CN107353813A - A kind of plastic paint and preparation method thereof and a kind of plastics sealing wax - Google Patents

A kind of plastic paint and preparation method thereof and a kind of plastics sealing wax Download PDF

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Publication number
CN107353813A
CN107353813A CN201710702251.8A CN201710702251A CN107353813A CN 107353813 A CN107353813 A CN 107353813A CN 201710702251 A CN201710702251 A CN 201710702251A CN 107353813 A CN107353813 A CN 107353813A
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China
Prior art keywords
plastic paint
modified
acrylic acid
paint
sealing wax
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Granted
Application number
CN201710702251.8A
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Chinese (zh)
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CN107353813B (en
Inventor
张林其
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Hebei Huichi New Material Technology Co.,Ltd.
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Hebei Huichi Decoration Material Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • C09D175/14Polyurethanes having carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention provides a kind of plastic paint and preparation method thereof and a kind of plastics sealing wax.Plastic paint provided by the invention includes modified resin, defoamer, dispersant, wetting agent, coalescents, levelling agent, thickener and water;Plastics sealing wax includes plastic paint and water.Due to using specific compositing formula, its drying time significantly reduces plastic paint and plastics sealing wax provided by the invention.The plastic paint and the surface drying time of plastics sealing wax provided from embodiment result, the application does solid work the time up to 40min, thickness of dry film is 10~12 μm, and the glossiness of dry film is 95 °, and adhesive force reaches 0 grade up to 15min;Film after 3 hours hardness can reach HB, F can be reached after 12 hours.

Description

A kind of plastic paint and preparation method thereof and a kind of plastics sealing wax
Technical field
The present invention relates to plastic paint technical field, more particularly to a kind of plastic paint and preparation method thereof and a kind of plastics water Paint.
Background technology
Plastic paint has the characteristics that hardness is high, gloss is high, divides richness height, ply adhesion is good, easily constructs, and is widely used in The product painting of plastic bottom material, aqueous plastic paint and conventional oil-based plastic paint can be divided into.
Water paint is the coating without organic solvent using water as diluent.Water paint is free of benzene, formaldehyde and toxic metals, Nontoxic non-stimulated smell, it is harmless, it is free from environmental pollution.In pay attention to day by day coating safety and the today's society of environmental protection index, The popularization of aqueous plastic paint is all highly beneficial to the reasonable utilization of resource and the improvement of environmental sanitation.
However, the rate of drying of traditional plastic paint is universal relatively slow, have a strong impact on that it is promoted and used.
The content of the invention
It is an object of the invention to provide a kind of plastic paint and preparation method thereof and a kind of plastics sealing wax.It is provided by the invention Plastic paint and plastics sealing wax are formed due to specific, and its drying time significantly reduces.
In order to realize foregoing invention purpose, the present invention provides following technical scheme:
The invention provides a kind of plastic paint, the component of following mass parts is included:
The modified resin includes methacrylic resin, acrylic acid modified polyurethane and epoxy-modified acrylic acid, described The mass ratio of methacrylic resin, acrylic acid modified polyurethane and epoxy-modified acrylic acid is (20~40):(30~50): (20~40).
Preferably, the pH value of the methacrylic resin is 7~8, and viscosity is 1000~8000cps, density 1.02 ~1.05g/mL, acid number are 50~70mg KOH/g, and hydroxyl value is 50~70mg KOH/g.
Preferably, the acrylic acid modified polyurethane is the acrylic acid modified polyurethane of 0535 model.
Preferably, the epoxy-modified acrylic acid is the epoxy-modified acrylic acid of 3442 models.
Preferably, the defoamer is the one or more in 805W, 2501,2502,2524 and 5100;
The dispersant is 760W;
The wetting agent is 5008,5285, the one or more in L45 and 245.
Preferably, the coalescents are dipropylene glycol methyl ether and/or dipropylene glycol n-butyl ether;
The levelling agent is the one or more in 3772,3251,3758 and 410 levelling agents;
The thickener is polyurethanes thickener.
