CN103666099B - A kind of printing Environment-friendlyink ink paint - Google Patents
A kind of printing Environment-friendlyink ink paint Download PDFInfo
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- CN103666099B CN103666099B CN201310748186.4A CN201310748186A CN103666099B CN 103666099 B CN103666099 B CN 103666099B CN 201310748186 A CN201310748186 A CN 201310748186A CN 103666099 B CN103666099 B CN 103666099B
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- auxiliary agent
- vegetable oil
- acrylic acid
- copolymer
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- 239000003973 paint Substances 0.000 title abstract description 17
- 239000012752 auxiliary agent Chemical group 0.000 claims abstract description 24
- 239000011230 binding agent Substances 0.000 claims abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical group O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000002253 acid Substances 0.000 claims abstract description 18
- 239000000049 pigment Substances 0.000 claims abstract description 16
- 239000002994 raw material Substances 0.000 claims abstract description 10
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 24
- 229920001577 copolymer Polymers 0.000 claims description 16
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 12
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 12
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 10
- 239000003995 emulsifying agent Substances 0.000 claims description 10
- 239000004925 Acrylic resin Substances 0.000 claims description 9
- 229920000178 Acrylic resin Polymers 0.000 claims description 9
- 239000002562 thickening agent Substances 0.000 claims description 9
- 229920002126 Acrylic acid copolymer Polymers 0.000 claims description 6
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 6
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- VLCAYQIMSMPEBW-UHFFFAOYSA-N methyl 3-hydroxy-2-methylidenebutanoate Chemical group COC(=O)C(=C)C(C)O VLCAYQIMSMPEBW-UHFFFAOYSA-N 0.000 claims description 6
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 6
- 229940114930 potassium stearate Drugs 0.000 claims description 5
- ANBFRLKBEIFNQU-UHFFFAOYSA-M potassium;octadecanoate Chemical compound [K+].CCCCCCCCCCCCCCCCCC([O-])=O ANBFRLKBEIFNQU-UHFFFAOYSA-M 0.000 claims description 5
- 241000196324 Embryophyta Species 0.000 claims description 4
- JIZCYLOUIAIZHQ-UHFFFAOYSA-N ethyl docosenyl Chemical compound CCCCCCCCCCCCCCCCCCCCCC(=O)OCC JIZCYLOUIAIZHQ-UHFFFAOYSA-N 0.000 claims description 4
- 229920002907 Guar gum Polymers 0.000 claims description 3
- 239000000665 guar gum Substances 0.000 claims description 3
- 235000010417 guar gum Nutrition 0.000 claims description 3
- 229960002154 guar gum Drugs 0.000 claims description 3
- 210000000582 semen Anatomy 0.000 claims description 3
- 150000001336 alkenes Chemical class 0.000 claims 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 2
- 240000001592 Amaranthus caudatus Species 0.000 claims 1
- 235000009328 Amaranthus caudatus Nutrition 0.000 claims 1
- 235000012735 amaranth Nutrition 0.000 claims 1
- 239000004178 amaranth Substances 0.000 claims 1
- WQDGUYZIAJKLAB-UHFFFAOYSA-N octan-2-yl nitrite Chemical compound CCCCCCC(C)ON=O WQDGUYZIAJKLAB-UHFFFAOYSA-N 0.000 claims 1
- 235000015112 vegetable and seed oil Nutrition 0.000 abstract description 20
- 239000008158 vegetable oil Substances 0.000 abstract description 20
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract description 15
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract description 15
- 150000002148 esters Chemical group 0.000 abstract description 10
- 231100000252 nontoxic Toxicity 0.000 abstract description 9
- 230000003000 nontoxic effect Effects 0.000 abstract description 9
- 239000011347 resin Substances 0.000 abstract description 7
- 229920005989 resin Polymers 0.000 abstract description 7
- 235000013305 food Nutrition 0.000 abstract description 6
- 230000007613 environmental effect Effects 0.000 abstract description 5
- 230000008901 benefit Effects 0.000 abstract description 4
- 239000000853 adhesive Substances 0.000 abstract description 3
- 230000001070 adhesive effect Effects 0.000 abstract description 3
- 230000006378 damage Effects 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 2
- 229920002401 polyacrylamide Polymers 0.000 abstract description 2
- 238000007711 solidification Methods 0.000 abstract description 2
- 230000008023 solidification Effects 0.000 abstract description 2
- 238000012546 transfer Methods 0.000 abstract description 2
- 238000004132 cross linking Methods 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 239000006185 dispersion Substances 0.000 description 15
- 239000000463 material Substances 0.000 description 12
- 239000004576 sand Substances 0.000 description 11
