CN109295806B - Multicolor overprint tipping paper with metallic luster and preparation method thereof - Google Patents
Multicolor overprint tipping paper with metallic luster and preparation method thereof Download PDFInfo
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- CN109295806B CN109295806B CN201811175144.5A CN201811175144A CN109295806B CN 109295806 B CN109295806 B CN 109295806B CN 201811175144 A CN201811175144 A CN 201811175144A CN 109295806 B CN109295806 B CN 109295806B
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/80—Paper comprising more than one coating
- D21H19/82—Paper comprising more than one coating superposed
- D21H19/822—Paper comprising more than one coating superposed two superposed coatings, both being pigmented
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/103—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds of aldehydes, e.g. phenol-formaldehyde resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/14—Printing inks based on carbohydrates
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/52—Cellulose; Derivatives thereof
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/58—Polymers or oligomers of diolefins, aromatic vinyl monomers or unsaturated acids or derivatives thereof
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/60—Polyalkenylalcohols; Polyalkenylethers; Polyalkenylesters
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/62—Macromolecular organic compounds or oligomers thereof obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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Abstract
The invention discloses multicolor overprint tipping paper with metallic luster and a preparation method thereof. The tipping paper takes the aluminum layer of the aluminum-plated tipping base paper as a printing surface, the ground color adopts transparent alcohol ester type printing ink, the printing ink contains polar hydroxyl groups and can be bonded with metal aluminum, the printing ink has excellent adhesive force to the metal aluminum, and the direct printing on the metal aluminum layer is realized; meanwhile, the ink is matched with tackifying resin, so that the bottom color ink layer, the metal aluminum layer and the multi-color overprinting ink layer are firmly attached and do not fall off; in addition, the adopted printing ink solvent has good release performance, and the safety and sanitation indexes of the tipping paper product meet the standards. Under the mutual combination of the aluminum layer metal luster and the printing ink luster, the tipping paper has the advantages of obvious metal luster visual effect, rich colors, high grade, luxury, strong three-dimensional texture decoration and certain anti-counterfeiting property.
Description
Technical Field
The invention relates to printing ink and tipping paper, in particular to multicolor overprinting tipping paper with metallic luster and a preparation method thereof.
Background
The tipping paper is a special industrial paper, mainly used for rolling and connecting a filter tip and a cigarette, and is commonly called as tipping paper. With the richness of the modern society and the abundance of the spiritual life, the change of the consumption concept and the health consciousness of people also has new requirements on cigarette packaging, the application of the tipping paper is not only limited to pure packaging, but also focuses on decoration, and the tipping paper has larger market potential and development space.
The printed product with metallic luster can produce the visual effect of glittering, transparence, luxury, elegant, unique, peculiar and magnificent, greatly improves the grade and grade of the commodity package, is particularly popular in the field of package decoration, and is mainly used for top-grade external packages of foods, cigarettes, wine, medicines, cosmetics, clothes, household appliances, toys, artware, gifts and the like.
The metallic ink is prepared from fine metallic flakes, aluminum flakes are used for silver ink, copper flakes are used for gold ink, when the ink is dried, the flakes form a thin layer on the surface of a printed product, and metallic luster such as gold or silver can be generated by the light reflected by metallic flake particles. Therefore, the magnificent metal surface effect can attract the eyes of consumers, thereby improving the grade and the competitiveness of the product. In addition, the metal ink also has the advantages of convenient application, capability of being printed like common ink, improvement on production efficiency and the like, so that the metal ink is popular in the packaging and printing industry. However, metallic inks have many disadvantages, such as that their metallic luster is generated by using the light reflected from large metallic flake particles, the effect does not reach the metallic luster of the reflecting mirror surface formed by cooling the metal by vacuum evaporation, and their preparation process can avoid destroying the metallic flake structure to cause no luster, without grinding, only by gentle stirring, the metallic luster effect is greatly reduced by uneven dispersion, and they are unstable and easy to precipitate during storage, the metallic ink layer has no printability, and multicolor prints with strong stereo and metallic feeling cannot be obtained.
