ~ 35 parts of distilled water, 10 ~ 15 parts of rutile type titanium white, surpasses 11 ~ 25 parts of aqueous aliphatic polyurethane rouge
Thin 8 ~ 12 parts of blanc fixe, 1 ~ 2 part of hydroxypropyl methyl cellulose, 0.5 ~ 2 part of dispersing agent, 0.5 ~ 1 part of thickener, coalescing aid
0.5 ~ 1 part, 0.5 ~ 1 part of 1,2- propylene glycol, 0.1 ~ 0.5 part of AMP-95 multifunction amine auxiliary agent, 0.1 ~ 0.2 part of defomaing agent, preservative
0.1 ~ 0.2 part, further include can neutralizer it is appropriate.
The preparation method of the decorative protection water-borne acrylic coatings of the electrophoresis ground, comprising the following steps: aqueous acrylamide
Acid resin, aqueous aliphatic polyurethane rouge, distilled water, rutile type titanium white, ultra-fine barium sulfate powder, hydroxypropyl methyl fiber
Element, dispersing agent, thickener, coalescing aid, 1,2- propylene glycol, AMP-95 multifunction amine auxiliary agent, defomaing agent, preservative are proportionally
It sequentially adds in high speed disperser, with 800 ~ 1200rpm of revolving speed stirring 5 ~ 15 minutes, obtains mixed emulsion;In stirring
It is middle that appropriate neutralizer is added, the pH value of mixed emulsion is adjusted, pH value is in 7.5 ~ 8.
Electrophoresis ground provided by the invention decorative protection water-borne acrylic coatings and preparation method thereof, solve at present
The high VOC emission of the paint used in the market problem not up to standard, response national green development are called, and environment-friendly products city is promoted
Field portion.
Specific embodiment
Technical characteristic of the invention is further illustrated combined with specific embodiments below:
Embodiment 1
The decorative protection water-borne acrylic coatings of electrophoresis ground, are made of following raw material according to mass fraction: water soluble acrylic acid
48 parts of resin, 15 parts of aqueous aliphatic polyurethane rouge, 28 parts of distilled water, 13 parts of rutile type titanium white, ultra-fine barium sulfate powder 10
Part, 2 parts of hydroxypropyl methyl cellulose, 2 parts of dispersing agent, 1 part of thickener, 0.8 part of coalescing aid, 0.5 part of 1,2- propylene glycol,
0.1 part of AMP-95 multifunction amine auxiliary agent, 0.2 part of defomaing agent, 0.2 part of preservative, further include can neutralizer it is appropriate.
The preparation method of the decorative protection water-borne acrylic coatings of the electrophoresis ground, comprising the following steps: aqueous acrylamide
Acid resin, aqueous aliphatic polyurethane rouge, distilled water, rutile type titanium white, ultra-fine barium sulfate powder, hydroxypropyl methyl fiber
Element, dispersing agent, thickener, coalescing aid, 1,2- propylene glycol, AMP-95 multifunction amine auxiliary agent, defomaing agent, preservative are proportionally
It sequentially adds in high speed disperser, with 800 ~ 1200rpm of revolving speed stirring 5 ~ 15 minutes, obtains mixed emulsion;In stirring
It is middle that appropriate neutralizer is added, the pH value of mixed emulsion is adjusted, pH value is in 7.5 ~ 8.
Embodiment 2
The decorative protection water-borne acrylic coatings of electrophoresis ground, are made of following raw material according to mass fraction: water soluble acrylic acid
45 ~ 55 parts of resin, 25 parts of aqueous aliphatic polyurethane rouge, 20 parts of distilled water, 105 parts of rutile type titanium white, ultra-fine barium sulfate
12 parts of powder, 1 part of hydroxypropyl methyl cellulose, 2 parts of dispersing agent, 1 part of thickener, 1 part of coalescing aid, 1 part of 1,2- propylene glycol,
0.1 part of AMP-95 multifunction amine auxiliary agent, 0.2 part of defomaing agent, 0.2 part of preservative, further include can neutralizer it is appropriate.
The preparation method of the decorative protection water-borne acrylic coatings of the electrophoresis ground, comprising the following steps: aqueous acrylamide
Acid resin, aqueous aliphatic polyurethane rouge, distilled water, rutile type titanium white, ultra-fine barium sulfate powder, hydroxypropyl methyl fiber
Element, dispersing agent, thickener, coalescing aid, 1,2- propylene glycol, AMP-95 multifunction amine auxiliary agent, defomaing agent, preservative are proportionally
It sequentially adds in high speed disperser, with 800 ~ 1200rpm of revolving speed stirring 5 ~ 15 minutes, obtains mixed emulsion;In stirring
It is middle that appropriate neutralizer is added, the pH value of mixed emulsion is adjusted, pH value is in 7.5 ~ 8.
