CN103740239B - A kind of PE solid color enamel - Google Patents
A kind of PE solid color enamel Download PDFInfo
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- CN103740239B CN103740239B CN201310740813.XA CN201310740813A CN103740239B CN 103740239 B CN103740239 B CN 103740239B CN 201310740813 A CN201310740813 A CN 201310740813A CN 103740239 B CN103740239 B CN 103740239B
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- solid color
- mill base
- color enamel
- dispersant
- hydroquinone
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Abstract
A kind of PE solid color enamel, according to weight fraction meter, comprise the unsaturated polyester resin of 35 55%, the color slurry of 20 35%, the styrene of 4 8%, the defoamer of 0.5 2%, the levelling agent of 0.5 2%, the anti-settling agent of 0.5 2%, the filler of 10 16%, wherein, described mill base is by the butyl acetate solution comprising 65 80wt% aldehyde ketone resin, dispersant, dimethylbenzene, color powder, the raw material mixed grinding of hydroquinone forms, the butyl acetate solution of 65 80wt% aldehyde ketone resin in described mill base, dispersant, dimethylbenzene, color powder, the weight ratio of hydroquinone is (45 55): (4 6): (12 16): (25 35): (0.1 0.3).Described PE solid color enamel has bright in luster;Using aldehyde ketone prefabricated paste, it is long that mill base stores the time, the safety of improving product;Single thickness can be coated with, and be difficult to that paint disease occurs, production efficiency is greatly improved for Furniture manufacturing.
Description
Technical field
The present invention relates to a kind of coating, particularly relate to a kind of PE solid color enamel.
Background technology
Woodcare paint refers to the resinoid paint on woodwork, has nitrate paint, polyurethane paint, Polyester Paint etc.,
Aqueous and oiliness can be divided into.Gao Guang, semi-matte, dumb light can be divided into by gloss.Along with the raising of people's life,
The development of furniture trend, real color furniture of all kinds, particularly cabinet, bathroom, showcase, children furniture is all subject to
To the favor of people, the consumption of woodcare paint is also in geometric growth.
Wherein, the main film forming matter of nitrate paint is based on nitrocotton, coordinate alkyd resin, modified rosin resin,
The soft or hard resin such as acrylic resin, amino resins collectively constitutes, and belongs to volatility paint, has fast drying, gloss
The feature such as soft, but the problem such as high humidity weather easily whitens, richness is low, hardness is low.
Polyurethane paint, is usually by isocyanate prepolymer (being also low molecule urethane polymer) and contains
Hydroxyl resin two parts form, commonly referred to curing agent component and host component.Polyurethane lacquer is tough, gloss
Plentiful, adhesive force is strong, water proof and wearable, corrosion resistance, but wet foaming, film efflorescence, asks containing TDI etc.
Topic.
Unsaturated polyester varnish, also referred to as PE paints, host, accelerator, initiator three mutually concocts and carry out
Polymerization is built bridge and is reacted and solidify, and its solvent is styrene, participates in reaction and have richness speed good, dry during film forming
Degree is fast, be suitable for the advantages such as industrialization production line balance.
At present, on market, the colored paint majority for the bright-colored of real color furniture is polyurethane colored paint, but poly-ammonia
Ester colored paint single thickness is coated with difficulty.PE paint can be coated with single thickness, but on market, PE paint mostly is white, seldom
There is bright colors, as Chinese patent CN102504627A discloses a kind of unsaturated polyester (UP) based white primer, because of
Production storage for the PE solid color enamel of bright colors is a urgent need to solve the problem.
Summary of the invention
For above-mentioned technical problem, the invention provides a kind of PE solid color enamel.
The PE solid color enamel that the present invention provides, according to weight fraction meter, comprises:
Wherein, described mill base is by comprising the butyl acetate solution of 65-80wt% aldehyde ketone resin, dispersant, diformazan
Benzene, toner, the mixed raw material of hydroquinone become, the acetic acid fourth of 65-80wt% aldehyde ketone resin in described mill base
Ester solution, dispersant, dimethylbenzene, toner, the weight ratio of hydroquinone are (45-55): (4-6): (12-16):
(25-35): (0.1-0.3).
