CN106947351A - A kind of anti-scribble antitheft door sealing wax and preparation method thereof - Google Patents
A kind of anti-scribble antitheft door sealing wax and preparation method thereof Download PDFInfo
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- CN106947351A CN106947351A CN201710108128.3A CN201710108128A CN106947351A CN 106947351 A CN106947351 A CN 106947351A CN 201710108128 A CN201710108128 A CN 201710108128A CN 106947351 A CN106947351 A CN 106947351A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1675—Polyorganosiloxane-containing compositions
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
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- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Sealing Material Composition (AREA)
Abstract
The present invention relates to technical field of aqueous paint, more particularly, to a kind of antitheft door water paint, specifically disclose a kind of anti-scribble antitheft door sealing wax and preparation method thereof, the sealing wax is included with hydroxyl acrylic acid water dispersoid, the water-base resin system that the aqueous emulsion of dimethyl polysiloxane fluid of complete Amino resin and hydroxy functional groups is constituted is mixed to prepare with auxiliary agent, sealing wax VOC content is low, smell is small, contaminated air environment can be avoided, it is small to Health Impact, more safety and environmental protection, adhesive force of the sealing wax with base material after film forming is good simultaneously, the decoration performance of paint film is good, richness and excellent gloss, anti- scribble excellent performance, easily clean.
Description
Technical field
The present invention relates to technical field of aqueous paint, more particularly, to a kind of antitheft door water paint.
Background technology
In China, antitheft door performs national standard, protective door in materials, security than general execution company standard,
Steel door requires high, and with the change of people's consumer need, more Functional Requirements are also proposed to antitheft door, such as paints
Decoration performance, safety and environmental protection performance, anti-scribble performance of film etc..
The current most of antitheft door of China is based on solvent based coating or powdery paints, for antitheft door with coating
Water paint is very few.Above antitheft door is primarily present following technological deficiency with coating：
1st, (volatile the organic compounds, abbreviation VOC of VOC contained by solvent based coating）Content
Very high, air pollution is serious, has tremendous influence to health, while there is disaster hidden-trouble in storage and using process；
2nd, powdery paints into after paint film, generally existing gloss difference, richness are low, transparency low ornamental difference the problem of；
3rd, existing antitheft door is very high with water paint product VOC, general to use water soluble acrylic resin's amino-stoving varnish, its
VOC is up to more than 300g/L, and smell is also very big；
4th, existing antitheft door water paint product also has compared with solvent based product certain poor into the gloss after paint film, richness
Away from causing decorative effect poor；
5th, existing antitheft door does not account for the feature of anti-scribble, especially antitheft door with coating with aqueous anti-graffiti coating still
Blank.
The content of the invention
The technical problem to be solved in the present invention is to provide anti-scribble antitheft door sealing wax of one kind and preparation method thereof, the sealing wax
VOC content is low, smell is small, can avoid contaminated air environment, small to Health Impact, more safety and environmental protection, while the water
The adhesive force painted with base material after film forming is good, and the decoration performance of paint film is good, richness and excellent gloss, anti-scribble excellent performance,
Easily clean.
In order to solve the above technical problems, the technical solution used in the present invention is：A kind of anti-scribble antitheft door sealing wax, including
Raw material components and its percentage by weight are as follows：
65~70% water-based acrylic resin, 10~12% water-compatible amino resin, 3~5% aqueous anti-scribble resin, 1~2%
Environmentally friendly solvent, 0.1~0.2% nertralizer, 0.3~0.5% defoamer, 0.4~0.6% levelling agent, 0.3~0.5%
Substrate wetting agents, 0.5~1.0% adhesion promoter, 7~17% deionized water, 1~2% thickener；
The water-based acrylic resin is hydroxyl acrylic acid water dispersoid, and the water-compatible amino resin is complete methyl-etherified amino tree
Fat, the aqueous anti-scribble resin is the aqueous emulsion of dimethyl polysiloxane fluid of hydroxy functional groups.