The invention provides a kind of preparation method of plastic paint described in above-mentioned technical proposal, comprise the following steps:
Modified resin, defoamer, dispersant, wetting agent, coalescents, levelling agent, thickener and water are mixed, moulded Material paint.
Preferably, the time of the mixing is 40~80min.
Preferably, the mixing is carried out under agitation, and the speed of the stirring is 600~800rpm.
Present invention also offers a kind of plastics sealing wax, plastic paint described in above-mentioned technical proposal or above-mentioned technical proposal are included The plastic paint and water that any one preparation method obtains, the mass ratio of the plastic paint and water is 1:(0.1~0.5).
The invention provides a kind of plastic paint and preparation method thereof and a kind of plastics sealing wax.Plastics enamel-cover provided by the invention Containing modified resin, defoamer, dispersant, wetting agent, coalescents, levelling agent, thickener and water;Plastics sealing wax includes plastic paint And water.Due to using specific compositing formula, its drying time significantly reduces plastic paint and plastics sealing wax provided by the invention.By Embodiment result understands that the plastic paint and the certainly dry of plastics sealing wax that the application provides can be carried out at room temperature, and its surface drying time can Up to 15min, the time is done solid work up to 40min, and thickness of dry film is 10~12 μm, and the glossiness of dry film is 95 °, and adhesive force reaches 0 grade; Film after 3 hours hardness can reach HB, F can be reached after 12 hours.
Embodiment
The invention provides a kind of plastic paint, the component of following mass parts is included:
The modified resin includes methacrylic resin, acrylic acid modified polyurethane and epoxy-modified acrylic acid, described The mass ratio of methacrylic resin, acrylic acid modified polyurethane and epoxy-modified acrylic acid is (20~40):(30~50): (20~40).
Plastic paint provided by the invention includes the modified resin of 70~80 mass parts, preferably 72~78 parts, more preferably 74~76 parts.In the present invention, the modified resin includes methacrylic resin, acrylic acid modified polyurethane and epoxide modified Acrylic acid, the mass ratio of the methacrylic resin, acrylic acid modified polyurethane and epoxy-modified acrylic acid be preferably (20~ 40):(30~50):(20~40), more preferably (25~35):(35~45):(25~35), most preferably 30:40:30.
The present invention does not have any particular determination to the source of the methacrylic resin, using those skilled in the art Known commercially available methacrylic resin.In the present invention, the outward appearance of the methacrylic resin is light yellow Transparency liquid, the content of non-volatile matter is 51 ± 2wt%, and glass transition temperature Tg is 60 DEG C;The methacrylic resin PH value be preferably 7~8;The viscosity (25 DEG C, Brookfield, LVTNo.4,60RPM) of the methacrylic resin is preferred For 1000~8000cps, more preferably 2000~6000cps, most preferably 4000~5000cps;The methacrylic acid tree The density of fat is preferably 1.02~1.05g/mL, more preferably 1.03~1.04g/mL;The acid number of the methacrylic resin Preferably 50~70mg KOH/g, more preferably 55~65mg KOH/g;The hydroxyl value of the methacrylic resin is preferably 50 ~70mg KOH/g, more preferably 55~65mg KOH/g.In the specific embodiment of the invention, the methacrylic resin is The methacrylic resin of 8750 commercially available models.
The present invention does not have any particular determination to the source of the acrylic acid modified polyurethane, using people in the art Commercially available acrylic acid modified polyurethane known to member.In the specific embodiment of the invention, the acrylic acid modified poly- ammonia Ester is the acrylic acid modified polyurethane of 0535 model.
The present invention does not have any particular determination to the source of the epoxy-modified acrylic acid, using those skilled in the art Known commercially available epoxy-modified acrylic acid.In the specific embodiment of the invention, the epoxy-modified acrylic acid is The epoxy-modified acrylic acid of 3442 models.
