CN109504173A - A kind of printing ink of high adhesion and preparation method thereof - Google Patents
A kind of printing ink of high adhesion and preparation method thereof Download PDFInfo
- Publication number
- CN109504173A CN109504173A CN201811416045.1A CN201811416045A CN109504173A CN 109504173 A CN109504173 A CN 109504173A CN 201811416045 A CN201811416045 A CN 201811416045A CN 109504173 A CN109504173 A CN 109504173A
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- parts
- ink
- high adhesion
- printing ink
- resin
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/033—Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The present invention provides a kind of printing ink and preparation method thereof of high adhesion, is related to printing ink processing technique field.The printing ink of the high adhesion is made of raw material from the following weight: 12-16 parts of acrylic resin, alcohol is polyurethane solutions 8-10 parts molten, 6-10 parts of terpene resin, 2-4 parts of ethyl acetate, 2-6 parts of vinyl chloride-vinyl acetate resin, 12-18 parts of isopropanol, 12-16 parts of pigment, 1-3 parts of thickener, 0.6-1.4 parts of anti skinning agent, 4-6 parts of filler, 1-2 parts of counnter attack ink, 0.4-0.8 parts of dispersing agent.Preparation method specifically includes that mixed dissolution, high-speed stirred, ultrasonic homogeneous.The present invention overcomes the deficiencies in the prior art, traditional ink is improved to the adhesion of printable fabric, and make not easily to fall off after ink setting, have many advantages, such as good practicability, while also there is safety and environmental protection, pollution-free, be suitble to promote producing and using.
Description
Technical field
The present invention relates to printing ink processing technique fields, and in particular to a kind of printing ink of high adhesion and its preparation
Method.
Background technique
Ink is important materials used for printing packaging materials, it is expressed the pattern and text on stock by printing
It include main component and auxiliary element in ink, they equably mix and form a kind of sticky colloidal fluid through repeat-rolling.
Printing ink is by the evenly dispersed pulpous state colloid mixed of the materials such as colorant, link stuff and auxiliary agent and solvent.Solvent type oil
The binder of ink is made of hard resin and a large amount of volatile organic solvents.It is after hard resin is dissolved in solvent, colorant is equal
Even to be dispersed in binder, ink is printed to printed medium, the rapid volatile dry conjunctiva of solvent.For ink, it is typically desirable to
Use the aesthetic effect and the printing characteristic that keeps for a long time that pleasant can be generated while shown on printed medium.These
The example of printing characteristic includes press quality, such as optical density (OD), coloration；And durability, such as water resistance, fade resistance, hold
Long property, the marker pen of resistance to bronsted lowry acids and bases bronsted lowry smear.
In the prior art, for the ink of printing, adhesive force is not strong, and pigment is easy to fall off, applicable limited material；Its
The toxicity such as a large amount of benzene class, ketone stronger solvent is used when preparation, during Printing ink producing when solvent is dealt with improperly,
It is easy to damage the body of direct labor, when ink is for when printing, the volatilization of ink Poisoning solvent also can be to printing
The body of worker generates certain injury, can also remain a certain amount of solvent on printed matter, certainly will also influence whether that printed matter makes
The health of user.
Summary of the invention
In view of the shortcomings of the prior art, the present invention provides a kind of printing ink and preparation method thereof of high adhesion, improve
Traditional ink makes not easily to fall off after ink setting to the adhesion of printable fabric, has good practicability, while also having
There are safety and environmental protection, pollution-free, suitable popularization production and application.
In order to achieve the above object, technical solution of the present invention is achieved by the following technical programs:
A kind of printing ink of high adhesion, the printing ink of the high adhesion are made of raw material from the following weight: propylene
12-16 parts of acid resin, alcohol is polyurethane solutions 8-10 parts molten, 6-10 parts of terpene resin, 2-4 parts of ethyl acetate, vinyl chloride-vinyl acetate resin 2-6
Part, 12-18 parts of isopropanol, 12-16 parts of pigment, 1-3 parts of thickener, 0.6-1.4 parts of anti skinning agent, 4-6 parts of filler, anti-reverse-printed
1-2 parts of agent, 0.4-0.8 parts of dispersing agent.