Preferably, described PE solid color enamel, in percentage by weight, comprise:
Wherein, described mill base is by comprising the butyl acetate solution of 65-80wt% aldehyde ketone resin, dispersant, diformazan
Benzene, toner, the mixed raw material of hydroquinone become, the acetic acid fourth of 65-80wt% aldehyde ketone resin in described mill base
Ester solution, dispersant, dimethylbenzene, toner, the weight ratio of hydroquinone are (45-55): (4-6): (12-16):
(25-35): (0.1-0.2).
Preferably, described mill base by the butyl acetate solution of 65-80wt% aldehyde ketone resin, dispersant, dimethylbenzene,
Toner, hydroquinone mixed grinding form.
Preferably, the acetic acid that butyl acetate solution is 70wt% aldehyde ketone resin of described 65-80wt% aldehyde ketone resin
Butyl acetate solution.
Wherein, described defoamer can selected from organic silicon defoamer or acrylate defoamer any one or several
Kind.
Wherein, described levelling agent can selected from polyether polyester modified organic silicon oxygen alkane or acrylic ester type any one
Or it is several.
Wherein, described anti-settling agent can selected from polyamide wax or aerosil any one or a few.
Wherein, described filler can be selected from any one or a few in Pulvis Talci, transparent powder, triple superphosphate.
Preferably, described talcous fineness is 1250 mesh.
Preferably, described filler comprises Pulvis Talci, and in terms of PE solid color enamel weight fraction, described Pulvis Talci is
10-14%。
Preferably, described filler comprises Pulvis Talci and transparent powder, in terms of PE solid color enamel weight fraction, and described cunning
Stone powder is 5-7%, described transparent powder is 5-8%.
Present invention also offers a kind of mill base, described mill base is by the butyl acetate comprising 65-80wt% aldehyde ketone resin
Solution, dispersant, dimethylbenzene, toner, the mixed raw material of hydroquinone become, 65-80wt% in described mill base
The butyl acetate solution of aldehyde ketone resin, dispersant, dimethylbenzene, toner, the weight ratio of hydroquinone are (45-55):
(4-6): (12-16): (25-35): (0.1-0.3).
Preferably, described mill base by comprise the butyl acetate solution of 65-80wt% aldehyde ketone resin, dispersant, two
Toluene, toner, the mixed raw material of hydroquinone become, the acetic acid of 65-80wt% aldehyde ketone resin in described mill base
Butyl acetate solution, dispersant, dimethylbenzene, toner, the weight ratio of hydroquinone are (45-50): (4-6): (14-15):
(25-35): (0.1-0.2).
The PE solid color enamel that the present invention provides has bright in luster, uses aldehyde ketone prefabricated paste, and mill base itself preserves
Time is long, the safety of improving product, can single thickness be coated with, and is difficult to paint disease occur, significantly carries for Furniture manufacturing
High production efficiency.
Detailed description of the invention
The PE solid color enamel that the present invention provides, according to weight fraction meter, comprises:
Wherein, described mill base is by comprising the butyl acetate solution of 65-80wt% aldehyde ketone resin, dispersant, diformazan
Benzene, toner, the raw material mixed grinding of hydroquinone form, the vinegar of 65-80wt% aldehyde ketone resin in described mill base
Acid butyl ester solution, dispersant, dimethylbenzene, toner, the weight ratio of hydroquinone are (45-55): (4-6):
(14-16): (25-35): (0.1-0.3).
Below by specific embodiment, the present invention is carried out detailed and concrete introduction, in order to be better understood from this
Bright, but following example are not limiting as the scope of the invention.
Embodiment 1
PE solid color enamel described in the present embodiment, by weight mark meter, comprise:
Wherein, mill base preparation process is: the butyl acetate solution of 80wt% aldehyde ketone resin, dispersant, dimethylbenzene,
Toner, hydroquinone mix homogeneously, below 80oC grinds and forms, and the butyl acetate of 80wt% aldehyde ketone resin is molten
Liquid, dispersant, dimethylbenzene, toner, the weight ratio of hydroquinone are 50:5:14.9:30:0.1.