In the present invention, the preparation method of modified resin described in above-mentioned technical proposal, preferably comprises following steps:
Methacrylic resin, acrylic acid modified polyurethane and epoxy-modified acrylic acid are mixed, obtain modified resin.
Order by merging of the present invention to the methacrylic resin, acrylic acid modified polyurethane and epoxy-modified acrylic acid There is no any particular/special requirement, can be mixed in any order.
In the present invention, the mixing is preferably carried out under agitation, and the speed of the stirring is preferably 600~ 800rpm, more preferably 650~750rpm, most preferably 700rpm.In the present invention, the temperature of the mixing be preferably 40~ 60 DEG C, more preferably 45~55 DEG C, most preferably 50 DEG C;The time of the mixing is preferably 40~80min, more preferably 50~ 70min, most preferably 60min.
On the basis of the modified resin of 70~80 mass parts, plastic paint provided by the invention includes 0.1~0.5 mass parts Defoamer, preferably 0.2~0.4 part, more preferably 0.3 part.In the specific embodiment of the invention, the defoamer is preferably One or more in 805W, 2501,2502,2524 and 5100.In the present invention, described 2501 contain organosilicon for commercially available Water-based emulsion shape defoamer, 2502 and 2524 be the commercially available aqueous defoamer containing organosilicon.
On the basis of the modified resin of 70~80 mass parts, plastic paint provided by the invention includes 0.2~0.5 mass parts Dispersant, preferably 0.3~0.4 part.In the present invention, the dispersant is preferably 760W.
On the basis of the modified resin of 70~80 mass parts, plastic paint provided by the invention includes the profit of 0.5~1 mass parts Humectant, preferably 0.6~0.9 part, more preferably 0.7~0.8 part.In the specific embodiment of the invention, the wetting agent is preferred For one or more of wetting agents in commercially available model 5008,5285, L45 and 245.In the present invention, described 5008 are The carboxylate of unsaturated polyamide, amine density are 0.89~0.91g/cm3, amine value is 20~24mg KOH/g, acid number is 2~ 8mg KOH/g, flash-point are 25 DEG C, and outward appearance is transparent brown color liquid;Described 5285 be the ionic copolymerization with acidic endgroups Thing, acid number are 70~85mg KOH/g.
On the basis of the modified resin of 70~80 mass parts, plastic paint provided by the invention includes the film forming of 6~9 mass parts Auxiliary agent, preferably 7~8 parts.In the present invention, the coalescents are preferably dipropylene glycol methyl ether (DPM) and/or DPG N-butyl ether (DPNB).In the present invention, when the coalescents preferably include DPM and DPNB simultaneously, DPM and DPNB quality Than being preferably (2.5~5.5):(2~4), more preferably (3.5~4.5):3.
The present invention does not have any particular determination to the DPM and DPNB source, ripe using those skilled in the art institute The commercially available DPM and DPNB known.
On the basis of the modified resin of 70~80 mass parts, plastic paint provided by the invention includes 0.1~0.5 mass parts Levelling agent, preferably 0.2~0.4 part, more preferably 0.3 part.In the specific embodiment of the invention, the levelling agent is preferably city One or more of wetting agents in the model 5008,5285 and 245 sold.In the present invention, described 5008 be unsaturated poly- The carboxylate of acid amides, amine density are 0.89~0.91g/cm3, amine value is 20~24mg KOH/g, and acid number is 2~8mg KOH/g, Flash-point is 25 DEG C, and outward appearance is transparent brown color liquid;Described 5285 be ionic copolymer with acidic endgroups, acid number 70 ~85mg KOH/g.
On the basis of the modified resin of 70~80 mass parts, plastic paint provided by the invention includes 0.1~0.5 mass parts Thickener, preferably 0.2~0.4 part, more preferably 0.3 part.In the present invention, the thickener is preferably polyurethanes thickening Agent, more preferably 299 thickeners.
