CN109529576B - 一种烟气低温脱硫脱硝喷淋洗涤塔 - Google Patents
一种烟气低温脱硫脱硝喷淋洗涤塔 Download PDFInfo
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- CN109529576B CN109529576B CN201811650127.2A CN201811650127A CN109529576B CN 109529576 B CN109529576 B CN 109529576B CN 201811650127 A CN201811650127 A CN 201811650127A CN 109529576 B CN109529576 B CN 109529576B
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- flue gas
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- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title claims abstract description 104
- 239000003546 flue gas Substances 0.000 title claims abstract description 104
- 238000006477 desulfuration reaction Methods 0.000 title claims abstract description 63
- 230000023556 desulfurization Effects 0.000 title claims abstract description 63
- 239000007921 spray Substances 0.000 title claims abstract description 49
- 238000001816 cooling Methods 0.000 claims abstract description 30
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 29
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- 230000003009 desulfurizing effect Effects 0.000 claims abstract description 23
- 238000012856 packing Methods 0.000 claims abstract description 22
- 238000005406 washing Methods 0.000 claims abstract description 17
- 239000000779 smoke Substances 0.000 claims abstract description 16
- 238000002156 mixing Methods 0.000 claims abstract description 15
- 229910021529 ammonia Inorganic materials 0.000 claims abstract description 12
- 230000003197 catalytic effect Effects 0.000 claims abstract description 12
- 238000005507 spraying Methods 0.000 claims abstract description 11
- 239000007789 gas Substances 0.000 claims abstract description 7
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims abstract description 3
- 235000011941 Tilia x europaea Nutrition 0.000 claims abstract description 3
- 239000004571 lime Substances 0.000 claims abstract description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 59
- 238000001179 sorption measurement Methods 0.000 claims description 36
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 14
- 229910052799 carbon Inorganic materials 0.000 claims description 9
- 230000001681 protective effect Effects 0.000 claims description 5
- 241000208125 Nicotiana Species 0.000 claims description 4
- 235000002637 Nicotiana tabacum Nutrition 0.000 claims description 4
- 239000000428 dust Substances 0.000 description 13
- 230000000694 effects Effects 0.000 description 11
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 6
- 238000010521 absorption reaction Methods 0.000 description 5
- 239000000945 filler Substances 0.000 description 5
- 238000011049 filling Methods 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 4
- 238000007789 sealing Methods 0.000 description 4
- 239000002250 absorbent Substances 0.000 description 3
- 230000002745 absorbent Effects 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 230000002035 prolonged effect Effects 0.000 description 3
- 238000000746 purification Methods 0.000 description 3
- 239000011362 coarse particle Substances 0.000 description 2
- TXKMVPPZCYKFAC-UHFFFAOYSA-N disulfur monoxide Inorganic materials O=S=S TXKMVPPZCYKFAC-UHFFFAOYSA-N 0.000 description 2
- 239000003344 environmental pollutant Substances 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 231100000719 pollutant Toxicity 0.000 description 2
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical compound S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000004523 catalytic cracking Methods 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/75—Multi-step processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D47/00—Separating dispersed particles from gases, air or vapours by liquid as separating agent
- B01D47/06—Spray cleaning
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D47/00—Separating dispersed particles from gases, air or vapours by liquid as separating agent