It is preferred that, the water-based acrylic resin is the product Antkote 2042 of ten thousand China's chemistry, and its solid content is in 41-
43%, hydroxy radical content 4.2%（Based on solids content）, VOC content is low；The water-compatible amino resin is the product in TaiWan, China Changchun
MR603 and/or CYMEL303, its solid content is more than 97%, and VOC content is low；The aqueous anti-scribble resin is that enlightening is high（TEGO）'s
The N of product Protect 5100, hydroxyl aqueous emulsion of dimethyl polysiloxane fluid, hydroxy radical content 0.8%, for being handed over amino resins high temperature
Connection, VOC content is low.
Further, the environmentally friendly solvent is the one or two in propandiol butyl ether, propylene glycol monomethyl ether, the adhesive force
Accelerator is polyester base phosphoric acid, and the substrate wetting agents are polyether siloxane copolymer, and the thickener thickens for alkali swelling type
Agent and the mixture of polyurethane-type thickener.
It is preferred that, the adhesion promoter is Lu Borun product Lubrizol 2063, and the substrate wetting agents are enlightening
It is high（TEGO）Wet 270, Wet KL245 in one or two；The polyurethane-type thickener is the product of bright icepro
TAFIGEL PUR40, the alkali swelling type thickener is Tao Shi（DOW）Product ACRYSO LASE-60；The defoamer is
Enlightening is high（TEGO）Airex 902W and Bi Ke（BYK）Two kinds of products of BYK-028 mixture.
Present invention also offers the preparation method of anti-scribble antitheft door sealing wax as previously described, comprise the following steps：
Step a, matches according to the raw material components, first mixes environmentally friendly solvent, nertralizer, add the raw material components
50% deionized water, stirs in proportioning, standby；
Step b, takes part steps a gained mixed liquors, it is mixed with adhesion promoter, adjustment mixed liquor pH value is stirred to 7-8
Mix uniform, it is standby；
Step c, water-based acrylic resin is added in pot of getting the raw materials ready, stirred, and then adds mixed liquor obtained by remaining step a
Enter into pot of getting the raw materials ready, mixed with water-based acrylic resin, stirred, then add defoamer, levelling agent, base material wetting successively
Agent, stirs, and is eventually adding step b gained mixtures, stirs；
Step d, water-compatible amino resin, aqueous anti-scribble resin are added sequentially in mixture obtained by step c, stirred,
Then thickener and remaining deionized water are added, stirring, adjustment viscosity is to qualified.
Further, the speed of the stirring is 500~1200r/min, and the time stirred every time is 3~10min.
It is using the beneficial effect produced by above-mentioned technical proposal：
1st, sealing wax of the present invention selects water-base resin system, and its VOC≤80g/L, smell is very low, than existing antitheft door coating more
Safety and environmental protection, can avoid contaminated air environment, small to Health Impact；
2nd, good resistant effect, energy have been reached as aqueous anti-scribble resin from hydroxyl aqueous emulsion of dimethyl polysiloxane fluid
Easily wipe a variety of scribble materials such as aqueous white board marker, watercolor pencil, dust-free chalk, shoe polish, ink, catsup, coffee ＆ tea stain
Or household stains, pollution wiping persistence is good repeatedly；
3rd, from polyester for main chain phosphate as adhesion promoter, solve because introduce siloxanes caused by with base material
The problem of adhesive force is not good, the adhesive force test of sealing wax of the present invention reaches 0 grade, and adhesive force is good, durable；
4th, from water soluble acrylic acid dispersion and water-compatible amino resin, when in use, solidify through 150 DEG C of high-temperature cross-linking, can
The water-based stoving paint coating of high glaze, high-decoration is obtained, impact resistance of coating is good, and resistance to petrol-resistance is good.
Embodiment
The invention provides one kind it is anti-scribble antitheft door sealing wax, including raw material components and its percentage by weight it is as follows：
65~70% water-based acrylic resin, 10~12% water-compatible amino resin, 3~5% aqueous anti-scribble resin, 1~2%
Environmentally friendly solvent, 0.1~0.2% nertralizer, 0.3~0.5% defoamer, 0.4~0.6% levelling agent, 0.3~0.5%
Substrate wetting agents, 0.5~1.0% adhesion promoter, 7~17% deionized water, 1~2% thickener；
The water-based acrylic resin is hydroxyl acrylic acid water dispersoid, and the water-compatible amino resin is complete methyl-etherified amino tree
Fat, the aqueous anti-scribble resin is the aqueous emulsion of dimethyl polysiloxane fluid of hydroxy functional groups.