- 239000000203 mixture Substances 0.000 description 10
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- 238000003756 stirring Methods 0.000 description 7
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 238000003801 milling Methods 0.000 description 5
- 238000004806 packaging method and process Methods 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 4
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 4
- 238000007334 copolymerization reaction Methods 0.000 description 4
- 125000004494 ethyl ester group Chemical group 0.000 description 4
- -1 polypropylene Polymers 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 235000010489 acacia gum Nutrition 0.000 description 3
- 239000001785 acacia senegal l. willd gum Substances 0.000 description 3
- 238000005576 amination reaction Methods 0.000 description 3
- 235000010445 lecithin Nutrition 0.000 description 3
- 239000000787 lecithin Substances 0.000 description 3
- 229940067606 lecithin Drugs 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000012860 organic pigment Substances 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 108010010803 Gelatin Proteins 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000576 food coloring agent Substances 0.000 description 2
- 239000008273 gelatin Substances 0.000 description 2
- 229920000159 gelatin Polymers 0.000 description 2
- 235000019322 gelatine Nutrition 0.000 description 2
- 235000011852 gelatine desserts Nutrition 0.000 description 2
- 239000001023 inorganic pigment Substances 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000011265 semifinished product Substances 0.000 description 2
- 235000010413 sodium alginate Nutrition 0.000 description 2
- 239000000661 sodium alginate Substances 0.000 description 2
- 229940005550 sodium alginate Drugs 0.000 description 2
- 235000012424 soybean oil Nutrition 0.000 description 2
- LUEWUZLMQUOBSB-FSKGGBMCSA-N (2s,3s,4s,5s,6r)-2-[(2r,3s,4r,5r,6s)-6-[(2r,3s,4r,5s,6s)-4,5-dihydroxy-2-(hydroxymethyl)-6-[(2r,4r,5s,6r)-4,5,6-trihydroxy-2-(hydroxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-4,5-dihydroxy-2-(hydroxymethyl)oxan-3-yl]oxy-6-(hydroxymethyl)oxane-3,4,5-triol Chemical compound O[C@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@@H](O[C@@H]2[C@H](O[C@@H](OC3[C@H](O[C@@H](O)[C@@H](O)[C@H]3O)CO)[C@@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O LUEWUZLMQUOBSB-FSKGGBMCSA-N 0.000 description 1
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
- 244000024893 Amaranthus tricolor Species 0.000 description 1
- 235000014748 Amaranthus tricolor Nutrition 0.000 description 1
- 235000001206 Amorphophallus rivieri Nutrition 0.000 description 1
- 244000247812 Amorphophallus rivieri Species 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 229920001503 Glucan Polymers 0.000 description 1
- 229920002581 Glucomannan Polymers 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 235000000177 Indigofera tinctoria Nutrition 0.000 description 1
- 241001446187 Kermes Species 0.000 description 1
- 229920002752 Konjac Polymers 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 229920002230 Pectic acid Polymers 0.000 description 1
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 1
- 238000003854 Surface Print Methods 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 239000002318 adhesion promoter Substances 0.000 description 1
- AEMOLEFTQBMNLQ-BKBMJHBISA-N alpha-D-galacturonic acid Chemical compound O[C@H]1O[C@H](C(O)=O)[C@H](O)[C@H](O)[C@H]1O AEMOLEFTQBMNLQ-BKBMJHBISA-N 0.000 description 1
- 229920006378 biaxially oriented polypropylene Polymers 0.000 description 1
- 239000011127 biaxially oriented polypropylene Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 235000010418 carrageenan Nutrition 0.000 description 1
- 239000000679 carrageenan Substances 0.000 description 1
- 229920001525 carrageenan Polymers 0.000 description 1
- 229940113118 carrageenan Drugs 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000006184 cosolvent Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 235000013355 food flavoring agent Nutrition 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 235000013611 frozen food Nutrition 0.000 description 1
- 229940014259 gelatin Drugs 0.000 description 1
- 229940046240 glucomannan Drugs 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 229940097275 indigo Drugs 0.000 description 1
- COHYTHOBJLSHDF-UHFFFAOYSA-N indigo powder Natural products N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 description 1
- 235000008446 instant noodles Nutrition 0.000 description 1
- CXORMDKZEUMQHX-UHFFFAOYSA-N kermesic acid Chemical compound O=C1C2=C(O)C(O)=CC(O)=C2C(=O)C2=C1C=C(O)C(C(O)=O)=C2C CXORMDKZEUMQHX-UHFFFAOYSA-N 0.000 description 1
- 239000000252 konjac Substances 0.000 description 1
- 235000010485 konjac Nutrition 0.000 description 1
