CN109551580A - 超疏水阻燃三聚氰胺板的制备方法 - Google Patents

超疏水阻燃三聚氰胺板的制备方法 Download PDF

Info

Publication number
CN109551580A
CN109551580A CN201811164047.6A CN201811164047A CN109551580A CN 109551580 A CN109551580 A CN 109551580A CN 201811164047 A CN201811164047 A CN 201811164047A CN 109551580 A CN109551580 A CN 109551580A
Authority
CN
China
Prior art keywords
parts
melamine plate
raw material
weight
super
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201811164047.6A
Other languages
English (en)
Other versions
CN109551580B (zh
Inventor
陆格珠
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nanjing Ailikesi Electronic Technology Co ltd
Original Assignee
Nanjing University of Aeronautics and Astronautics
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nanjing University of Aeronautics and Astronautics filed Critical Nanjing University of Aeronautics and Astronautics
Priority to CN201811164047.6A priority Critical patent/CN109551580B/zh
Publication of CN109551580A publication Critical patent/CN109551580A/zh
Application granted granted Critical
Publication of CN109551580B publication Critical patent/CN109551580B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27D—WORKING VENEER OR PLYWOOD
    • B27D5/00—Other working of veneer or plywood specially adapted to veneer or plywood
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/02—Processes; Apparatus
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/52—Impregnating agents containing mixtures of inorganic and organic compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02—Homopolymers or copolymers of hydrocarbons
    • C09D125/04—Homopolymers or copolymers of styrene
    • C09D125/08—Copolymers of styrene
    • C09D125/14—Copolymers of styrene with unsaturated esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/66—Salts, e.g. alums
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/20—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/16—Sizing or water-repelling agents
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/34—Ignifugeants
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
    • D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
    • D21H23/22—Addition to the formed paper
    • D21H23/32—Addition to the formed paper by contacting paper with an excess of material, e.g. from a reservoir or in a manner necessitating removal of applied excess material from the paper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K2240/00—Purpose of the treatment
    • B27K2240/30—Fireproofing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K2240/00—Purpose of the treatment
    • B27K2240/70—Hydrophobation treatment

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Forests & Forestry (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Reinforced Plastic Materials (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

本发明公开了一种超疏水阻燃三聚氰胺板的制备方法，属于板材领域。该方法包括以下步骤：步骤一，将三聚氰胺板用乙醇溶液洗涤，干燥，备用；步骤二，将苯丙乳液、玻璃纤维、藻酸丙二醇酯、氰尿酸三钠、钛酸丁酯混合均匀，升温至75～80℃，保持20～30min，冷却后，将三聚氰胺板浸入其中3～5h，取出，干燥；步骤三，将十六烷基三甲氧基硅烷、焦硫酸钠、吡咯烷酮羧酸钠、四硼酸钾和氨水混合，再次将三聚氰胺板浸入，浸入40～50min后，取出，干燥，即可。本发明具有以下有益效果：氰尿酸三钠的加入可以提高本发明的防水性能，接触角大于150°。吡咯烷酮羧酸钠对本发明三聚氰胺板的阻燃效果较好，防止火灾。

