CN107141914A - A kind of container water-based metal heavy antisepsis acrylic acid top-coat and preparation method thereof - Google Patents
A kind of container water-based metal heavy antisepsis acrylic acid top-coat and preparation method thereof Download PDFInfo
- Publication number
- CN107141914A CN107141914A CN201710340879.8A CN201710340879A CN107141914A CN 107141914 A CN107141914 A CN 107141914A CN 201710340879 A CN201710340879 A CN 201710340879A CN 107141914 A CN107141914 A CN 107141914A
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- parts
- water
- coat
- based metal
- acrylic acid
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2265—Oxides; Hydroxides of metals of iron
- C08K2003/2272—Ferric oxide (Fe2O3)
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to container water-based metal heavy antisepsis acrylic acid top-coat, it is made up of following raw material：15 20 parts of water-borne Self-Crosslinked Acrylic emulsion；10 20 parts of filling material；0.1 0.5 parts of wetting dispersing agent；40 60 parts of deionized water；0.1 0.5 parts of adhesion promoter；5 10 parts of coalescents；15 parts of thickener.The heavy-duty antiseptic paint has good workability, and strong to metal adhesive power, excitant is extremely low, VOC free discharge, environmentally friendly.
Description
Technical field
The present invention relates to anticorrosive paint field, and in particular to a kind of container with watersoluble metal heavy acrylic acid top-coat and its
Preparation method.
Background technology
With the development of modern society, the raising of human living standard, the progressively awakening of energy-conserving and environment-protective consciousness, and high score
The high speed development of scarabaeidae is also more and more stricter for the requirement of environmental protection.
With Guangdong Province's provincial standard《Container manufacture Volatile organic emissions standard》Formulation, and the national tax
Department imposes the consumption tax to the painting of high VOC content；Comprehensive Water-borne modification of coating container is more and more urgent.
It is contemplated that in following very long-term, development environment friendly water paint will turn into China's coating research field
Emphasis, focus, to comply with research, realizing that I takes charge of comprehensive update and the environmental protection mesh of coating container
Mark, therefore intend carrying out the research and development of container water-based metal heavy antisepsis acrylic acid top-coat.
Container plant requirement is not done in production line rhythm of production, production technology under the conditions of big variation, the construction that can have had
Performance, while being not less than the performance of oiliness acrylic acid top-coat again.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of container water-based metal heavy antisepsis acrylic acid top-coat.Should
Anticorrosive paint has excellent workability, suitable viscosity, sagging performance, rapid draing ability.Paint film mechanical performance；It is excellent
Elegant adhesive force, pliability, impact resistance and good decay resistance.What is solved is the morning under the conditions of case factory production line
Phase water resistance, long-term hydrolytic resistance, initial hardness, drying varniss performance and various film defects.The consumption of coalescents is reduced,
VOC content is reduced, reaches in the case of suitable gloss and hardness, reduces film-forming temperature, it is ensured that the construction under the conditions of winter low temperature
Performance.
The technical problems to be solved by the invention are achieved by the following technical programs：
A kind of container water-based metal heavy antisepsis acrylic acid top-coat, is made up of following parts by weight raw material：
15-20 parts of water-borne Self-Crosslinked Acrylic emulsion；
10-20 parts of filling material；
0.1-0.5 parts of wetting dispersing agent；
40-60 parts of deionized water；
0.1-0.5 parts of adhesion promoter；
5-10 parts of coalescents；
1-5 parts of thickener.
Further, described filling material includes titanium dioxide, micaceous iron oxide, at least one of superfine talcum powder.
Further, described coalescents include propandiol butyl ether, at least one of propylene glycol methyl ether acetate.
Further, described adhesion promoter is organosilan.Further, described organosilan is road health
Peaceful Z6040.
Further, described wetting dispersing agent is sodium dioctyl sulfosuccinate.
A kind of preparation method of described container water-based metal heavy antisepsis acrylic acid top-coat：
（1）Corresponding raw material is weighed by the formula；
（2）Water-borne Self-Crosslinked Acrylic emulsion is added in agitator, wetting dispersing agent is added and stirs 10 ~ 20min；
（3）Color stuffing is added in agitator, 30 ~ 50min is quickly stirred, it is ensured that be well mixed；
（4）Thickener, coalescents, adhesion promoter are added in filtrate, stirring 20min obtains finished product.