- AIHDCSAXVMAMJH-GFBKWZILSA-N levan Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)OC[C@@H]1[C@@H](O)[C@H](O)[C@](CO)(CO[C@@H]2[C@H]([C@H](O)[C@@](O)(CO)O2)O)O1 AIHDCSAXVMAMJH-GFBKWZILSA-N 0.000 description 1
- TWNIBLMWSKIRAT-VFUOTHLCSA-N levoglucosan Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@H]2CO[C@@H]1O2 TWNIBLMWSKIRAT-VFUOTHLCSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- APWFFUVXHHQZBH-UHFFFAOYSA-N octan-2-yl nitrite prop-2-enoic acid Chemical compound N(=O)OC(C)CCCCCC.C(C=C)(=O)O APWFFUVXHHQZBH-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000001814 pectin Substances 0.000 description 1
- 235000010987 pectin Nutrition 0.000 description 1
- 229920001277 pectin Polymers 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 210000002706 plastid Anatomy 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000013557 residual solvent Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000001587 sorbitan monostearate Substances 0.000 description 1
- 235000011076 sorbitan monostearate Nutrition 0.000 description 1
- 229940035048 sorbitan monostearate Drugs 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of printing Environment-friendlyink ink paint, be by pigment, acrylic acid binder, vegetable oil, vegetable oil acid esters, water, auxiliary agent form；Described each parts by weight of raw materials array becomes as follows: pigment 1 10 parts, acrylic acid binder 30 80 parts, vegetable oil 5 30 parts, vegetable oil acid esters 5 10 parts, 5 50 parts of water, auxiliary agent 1 10 parts；The printing Environment-friendlyink ink paint of the present invention have employed safe and nontoxic harmless, the raw material of environmental protection and food grade accessory ingredients produces, and the printing for food wrapper has nontoxic, the advantage of environmental protection.After the solidification crosslinking of acrylic acid binder, resistance to transfer ability is good, and human non-toxic does harm to aqueous polyacrylamide acid resin binder and the auxiliary agent of effect so that the printability of product is good, adhesive force is strong.
Description
Technical field
The present invention relates to a kind of coating, specifically a kind of printing Environment-friendlyink ink paint, belong to technical field of chemical paint.
Background technology
Ink by chromoplast (such as pigment, dyestuff etc.), link stuff, fill out that the materials such as (filling) material, additional material form uniform
Mixture；Can print, and be dried in printed body；It is to have color, there is the pulpous state adherent of certain fluidity.Ink
Being the important materials for packaging material printing, pattern, literal table present stock curing ink are included main by printing by it
Wanting composition and auxiliary element, they mix equably and form a kind of viscosity colloidal fluid through repeat-rolling.
In the printing technology of existing packaging for foodstuff, often use the armaticity chlorinated polypropylene containing benzene ring structure
Ink, such ink mainly uses the mode of gravure, is applied in Biaxially oriented polypropylene plastic material print.This ink
Printability excellent, processing characteristics after printing is good, fast drying, but owing to the manufacturing process of (1) such ink contains
Toluene, toluene is the material that a kind of toxicity is bigger, and the residual solvent value in leaflet is higher；(2) heat of chlorinated polypropylene is steady
Qualitative difference, during producing and depositing, easily discharges chlorine, forms hydrogen chloride so that ink presents stronger acidity, just
Printing plate cylinder can be produced serious corrosion；(3) organic volatile that benzene soluble ink produces can damage the ozone layer, and
Also the health and safety of operator, direct labor can be worked the mischief during use, remain in the residual in packing articles
Food in packaging bag under certain conditions, also can be caused a certain degree of pollution by thing.Therefore, the existence of drawbacks described above makes
The application obtaining benzene soluble ink is gradually controlled or is forbidden, more research is the ink that steering ring guaranteed cost is high.Such as, specially
Profit ZL200510044632.9 discloses a kind of environment protection plastic printing ink and preparation method thereof, and this ink is by having
Machine pigment or inorganic pigment, antistatic additive, emulsifying agent, alcohol are fused into PVB resin and alcohols solvent composition, and preparation method is: press
Alcohol is fused into PVB resin dissolving by ratio alcohols solvent becomes translucent resin solution, by organic pigment and inorganic pigment
Mix with resin solution, dispersed with stirring prepares semi-finished product mill base；By the above-mentioned semi-finished product mill base through dispersed with stirring at sand mill