On the basis of the modified resin of 70~80 mass parts, plastic paint provided by the invention includes 5~10 parts of water, preferably For 6~8 parts.In the present invention, the water is preferably deionization, distilled water or anion water.In the present invention, the anion Water uses the anion water of the commercial source of any kind.
On the basis of the modified resin of 70~80 mass parts, plastic paint provided by the invention is preferably also comprising 10~25 parts Face is starched, more preferably 15~20 parts.The present invention does not have any particular/special requirement to the species of face slurry, using art technology Plastic paint known to personnel is starched with face;Specifically, when to obtain the plastic paint of specific color, specific color is added Face is starched.
In the present invention, the plastic paint is applied in a manner of roller coating or brushing etc. be not high to paint vehicle fluidity to plastics It is coated.
The invention provides a kind of preparation method of plastic paint described in above-mentioned technical proposal, comprise the following steps:
Modified resin, defoamer, dispersant, wetting agent, coalescents, levelling agent, thickener and water are mixed, moulded Material paint.
The present invention is to the modified resin, defoamer, dispersant, wetting agent, coalescents, levelling agent, thickener and water Order by merging there is no any particular/special requirement, preferably first modified resin, defoamer, dispersant, wetting agent, film forming are helped Agent, thickener and water mixing, finally add levelling agent.
In the present invention, when the plastic paint preferably also comprising face slurry when, the present invention will by modified resin, defoamer, point Powder, wetting agent, coalescents, levelling agent, thickener, face slurry and water mixing, obtain plastic paint.
In the present invention, the mixing is preferably carried out under agitation, and the speed of the stirring is preferably 600~ 800rpm, more preferably 650~750rpm, most preferably 700rpm.In the present invention, the temperature of the mixing is preferably room Temperature;The time of the mixing is preferably 40~80min, more preferably 50~70min, most preferably 60min.
Present invention also offers a kind of plastics sealing wax, plastic paint described in above-mentioned technical proposal or above-mentioned technical proposal are included The plastic paint and water that any one preparation method obtains.In the present invention, the mass ratio of the plastic paint and water is 1:(0.1~ 0.5), preferably 1:0.3.In the present invention, the plastics sealing wax stirs equal after when in use directly mixing plastic paint and water It is even.In the present invention, the plastics sealing wax is applied to carry out plastics in a manner of spraying etc. is higher to paint vehicle fluidity Coating.
In the present invention, after plastic paint and the plastics sealing wax is coated on frosting, the thickness of dry film is preferably 10~ 15 μm, more preferably 12~13 μm.Can being carried out at room temperature from dry for plastic paint and plastics sealing wax provided by the invention, it is preferably 20~25 DEG C.
Plastic paint provided by the invention and preparation method thereof and plastics sealing wax are carried out specifically with reference to embodiment It is bright, but they can not be interpreted as limiting the scope of the present invention.
Embodiment 1
Methacrylic resin (8750), acrylic acid modified polyurethane (0535) and epoxy-modified acrylic acid (3442) are pressed According to 30:40:30 mass ratio mixing, stirs 60min with 700rpm rotating speed, obtains modified resin.
By 70 mass parts modified resins, 0.3 mass parts defoamer (805W), 0.2 part of dispersant (760W), 0.5 mass parts Wetting agent (3772), 2.5 parts of DPNB, 4 parts of DPM, 0.3 mass parts levelling agent (410), 5 parts of distilled water and 0.3 mass parts thickener (299) mix, 60min is stirred with 700rpm rotating speed, obtains plastic paint.
By the plastic paint roller coating in plastic sheet surface, plastics lacquer coat is formed.Understood by measure, the plastics lacquer coat Surface drying time be 15min, it is 44min to do solid work the time, and thickness of dry film is 10 μm, and the glossiness of dry film is 95 °, and adhesive force reaches 0 grade;Film after 3 hours hardness can reach HB, F can be reached after 12 hours.
Embodiment 2
Methacrylic resin (8750), acrylic acid modified polyurethane (0535) and epoxy-modified acrylic acid (3442) are pressed According to 32:38:30 mass ratio mixing, stirs 60min with 700rpm rotating speed, obtains modified resin.