Preferably, the printing ink for stating high adhesion is made of raw material from the following weight: 14 parts of acrylic resin, alcohol are molten
9 parts of polyurethane solutions, 8 parts of terpene resin, 3 parts of ethyl acetate, 4 parts of vinyl chloride-vinyl acetate resin, 16 parts of isopropanol, 14 parts of pigment, thickener 2
Part, 1 part of anti skinning agent, 5 parts of filler, 1.5 parts of counnter attack ink, 0.6 part of dispersing agent.
Preferably, the anti skinning agent is the mixture of ferrous sulfate and thio-2 acid dibasic acid esters mass ratio 2: 1.
Preferably, the filler is the mixture of calcium carbonate, talcum powder and aluminium hydroxide mass ratio 4: 1: 1.
Preferably, the counnter attack ink is cornstarch.
Preferably, the dispersing agent is triethyl group hexyl phosphoric acid, lauryl sodium sulfate, methyl anyl alcohol, cellulose derive
Any one in object.
The preparation method of the ink the following steps are included:
(1) liquid is dissolved by heating into reaction kettle after mixing acrylic resin, terpene resin and the molten polyurethane solutions of alcohol
Body resin, it is rear spare；
(2) aforesaid liquid resin is mixed with ethyl acetate and vinyl chloride-vinyl acetate resin and pigment, at a temperature of 25 DEG C, in blender
In 50-80min stirred with the revolving speed of 200-300r/min, it is spare mill base must to be dyed；
(3) above-mentioned dyeing mill base is kept the temperature 25 DEG C after isopropanol, filler and dispersant, with turning for 500-600r/min
Speed stirring 40-60min, it is spare to obtain mixed slurry；
(4) above-mentioned mixed slurry is added after thickener, anti skinning agent and counnter attack ink mix and carries out homogeneous in homogenizer, then
Filtering and impurity removing obtains of the invention with ink.
Preferably, the homogeneous manner is ultrasonic vibration homogeneous, power 400-500W, homogenizing time 20-30min.
The present invention provides a kind of printing ink and preparation method thereof of high adhesion, and advantage is compared with prior art:
(1) it is main base that the present invention, which selects acrylic resin, the molten polyurethane solutions of alcohol and terpene resin, is mutually mixed, can have
Effect promotes the adhesion of product, enhances ink quality.
(2) present invention first by acrylic resin, the molten polyurethane solutions of alcohol and the terpene resin heat of mixing melt into liquid resin it
It is mixed again with other materials afterwards, efficiency enhances the stability of product.
(3) present invention can effectively promote the comprehensive performance of ink added with each substances such as ethyl acetate, vinyl chloride-vinyl acetate resins,
Make not easily to fall off after ink setting, and each adding ingredient safety non-pollution simultaneously, meets environmental protection concept.
Specific embodiment
In order to make the object, technical scheme and advantages of the embodiment of the invention clearer, below with reference to the embodiment of the present invention pair
Technical solution in the embodiment of the present invention is clearly and completely described, it is clear that described embodiment is a part of the invention
Embodiment, instead of all the embodiments.Based on the embodiments of the present invention, those of ordinary skill in the art are not making wound
Every other embodiment obtained under the premise of the property made labour, shall fall within the protection scope of the present invention.
Embodiment 1:
A kind of printing ink of high adhesion, the printing ink of the high adhesion are made of raw material from the following weight: propylene
8 parts of the molten polyurethane solutions of 12 parts of acid resin, alcohol, 6 parts of terpene resin, 2 parts of ethyl acetate, 2 parts of vinyl chloride-vinyl acetate resin, 12 parts of isopropanol,
12 parts of pigment, 1 part of thickener, 0.6 part of anti skinning agent, 4 parts of filler, 1 part of counnter attack ink, 0.4 part of dispersing agent.