Inside it is fully ground, successively adds antistatic additive, emulsifying agent and adhesion promoter, be sufficiently stirred for modulation, obtain without the molten ring of benzene alcohol
Protect plastic printing ink finished product；Ink finished product is put into filter filter, final product packaging warehouse-in.This ink has resistant to cook
Boiling, resistance to steaming and decocting, anti-freezing, can be used for milk, drinks, flavoring agent, aquatic products, instant noodles frozen food, wash by super low temperature quick frozen
The surface printing of the packaging such as clothing powder, medicine.Application number: the patent of invention of 201310086603.3 discloses a kind of water-based printing oil
Ink and application thereof, its described water-based printing ink is a kind of environment-friendly type aqueous printing-ink being applicable to cigarette filter printing,
This ink, using water as main solvent, has nontoxic, free from extraneous odour, adhesive force, drying property and resistance to water can meet printing and produce
Product requirement.It is prepared raw material and comprises: high acid value acrylic resin amination liquid (A), and it is through amination with high acid value acrylic resin
The water-soluble resin liquid that reaction is made, acrylate copolymer emulsion is as film former.In typical embodiment, it is former
Material component includes high acid value acrylic resin amination liquid (A), acrylate copolymer emulsion (B), (C), nontoxic nothing
Machine pigment and organic pigment (D), inserts are superfine light calcium carbonate, main solvent water and a small amount of co-solvent and functional
Auxiliary agent class.
Summary of the invention
Present invention aim at for the deficiencies in the prior art, it is provided that a kind of Environment-friendlyink ink paint, it is adaptable to packaging for foodstuff
Paper, has nontoxic, environmental protection, an advantage that printability is good.
For solving the problems referred to above, the technical solution adopted in the present invention is: a kind of printing Environment-friendlyink ink paint, by face
Material, acrylic acid binder, vegetable oil, vegetable oil acid esters, water, auxiliary agent form；Described each parts by weight of raw materials array becomes as follows: pigment
1-10 part, acrylic acid binder 30-80 part, vegetable oil 5-30 part, vegetable oil acid esters 5-10 part, water 5-50 part, auxiliary agent 1-10 part.
Described acrylic resin binder is by the copolymer of 2-EHA Yu ethyl acrylate, acrylic acid 2-
Octyl Nitrite, methyl methacrylate and acrylic acid copolymer, n-butyl acrylate, styrene, methacrylic acid and methyl
The copolymer of 2-(Acryloyloxy)ethanol, and the copolymer of butyl acrylate, styrene, methacrylic acid and hydroxyethyl methylacrylate
Composition, its proportion of composing is 2-4:2-8:1-2:1.
Described vegetable oil acid esters is the one in soya oil acid methyl ester, behenic acid ethyl ester or Oleum Cocois Exceed 600.
Described pigment is natural organic pigment or food coloring.
Described auxiliary agent is: emulsifying agent, levelling agent, thickening agent, and described emulsifying agent, levelling agent, thickening agent are food stage.
The printing Environment-friendlyink ink paint of the present invention, use following steps prepare: first by pigment, acrylic acid binder,
Vegetable oil, vegetable oil acid esters, water is mixed in proportion in Scattered Kettle, 400-600 turn/speed conditions of min under, carry out at a high speed
Dispersion 20-30min, after the mill base sand mill sand milling then dispersion obtained to particle size dispersion is uniform, adds auxiliary agent, and stirring is all
Even, filter.
The preferred naturally occurring emulsifying agent of emulsifying agent of the present invention, such as lecithin, modified soy bean lipoid, potassium stearate, polyoxy
One or more in ethylene sorbitan monostearate；Thickening agent is preferably derived from the one in natural thickening agent or several
Kind, such as arabic gum, pectin, Konjac glucomannan, guar gum, sodium alginate, carrageenan, gelatin, glucosan, levan.
The present invention provides the benefit that relative to prior art: have employed safe and nontoxic harmless, the raw material of environmental protection and food
Level auxiliary agent produces, and the printing for food wrapper has nontoxic, the advantage of environmental protection.The solidification of acrylic acid binder is handed over
After connection, resistance to transfer ability is good, and human non-toxic does harm to aqueous polyacrylamide acid resin binder and the auxiliary agent of effect so that product
Printability good, adhesive force is strong.