Description

超疏水阻燃三聚氰胺板的制备方法
技术领域
本发明属于板材领域，尤其涉及一种超疏水阻燃三聚氰胺板的制备方法。
背景技术
三聚氰胺板，是将带有不同颜色或纹理的纸放入三聚氰胺树脂胶粘剂中浸泡，然后干燥到一定固化程度，将其铺装在刨花板、防潮板、中密度纤维板、胶合板、细木工板、多层板或其他硬质纤维板表面，经热压而成的装饰板。在生产过程中，一般是由数层纸张组合而成，数量多少根据用途而定。
申请号为201810627334.X的中国专利申请公开了一种环保型生物质复合阻燃板材料。本发明以玉米秸秆和木材为原料，以氯化镁，硫酸镁、氧化镁和硅酸钠组成的水溶液为无机胶黏剂，采用热压工艺制备出环保型生物质复合阻燃板材料，本发明制备出的生物质复合阻燃板材料阻燃抑烟性能优异，制备出环保型生物质复合阻燃板材料点燃时间为410秒，符合高层建筑建材5-7min的要求，可用作为高层建筑材料，可以保障火灾中人员的安全疏散，降低了火灾危险。
发明内容
本发明提供了一种超疏水阻燃三聚氰胺板的制备方法，防水性能和阻燃性能均较好。
为了解决上述技术问题，本发明采用以下技术方案：
超疏水阻燃三聚氰胺板的制备方法，包括以下步骤：
步骤一，将三聚氰胺板用乙醇溶液洗涤，干燥，备用；
步骤二，将苯丙乳液、玻璃纤维、藻酸丙二醇酯、氰尿酸三钠、钛酸丁酯混合均匀，升温至75～80℃，保持20～30min，冷却后，将三聚氰胺板浸入其中3～5h，取出，干燥；所述原料按照重量份计：苯丙乳液200～230份、玻璃纤维40～80份、藻酸丙二醇酯40～50份、氰尿酸三钠10～20份和钛酸丁酯20～26份；
步骤三，将十六烷基三甲氧基硅烷、焦硫酸钠、吡咯烷酮羧酸钠、四硼酸钾和氨水混合，再次将三聚氰胺板浸入，浸入40～50min后，取出，干燥，即可；所述原料按照重量份计：十六烷基三甲氧基硅烷40～70份、焦硫酸钠34～37份、吡咯烷酮羧酸钠4～7份、四硼酸钾20～90份和氨水70～120份。
作为优选，步骤二所述原料按照重量份计，苯丙乳液210份、玻璃纤维60份、藻酸丙二醇酯45份、氰尿酸三钠15份和钛酸丁酯24份；步骤三所述原料按照重量份计，十六烷基三甲氧基硅烷60份、焦硫酸钠35份、吡咯烷酮羧酸钠6份、四硼酸钾50份和氨水100份。
作为优选，步骤二所述原料按照重量份计，苯丙乳液200份、玻璃纤维40份、藻酸丙二醇酯40份、氰尿酸三钠10份和钛酸丁酯20份；步骤三所述原料按照重量份计，十六烷基三甲氧基硅烷70份、焦硫酸钠37份、吡咯烷酮羧酸钠7份、四硼酸钾90份和氨水120份。
作为优选，步骤二所述原料按照重量份计，苯丙乳液200份、玻璃纤维40份、藻酸丙二醇酯40份、氰尿酸三钠10份和钛酸丁酯20份；步骤三所述原料按照重量份计，十六烷基三甲氧基硅烷40份、焦硫酸钠34份、吡咯烷酮羧酸钠4份、四硼酸钾20份和氨水70份。
作为优选，步骤二所述原料按照重量份计，苯丙乳液210份、玻璃纤维50份、藻酸丙二醇酯43份、氰尿酸三钠13份和钛酸丁酯22份；步骤三所述原料按照重量份计，十六烷基三甲氧基硅烷45份、焦硫酸钠36份、吡咯烷酮羧酸钠5份、四硼酸钾79份和氨水80份。
作为优选，氨水的质量浓度为25％～30％。
作为优选，乙醇溶液的质量浓度为30～80％。
本发明具有以下有益效果：氰尿酸三钠的加入可以提高本发明的防水性能，接触角大于150°。吡咯烷酮羧酸钠对本发明三聚氰胺板的阻燃效果较好，防止火灾。
具体实施方式
下面结合具体实施例对本发明作进一步详细介绍。
实施例1
超疏水阻燃三聚氰胺板的制备方法，包括以下步骤：
步骤一，将三聚氰胺板用质量浓度为40％的乙醇溶液洗涤，干燥，备用；
步骤二，将苯丙乳液、玻璃纤维、藻酸丙二醇酯、氰尿酸三钠、钛酸丁酯混合均匀，升温至75～80℃，保持25min，冷却后，将三聚氰胺板浸入其中4h，取出，干燥；
步骤三，将十六烷基三甲氧基硅烷、焦硫酸钠、吡咯烷酮羧酸钠、四硼酸钾和质量浓度为25％～30％的氨水混合，再次将三聚氰胺板浸入，浸入45min后，取出，干燥，即可；
步骤二所述原料按照重量份计，苯丙乳液210份、玻璃纤维60份、藻酸丙二醇酯45份、氰尿酸三钠15份和钛酸丁酯24份；步骤三所述原料按照重量份计，十六烷基三甲氧基硅烷60份、焦硫酸钠35份、吡咯烷酮羧酸钠6份、四硼酸钾50份和氨水100份。
实施例2
超疏水阻燃三聚氰胺板的制备方法，包括以下步骤：