The aluminized tipping paper takes the aluminum layer as a printing surface, the surface of the aluminum layer is smooth, the aluminum layer has a mirror surface effect, no micropores exist, the surface ink absorption performance is poor, and the phenomenon that the ink layer falls off is easily caused due to poor adhesion by adopting alcohol ink or water-based ink which is relatively environment-friendly. The ester soluble ink has strong adhesive force, a firm ink layer can be obtained on the aluminum layer, and in order to obtain a printed product with rich colors, the ester soluble ink of the same system needs to be adopted in the subsequent overprinting process, but the solvent release of the ester soluble system is poor, and the VOC residue in the product exceeds the standard. At present, a method of firstly coating a layer of base coat on an aluminum layer and then printing is also presented to overcome the problems of adhesion fastness and solvent residue, for example, the disclosed invention patent of 'transfer type tipping paper and a preparation method thereof, application No. 201710228740.4', provides a method of firstly coating a transparent base coat liquid containing resin on a metal aluminum layer and then carrying out gravure ink printing, so as to solve the problem that the metal aluminum layer cannot be directly printed, but the method of arranging the base coat has the defects of increased production cost, low production efficiency and monotonous color.
Disclosure of Invention
In order to overcome the defects in the prior art, the invention aims to provide the multicolor overprinting tipping paper with obvious metal luster visual effect, rich colors, high grade and luxury and the preparation method thereof. The tipping paper takes the aluminum layer of the aluminum-plated tipping base paper as a printing surface, the ground color adopts transparent alcohol ester type printing ink, the printing ink contains polar hydroxyl groups and can be bonded with metal aluminum, the printing ink has excellent adhesive force to the metal aluminum, and the direct printing on the metal aluminum layer is realized.
In order to achieve the purpose, the invention adopts the following technical means: the multicolor overprinting tipping paper with metallic luster comprises an aluminum-plated tipping raw paper layer, an ink layer and a gloss oil layer 8, wherein the aluminum-plated tipping raw paper layer sequentially comprises an anti-curling layer 1, a tipping white raw paper layer 2, a composite glue layer 3, an aluminum-plated layer 4 and a stripping protective layer 5 from inside to outside, and the quantitative tipping white raw paper layer is 32-45g/m2The single side of the base paper is polished and connected with white base paper; the ink layers comprise a bottom color transparent ink layer 6 and an overprint ink layer 7; the base color transparent ink layer 6, the overprint ink layer 7 and the gloss oil layer 8 are printed on the peeling protective layer 5 in sequence.
The bottom color transparent ink layer is a full-color ink layer, and the raw materials are as follows according to the weight portion: 5-20 parts of aldehyde ketone resin, 1-10 parts of vinyl chloride-acetate resin, 1-10 parts of rosin pentaerythritol ester, 5-25 parts of cellulose acetate butyrate, 1-15 parts of transparent pigment, 1-5 parts of microcrystalline wax, 20-35 parts of ethanol and 20-35 parts of ethyl acetate. Preferably, the raw materials are as follows according to the weight portion: 10-15 parts of aldehyde ketone resin, 5-8 parts of vinyl chloride-acetate resin, 3-5 parts of rosin pentaerythritol ester, 10-15 parts of cellulose acetate butyrate, 5-8 parts of transparent pigment, 2-4 parts of microcrystalline wax, 25-30 parts of ethanol and 25-30 parts of ethyl acetate.
The overprint ink layer is at least one of one color, two colors, three color patterns or line characters, and the used raw materials are as follows according to the weight portion: 5-20 parts of polyvinyl butyral, 5-25 parts of cellulose acetate butyrate, 1-10 parts of pigment, 1-5 parts of microcrystalline wax and 40-70 parts of ethanol. Preferably, the raw materials are as follows according to the weight portion: 10-15 parts of polyvinyl butyral, 15-20 parts of cellulose acetate butyrate, 3-5 parts of pigment, 2-4 parts of microcrystalline wax and 60-65 parts of ethanol.