Detailed description of the invention
Being described in further details the present invention below by embodiment, these embodiments are only used for the present invention is described, and
Do not limit the scope of the invention.
The printing Environment-friendlyink ink paint of embodiment 1 the present embodiment, uses the raw material of following parts by weight to prepare: Fructus Citri Limoniae
Yellow natural plants pigment 1 part, acrylic acid binder 30 parts, soybean oil 25 parts, Oleum Cocois Exceed 600 8 parts, 5 parts of water, auxiliary agent 1-
10 parts；
Wherein, the acrylic resin binder used is by the copolymerization of 2-EHA Yu ethyl acrylate
Thing, 2-EHA, methyl methacrylate and acrylic acid copolymer, n-butyl acrylate, styrene, methyl
Acrylic acid and the copolymer of hydroxyethyl methylacrylate, and butyl acrylate, styrene, methacrylic acid and hydroxyethyl methacrylate
The copolymer composition of ethyl ester, its proportion of composing is 4:8:1:1；
The auxiliary agent used is: potassium stearate emulsifying agent, isopropanol levelling agent, sodium alginate thickening agent.
The printing Environment-friendlyink ink paint of the present embodiment, uses following steps to prepare: first pigment, acrylic acid are connected
Material, vegetable oil, vegetable oil acid esters, water are mixed in proportion in Scattered Kettle, under the speed conditions of 400 turns/min, carry out at a high speed
Dispersion 20min, after the mill base sand mill sand milling then dispersion obtained to particle size dispersion is uniform, adds auxiliary agent, stirs,
Filter.
The printing Environment-friendlyink ink paint of embodiment 2 the present embodiment, uses the raw material of following parts by weight to prepare: Amaranthus mangostanus L.
Red natural plants pigment 3 parts, acrylic acid binder 60 parts, Oleum Arachidis hypogaeae semen 30 parts, behenic acid ethyl ester 7 parts, 30 parts of water, auxiliary agent 1-10
Part；
Wherein, the acrylic resin binder used is by the copolymerization of 2-EHA Yu ethyl acrylate
Thing, 2-EHA, methyl methacrylate and acrylic acid copolymer, n-butyl acrylate, styrene, methyl
Acrylic acid and the copolymer of hydroxyethyl methylacrylate, and butyl acrylate, styrene, methacrylic acid and hydroxyethyl methacrylate
The copolymer composition of ethyl ester, its proportion of composing is 3:5:2:1；
The auxiliary agent used is: potassium stearate emulsifying agent, isopropanol levelling agent, guar gum thickener.
The printing Environment-friendlyink ink paint of the present embodiment, uses following steps to prepare: first pigment, acrylic acid are connected
Material, vegetable oil, vegetable oil acid esters, water are mixed in proportion in Scattered Kettle, under the speed conditions of 500 turns/min, carry out at a high speed
Dispersion 25min, after the mill base sand mill sand milling then dispersion obtained to particle size dispersion is uniform, adds auxiliary agent, stirs,
Filter.
The printing Environment-friendlyink ink paint of embodiment 3 the present embodiment, uses the raw material of following parts by weight to prepare: kermes
Red natural plants pigment 10 parts, acrylic acid binder 80 parts, Oleum Cocois 10 parts, Oleum Cocois Exceed 600 10 parts, 50 parts of water, auxiliary agent
10 parts；
Wherein, the acrylic resin binder used is by the copolymerization of 2-EHA Yu ethyl acrylate
Thing, 2-EHA, methyl methacrylate and acrylic acid copolymer, n-butyl acrylate, styrene, methyl
Acrylic acid and the copolymer of hydroxyethyl methylacrylate, and butyl acrylate, styrene, methacrylic acid and hydroxyethyl methacrylate
The copolymer composition of ethyl ester, its proportion of composing is 4:2:1:1；
The auxiliary agent used is: emulsifying agent (lecithin), isopropanol levelling agent, arabic gum thickening agent, pectate thickener.
The printing Environment-friendlyink ink paint of the present embodiment, uses following steps to prepare: first pigment, acrylic acid are connected
Material, vegetable oil, vegetable oil acid esters, water are mixed in proportion in Scattered Kettle, under the speed conditions of 600 turns/min, carry out at a high speed
Dispersion 30min, after the mill base sand mill sand milling then dispersion obtained to particle size dispersion is uniform, adds auxiliary agent, stirs,
Filter.