步骤一，将三聚氰胺板用质量浓度为30％的乙醇溶液洗涤，干燥，备用；
步骤二，将苯丙乳液、玻璃纤维、藻酸丙二醇酯、氰尿酸三钠、钛酸丁酯混合均匀，升温至75～80℃，保持20min，冷却后，将三聚氰胺板浸入其中3h，取出，干燥；
步骤三，将十六烷基三甲氧基硅烷、焦硫酸钠、吡咯烷酮羧酸钠、四硼酸钾和质量浓度为25％的氨水混合，再次将三聚氰胺板浸入，浸入40min后，取出，干燥，即可；
步骤二所述原料按照重量份计，苯丙乳液200份、玻璃纤维40份、藻酸丙二醇酯40份、氰尿酸三钠10份和钛酸丁酯20份；步骤三所述原料按照重量份计，十六烷基三甲氧基硅烷70份、焦硫酸钠37份、吡咯烷酮羧酸钠7份、四硼酸钾90份和氨水120份。
实施例3
超疏水阻燃三聚氰胺板的制备方法，包括以下步骤：
步骤一，将三聚氰胺板用质量浓度为80％的乙醇溶液洗涤，干燥，备用；
步骤二，将苯丙乳液、玻璃纤维、藻酸丙二醇酯、氰尿酸三钠、钛酸丁酯混合均匀，升温至75～80℃，保持30min，冷却后，将三聚氰胺板浸入其中5h，取出，干燥；
步骤三，将十六烷基三甲氧基硅烷、焦硫酸钠、吡咯烷酮羧酸钠、四硼酸钾和质量浓度为30％的氨水混合，再次将三聚氰胺板浸入，浸入50min后，取出，干燥，即可；
步骤二所述原料按照重量份计，苯丙乳液200份、玻璃纤维40份、藻酸丙二醇酯40份、氰尿酸三钠10份和钛酸丁酯20份；步骤三所述原料按照重量份计，十六烷基三甲氧基硅烷40份、焦硫酸钠34份、吡咯烷酮羧酸钠4份、四硼酸钾20份和氨水70份。
实施例4
超疏水阻燃三聚氰胺板的制备方法，包括以下步骤：
步骤一，将三聚氰胺板用质量浓度为60％的乙醇溶液洗涤，干燥，备用；
步骤二，将苯丙乳液、玻璃纤维、藻酸丙二醇酯、氰尿酸三钠、钛酸丁酯混合均匀，升温至75～80℃，保持22min，冷却后，将三聚氰胺板浸入其中4h，取出，干燥；
步骤三，将十六烷基三甲氧基硅烷、焦硫酸钠、吡咯烷酮羧酸钠、四硼酸钾和质量浓度为28％的氨水混合，再次将三聚氰胺板浸入，浸入43min后，取出，干燥，即可；
步骤二所述原料按照重量份计，苯丙乳液210份、玻璃纤维50份、藻酸丙二醇酯43份、氰尿酸三钠13份和钛酸丁酯22份；步骤三所述原料按照重量份计，十六烷基三甲氧基硅烷45份、焦硫酸钠36份、吡咯烷酮羧酸钠5份、四硼酸钾79份和氨水80份。
对照例1
与实施例1的区别在于：未加氰尿酸三钠。
超疏水阻燃三聚氰胺板的制备方法，包括以下步骤：
步骤一，将三聚氰胺板用质量浓度为40％的乙醇溶液洗涤，干燥，备用；
步骤二，将苯丙乳液、玻璃纤维、藻酸丙二醇酯、氰尿酸三钠、钛酸丁酯混合均匀，升温至75～80℃，保持25min，冷却后，将三聚氰胺板浸入其中4h，取出，干燥；
步骤三，将十六烷基三甲氧基硅烷、焦硫酸钠、吡咯烷酮羧酸钠、四硼酸钾和质量浓度为25％～30％的氨水混合，再次将三聚氰胺板浸入，浸入45min后，取出，干燥，即可；
步骤二所述原料按照重量份计，苯丙乳液210份、玻璃纤维60份、藻酸丙二醇酯45份、氰尿酸三钠15份和钛酸丁酯24份；步骤三所述原料按照重量份计，十六烷基三甲氧基硅烷60份、焦硫酸钠35份、吡咯烷酮羧酸钠6份、四硼酸钾50份和氨水100份。
对照例2
与实施例2的区别在于：未加吡咯烷酮羧酸钠。
超疏水阻燃三聚氰胺板的制备方法，包括以下步骤：
步骤一，将三聚氰胺板用质量浓度为30％的乙醇溶液洗涤，干燥，备用；
步骤二，将苯丙乳液、玻璃纤维、藻酸丙二醇酯、氰尿酸三钠、钛酸丁酯混合均匀，升温至75～80℃，保持20min，冷却后，将三聚氰胺板浸入其中3h，取出，干燥；
步骤三，将十六烷基三甲氧基硅烷、焦硫酸钠、四硼酸钾和质量浓度为25％的氨水混合，再次将三聚氰胺板浸入，浸入40min后，取出，干燥，即可；
步骤二所述原料按照重量份计，苯丙乳液200份、玻璃纤维40份、藻酸丙二醇酯40份、氰尿酸三钠10份和钛酸丁酯20份；步骤三所述原料按照重量份计，十六烷基三甲氧基硅烷70份、焦硫酸钠37份、四硼酸钾90份和氨水120份。
测试本发明的接触角和极限氧指数：
从表中可以看出，氰尿酸三钠的加入可以提高本发明的防水性能，接触角大于150°。吡咯烷酮羧酸钠对本发明三聚氰胺板的阻燃效果较好，防止火灾。
以上所述，仅为本发明较佳的具体实施方案，本发明的保护范围不限于此，任何熟悉本技术领域的技术人员在本发明披露的技术范围内，可显而易见地得到的技术方案的简单变化或等效替换均落入本发明的保护范围内。