Beneficial effect：
The anticorrosive paint has excellent workability, suitable viscosity, sagging performance, rapid draing ability.Paint film machinery
Performance；Outstanding adhesive force, pliability, impact resistance and good decay resistance.What is solved is case factory production lines
Early stage water resistance, long-term hydrolytic resistance, initial hardness, drying varniss performance and various film defects under part.Film forming is reduced to help
The consumption of agent, reduces VOC content, reaches in the case of suitable gloss and hardness, film-forming temperature is reduced, in the winter time under cryogenic conditions
Also preferable workability is possessed.
Embodiment
With reference to embodiment, the present invention will be described in detail, and embodiment is only the preferred embodiment of the present invention,
It is not limitation of the invention.
Organosilan uses DOW CORNING Z6040, and remaining component is conventional commercial product.
Embodiment 1
A kind of container water-based metal heavy antisepsis acrylic acid top-coat, is made up of following parts by weight raw material：
15 parts of water-borne Self-Crosslinked Acrylic emulsion；
10 parts of titanium dioxide, 10 parts of micaceous iron oxide；
0.2 part of sodium dioctyl sulfosuccinate；
50 parts of deionized water；
0.2 part of organosilan；
5 parts of propandiol butyl ether, 5 parts of propylene glycol methyl ether acetate；
1 part of thickener.
The preparation method of described container water-based metal heavy antisepsis acrylic acid top-coat：
（1）Corresponding raw material is weighed by the formula；
（2）Water-borne Self-Crosslinked Acrylic emulsion is added in agitator, wetting dispersing agent is added and stirs 10 ~ 20min；
（3）Color stuffing is added in agitator, 30 ~ 50min is quickly stirred, it is ensured that be well mixed；
（4）Thickener, coalescents, adhesion promoter are added in filtrate, stirring 20min obtains finished product.
Embodiment 2
A kind of container water-based metal heavy antisepsis acrylic acid top-coat, is made up of following parts by weight raw material：
20 parts of water-borne Self-Crosslinked Acrylic emulsion；
10 parts of titanium dioxide, 5 parts of superfine talcum powder；
0.5 part of sodium dioctyl sulfosuccinate；
60 parts of deionized water；
0.1 part of organosilan；
5 parts of propylene glycol methyl ether acetate；
5 parts of thickener.
The preparation method of described container water-based metal heavy antisepsis acrylic acid top-coat：
（1）Corresponding raw material is weighed by the formula；
（2）Water-borne Self-Crosslinked Acrylic emulsion is added in agitator, wetting dispersing agent is added and stirs 10 ~ 20min；
（3）Color stuffing is added in agitator, 30 ~ 50min is quickly stirred, it is ensured that be well mixed；
（4）Thickener, coalescents, adhesion promoter are added in filtrate, stirring 20min obtains finished product.
Embodiment 3
A kind of container water-based metal heavy antisepsis acrylic acid top-coat, is made up of following parts by weight raw material：
18 parts of water-borne Self-Crosslinked Acrylic emulsion；
4 parts of titanium dioxide, 3 parts of micaceous iron oxide, 3 parts of superfine talcum powder；
0.1 part of sodium dioctyl sulfosuccinate；
40 parts of deionized water；
0.2 part of organosilan；
10 parts of propandiol butyl ether；
3 parts of thickener.
The preparation method of described container water-based metal heavy antisepsis acrylic acid top-coat：
（1）Corresponding raw material is weighed by the formula；
（2）Water-borne Self-Crosslinked Acrylic emulsion is added in agitator, wetting dispersing agent is added and stirs 10 ~ 20min；
（3）Color stuffing is added in agitator, 30 ~ 50min is quickly stirred, it is ensured that be well mixed；
（4）Thickener, coalescents, adhesion promoter are added in filtrate, stirring 20min obtains finished product.
Following test is carried out to the finish paint of embodiment 1,2,3：
Glossiness：By national standard《GB/T1743-89》Test glossiness.
Rate of drying：By national standard《GB/T 1728–1979》Cotton pellet method is blown to be tested.
Hardness：Press《The hardness of film pencil determination methods of GB6739-86》Tested.
Smell：Nose is heard.
Adhesive force：By national standard《GB9286-1988》By carrying out cross-cut methods test to film coated surface.
Most film-forming temperature tests.
Claims (6)
1. a kind of container water-based metal heavy antisepsis acrylic acid top-coat, it is characterised in that described container water-based metal
Heavy antisepsis epoxy finish is made up of following parts by weight raw material：
15-20 parts of water-borne Self-Crosslinked Acrylic emulsion；
10-20 parts of filling material；
0.1-0.5 parts of wetting dispersing agent；
40-60 parts of deionized water；
0.1-0.5 parts of adhesion promoter；
5-10 parts of coalescents；
1-5 parts of thickener.
