CN107722801A - A kind of water-based heavy antisepsis finish paint and preparation method thereof - Google Patents

A kind of water-based heavy antisepsis finish paint and preparation method thereof Download PDF

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Publication number
CN107722801A
CN107722801A CN201710929152.3A CN201710929152A CN107722801A CN 107722801 A CN107722801 A CN 107722801A CN 201710929152 A CN201710929152 A CN 201710929152A CN 107722801 A CN107722801 A CN 107722801A
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CN
China
Prior art keywords
parts
water
finish paint
based heavy
heavy antisepsis
Prior art date
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Withdrawn
Application number
CN201710929152.3A
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Chinese (zh)
Inventor
魏喜成
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Individual
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Individual
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Priority to CN201710929152.3A priority Critical patent/CN107722801A/en
Publication of CN107722801A publication Critical patent/CN107722801A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/06Unsaturated polyesters having carbon-to-carbon unsaturation
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02Organic and inorganic ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2265Oxides; Hydroxides of metals of iron
    • C08K2003/2272Ferric oxide (Fe2O3)
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/06Ethers; Acetals; Ketals; Ortho-esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/10Esters; Ether-esters
    • C08K5/101Esters; Ether-esters of monocarboxylic acids
    • C08K5/103Esters; Ether-esters of monocarboxylic acids with polyalcohols
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/36Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/41Compounds containing sulfur bound to oxygen
    • C08K5/42Sulfonic acids; Derivatives thereof

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Paints Or Removers (AREA)

Abstract

The present invention relates to paint field, discloses a kind of water-based heavy antisepsis finish paint, is made up of following raw material:15 20 parts of waterborne polyester acrylic resin;10 20 parts of filling material;0.1 0.5 parts of wetting dispersing agent;40 60 parts of deionized water;0.1 0.5 parts of adhesion promoter;5 10 parts of coalescents;15 parts of thickener.The heavy-duty antiseptic paint has good workability, strong to metal adhesive power, and excitant is extremely low, VOC free discharge, environmentally friendly.

Description

A kind of water-based heavy antisepsis finish paint and preparation method thereof
Technical field
The present invention relates to anticorrosive paint field, and in particular to a kind of water-based heavy antisepsis finish paint and preparation method thereof.
Background technology
With the development of modern society, the raising of human living standard, the progressively awakening of energy conservation and environmental awareness, and high score Requirement of the high speed development of scarabaeidae for environmental protection is also more and more stricter.
With Guangdong Province's provincial standard《Container manufacture Volatile organic emissions standard》Formulation, and the national tax Department imposes the consumption tax to the painting of high VOC content;Comprehensive Water-borne modification of coating container is more and more urgent.
It is contemplated that in following very long-term, development environment friendly water paint will turn into China's coating research field Emphasis, focus, to comply with research, realizing that I takes charge of comprehensive update of coating container and green mesh Mark, therefore intend carrying out the research and development of water-based heavy antisepsis finish paint.
Under the conditions of big variation is not done in container plant requirement in production line rhythm of production, production technology, the construction that can have Performance, while it is not less than the performance of oiliness acrylic acid top-coat again.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of water-based heavy antisepsis finish paint.The anticorrosive paint has excellent Workability, suitable viscosity, sagging performance, rapid draing ability.Paint film mechanical performance;Outstanding adhesive force, pliability, Impact resistance and good decay resistance.Solve is early stage water resistance under the conditions of case factory production line, long-term water-fast Xie Xing, initial hardness, drying varniss performance and various film defects.The dosage of coalescents is reduced, VOC content is reduced, reaches In the case of suitable gloss and hardness, film-forming temperature is reduced, ensures the workability under the conditions of winter low temperature.
The technical problems to be solved by the invention are achieved by the following technical programs:
A kind of water-based heavy antisepsis finish paint, is made up of following parts by weight raw material:
Waterborne polyester acrylic resin 15-20 parts;
Filling material 10-20 parts;
Wetting dispersing agent 0.1-0.5 parts;
Deionized water 40-60 parts;
Adhesion promoter 0.1-0.5 parts;
Coalescents 5-10 parts;
Thickener 1-5 parts.
Further, described filling material includes titanium dioxide, micaceous iron oxide, at least one of superfine talcum powder.
Further, described coalescents include propandiol butyl ether, at least one of propylene glycol methyl ether acetate.
Further, described adhesion promoter is organosilan.Further, described organosilan is road health Peaceful Z6040.
Further, described wetting dispersing agent is sodium dioctyl sulfosuccinate.
A kind of preparation method of described water-based heavy antisepsis finish paint:
(1)Corresponding raw material is weighed by the formula;
(2)Waterborne polyester acrylic resin is added in agitator, wetting dispersing agent is added and stirs 10 ~ 20min;
(3)Color stuffing is added in agitator, quickly stirs 30 ~ 50min, is ensured well mixed;
(4)Thickener, coalescents, adhesion promoter are added in filtrate, stirring 20min obtains finished product.
Beneficial effect:
The anticorrosive paint has excellent workability, suitable viscosity, sagging performance, rapid draing ability.Paint film machinery Performance;Outstanding adhesive force, pliability, impact resistance and good decay resistance.What is solved is case factory production lines Early stage water resistance, long-term hydrolytic resistance, initial hardness, drying varniss performance and various film defects under part.Film forming is reduced to help The dosage of agent, VOC content is reduced, in the case of reaching suitable gloss and hardness, film-forming temperature is reduced, in the winter time under cryogenic conditions Also preferable workability is possessed.
Embodiment
With reference to embodiment, the present invention will be described in detail, and embodiment is only the preferred embodiment of the present invention, It is not limitation of the invention.
Organosilan uses DOW CORNING Z6040, and remaining component is conventional commercial product.
Embodiment 1
A kind of water-based heavy antisepsis finish paint, is made up of following parts by weight raw material:
15 parts of waterborne polyester acrylic resin;
10 parts of titanium dioxide, 10 parts of micaceous iron oxide;
0.2 part of sodium dioctyl sulfosuccinate;
50 parts of deionized water;
0.2 part of organosilan;
5 parts of propandiol butyl ether, 5 parts of propylene glycol methyl ether acetate;
1 part of thickener.
The preparation method of described water-based heavy antisepsis finish paint:
(1)Corresponding raw material is weighed by the formula;
(2)Waterborne polyester acrylic resin is added in agitator, wetting dispersing agent is added and stirs 10 ~ 20min;
(3)Color stuffing is added in agitator, quickly stirs 30 ~ 50min, is ensured well mixed;
(4)Thickener, coalescents, adhesion promoter are added in filtrate, stirring 20min obtains finished product.
Embodiment 2
A kind of water-based heavy antisepsis finish paint, is made up of following parts by weight raw material:
20 parts of waterborne polyester acrylic resin;
10 parts of titanium dioxide, 5 parts of superfine talcum powder;
0.5 part of sodium dioctyl sulfosuccinate;
60 parts of deionized water;
0.1 part of organosilan;
5 parts of propylene glycol methyl ether acetate;
5 parts of thickener.
The preparation method of described water-based heavy antisepsis finish paint:
(1)Corresponding raw material is weighed by the formula;
(2)Waterborne polyester acrylic resin is added in agitator, wetting dispersing agent is added and stirs 10 ~ 20min;
(3)Color stuffing is added in agitator, quickly stirs 30 ~ 50min, is ensured well mixed;
(4)Thickener, coalescents, adhesion promoter are added in filtrate, stirring 20min obtains finished product.
Embodiment 3
A kind of water-based heavy antisepsis finish paint, is made up of following parts by weight raw material:
18 parts of waterborne polyester acrylic resin;
4 parts of titanium dioxide, 3 parts of micaceous iron oxide, 3 parts of superfine talcum powder;
0.1 part of sodium dioctyl sulfosuccinate;
40 parts of deionized water;
0.2 part of organosilan;
10 parts of propandiol butyl ether;
3 parts of thickener.
The preparation method of described water-based heavy antisepsis finish paint:
(1)Corresponding raw material is weighed by the formula;
(2)Waterborne polyester acrylic resin is added in agitator, wetting dispersing agent is added and stirs 10 ~ 20min;
(3)Color stuffing is added in agitator, quickly stirs 30 ~ 50min, is ensured well mixed;
(4)Thickener, coalescents, adhesion promoter are added in filtrate, stirring 20min obtains finished product.