Sealing wax of the present invention is used as baking vanish, is coated on after base material, and toasted sizing forms water-based stoving paint coating.Wherein select
With water soluble acrylic acid dispersion and water-compatible amino resin, solidified by 150 DEG C of high-temperature cross-linkings, high glaze, high dress can be obtained
The water-based stoving paint coating of decorations property, its VOC≤80g/L, smell is very low, prevents from polluting environment.
Sealing wax of the present invention carries out high-temperature cross-linking from hydroxyl aqueous emulsion of dimethyl polysiloxane fluid with main body amino resins, makes silicon
Oxygen key is stayed in coating, is reduced coating surface energy, with fabulous solvent resistance, is obtained anti-antigraffiti effect, pollutes lasting repeatedly
Property is good.
Sealing wax of the present invention, as adhesion promoter, passes through phosphate and metal surface from the phosphate that polyester is main chain
Bonding action, it is possible to increase the adhesive force of coating and base material, solve because introduce siloxanes caused by with base material adhesive force not
Good the problem of.
The present invention is compounded from different types of defoamer, solves system air bubble problem；Increased from different types of
Thick dose of compounding, solves the thixotropic property of system.
Illustrate below and the present invention is described in further detail.
Embodiment 1
A kind of anti-scribble antitheft door sealing wax, including raw material components and its percentage by weight it is as follows：
Water-based acrylic resin 70%
Water-compatible amino resin 12%
Aqueous anti-scribble resin 5%
Environmentally friendly solvent 2%
Nertralizer 0.2%
Defoamer 0.3%
Levelling agent 0.6%
Substrate wetting agents 0.3%
Adhesion promoter 1%
Deionized water 7.6%
Thickener 1%.
Wherein, water-based acrylic resin used is the product Antkote 2042 of ten thousand China's chemistry, water-compatible amino resin used
For the product MR603 in TaiWan, China Changchun, aqueous anti-scribble resin used is that enlightening is high（TEGO）The N of product Protect 5100,
Adhesion promoter used is Lu Borun product Lubrizol 2063, and substrate wetting agents used are that enlightening is high（TEGO）Wet
270；Thickener used is product the TAFIGEL PUR40 and Tao Shi of bright icepro（DOW）Product ACRYSO LASE-60 press quality
Than for 1：1 mixture, defoamer used is that enlightening is high（TEGO）Airex 902W and Bi Ke（BYK）Two kinds of BYK-028 production
Product are 5 in mass ratio：3 mixture, environmentally friendly solvent used is propandiol butyl ether, and nertralizer used is the AMP- of DOW Chemical
95, the PW336 that levelling agent used is first created for France.
The specific preparation method of the sealing wax is：
Step a, matches according to the raw material components, is first mixed environmentally friendly solvent, nertralizer, adds 50% in formula
Deionized water, is stirred 3 minutes with 500r/min speed, standby；
Step b, takes part steps a gained mixed liquors, it is mixed with adhesion promoter, adjustment mixed liquor pH value to 7-8, with
500r/min speed is stirred 3 minutes, standby；
Step c, water-based acrylic resin is added in pot of getting the raw materials ready, and is stirred 5 minutes with 500r/min speed, then by residue
Mixed liquor obtained by step a is added in pot of getting the raw materials ready, and is mixed with water-based acrylic resin, and 10 points are stirred with 900r/min speed
Clock, then defoamer, levelling agent, substrate wetting agents are added successively, stirred 10 minutes with 1200r/min speed, be eventually adding step
Mixture obtained by rapid b, stirs；
Step d, water-compatible amino resin, aqueous anti-scribble resin is added sequentially in mixture obtained by step c, with 900r/min
Speed stir 10 minutes, then add thickener and remaining deionized water, stirred 10 minutes with 1000r/min speed,
Viscosity is adjusted to qualified.
Anti- scribble antitheft door sealing wax made from the present embodiment and in the market solvent based product, the performance comparison of aqueous product,
It see the table below.