The gloss oil layer comprises materials of acrylate copolymer and microcrystalline wax, and the raw materials are as follows in parts by weight: 20-45 parts of acrylate copolymer, 1-5 parts of microcrystalline wax and 50-79 parts of ethanol. Preferably, the raw materials are as follows according to the weight portion: 30-35 parts of acrylate copolymer, 1-3 parts of microcrystalline wax and 62-69 parts of ethanol.
Among them, the aldehyde-ketone resin is commonly known as polyketone resin, ketone-aldehyde resin, which is a neutral, nonsaponifiable type cyclohexanone-formaldehyde resin having high brightness and light resistance, and is pale white granular or lumpy solid, soluble in most of the solvents commonly used, and compatible with most of the other resins. The high-gloss and high-gloss aqueous ink is mainly used in solvent-based ink, paint, universal color paste, adhesive and other systems, and is used for improving the glossiness, the adhesive force, the quick drying property, the leveling property, the pigment wettability, the solid content and the like of products.
The vinyl chloride-vinyl acetate copolymer is completely dissolved in organic solvent such as ketone and ester. Very good solubility, high toughness and corrosion resistance of vinyl chloride and strong viscosity and plasticity of vinyl acetate. Has excellent adhesion to metal, especially aluminum, and also has excellent adhesion to PVC products, paper, fiber, glass, ceramic tile, sand and stone, and wood. Has high dispersibility to the pigment, excellent film forming property and solvent release property, flexibility, high wear resistance, chemical resistance, flame retardance, good solubility and manufacturability and wide dispensability. Therefore, the vinyl chloride-vinyl acetate copolymer resin, which is a preferred adhesive resin for preparing industrial coatings, has excellent pigment dispersibility, color developability and good polymer compatibility due to the hydroxyl functional groups contained in the resin, and is used in combination with PU (polyurethane) resin, alkyd resin, epoxy resin, urea resin, aldehyde ketone resin, melamine resin, acrylic resin and the like, so that the characteristics of different resins are fully utilized.
The rosin pentaerythritol ester is synthesized by esterification of modified rosin or light-colored rosin and pentaerythritol, and is prepared into irregular transparent massive, flaky or granular solid after vacuum treatment, and the irregular transparent massive, flaky or granular solid is widely applied to the adhesive industry as a tackifier. The product has excellent heat resistance, ageing resistance, stability, compatibility, solubility, surface resistance and color retention. Excellent viscosity, internal cohesion, excellent heat resistance, good compatibility with wax and EVA polymers, and excellent oxidation resistance, and is mainly used in hot melt adhesive, pressure sensitive adhesive and rubber industries.
Cellulose Acetate Butyrate (CAB) is used as an auxiliary agent, modified resin or a main film forming substance in printing ink and coating, and can improve leveling property, reduce craters, shorten drying time, reduce pressure adhesion, stabilize a carrier by a metal pigment, improve grinding property, ultraviolet light stability and yellowing resistance, improve spraying property, enhance frost crack resistance, reduce solvent cracks, improve sliding property, reduce plasticizer migration property, control viscosity, grind a pigment medium, control aluminum powder directional arrangement and have the function of re-dissolving resistance of a solvent.
The microcrystalline wax is superfine polyethylene wax micropowder, and the product is white powder, and has the special properties of low viscosity, high softening point, white color, high glossiness, good lubricity, higher hardness, good wear resistance, adhesion resistance, stain resistance, precipitation resistance, scratch resistance, smooth hand feeling, excellent dispersibility and the like. It has good light resistance and chemical property, can be used as a carrier of pigment, can improve the wear resistance of paint and ink, improves the dispersibility of pigment and filler, and prevents pigment from sinking. The ink is applied to the fields of woodenware paint, industrial paint, powder coating, inner printing, surface printing, silk screen, relief printing, intaglio printing and the like.