Claims (6)

1. a kind of water-based heavy antisepsis finish paint, it is characterised in that described water-based heavy antisepsis finish paint is by following parts by weight raw material group Into:
Waterborne polyester acrylic emulsion 15-20 parts;
Filling material 10-20 parts;
Wetting dispersing agent 0.1-0.5 parts;
Deionized water 40-60 parts;
Adhesion promoter 0.1-0.5 parts;
Coalescents 5-10 parts;
Thickener 1-5 parts.
2. water-based heavy antisepsis finish paint according to claim 1, it is characterised in that described filling material includes titanium dioxide, cloud At least one of female iron oxide, superfine talcum powder.
3. water-based heavy antisepsis finish paint according to claim 1, it is characterised in that described coalescents include propane diols fourth At least one of ether, propylene glycol methyl ether acetate.
4. water-based heavy antisepsis finish paint according to claim 1, it is characterised in that described adhesion promoter is organosilicon Alkane.
5. water-based heavy antisepsis finish paint according to claim 1, it is characterised in that described wetting dispersing agent is dioctyl sulphur Change sodium succinate.
6. the preparation method of the water-based heavy antisepsis finish paint described in a kind of claim 1-5 any one, it is characterised in that described Preparation method is:
(1)Corresponding raw material is weighed by the formula;
(2)Waterborne polyester acrylic resin is added in agitator, wetting dispersing agent is added and stirs 10 ~ 20min;
(3)Color stuffing is added in agitator, quickly stirs 30 ~ 50min, is ensured well mixed;
(4)Thickener, coalescents, adhesion promoter are added in filtrate, stirring 20min obtains finished product.
CN201710929152.3A 2017-10-09 2017-10-09 A kind of water-based heavy antisepsis finish paint and preparation method thereof Withdrawn CN107722801A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710929152.3A CN107722801A (en) 2017-10-09 2017-10-09 A kind of water-based heavy antisepsis finish paint and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710929152.3A CN107722801A (en) 2017-10-09 2017-10-09 A kind of water-based heavy antisepsis finish paint and preparation method thereof

Publications (1)

Publication Number Publication Date
CN107722801A true CN107722801A (en) 2018-02-23

Family

ID=61209739

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710929152.3A Withdrawn CN107722801A (en) 2017-10-09 2017-10-09 A kind of water-based heavy antisepsis finish paint and preparation method thereof

Country Status (1)

Country Link
CN (1) CN107722801A (en)

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Application publication date: 20180223

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