By 75 mass parts modified resins, 0.3 mass parts defoamer (901W), 0.4 part of dispersant (760W), 0.6 mass parts Wetting agent (5008), 4 parts of DPNB, 4 parts of DPM, 0.3 mass parts levelling agent (3758), 10 parts of distilled water and 0.3 mass parts thickener (299) mix, 60min is stirred with 700rpm rotating speed, obtains plastic paint.
By the plastic paint and water according to 1:0.3 mass ratio is well mixed, and obtains plastics sealing wax.
The plastics sealing wax is sprayed at plastic sheet surface, forms plastics sealing wax coating.Understood by measure, the plastic paint The surface drying time of coating is 19min, and it is 43min to do solid work the time, and thickness of dry film is 11 μm, and the glossiness of dry film is 95 °, adhesive force Reach 0 grade;Film after 3 hours hardness can reach HB, F can be reached after 12 hours.
Embodiment 3
Methacrylic resin (8750), acrylic acid modified polyurethane (0535) and epoxy-modified acrylic acid (3442) are pressed According to 30:42:38 mass ratio mixing, stirs 60min with 700rpm rotating speed, obtains modified resin.
By 80 mass parts modified resins, 0.5 mass parts defoamer (2501), 0.5 part of dispersant (760W), 0.8 mass parts Wetting agent (5285), 5 parts of DPNB, 3.5 parts of DPM, 0.1 mass parts levelling agent (3251), 8 parts of distilled water and the thickening of 0.5 mass parts Agent (299) mixes, and stirs 50min with 800rpm rotating speed, obtains plastic paint.
By the plastic paint and water according to 1:0.3 mass ratio is well mixed, and obtains plastics sealing wax.
The plastics sealing wax is sprayed at plastic sheet surface, forms plastics sealing wax coating.Understood by measure, the plastic paint The surface drying time of coating is 17min, and it is 40min to do solid work the time, and thickness of dry film is 12 μm, and the glossiness of dry film is 95 °, adhesive force Reach 0 grade;Film after 3 hours hardness can reach HB, F can be reached after 12 hours.
As seen from the above embodiment, the invention provides a kind of plastic paint and preparation method thereof and a kind of plastics sealing wax.This The plastic paint that invention provides includes modified resin, defoamer, wetting agent, levelling agent, thickener, butyl glycol ether and water;Plastics Sealing wax includes plastic paint and water.Due to using specific compositing formula, it is dried plastic paint and plastics sealing wax provided by the invention Time significantly reduces.From embodiment result, plastic paint and the certainly dry of plastics sealing wax that the application provides can enter at room temperature OK, its surface drying time is up to 15min, and it up to 40min, thickness of dry film is 10~12 μm to do solid work the time, and the glossiness of dry film is 95 °, adhesive force reaches 0 grade;Film after 3 hours hardness can reach HB, F can be reached after 12 hours.
Described above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For member, under the premise without departing from the principles of the invention, some improvements and modifications can also be made, these improvements and modifications also should It is considered as protection scope of the present invention.

Claims (10)

1. a kind of plastic paint, include the component of following mass parts:
The modified resin includes methacrylic resin, acrylic acid modified polyurethane and epoxy-modified acrylic acid, the methyl The mass ratio of acrylic resin, acrylic acid modified polyurethane and epoxy-modified acrylic acid is (20~40):(30~50):(20~ 40)。
2. plastic paint according to claim 1, it is characterised in that the pH value of the methacrylic resin is 7~8, is glued It is 1.02~1.05g/mL to spend for 1000~8000cps, density, and acid number is 50~70mg KOH/g, and hydroxyl value is 50~70mg KOH/g。
3. plastic paint according to claim 1, it is characterised in that the acrylic acid modified polyurethane is the third of 0535 model Olefin(e) acid modified polyurethane.