Polyvinyl butyral PVB is a commonly used support that has strong bonding forces, high optical clarity, easy adhesion to a variety of different surfaces, high toughness and high elasticity. The structure is white powder, the relative density is 1.08-1.10, and the organic solvent can be dissolved in methanol, ethanol, ketones, alkyl halides and aromatic solvents. Because of containing high hydroxyl, the polyvinyl butyral resin has good dispersibility on pigment, so the polyvinyl butyral resin is widely applied to printing ink and paint, alcohol-soluble ink is produced by PVB, is non-toxic, harmless and environment-friendly, and meets the requirements of national food packaging safety standard.
The acrylic ester copolymer is thermoplastic acrylic resin, and is prepared by polymerizing acrylic acid, methacrylic acid and derivatives thereof, such as esters, nitriles and amides. The softening by heating and the solidification by cooling can be repeated. The general linear high molecular compound can be a homopolymer or a copolymer, and has good physical and mechanical properties, excellent weather resistance, chemical resistance and water resistance, and high light and color retention. The molecular weight of the hot acrylic resin used in the paint industry is 75000-120000 generally, and nitrocellulose, cellulose acetate butyrate, perchloroethylene resin and the like are commonly used to be combined with the hot acrylic resin to improve the performance of a coating. Acrylic resin is widely applied to solvent-based ink, most of which can be dissolved in solvents such as aromatic hydrocarbon, esters and the like, and some of which can be dissolved in alcohol solvents, and is mainly used for manufacturing gravure ink and flexographic ink. The transparent and colorless varnish is used for manufacturing the varnish due to the characteristics of transparency and colorlessness.
Ethanol is an organic substance, commonly called alcohol, is saturated monohydric alcohol with a hydroxyl group, is flammable and volatile colorless transparent liquid at normal temperature and normal pressure, and has the smell of bouquet and slight irritation in an aqueous solution. Has the smell of wine and pungent taste, and is slightly sweet. The ethanol has wide application range, and can be used for preparing acetic acid, beverages, essence, paint, ink and the like.
Ethyl acetate is a colorless clear liquid, a fast drying solvent for cellulose nitrate, ethyl cellulose, cellulose acetate and neoprene, and also a low toxicity solvent used industrially.
The invention relates to a preparation method of multicolor overprint tipping paper with metallic luster, which comprises the following steps:
firstly, preparing ink
Preparation of bottom color transparent ink
a. Adding the solvent weighed according to the proportion into a container, and stirring at the normal temperature for 3-5 min at the stirring speed of 60-100r/min to obtain a mixed solution A;
b. under the condition of low-speed stirring at 60-100r/min, sequentially adding aldehyde ketone resin, vinyl chloride-acetate copolymer, rosin pentaerythritol ester and cellulose acetate butyrate which are weighed according to the proportion into the mixed solution A, cleaning the fed materials after feeding, putting the materials adhered to the cylinder wall, the stirring shaft and the like into a feeding cylinder until the fed materials are dissolved into a whole, gradually increasing the stirring speed to 600-1000r/min, and stirring at normal temperature for 2-4 h to completely dissolve the film-forming resin to obtain a mixed solution B;
c. adding the microcrystalline wax weighed according to the proportion into the mixed solution B, stirring for 0.5-1h at the stirring speed of 600-: 1, adding the mixed solvent of ethanol and ethyl acetate to 100 parts to obtain mixed solution C;
d. under the condition of low-speed stirring at 60-100r/min, adding the weighed transparent pigment in proportion into the mixed solution C, gradually increasing the stirring speed to 600-1000r/min, stirring at normal temperature for 0.5-1h, standing and soaking for 8h, performing sand grinding on the uniformly mixed and dispersed ink until the fineness is less than or equal to 20 mu m, and filtering by a 200-mesh screen to obtain the bottom color transparent ink.