Embodiment 2
PE solid color enamel described in the present embodiment, by weight mark meter, comprise:
Wherein, mill base preparation process is: the butyl acetate solution of 65wt% aldehyde ketone resin, dispersant, dimethylbenzene,
Toner, hydroquinone mix homogeneously, below 80oC grinds and forms, and the butyl acetate of 65wt% aldehyde ketone resin is molten
Liquid, dispersant, dimethylbenzene, toner, the weight ratio of hydroquinone are 45:5:14.8:35:0.2.
Embodiment 3
PE solid color enamel described in the present embodiment, by weight mark meter, comprise:
Wherein, mill base preparation process is: the butyl acetate solution of 70wt% aldehyde ketone resin, dispersant, dimethylbenzene,
Toner, hydroquinone mix homogeneously, below 80oC grinds and forms, and the butyl acetate of 70wt% aldehyde ketone resin is molten
Liquid, dispersant, dimethylbenzene, toner, the weight ratio of hydroquinone are 55:5:14.8:25:0.2.
Embodiment 4
PE solid color enamel described in the present embodiment, by weight mark meter, comprise:
Wherein, mill base preparation process is: the butyl acetate solution of 70wt% aldehyde ketone resin, dispersant, dimethylbenzene,
Toner, hydroquinone mix homogeneously, below 80oC grinds and forms, and the butyl acetate of 70wt% aldehyde ketone resin is molten
Liquid, dispersant, dimethylbenzene, toner, the weight ratio of hydroquinone are 50:4:14.9:31:0.1.
Embodiment 5
PE solid color enamel described in the present embodiment, by weight mark meter, comprise:
Wherein, mill base preparation process is: the butyl acetate solution of 70wt% aldehyde ketone resin, dispersant, dimethylbenzene,
Toner, hydroquinone mix homogeneously, below 80oC grinds and forms, and the butyl acetate of 70wt% aldehyde ketone resin is molten
Liquid, dispersant, dimethylbenzene, toner, the weight ratio of hydroquinone are 49:6:14.9:29:0.1.
The PE paint that the present invention provides is bright in luster;Using aldehyde ketone prefabricated paste, mill base itself can store 1 year,
And the paint shelf-life that normally unsaturated-resin is made is only 90 days-120 days, the storage time is greatly prolonged, also
The safety of improving product;Single thickness can be coated with, and be difficult to that paint disease occurs, production is greatly improved for Furniture manufacturing
Efficiency.
Being described in detail the specific embodiment of the present invention above, but it is intended only as example, the present invention is also
It is not restricted to particular embodiments described above.To those skilled in the art, any the present invention is carried out
Equivalent modifications and substitute the most all among scope of the invention.Therefore, without departing from the spirit of the present invention and model
Enclose lower made impartial conversion and amendment, all should contain within the scope of the invention.
Claims (10)
1. a PE solid color enamel, it is characterised in that in percentage by weight, comprise:
Wherein, described mill base by comprise the butyl acetate solution of 65-80wt% aldehyde ketone resin, dispersant, two
Toluene, toner, the mixed raw material of hydroquinone become, the acetic acid of 65-80wt% aldehyde ketone resin in described mill base
Butyl acetate solution, dispersant, dimethylbenzene, toner, the weight ratio of hydroquinone are (45-55): (4-6): (12-16):
(25-35): (0.1-0.3).
PE solid color enamel the most according to claim 1, it is characterised in that described defoamer disappears selected from organosilicon
Any one or a few in infusion, acrylate defoamer.
PE solid color enamel the most according to claim 1, it is characterised in that described levelling agent is selected from polyether polyester
Modified organic silicon oxygen alkane or acrylic ester type any one or a few.
PE solid color enamel the most according to claim 1, it is characterised in that described anti-settling agent is selected from polyamide wax
Or aerosil any one or a few.
PE solid color enamel the most according to claim 1, it is characterised in that in terms of PE solid color enamel weight, institute
Stating filler weight percentage ratio is 10-14%.
PE solid color enamel the most according to claim 1 or 5, it is characterised in that described filler selected from Pulvis Talci,
Any one or a few in transparent powder, triple superphosphate.
PE solid color enamel the most according to claim 6, it is characterised in that described filler includes at least Pulvis Talci.