Embodiment 3
The decorative protection water-borne acrylic coatings of electrophoresis ground, are made of following raw material according to mass fraction: water soluble acrylic acid
45 parts of resin, 11 parts of aqueous aliphatic polyurethane rouge, 35 parts of distilled water, 10 parts of rutile type titanium white, ultra-fine barium sulfate powder 10
Part, 2 parts of hydroxypropyl methyl cellulose, 1 part of dispersing agent, 0.6 part of thickener, 0.7 part of coalescing aid, 0.8 part of 1,2- propylene glycol,
0.4 part of AMP-95 multifunction amine auxiliary agent, 0.1 part of defomaing agent, 0.2 part of preservative, further include can neutralizer it is appropriate.
The preparation method of the decorative protection water-borne acrylic coatings of the electrophoresis ground, comprising the following steps: aqueous acrylamide
Acid resin, aqueous aliphatic polyurethane rouge, distilled water, rutile type titanium white, ultra-fine barium sulfate powder, hydroxypropyl methyl fiber
Element, dispersing agent, thickener, coalescing aid, 1,2- propylene glycol, AMP-95 multifunction amine auxiliary agent, defomaing agent, preservative are proportionally
It sequentially adds in high speed disperser, with 800 ~ 1200rpm of revolving speed stirring 5 ~ 15 minutes, obtains mixed emulsion;In stirring
It is middle that appropriate neutralizer is added, the pH value of mixed emulsion is adjusted, pH value is in 7.5 ~ 8.
The above description is merely a specific embodiment, but scope of protection of the present invention is not limited thereto, any
The change or replacement expected without creative work, should be covered by the protection scope of the present invention.Therefore, of the invention
Protection scope should be determined by the scope of protection defined in the claims.
Claims (2)
1. the decorative protection water-borne acrylic coatings of electrophoresis ground, which is characterized in that by following raw material according to mass parts numeral system
At: 45 ~ 55 parts of water-based acrylic resin, 11 ~ 25 parts of aqueous aliphatic polyurethane rouge, 20 ~ 35 parts of distilled water, rutile titanium dioxide
10 ~ 15 parts of powder, 8 ~ 12 parts of ultra-fine barium sulfate powder, 1 ~ 2 part of hydroxypropyl methyl cellulose, 0.5 ~ 2 part of dispersing agent, thickener 0.5 ~
1 part, 0.5 ~ 1 part of coalescing aid, 0.5 ~ 1 part of 1,2- propylene glycol, 0.1 ~ 0.5 part of AMP-95 multifunction amine auxiliary agent, defomaing agent 0.1 ~
0.2 part, 0.1 ~ 0.2 part of preservative, further include can neutralizer it is appropriate.
2. the electrophoresis ground according to claim 1 preparation method of decorative protection water-borne acrylic coatings, feature
It is, comprising the following steps: water-based acrylic resin, distilled water, rutile type titanium white, surpasses aqueous aliphatic polyurethane rouge
Thin blanc fixe, hydroxypropyl methyl cellulose, dispersing agent, thickener, coalescing aid, 1,2- propylene glycol, AMP-95 multifunction amine
Auxiliary agent, defomaing agent, preservative proportionally sequentially add in high speed disperser, stir 5 ~ 15 points with 800 ~ 1200rpm of revolving speed
Clock obtains mixed emulsion;Appropriate neutralizer is added in stirring, adjusts the pH value of mixed emulsion, pH value is in 7.5 ~ 8.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201811558649.XA CN109608967A (en) | 2018-12-19 | 2018-12-19 | Electrophoresis ground decorative protection water-borne acrylic coatings and preparation method thereof |
Applications Claiming Priority (1)
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CN201811558649.XA CN109608967A (en) | 2018-12-19 | 2018-12-19 | Electrophoresis ground decorative protection water-borne acrylic coatings and preparation method thereof |
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CN109608967A true CN109608967A (en) | 2019-04-12 |
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CN201811558649.XA Pending CN109608967A (en) | 2018-12-19 | 2018-12-19 | Electrophoresis ground decorative protection water-borne acrylic coatings and preparation method thereof |
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1796471A (en) * | 2004-12-28 | 2006-07-05 | 日本油漆株式会社 | Pigment dispersion and coating |
CN101747818A (en) * | 2009-11-27 | 2010-06-23 | 广州擎天实业有限公司 | Water-based paint for quick-drying alcohol-resistance plastics and preparation method thereof |
WO2012137864A1 (en) * | 2011-04-06 | 2012-10-11 | 関西ペイント株式会社 | Method for forming multi-layered coating film |
CN105462466A (en) * | 2014-09-26 | 2016-04-06 | 立邦涂料(中国)有限公司 | High-pinhole limit aqueous coating composition |
-
2018
- 2018-12-19 CN CN201811558649.XA patent/CN109608967A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1796471A (en) * | 2004-12-28 | 2006-07-05 | 日本油漆株式会社 | Pigment dispersion and coating |
CN101747818A (en) * | 2009-11-27 | 2010-06-23 | 广州擎天实业有限公司 | Water-based paint for quick-drying alcohol-resistance plastics and preparation method thereof |
WO2012137864A1 (en) * | 2011-04-06 | 2012-10-11 | 関西ペイント株式会社 | Method for forming multi-layered coating film |
CN105462466A (en) * | 2014-09-26 | 2016-04-06 | 立邦涂料(中国)有限公司 | High-pinhole limit aqueous coating composition |
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Application publication date: 20190412 |