② preparing overprint printing ink.
a. Adding ethanol weighed according to a ratio into a container, sequentially adding polyvinyl butyral and cellulose acetate butyrate weighed according to the ratio under the low-speed stirring condition of 60-100r/min, cleaning materials adhered to a cylinder wall, a stirring shaft and the like in a feeding cylinder after feeding until the fed materials are dissolved into a whole, gradually increasing the stirring speed to 600-1000r/min, and stirring at normal temperature for 2-4 h to completely dissolve resin to obtain a mixed solution D;
b. adding microcrystalline wax weighed according to the proportion into the mixed solution D, stirring for 0.5-1h at the stirring speed of 600-1000r/min until the microcrystalline wax is completely and uniformly dispersed, and supplementing 100 parts of ethanol to obtain mixed solution E;
c. under the condition of low-speed stirring at 60-100r/min, adding the pigment weighed according to the proportion into the mixed solution E, gradually increasing the stirring speed to 600-1000r/min, stirring at normal temperature for 0.5-1h, standing and soaking for 8h, performing sand grinding on the uniformly mixed and dispersed ink until the fineness is less than or equal to 20 mu m, and filtering by a 200-mesh screen to obtain the overprint ink.
Preparing gloss oil.
a. Adding ethanol weighed according to the proportion into a container, adding an acrylate copolymer weighed according to the proportion under the low-speed stirring condition of 60-100r/min, cleaning materials adhered to a cylinder wall, a stirring shaft and the like in a feeding cylinder after feeding until the fed materials are dissolved into a whole, gradually increasing the stirring speed to 600 plus materials/min, stirring at normal temperature for 2-4 h, and completely dissolving resin to obtain a mixed solution F;
b. and adding the microcrystalline wax weighed according to the proportion into the mixed solution F, stirring for 0.5-1h at the stirring speed of 600-1000r/min until the microcrystalline wax is completely and uniformly dispersed, complementing the mixture to 100 parts by using ethanol, and filtering by using a 200-mesh screen to obtain the gloss oil.
Printing
Firstly, mixing the prepared bottom color transparent ink in an environment with the temperature of 22-28 ℃ and the relative humidity of 50-60% according to the mixing ratio of 1: 1, diluting the viscosity to 12s-18s English 2# cup by using an ethanol and ethyl acetate solvent, drying at the temperature of 130 ℃ and 150 ℃ by using a printing plate of 80 lines/cm, and printing at the speed of 180 ℃ and 200m/min, wherein the viscosity is 0.5-0.8g/m2Printing process with dry coating amount of 32-45g/m2The aluminum layer surface of the aluminum-plated tipping base paper is subjected to ground color printing.
Secondly, diluting the prepared overprinting ink to 12s-18s British 2# cup by using ethanol under the environment of 22-28 ℃ of temperature and 50-60% of relative humidity, adopting a 90-line/cm pattern or a letter master plate, and drying at 70-80 DEG CThe printing speed is 180 DEG and 200m/min, 0.1-0.3g/m2Printing process with dry coating amount of 32-45g/m2The surface of the base color ink of the aluminized tipping paper is printed in an overlapping manner.
Thirdly, diluting the prepared gloss oil to 12s-18s English 2# cup by using ethanol under the environment of 22-28 ℃ of temperature and 50-60% of relative humidity, adopting a printing plate of 80 lines/cm, drying at the temperature of 130 ℃ and at the printing speed of 180 ℃ for well-drying at 200m/min, and setting the viscosity at 0.1-0.3g/m2Printing process with dry coating amount of 32-45g/m2The surface of the ink layer of the aluminized tipping paper is printed in an overlapping mode, and then is dried and rolled.
Thirdly, slitting, punching, inspecting and packaging
And cutting and rolling the printed semi-finished tipping paper according to a specified specification, placing the semi-finished tipping paper on a laser drilling machine for single-row laser drilling to increase the air permeability of the product, sampling and detecting related indexes after rolling, and packaging after the semi-finished tipping paper is qualified to obtain the multicolor overprint tipping paper with metallic luster.
The invention has the following beneficial effects:
the multicolor overprinting tipping paper with metallic luster takes the aluminum layer of the aluminum-plated tipping base paper as a printing surface, the ground color adopts transparent alcohol ester type printing ink, the printing ink contains polar hydroxyl groups which can be bonded with metallic aluminum, and the printing ink has excellent adhesive force to the metallic aluminum, so that the direct printing on the metallic aluminum layer is realized; meanwhile, the ink is matched with tackifying resin, so that the bottom color ink layer, the metal aluminum layer and the multi-color overprinting ink layer are firmly attached and do not fall off, the gloss oil layer can brighten the whole printing ink and prevent the ink layer from falling off.