Wherein, the anti skinning agent is the mixture of ferrous sulfate and thio-2 acid dibasic acid esters mass ratio 2: 1；The filling
Agent is the mixture of calcium carbonate, talcum powder and aluminium hydroxide mass ratio 4: 1: 1；The counnter attack ink is cornstarch；Described point
Powder is triethyl group hexyl phosphoric acid, lauryl sodium sulfate, methyl anyl alcohol, any one in cellulose derivative.
The preparation method of the ink the following steps are included:
(1) liquid is dissolved by heating into reaction kettle after mixing acrylic resin, terpene resin and the molten polyurethane solutions of alcohol
Body resin, it is rear spare；
(2) aforesaid liquid resin is mixed with ethyl acetate and vinyl chloride-vinyl acetate resin and pigment, at a temperature of 25 DEG C, in blender
In 50-80min stirred with the revolving speed of 200-300r/min, it is spare mill base must to be dyed；
(3) above-mentioned dyeing mill base is kept the temperature 25 DEG C after isopropanol, filler and dispersant, with turning for 500-600r/min
Speed stirring 40-60min, it is spare to obtain mixed slurry；
(4) above-mentioned mixed slurry is added after thickener, anti skinning agent and counnter attack ink mix and carries out homogeneous in homogenizer, then
Filtering and impurity removing obtains of the invention with ink.
The homogeneous manner is ultrasonic vibration homogeneous, power 400-500W, homogenizing time 20-30min.
Embodiment 2:
A kind of printing ink of high adhesion, the printing ink of the high adhesion are made of raw material from the following weight: propylene
10 parts of the molten polyurethane solutions of 16 parts of acid resin, alcohol, 10 parts of terpene resin, 4 parts of ethyl acetate, 6 parts of vinyl chloride-vinyl acetate resin, isopropanol 18
Part, 16 parts of pigment, 3 parts of thickener, 1.4 parts of anti skinning agent, 6 parts of filler, 2 parts of counnter attack ink, 0.8 part of dispersing agent.
Wherein, the anti skinning agent is the mixture of ferrous sulfate and thio-2 acid dibasic acid esters mass ratio 2: 1；The filling
Agent is the mixture of calcium carbonate, talcum powder and aluminium hydroxide mass ratio 4: 1: 1；The counnter attack ink is cornstarch；Described point
Powder is triethyl group hexyl phosphoric acid, lauryl sodium sulfate, methyl anyl alcohol, any one in cellulose derivative.
The preparation method of the ink the following steps are included:
(1) liquid is dissolved by heating into reaction kettle after mixing acrylic resin, terpene resin and the molten polyurethane solutions of alcohol
Body resin, it is rear spare；
(2) aforesaid liquid resin is mixed with ethyl acetate and vinyl chloride-vinyl acetate resin and pigment, at a temperature of 25 DEG C, in blender
In 50-80min stirred with the revolving speed of 200-300r/min, it is spare mill base must to be dyed；
(3) above-mentioned dyeing mill base is kept the temperature 25 DEG C after isopropanol, filler and dispersant, with turning for 500-600r/min
Speed stirring 40-60min, it is spare to obtain mixed slurry；
(4) above-mentioned mixed slurry is added after thickener, anti skinning agent and counnter attack ink mix and carries out homogeneous in homogenizer, then
Filtering and impurity removing obtains of the invention with ink.
The homogeneous manner is ultrasonic vibration homogeneous, power 400-500W, homogenizing time 20-30min.