Claims (7)

1.超疏水阻燃三聚氰胺板的制备方法，其特征在于，包括以下步骤：
步骤一，将三聚氰胺板用乙醇溶液洗涤，干燥，备用；
步骤二，将苯丙乳液、玻璃纤维、藻酸丙二醇酯、氰尿酸三钠、钛酸丁酯混合均匀，升温至75～80℃，保持20～30min，冷却后，将三聚氰胺板浸入其中3～5h，取出，干燥；所述原料按照重量份计：苯丙乳液200～230份、玻璃纤维40～80份、藻酸丙二醇酯40～50份、氰尿酸三钠10～20份和钛酸丁酯20～26份；
步骤三，将十六烷基三甲氧基硅烷、焦硫酸钠、吡咯烷酮羧酸钠、四硼酸钾和氨水混合，再次将三聚氰胺板浸入，浸入40～50min后，取出，干燥，即可；所述原料按照重量份计：十六烷基三甲氧基硅烷40～70份、焦硫酸钠34～37份、吡咯烷酮羧酸钠4～7份、四硼酸钾20～90份和氨水70～120份。
2.根据权利要求1所述的超疏水阻燃三聚氰胺板的制备方法，其特征在于，步骤二所述原料按照重量份计，苯丙乳液210份、玻璃纤维60份、藻酸丙二醇酯45份、氰尿酸三钠15份和钛酸丁酯24份；步骤三所述原料按照重量份计，十六烷基三甲氧基硅烷60份、焦硫酸钠35份、吡咯烷酮羧酸钠6份、四硼酸钾50份和氨水100份。
3.根据权利要求1所述的超疏水阻燃三聚氰胺板的制备方法，其特征在于，步骤二所述原料按照重量份计，苯丙乳液200份、玻璃纤维40份、藻酸丙二醇酯40份、氰尿酸三钠10份和钛酸丁酯20份；步骤三所述原料按照重量份计，十六烷基三甲氧基硅烷70份、焦硫酸钠37份、吡咯烷酮羧酸钠7份、四硼酸钾90份和氨水120份。
4.根据权利要求1所述的超疏水阻燃三聚氰胺板的制备方法，其特征在于，步骤二所述原料按照重量份计，苯丙乳液200份、玻璃纤维40份、藻酸丙二醇酯40份、氰尿酸三钠10份和钛酸丁酯20份；步骤三所述原料按照重量份计，十六烷基三甲氧基硅烷40份、焦硫酸钠34份、吡咯烷酮羧酸钠4份、四硼酸钾20份和氨水70份。
5.根据权利要求1所述的超疏水阻燃三聚氰胺板的制备方法，其特征在于，步骤二所述原料按照重量份计，苯丙乳液210份、玻璃纤维50份、藻酸丙二醇酯43份、氰尿酸三钠13份和钛酸丁酯22份；步骤三所述原料按照重量份计，十六烷基三甲氧基硅烷45份、焦硫酸钠36份、吡咯烷酮羧酸钠5份、四硼酸钾79份和氨水80份。
6.根据权利要求1所述的超疏水阻燃三聚氰胺板的制备方法，其特征在于，氨水的质量浓度为25％～30％。
7.根据权利要求1所述的超疏水阻燃三聚氰胺板的制备方法，其特征在于，乙醇溶液的质量浓度为30～80％。
CN201811164047.6A 2018-10-04 2018-10-04 超疏水阻燃三聚氰胺板的制备方法 Active CN109551580B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811164047.6A CN109551580B (zh) 2018-10-04 2018-10-04 超疏水阻燃三聚氰胺板的制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811164047.6A CN109551580B (zh) 2018-10-04 2018-10-04 超疏水阻燃三聚氰胺板的制备方法