The multicolor overprinting tipping paper with metallic luster prepared by the invention has good ink solvent release, and the safety and sanitation indexes of the tipping paper product meet the standards.
The multicolor overprinting tipping paper with metallic luster prepared by the invention has the advantages of obvious metallic luster visual effect, rich colors, high grade, luxury, strong three-dimensional texture decoration and certain anti-counterfeiting property.
Drawings
Figure 1 is a schematic diagram of the structure of the tipping paper of the present invention.
In the figure: the anti-curling layer 1, the tipping white raw paper layer 2, the composite glue layer 3, the aluminized layer 4, the peeling protective layer 5, the bottom color transparent ink layer 6, the overprint ink layer 7 and the gloss oil layer 8.
Detailed Description
Example 1
A multicolor overprinting tipping paper with metallic luster comprises an aluminum-plated tipping base paper layer, an ink layer and a gloss oil layer 8, wherein the aluminum-plated tipping base paper layer sequentially comprises an anti-curling layer 1, a tipping white base paper layer 2, a composite glue layer 3, an aluminum-plated layer 4 and a stripping protective layer 5 from inside to outside, and the ink layer comprises a bottom transparent ink layer 6 and an overprinting ink layer 7; the base color transparent ink layer 6, the overprint ink layer 7 and the gloss oil layer 8 are printed on the peeling protective layer 5 in sequence.
The method is implemented according to the following technical scheme:
(1) the basis weight of the printing substrate was 45g/m2The aluminized base tipping paper of (1);
(2) the specific formula of the ground color transparent ink comprises the following components in parts by weight: 10 parts of aldehyde ketone resin, 7 parts of vinyl chloride-acetate resin, 3 parts of rosin pentaerythritol ester, 15 parts of cellulose acetate butyrate, 5 parts of transparent pigment yellow, 2 parts of microcrystalline wax, 29 parts of ethanol and 29 parts of ethyl acetate;
(3) the specific formula of the ink for overprinting comprises the following components in parts by weight: 10 parts of polyvinyl butyral, 20 parts of cellulose acetate butyrate, 3 parts of pigment red, 2 parts of microcrystalline wax and 65 parts of ethanol;
(4) the gloss oil comprises the following specific formula in parts by weight: 30 parts of acrylate copolymer, 1 part of microcrystalline wax and 69 parts of ethanol.
The production is carried out according to the following steps:
firstly, preparing ink
Preparation of bottom color transparent ink
a. Adding the solvent weighed according to the proportion into a container, and stirring at the normal temperature for 3-5 min at the stirring speed of 60-100r/min to obtain a mixed solution A;
b. under the condition of low-speed stirring at 60-100r/min, sequentially adding aldehyde ketone resin, vinyl chloride-acetate copolymer, rosin pentaerythritol ester and cellulose acetate butyrate which are weighed according to the proportion into the mixed solution A, cleaning the fed materials after feeding, putting the materials adhered to the cylinder wall, the stirring shaft and the like into a feeding cylinder until the fed materials are dissolved into a whole, gradually increasing the stirring speed to 600-1000r/min, and stirring at normal temperature for 2-4 h to completely dissolve the film-forming resin to obtain a mixed solution B;
c. adding the microcrystalline wax weighed according to the proportion into the mixed solution B, stirring for 0.5-1h at the stirring speed of 600-: 1, adding the mixed solvent of ethanol and ethyl acetate to 100 parts to obtain mixed solution C;
d. under the condition of low-speed stirring at 60-100r/min, adding the weighed transparent pigment in proportion into the mixed solution C, gradually increasing the stirring speed to 600-1000r/min, stirring at normal temperature for 0.5-1h, standing and soaking for 8h, performing sand grinding on the uniformly mixed and dispersed ink until the fineness is less than or equal to 20 mu m, and filtering by a 200-mesh screen to obtain the bottom color transparent ink.