- B01D47/14—Packed scrubbers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D50/00—Combinations of methods or devices for separating particles from gases or vapours
- B01D50/60—Combinations of devices covered by groups B01D46/00 and B01D47/00
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/50—Sulfur oxides
- B01D53/501—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
- B01D53/502—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound characterised by a specific solution or suspension
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/77—Liquid phase processes
- B01D53/78—Liquid phase processes with gas-liquid contact
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8621—Removing nitrogen compounds
- B01D53/8625—Nitrogen oxides
- B01D53/8631—Processes characterised by a specific device
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/90—Injecting reactants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/20—Reductants
- B01D2251/206—Ammonium compounds
- B01D2251/2062—Ammonia
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/40—Alkaline earth metal or magnesium compounds
- B01D2251/404—Alkaline earth metal or magnesium compounds of calcium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/02—Other waste gases
- B01D2258/0283—Flue gases
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Treating Waste Gases (AREA)
Abstract
Description
Claims (7)
Priority Applications (1)
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CN201811650127.2A CN109529576B (zh) | 2018-12-31 | 2018-12-31 | 一种烟气低温脱硫脱硝喷淋洗涤塔 |
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CN201811650127.2A CN109529576B (zh) | 2018-12-31 | 2018-12-31 | 一种烟气低温脱硫脱硝喷淋洗涤塔 |
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CN109529576A CN109529576A (zh) | 2019-03-29 |
CN109529576B true CN109529576B (zh) | 2024-03-22 |
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Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN110772983A (zh) * | 2019-11-11 | 2020-02-11 | 中国科学院山西煤炭化学研究所 | 一种烟气低温脱硝的装置及方法 |
CN111974130B (zh) * | 2020-08-12 | 2022-01-28 | 西昌市蓝鼎环保科技有限公司 | 一种可加快处理速率的化工废气预处理装置 |
CN112473349A (zh) * | 2020-11-06 | 2021-03-12 | 马鞍山科宇环境工程有限公司 | 一种化工厂烟气脱硫脱硝除尘设备 |
CN113828154A (zh) * | 2021-10-29 | 2021-12-24 | 宜兴市苏哈电力设备有限公司 | 一种占地面积小的烟气脱硫脱硝处理装置 |
CN117861370A (zh) * | 2023-02-21 | 2024-04-12 | 吴德明 | 一种用于回收废气的脱硫脱硝装置 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH1119468A (ja) * | 1997-07-07 | 1999-01-26 | Mitsubishi Heavy Ind Ltd | ガス精製方法 |
CN204502755U (zh) * | 2015-03-31 | 2015-07-29 | 武汉钢铁(集团)公司 | 一种湿法脱除烟气中二氧化硫和氮氧化物的装置 |
CN204891568U (zh) * | 2015-08-18 | 2015-12-23 | 江苏一同环保工程技术有限公司 | 锅炉烟气一体化分布式脱硫脱硝装置 |
CN210251824U (zh) * | 2018-12-31 | 2020-04-07 | 南京格洛特环境工程股份有限公司 | 一种烟气低温脱硫脱硝喷淋洗涤塔 |
-
2018
- 2018-12-31 CN CN201811650127.2A patent/CN109529576B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH1119468A (ja) * | 1997-07-07 | 1999-01-26 | Mitsubishi Heavy Ind Ltd | ガス精製方法 |
CN204502755U (zh) * | 2015-03-31 | 2015-07-29 | 武汉钢铁(集团)公司 | 一种湿法脱除烟气中二氧化硫和氮氧化物的装置 |
CN204891568U (zh) * | 2015-08-18 | 2015-12-23 | 江苏一同环保工程技术有限公司 | 锅炉烟气一体化分布式脱硫脱硝装置 |
CN210251824U (zh) * | 2018-12-31 | 2020-04-07 | 南京格洛特环境工程股份有限公司 | 一种烟气低温脱硫脱硝喷淋洗涤塔 |
Non-Patent Citations (1)
Title |
---|
烟气脱硫除尘的新解决方案――文氏棒塔洗涤技术;孙国刚;王晓晗;王新成;张玉明;;炼油技术与工程(第04期);第20-23页 * |
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Inventor after: Ma Junjun Inventor after: Han Zhengchang Inventor after: Sun Hao Inventor after: Tao Zhihui Inventor after: Huang Haifeng Inventor after: Zhu Jiaming Inventor after: Zhang Shoubing Inventor after: Han Feng Inventor after: Wu Chuanbao Inventor before: Han Zhengchang Inventor before: Ma Junjun Inventor before: Sun Hao Inventor before: Tao Zhihui Inventor before: Huang Haifeng Inventor before: Zhu Jiaming Inventor before: Zhang Shoubing Inventor before: Han Feng Inventor before: Wu Chuanbao |
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