2. container according to claim 1 water-based metal heavy antisepsis acrylic acid top-coat, it is characterised in that described fills out
Pigment includes titanium dioxide, micaceous iron oxide, at least one of superfine talcum powder.
3. container according to claim 1 water-based metal heavy antisepsis acrylic acid top-coat, it is characterised in that it is described into
Film auxiliary agent includes propandiol butyl ether, at least one of propylene glycol methyl ether acetate.
4. container according to claim 1 water-based metal heavy antisepsis acrylic acid top-coat, it is characterised in that described is attached
Adhesion promoter is organosilan.
5. container according to claim 1 water-based metal heavy antisepsis acrylic acid top-coat, it is characterised in that described profit
Hygroscopic water powder is sodium dioctyl sulfosuccinate.
6. the preparation method of the container water-based metal heavy antisepsis acrylic acid top-coat according to claim 1-5, its feature
It is, described preparation method is：
（1）Corresponding raw material is weighed by the formula；
（2）Water-borne Self-Crosslinked Acrylic emulsion is added in agitator, wetting dispersing agent is added and stirs 10 ~ 20min；
（3）Color stuffing is added in agitator, 30 ~ 50min is quickly stirred, it is ensured that be well mixed；
（4）Thickener, coalescents, adhesion promoter are added in filtrate, stirring 20min obtains finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710340879.8A CN107141914A (en) | 2017-05-16 | 2017-05-16 | A kind of container water-based metal heavy antisepsis acrylic acid top-coat and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710340879.8A CN107141914A (en) | 2017-05-16 | 2017-05-16 | A kind of container water-based metal heavy antisepsis acrylic acid top-coat and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107141914A true CN107141914A (en) | 2017-09-08 |
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ID=59777277
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710340879.8A Pending CN107141914A (en) | 2017-05-16 | 2017-05-16 | A kind of container water-based metal heavy antisepsis acrylic acid top-coat and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107141914A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109021738A (en) * | 2018-05-31 | 2018-12-18 | 无锡市海轮涂料有限公司 | A kind of weather-proof cross-linking aqueous acrylic acid top-coat |
| CN109880417A (en) * | 2019-01-28 | 2019-06-14 | 河北惠驰装饰材料有限公司 | Watersoluble metal self-drying paint and preparation method thereof |
| CN110358400A (en) * | 2019-07-23 | 2019-10-22 | 上海工程技术大学 | A kind of aqueous quick-drying coil steel coating and preparation method thereof based on monodisperse polyacrylic resin |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101885941A (en) * | 2010-08-20 | 2010-11-17 | 湖南先悦科技有限公司 | Underwater epoxy resin coating and preparation method thereof |
| CN103788787A (en) * | 2013-10-21 | 2014-05-14 | 广州擎天材料科技有限公司 | Single-component water-based natural drying finishing coat for construction crane and preparation method thereof |
| CN106519905A (en) * | 2016-11-21 | 2017-03-22 | 牛宝芬 | Waterborne heavy anticorrosion coating for metal |
-
2017
- 2017-05-16 CN CN201710340879.8A patent/CN107141914A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101885941A (en) * | 2010-08-20 | 2010-11-17 | 湖南先悦科技有限公司 | Underwater epoxy resin coating and preparation method thereof |
| CN103788787A (en) * | 2013-10-21 | 2014-05-14 | 广州擎天材料科技有限公司 | Single-component water-based natural drying finishing coat for construction crane and preparation method thereof |
| CN106519905A (en) * | 2016-11-21 | 2017-03-22 | 牛宝芬 | Waterborne heavy anticorrosion coating for metal |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109021738A (en) * | 2018-05-31 | 2018-12-18 | 无锡市海轮涂料有限公司 | A kind of weather-proof cross-linking aqueous acrylic acid top-coat |
| CN109880417A (en) * | 2019-01-28 | 2019-06-14 | 河北惠驰装饰材料有限公司 | Watersoluble metal self-drying paint and preparation method thereof |
| CN110358400A (en) * | 2019-07-23 | 2019-10-22 | 上海工程技术大学 | A kind of aqueous quick-drying coil steel coating and preparation method thereof based on monodisperse polyacrylic resin |
| CN110358400B (en) * | 2019-07-23 | 2021-04-09 | 上海工程技术大学 | Water-based quick-drying coil steel coating based on monodisperse polyacrylic resin and preparation method thereof |
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Application publication date: 20170908 |