Embodiment 3:
A kind of printing ink of high adhesion, the printing ink of the high adhesion are made of raw material from the following weight: propylene
9 parts of the molten polyurethane solutions of 14 parts of acid resin, alcohol, 8 parts of terpene resin, 3 parts of ethyl acetate, 4 parts of vinyl chloride-vinyl acetate resin, 16 parts of isopropanol,
14 parts of pigment, 2 parts of thickener, 1 part of anti skinning agent, 5 parts of filler, 1.5 parts of counnter attack ink, 0.6 part of dispersing agent.
Wherein, the anti skinning agent is the mixture of ferrous sulfate and thio-2 acid dibasic acid esters mass ratio 2: 1；The filling
Agent is the mixture of calcium carbonate, talcum powder and aluminium hydroxide mass ratio 4: 1: 1；The counnter attack ink is cornstarch；Described point
Powder is triethyl group hexyl phosphoric acid, lauryl sodium sulfate, methyl anyl alcohol, any one in cellulose derivative.
The preparation method of the ink the following steps are included:
(1) liquid is dissolved by heating into reaction kettle after mixing acrylic resin, terpene resin and the molten polyurethane solutions of alcohol
Body resin, it is rear spare；
(2) aforesaid liquid resin is mixed with ethyl acetate and vinyl chloride-vinyl acetate resin and pigment, at a temperature of 25 DEG C, in blender
In 50-80min stirred with the revolving speed of 200-300r/min, it is spare mill base must to be dyed；
(3) above-mentioned dyeing mill base is kept the temperature 25 DEG C after isopropanol, filler and dispersant, with turning for 500-600r/min
Speed stirring 40-60min, it is spare to obtain mixed slurry；
(4) above-mentioned mixed slurry is added after thickener, anti skinning agent and counnter attack ink mix and carries out homogeneous in homogenizer, then
Filtering and impurity removing obtains of the invention with ink.
The homogeneous manner is ultrasonic vibration homogeneous, power 400-500W, homogenizing time 20-30min.
Embodiment 4:
The performance of embodiment 1-3 products obtained therefrom is detected, as a result as shown in the table:
| Test item | Fineness | Viscosity (S/25 DEG C) | First stemness (㎜) | Attachment fastness (%) |
| Embodiment 1 | 22 | 57 | 46 | 100 |
| Embodiment 2 | 20 | 60 | 42 | 100 |
| Embodiment 3 | 16 | 67 | 44 | 100 |
The present invention gained ink obtained by upper table has good adhesiveness and quick-drying, and all kinds of printings now is suitble to use.
It should be noted that, in this document, relational terms such as first and second and the like are used merely to a reality
Body or operation are distinguished with another entity or operation, are deposited without necessarily requiring or implying between these entities or operation
In any actual relationship or order or sequence.Moreover, the terms "include", "comprise" or its any other variant are intended to
Non-exclusive inclusion, so that the process, method, article or equipment including a series of elements is not only wanted including those
Element, but also including other elements that are not explicitly listed, or further include for this process, method, article or equipment
Intrinsic element.In the absence of more restrictions, the element limited by sentence "including a ...", it is not excluded that
There is also other identical elements in process, method, article or equipment including the element.
The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations；Although with reference to the foregoing embodiments
Invention is explained in detail, those skilled in the art should understand that: it still can be to aforementioned each implementation
Technical solution documented by example is modified or equivalent replacement of some of the technical features；And these modification or
Replacement, the spirit and scope for technical solution of various embodiments of the present invention that it does not separate the essence of the corresponding technical solution.
Claims (8)
1. a kind of printing ink of high adhesion, which is characterized in that the printing ink of the high adhesion is by following parts by weight
Raw material is made: 12-16 parts of acrylic resin, alcohol is polyurethane solutions 8-10 parts molten, 6-10 parts of terpene resin, 2-4 parts of ethyl acetate,
2-6 parts of vinyl chloride-vinyl acetate resin, 12-18 parts of isopropanol, 12-16 parts of pigment, 1-3 parts of thickener, 0.6-1.4 parts of anti skinning agent, filler
4-6 parts, 1-2 parts of counnter attack ink, 0.4-0.8 parts of dispersing agent.