PE solid color enamel the most according to claim 1, it is characterised in that in percentage by weight, comprise:
9. a PE solid color enamel mill base according to claim 1, it is characterised in that described mill base is by comprising
The butyl acetate solution of 65-80wt% aldehyde ketone resin, dispersant, dimethylbenzene, toner, the raw material of hydroquinone
Mixed grinding forms, the butyl acetate solution of 65-80wt% aldehyde ketone resin, dispersant, diformazan in described mill base
Benzene, toner, the weight ratio of hydroquinone are (45-55): (4-6): (12-16): (25-35): (0.1-0.3).
PE solid color enamel mill base the most according to claim 9, it is characterised in that described mill base is by comprising
The butyl acetate solution of 65-80wt% aldehyde ketone resin, dispersant, dimethylbenzene, toner, the raw material of hydroquinone
Mixed grinding forms, the butyl acetate solution of 65-80wt% aldehyde ketone resin, dispersant, diformazan in described mill base
Benzene, toner, the weight ratio of hydroquinone are (45-50): (4-6): (14-15): (25-35): (0.1-0.2).
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CN201310740813.XA CN103740239B (en) | 2013-12-27 | 2013-12-27 | A kind of PE solid color enamel |
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CN201310740813.XA CN103740239B (en) | 2013-12-27 | 2013-12-27 | A kind of PE solid color enamel |
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CN103740239A CN103740239A (en) | 2014-04-23 |
CN103740239B true CN103740239B (en) | 2016-12-07 |
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Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN104497814A (en) * | 2014-12-11 | 2015-04-08 | 三棵树涂料股份有限公司 | Aldehyde-ketone resin modified unsaturated polyester primer and preparation method thereof |
CN105086785A (en) * | 2015-08-26 | 2015-11-25 | 成都展辰涂料有限公司 | Unsaturated polyester transparent primer for construction in high-humidity environment |
CN107163205B (en) * | 2017-05-12 | 2019-03-22 | 常州大学 | A kind of unsaturated polyester (UP) performed polymer of ketone group containing and its preparation method and application |
Citations (6)
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CN102286240A (en) * | 2011-09-14 | 2011-12-21 | 上海长润发涂料有限公司 | PE (Polyurethane) gloss white paint |
CN102504627A (en) * | 2011-10-22 | 2012-06-20 | 李远登 | Unsaturated polyester white base coat |
CN103045057A (en) * | 2013-01-21 | 2013-04-17 | 常州众杰复合材料有限公司 | Antistatic color gel coat and preparation method thereof |
CN103045055A (en) * | 2012-12-12 | 2013-04-17 | 澳达树熊涂料(惠州)有限公司 | High-hardness unsaturated polyester full-bright top-coat paint and preparation method thereof |
CN103305062A (en) * | 2013-07-12 | 2013-09-18 | 三棵树涂料股份有限公司 | Environment-friendly general color paste and preparation method thereof |
CN103360922A (en) * | 2012-03-28 | 2013-10-23 | 展辰涂料集团股份有限公司 | Impermeable white unsaturated polyester furniture coating |
-
2013
- 2013-12-27 CN CN201310740813.XA patent/CN103740239B/en active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102286240A (en) * | 2011-09-14 | 2011-12-21 | 上海长润发涂料有限公司 | PE (Polyurethane) gloss white paint |
CN102504627A (en) * | 2011-10-22 | 2012-06-20 | 李远登 | Unsaturated polyester white base coat |
CN103360922A (en) * | 2012-03-28 | 2013-10-23 | 展辰涂料集团股份有限公司 | Impermeable white unsaturated polyester furniture coating |
CN103045055A (en) * | 2012-12-12 | 2013-04-17 | 澳达树熊涂料(惠州)有限公司 | High-hardness unsaturated polyester full-bright top-coat paint and preparation method thereof |
CN103045057A (en) * | 2013-01-21 | 2013-04-17 | 常州众杰复合材料有限公司 | Antistatic color gel coat and preparation method thereof |
CN103305062A (en) * | 2013-07-12 | 2013-09-18 | 三棵树涂料股份有限公司 | Environment-friendly general color paste and preparation method thereof |
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Address after: 201506 No. 578 Xia Sheng Road, Jinshan District, Shanghai Patentee after: Shanghai Libang Changrunfa Coatings Co., Ltd. Address before: 201506 No. 578 Xia Sheng Road, Jinshan District, Shanghai Patentee before: Shanghai Changrunfa Paint Co., Ltd. |
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