Embodiment 2
A kind of anti-scribble antitheft door sealing wax, including raw material components and its percentage by weight it is as follows：
Water-based acrylic resin 68%
Water-compatible amino resin 11%
Aqueous anti-scribble resin 4%
Environmentally friendly solvent 1.5%
Nertralizer 0.2%
Defoamer 0.4%
Levelling agent 0.5%
Substrate wetting agents 0.4%
Adhesion promoter 0.8%
Deionized water 11.7%
Thickener 1.5%.
Wherein, water-based acrylic resin used is the product Antkote 2042 of ten thousand China's chemistry, water-compatible amino resin used
It is 1 in mass ratio for the product MR603 and CYMEL303 in TaiWan, China Changchun：1 mixture, aqueous anti-scribble resin used
It is high for enlightening（TEGO）The N of product Protect 5100, adhesion promoter used be Lu Borun product Lubrizol 2063,
Substrate wetting agents used are that enlightening is high（TEGO）Wet 270 and Wet KL245 in mass ratio be 1：1 mixture；Thickening used
Agent is product the TAFIGEL PUR40 and Tao Shi of bright icepro（DOW）Product ACRYSO LASE-60 in mass ratio be 1：1 mixing
Thing, defoamer used is that enlightening is high（TEGO）Airex 902W and Bi Ke（BYK）Two kinds of products of BYK-028 in mass ratio be 5：
3 mixture, environmentally friendly solvent used is that propandiol butyl ether and propylene glycol monomethyl ether are 1 in mass ratio：1 mixture, neutralization used
Agent is the AMP-95 of DOW Chemical, the PW336 that levelling agent used is first created for France.
The specific preparation method of the sealing wax is：
Step a, matches according to the raw material components, is first mixed environmentally friendly solvent, nertralizer, adds 50% in formula
Deionized water, is stirred 3 minutes with 500r/min speed, standby；
Step b, takes part steps a gained mixed liquors, it is mixed with adhesion promoter, adjustment mixed liquor pH value to 7-8, with
500r/min speed is stirred 3 minutes, standby；
Step c, water-based acrylic resin is added in pot of getting the raw materials ready, and is stirred 5 minutes with 500r/min speed, then by residue
Mixed liquor obtained by step a is added in pot of getting the raw materials ready, and is mixed with water-based acrylic resin, and 10 points are stirred with 900r/min speed
Clock, then defoamer, levelling agent, substrate wetting agents are added successively, stirred 10 minutes with 1200r/min speed, be eventually adding step
Mixture obtained by rapid b, stirs；
Step d, water-compatible amino resin, aqueous anti-scribble resin is added sequentially in mixture obtained by step c, with 900r/min
Speed stir 10 minutes, then add thickener and remaining deionized water, stirred 10 minutes with 1000r/min speed,
Viscosity is adjusted to qualified.
The anti-scribble antitheft door sealing wax of the present embodiment and in the market solvent based product, the performance comparison of aqueous product, see below
Table.
Embodiment 3
A kind of anti-scribble antitheft door sealing wax, including raw material components and its percentage by weight it is as follows：
Water-based acrylic resin 65%
Water-compatible amino resin 10%
Aqueous anti-scribble resin 3%
Environmentally friendly solvent 1%
Nertralizer 0.1%
Defoamer 0.5%
Levelling agent 0.4%
Substrate wetting agents 0.5%
Adhesion promoter 0.5%
Deionized water 17%
Thickener 2%.
Wherein, water-based acrylic resin used is the product Antkote 2042 of ten thousand China's chemistry, water-compatible amino resin used
For the production CYMEL303 in TaiWan, China Changchun, aqueous anti-scribble resin used is that enlightening is high（TEGO）Product Protect 5100
N, adhesion promoter used is Lu Borun product Lubrizol 2063, and substrate wetting agents used are that enlightening is high（TEGO）Wet
KL245；Thickener used is product the TAFIGEL PUR40 and Tao Shi of bright icepro（DOW）Product ACRYSO LASE-60 press matter
Amount is than being 1：1 mixture, defoamer used is that enlightening is high（TEGO）Airex 902W and Bi Ke（BYK）Two kinds of BYK-028
Product is 5 in mass ratio：3 mixture, environmentally friendly solvent used is propylene glycol monomethyl ether.Nertralizer used is the AMP- of DOW Chemical
95, the PW336 that levelling agent used is first created for France.