Publications (2)

Publication Number Publication Date
CN109551580A true CN109551580A (zh) 2019-04-02
CN109551580B CN109551580B (zh) 2023-06-23

Family

ID=65864710

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201811164047.6A Active CN109551580B (zh) 2018-10-04 2018-10-04 超疏水阻燃三聚氰胺板的制备方法

Country Status (1)

Country Link
CN (1) CN109551580B (zh)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101439524A (zh) * 2008-12-29 2009-05-27 张友全 一种三聚氰胺饰面板及其制备方法
JP2011005792A (ja) * 2009-06-29 2011-01-13 Aica Kogyo Co Ltd 不燃性メラミン化粧板
CN102821957A (zh) * 2010-03-23 2012-12-12 爱克工业株式会社 三聚氰胺装饰板
CN104859000A (zh) * 2014-12-25 2015-08-26 王玉燕 一种高性能环保增强阻燃防腐木材的生产方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101439524A (zh) * 2008-12-29 2009-05-27 张友全 一种三聚氰胺饰面板及其制备方法
JP2011005792A (ja) * 2009-06-29 2011-01-13 Aica Kogyo Co Ltd 不燃性メラミン化粧板
CN102821957A (zh) * 2010-03-23 2012-12-12 爱克工业株式会社 三聚氰胺装饰板
US20130011641A1 (en) * 2010-03-23 2013-01-10 Aica Kogyo Co., Ltd. Melamine Decorative Board
CN104859000A (zh) * 2014-12-25 2015-08-26 王玉燕 一种高性能环保增强阻燃防腐木材的生产方法

Also Published As

Publication number Publication date
CN109551580B (zh) 2023-06-23

Similar Documents

Publication Publication Date Title
CN111253075B (zh) 一种岩棉产品及其制备方法
CN109881528B (zh) 一种利用阻燃植物纤维制备的阻燃装饰原纸及其制备方法
CN103878847A (zh) 一种难燃木材及其制备方法和应用
WO2014015818A1 (zh) 一种环保型建材及其制备方法
CN105108868A (zh) 利用废旧室内用热处理木材制备刨花板的方法及刨花板
KR101706226B1 (ko) 방염패널 제조방법
CN112300737A (zh) 环保阻燃型饰面装饰纸
CN111116100A (zh) 一种抗菌阻燃石英板材制备方法
CN105040848A (zh) 一种制备防火板的方法
CN108972751A (zh) 环保无醛阻燃剂及人造板加工方法
CN109551580A (zh) 超疏水阻燃三聚氰胺板的制备方法
CN109535689A (zh) 一种聚氨酯仿木材料用核壳型阻燃剂及制备方法
CN110355845B (zh) 一种增强、阻燃炭化橡胶木板材的制备方法
CN107446504A (zh) 一种饰面层材料及其制备方法
CN108927860A (zh) 一种人造胶合板的加工方法
CN206048946U (zh) 一种结构型复合材料板
CN108943250A (zh) 一种人造刨花板的加工方法
CN108972785A (zh) 木材环保无醛阻燃剂
CN102717418A (zh) 一种高强耐水纤维板的制造方法
CN109235118A (zh) 一种阻燃防水玻璃纤维增强装饰板的制备方法
CN106833259B (zh) 一种塑料表面阻燃涂层及其制备方法
CN111285659A (zh) 防火复合板基材及防火复合板基材制备方法与防火复合板
CN109535461A (zh) 一种用于塑料表面的梯度阻燃涂层的制备方法
CN112661478B (zh) 一种耐火抗折竹纤维板及其制备方法
CN108676187A (zh) 一种快装防火顶墙板的制备方法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
TA01 Transfer of patent application right
TA01 Transfer of patent application right

Effective date of registration: 20230601

Address after: Room A06, Zhongchuang District, Xingang Maker Space, Building B1, Huizhi Science and Technology Park, No. 8 Hengtai Road, Nanjing Economic and Technological Development Zone, Jiangsu Province, 210000

Applicant after: NANJING AILIKESI ELECTRONIC TECHNOLOGY Co.,Ltd.

Address before: Lishui industrial new town science and technology innovation center, Lishui Economic Development Zone, Nanjing, Jiangsu Province

Applicant before: NANJING AEROSPACE UNIVERSITY LISHUI IMITATION PRODUCTION INDUSTRY RESEARCH INSTITUTE Co.,Ltd.

GR01 Patent grant
GR01 Patent grant