4. plastic paint according to claim 1, it is characterised in that the epoxy-modified acrylic acid is the epoxy of 3442 models Modified acroleic acid.
5. according to the plastic paint described in Claims 1 to 4 any one, it is characterised in that the defoamer be 805W, 2501st, the one or more in 2502,2524 and 5100;
The dispersant is 760W;
The wetting agent is 5008,5285, the one or more in L45 and 245.
6. according to the plastic paint described in Claims 1 to 4 any one, it is characterised in that the coalescents are DPG Methyl ether and/or dipropylene glycol n-butyl ether;
The levelling agent is the one or more in 3772,3251,3758 and 410 levelling agents;
The thickener is polyurethanes thickener.
7. the preparation method of plastic paint, is comprised the following steps described in claim 1~6 any one:
Modified resin, defoamer, dispersant, wetting agent, coalescents, levelling agent, thickener and water are mixed, obtain plastics Paint.
8. preparation method according to claim 7, it is characterised in that the time of the mixing is 40~80min.
9. the preparation method according to claim 7 or 8, it is characterised in that the mixing is carried out under agitation, described The speed of stirring is 600~800rpm.
10. a kind of plastics sealing wax, any one comprising plastic paint or claim 7~9 described in claim 1~6 any one The plastic paint and water that item preparation method obtains, the mass ratio of the plastic paint and water is 1:(0.1~0.5).
CN201710702251.8A 2017-08-16 2017-08-16 Plastic paint, preparation method thereof and plastic water paint Active CN107353813B (en)

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CN107353813B CN107353813B (en) 2020-04-10

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110804351A (en) * 2018-08-02 2020-02-18 重庆韩拓科技有限公司 Environment-friendly water-based PVC film primer and preparation method and application thereof
CN114854258A (en) * 2022-05-17 2022-08-05 中山蓝海洋水性涂料有限公司 High-hardness impact-resistant water-based metal matte baking paint for computer case and preparation method thereof

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CN101747818A (en) * 2009-11-27 2010-06-23 广州擎天实业有限公司 Water-based paint for quick-drying alcohol-resistance plastics and preparation method thereof
CN102167941A (en) * 2010-02-26 2011-08-31 温州邦轩科技有限公司 Aqueous plastic coating paint
CN104559553A (en) * 2013-10-25 2015-04-29 青岛德固建筑材料有限公司 Water-based plastic paint
CN104673020A (en) * 2015-03-05 2015-06-03 廊坊立邦涂料有限公司 Single-coating, high-gloss and boiling-resisting plastic paint and preparation method thereof
CN105885582A (en) * 2016-05-26 2016-08-24 杭州高思途实业有限公司 Water-borne plastic paint and preparation method thereof
CN106519840A (en) * 2016-10-31 2017-03-22 陈少双 Plastic paint and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN101747818A (en) * 2009-11-27 2010-06-23 广州擎天实业有限公司 Water-based paint for quick-drying alcohol-resistance plastics and preparation method thereof
CN102167941A (en) * 2010-02-26 2011-08-31 温州邦轩科技有限公司 Aqueous plastic coating paint
CN104559553A (en) * 2013-10-25 2015-04-29 青岛德固建筑材料有限公司 Water-based plastic paint
CN104673020A (en) * 2015-03-05 2015-06-03 廊坊立邦涂料有限公司 Single-coating, high-gloss and boiling-resisting plastic paint and preparation method thereof
CN105885582A (en) * 2016-05-26 2016-08-24 杭州高思途实业有限公司 Water-borne plastic paint and preparation method thereof
CN106519840A (en) * 2016-10-31 2017-03-22 陈少双 Plastic paint and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110804351A (en) * 2018-08-02 2020-02-18 重庆韩拓科技有限公司 Environment-friendly water-based PVC film primer and preparation method and application thereof
CN114854258A (en) * 2022-05-17 2022-08-05 中山蓝海洋水性涂料有限公司 High-hardness impact-resistant water-based metal matte baking paint for computer case and preparation method thereof

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