The specific preparation method of the sealing wax is：
Step a, matches according to the raw material components, is first mixed environmentally friendly solvent, nertralizer, adds 50% in formula
Deionized water, is stirred 3 minutes with 500r/min speed, standby；
Step b, takes part steps a gained mixed liquors, it is mixed with adhesion promoter, adjustment mixed liquor pH value to 7-8, with
500r/min speed is stirred 3 minutes, standby；
Step c, water-based acrylic resin is added in pot of getting the raw materials ready, and is stirred 5 minutes with 500r/min speed, then by residue
Mixed liquor obtained by step a is added in pot of getting the raw materials ready, and is mixed with water-based acrylic resin, and 10 points are stirred with 900r/min speed
Clock, then defoamer, levelling agent, substrate wetting agents are added successively, stirred 10 minutes with 1200r/min speed, be eventually adding step
Mixture obtained by rapid b, stirs；
Step d, water-compatible amino resin, aqueous anti-scribble resin is added sequentially in mixture obtained by step c, with 900r/min
Speed stir 10 minutes, then add thickener and remaining deionized water, stirred 10 minutes with 1000r/min speed,
Viscosity is adjusted to qualified.
The anti-scribble antitheft door sealing wax of the present embodiment and in the market solvent based product, the performance comparison of aqueous product, see below
Table.
The anti-scribble antitheft door sealing wax that the present invention is provided is described in detail above, using specific case to this in the present invention
The embodiment of invention is set forth, and the explanation of above example is only intended to help and understands the present invention, it is noted that for
For those skilled in the art, under the premise without departing from the principles of the invention, some improvement can be also carried out to the present invention,
These improvement are also fallen into the protection domain of the claims in the present invention.
Claims (10)
1. a kind of anti-scribble antitheft door sealing wax, it is characterised in that as follows including raw material components and its percentage by weight：
65~70% water-based acrylic resin, 10~12% water-compatible amino resin, 3~5% aqueous anti-scribble resin, 1~2%
Environmentally friendly solvent, 0.1~0.2% nertralizer, 0.3~0.5% defoamer, 0.4~0.6% levelling agent, 0.3~0.5%
Substrate wetting agents, 0.5~1.0% adhesion promoter, 7~17% deionized water, 1~2% thickener；
The water-based acrylic resin is hydroxyl acrylic acid water dispersoid, and the water-compatible amino resin is complete methyl-etherified amino tree
Fat, the aqueous anti-scribble resin is the aqueous emulsion of dimethyl polysiloxane fluid of hydroxy functional groups.
2. anti-scribble antitheft door sealing wax according to claim 1, it is characterised in that the water-based acrylic resin is ten thousand China
The product Antkote 2042 of chemistry.
3. anti-scribble antitheft door sealing wax according to claim 1, it is characterised in that the water-compatible amino resin is Chinese platform
The product MR603 and/or CYMEL303 in gulf Changchun.
4. anti-scribble antitheft door sealing wax according to claim 1, it is characterised in that the aqueous anti-scribble resin is that enlightening is high
The N of product Protect 5100.
5. it is according to claim 1 it is anti-scribble antitheft door sealing wax, it is characterised in that the environmentally friendly solvent be propandiol butyl ether,
One or two in propylene glycol monomethyl ether, the adhesion promoter is polyester base phosphoric acid, and the substrate wetting agents are polyethers silicon
Siloxane copolymers, the thickener is the mixture of alkali swelling type thickener and polyurethane-type thickener.
6. anti-scribble antitheft door sealing wax according to claim 5, it is characterised in that the adhesion promoter is Lu Borun
Product Lubrizol 2063, the substrate wetting agents are the one or two in high Wet 270, the Wet KL245 of enlightening.
7. anti-scribble antitheft door sealing wax according to claim 5, it is characterised in that the polyurethane-type thickener is insulted to be bright
Product TAFIGEL PUR40, the alkali swelling type thickener be Tao Shi product ACRYSO LASE-60.