The printing Environment-friendlyink ink paint of embodiment 4 the present embodiment, uses the raw material of following parts by weight to prepare: indigo
Food coloring 5 parts, acrylic acid binder 55 parts, vegetable oil Oleum Arachidis hypogaeae semen 5 parts, behenic acid ethyl ester 5 parts, 40 parts of water, auxiliary agent 3 parts；
Wherein, the acrylic resin binder used is by the copolymerization of 2-EHA Yu ethyl acrylate
Thing, 2-EHA, methyl methacrylate and acrylic acid copolymer, n-butyl acrylate, styrene, methyl
Acrylic acid and the copolymer of hydroxyethyl methylacrylate, and butyl acrylate, styrene, methacrylic acid and hydroxyethyl methacrylate
The copolymer composition of ethyl ester, its proportion of composing is 2:8:2:1；
The auxiliary agent used is: lecithin potassium stearate, isopropanol, arabic gum, gelatin.
The printing Environment-friendlyink ink paint of the present embodiment, uses following steps to prepare: first pigment, acrylic acid are connected
Material, vegetable oil, vegetable oil acid esters, water are mixed in proportion in Scattered Kettle, under the speed conditions of 400 turns/min, carry out at a high speed
Dispersion 20min, after the mill base sand mill sand milling then dispersion obtained to particle size dispersion is uniform, adds auxiliary agent, stirs,
Filter.
Claims (1)
1. a printing environment-friendly ink, uses the raw material of following parts by weight to prepare: amaranth natural plants pigment 3 parts, third
Olefin(e) acid binder 60 parts, Oleum Arachidis hypogaeae semen 30 parts, behenic acid ethyl ester 7 parts, 30 parts of water, auxiliary agent 1-10 part；
Wherein, the acrylic resin binder used is by the copolymer of 2-EHA Yu ethyl acrylate, third
Olefin(e) acid 2-Octyl Nitrite, methyl methacrylate and acrylic acid copolymer, n-butyl acrylate, styrene, methacrylic acid
With the copolymer of hydroxyethyl methylacrylate, and butyl acrylate, styrene, methacrylic acid and hydroxyethyl methylacrylate
Copolymer forms, and its proportion of composing is 3:5:2:1；
The auxiliary agent used is: potassium stearate emulsifying agent, isopropanol levelling agent, guar gum thickener.
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| CN109021200A (en) * | 2018-08-15 | 2018-12-18 | 芜湖扬展新材料科技服务有限公司 | A kind of modified aqueous polyurethane ink adhesive and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102382510A (en) * | 2011-09-15 | 2012-03-21 | 银川市富邦印刷包装有限公司 | Flexographic printing water-based ink for food packaging |
| CN102643577A (en) * | 2012-05-03 | 2012-08-22 | 中钞油墨有限公司 | Environment-friendly printing ink suitable for high speed rotary printing |
| CN102732093A (en) * | 2012-06-06 | 2012-10-17 | 太湖集友纸业有限公司 | Environmentally-friendly aqueous varnish printing ink and its preparation method |
| CN103254679A (en) * | 2013-05-24 | 2013-08-21 | 苏州凹凸彩印厂 | Environment-friendly lithographic offset printing ink with aroma and preparation method thereof |
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| JP2585927B2 (en) * | 1992-07-28 | 1997-02-26 | 東北リコー株式会社 | Emulsion ink for stencil printing |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102382510A (en) * | 2011-09-15 | 2012-03-21 | 银川市富邦印刷包装有限公司 | Flexographic printing water-based ink for food packaging |
| CN102643577A (en) * | 2012-05-03 | 2012-08-22 | 中钞油墨有限公司 | Environment-friendly printing ink suitable for high speed rotary printing |
| CN102732093A (en) * | 2012-06-06 | 2012-10-17 | 太湖集友纸业有限公司 | Environmentally-friendly aqueous varnish printing ink and its preparation method |
| CN103254679A (en) * | 2013-05-24 | 2013-08-21 | 苏州凹凸彩印厂 | Environment-friendly lithographic offset printing ink with aroma and preparation method thereof |
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Effective date of registration: 20220119 Address after: 516000 lot of Fudi village, Honghai fine chemical base, Yonghu Town, Huiyang District, Huizhou City, Guangdong Province (d-8-1) Patentee after: Huizhou huashide Chemical Co.,Ltd. Address before: 516025 No. 64, Sandong Road, Sandong Town, Huicheng District, Huizhou City, Guangdong Province Patentee before: Zhang Jinbi |