2. a kind of printing ink of high adhesion according to claim 1, which is characterized in that the printing of the high adhesion
Ink is made of raw material from the following weight: 9 parts of the molten polyurethane solutions of 14 parts of acrylic resin, alcohol, 8 parts of terpene resin, acetic acid
3 parts of ethyl ester, 4 parts of vinyl chloride-vinyl acetate resin, 16 parts of isopropanol, 14 parts of pigment, 2 parts of thickener, 1 part of anti skinning agent, 5 parts of filler, counnter attack
1.5 parts of ink, 0.6 part of dispersing agent.
3. a kind of printing ink of high adhesion according to claim 1 to 2, it is characterised in that: the anti skinning agent is sulphur
The sour ferrous mixture with thio-2 acid dibasic acid esters mass ratio 2: 1.
4. a kind of printing ink of high adhesion according to claim 1 to 2, it is characterised in that: the filler is carbonic acid
The mixture of calcium, talcum powder and aluminium hydroxide mass ratio 4: 1: 1.
5. a kind of printing ink of high adhesion according to claim 1 to 2, it is characterised in that: the counnter attack ink is jade
Rice starch.
6. a kind of printing ink of high adhesion according to claim 1 to 2, it is characterised in that: the dispersing agent is three second
Base hexyl phosphoric acid, lauryl sodium sulfate, methyl anyl alcohol, any one in cellulose derivative.
7. a kind of preparation method of the printing ink of high adhesion, which is characterized in that the preparation method of the ink includes following
Step:
(1) liquid is dissolved by heating into reaction kettle after mixing acrylic resin, terpene resin and the molten polyurethane solutions of alcohol
Body resin, it is rear spare；
(2) aforesaid liquid resin is mixed with ethyl acetate and vinyl chloride-vinyl acetate resin and pigment, at a temperature of 25 DEG C, in blender
In 50-80min stirred with the revolving speed of 200-300r/min, it is spare mill base must to be dyed；
(3) above-mentioned dyeing mill base is kept the temperature 25 DEG C after isopropanol, filler and dispersant, with turning for 500-600r/min
Speed stirring 40-60min, it is spare to obtain mixed slurry；
(4) above-mentioned mixed slurry is added after thickener, anti skinning agent and counnter attack ink mix and carries out homogeneous in homogenizer, then
Filtering and impurity removing obtains of the invention with ink.
8. a kind of preparation method of the printing ink of high adhesion according to claim 7, it is characterised in that: described
Homogeneous manner is ultrasonic vibration homogeneous, power 400-500W, homogenizing time 20-30min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811416045.1A CN109504173A (en) | 2018-11-26 | 2018-11-26 | A kind of printing ink of high adhesion and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811416045.1A CN109504173A (en) | 2018-11-26 | 2018-11-26 | A kind of printing ink of high adhesion and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109504173A true CN109504173A (en) | 2019-03-22 |
Family
ID=65750510
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811416045.1A Withdrawn CN109504173A (en) | 2018-11-26 | 2018-11-26 | A kind of printing ink of high adhesion and preparation method thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN109504173A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111154349A (en) * | 2020-01-16 | 2020-05-15 | 上海立邦长润发涂料有限公司 | PU (polyurethane) water-based refinishing paint and preparation method thereof |
-
2018
- 2018-11-26 CN CN201811416045.1A patent/CN109504173A/en not_active Withdrawn
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111154349A (en) * | 2020-01-16 | 2020-05-15 | 上海立邦长润发涂料有限公司 | PU (polyurethane) water-based refinishing paint and preparation method thereof |
| CN111154349B (en) * | 2020-01-16 | 2021-11-16 | 上海立邦长润发涂料有限公司 | PU (polyurethane) water-based refinishing paint and preparation method thereof |
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Application publication date: 20190322 |