8. anti-scribble antitheft door sealing wax according to claim 1, it is characterised in that the defoamer is the high Airex of enlightening
The mixture of 902W and Bi Ke two kinds of products of BYK-028.
9. the preparation method of anti-scribble antitheft door sealing wax as any one of claim 1-8, it is characterised in that including as follows
Step：
Step a, matches according to the raw material components, first mixes environmentally friendly solvent, nertralizer, add the raw material components
50% deionized water, stirs in proportioning, standby；
Step b, takes part steps a gained mixed liquors, it is mixed with adhesion promoter, adjustment mixed liquor pH value is stirred to 7-8
Mix uniform, it is standby；
Step c, water-based acrylic resin is added in pot of getting the raw materials ready, stirred, and then adds mixed liquor obtained by remaining step a
Enter into pot of getting the raw materials ready, mixed with water-based acrylic resin, stirred, then add defoamer, levelling agent, base material wetting successively
Agent, stirs, and is eventually adding step b gained mixtures, stirs；
Step d, water-compatible amino resin, aqueous anti-scribble resin are added sequentially in mixture obtained by step c, stirred,
Then thickener and remaining deionized water are added, stirring, adjustment viscosity is to qualified.
10. according to claim 9 it is anti-scribble antitheft door sealing wax preparation method, it is characterised in that the speed of the stirring
For 500~1200r/min, the time stirred every time is 3~10min.
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| CN107556891A (en) * | 2017-09-18 | 2018-01-09 | 重庆三峡油漆股份有限公司 | A kind of Men Yeyong water-based finishing varnish |
| CN108456445A (en) * | 2018-01-26 | 2018-08-28 | 河北晨阳工贸集团有限公司 | A kind of reflection heat-insulating type automobile finiss and preparation method thereof |
| CN108610888A (en) * | 2018-03-14 | 2018-10-02 | 河北晨阳工贸集团有限公司 | A kind of metal surface sealing wax and preparation method thereof |
| CN109666320A (en) * | 2018-11-20 | 2019-04-23 | 河北晨阳工贸集团有限公司 | Aqueous amino-stoving varnish and preparation method thereof with resistance to acid and alkali and soil resistance |
| CN109913063A (en) * | 2019-01-29 | 2019-06-21 | 河北晨阳工贸集团有限公司 | A kind of anti-graffiti interior wall sealing wax of fluorescence and preparation method thereof |
| CN110591553A (en) * | 2019-09-29 | 2019-12-20 | 佛山市红树水性印涂材料有限公司 | Low-temperature-cured high-hardness wear-resistant water-based organic silicon coating and preparation method thereof |
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| CN107286770A (en) * | 2017-06-09 | 2017-10-24 | 河北晨阳工贸集团有限公司 | A kind of scrubbing resistance blackboard paint and preparation method thereof |
| CN107459892A (en) * | 2017-08-02 | 2017-12-12 | 河北晨阳工贸集团有限公司 | A kind of farm machinery baking vanish and preparation method thereof |
| CN107556891A (en) * | 2017-09-18 | 2018-01-09 | 重庆三峡油漆股份有限公司 | A kind of Men Yeyong water-based finishing varnish |
| CN108456445A (en) * | 2018-01-26 | 2018-08-28 | 河北晨阳工贸集团有限公司 | A kind of reflection heat-insulating type automobile finiss and preparation method thereof |
| CN108610888A (en) * | 2018-03-14 | 2018-10-02 | 河北晨阳工贸集团有限公司 | A kind of metal surface sealing wax and preparation method thereof |
| CN109666320A (en) * | 2018-11-20 | 2019-04-23 | 河北晨阳工贸集团有限公司 | Aqueous amino-stoving varnish and preparation method thereof with resistance to acid and alkali and soil resistance |
| CN109913063A (en) * | 2019-01-29 | 2019-06-21 | 河北晨阳工贸集团有限公司 | A kind of anti-graffiti interior wall sealing wax of fluorescence and preparation method thereof |
| CN110591553A (en) * | 2019-09-29 | 2019-12-20 | 佛山市红树水性印涂材料有限公司 | Low-temperature-cured high-hardness wear-resistant water-based organic silicon coating and preparation method thereof |
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