Preparation of overprinting ink
a. Adding ethanol weighed according to a ratio into a container, sequentially adding polyvinyl butyral and cellulose acetate butyrate weighed according to the ratio under the low-speed stirring condition of 60-100r/min, cleaning materials adhered to a cylinder wall, a stirring shaft and the like in a feeding cylinder after feeding until the fed materials are dissolved into a whole, gradually increasing the stirring speed to 600-1000r/min, and stirring at normal temperature for 2-4 h to completely dissolve resin to obtain a mixed solution D;
b. adding microcrystalline wax weighed according to the proportion into the mixed solution D, stirring for 0.5-1h at the stirring speed of 600-1000r/min until the microcrystalline wax is completely and uniformly dispersed, and supplementing 100 parts of ethanol to obtain mixed solution E;
c. under the condition of low-speed stirring at 60-100r/min, adding the pigment weighed according to the proportion into the mixed solution E, gradually increasing the stirring speed to 600-1000r/min, stirring at normal temperature for 0.5-1h, standing and soaking for 8h, performing sand grinding on the uniformly mixed and dispersed ink until the fineness is less than or equal to 20 mu m, and filtering by a 200-mesh screen to obtain the overprint ink.
Preparation of gloss oil
a. Adding ethanol weighed according to the proportion into a container, adding an acrylate copolymer weighed according to the proportion under the low-speed stirring condition of 60-100r/min, cleaning materials adhered to a cylinder wall, a stirring shaft and the like in a feeding cylinder after feeding until the fed materials are dissolved into a whole, gradually increasing the stirring speed to 600 plus materials/min, stirring at normal temperature for 2-4 h, and completely dissolving resin to obtain a mixed solution F;
b. and adding the microcrystalline wax weighed according to the proportion into the mixed solution F, stirring for 0.5-1h at the stirring speed of 600-1000r/min until the microcrystalline wax is completely and uniformly dispersed, complementing the mixture to 100 parts by using ethanol, and filtering by using a 200-mesh screen to obtain the gloss oil.
Printing
And (3) mixing the prepared ground color transparent ink in an environment with the temperature of 22-28 ℃ and the relative humidity of 50-60% according to the mixing ratio of 1: 1, diluting the viscosity to 12s-18s English 2# cup by using an ethanol and ethyl acetate solvent, drying at the temperature of 130 ℃ and 150 ℃ by using a printing plate of 80 lines/cm, and printing at the speed of 180 ℃ and 200m/min, wherein the viscosity is 0.5-0.8g/m2Printing process of dry coating amount at 45g/m2The aluminum layer surface of the aluminum-plated tipping base paper is subjected to ground color printing.
Diluting the prepared overprinting ink to 12s-18s English 2# cup by using ethanol under the environment of the temperature of 22-28 ℃ and the relative humidity of 50-60 percent, and adopting a pattern plate of 90 lines/cm, the drying temperature of 70-80 ℃, the printing speed of 180 DEG/min, the printing speed of 0.1-0.3g/m2Printing process of dry coating amount at 45g/m2The surface of the base color ink of the aluminized tipping paper is printed in an overlapping manner.
Diluting the prepared gloss oil with ethanol to 12s-18s British 2# cup at the temperature of 22-28 ℃ and the relative humidity of 50-60%, and adopting a printing plate of 80 lines/cm, the drying temperature of 130-2Printing process of dry coating amount at 45g/m2The surface of the ink layer of the aluminized tipping paper is printed in an overlapping mode, and then is dried and rolled.
Thirdly, slitting, punching, inspecting and packaging
And cutting and rolling the printed semi-finished tipping paper according to a specified specification, placing the semi-finished tipping paper on a laser drilling machine for single-row laser drilling to increase the air permeability of the product, sampling and detecting related indexes after rolling, and packaging after the semi-finished tipping paper is qualified to obtain the multicolor overprint tipping paper with metallic luster. The tipping paper takes transparent pigment yellow as bottom ink, red pattern ink and transparent gloss oil are overprinted, each ink layer is firmly attached and does not fall off, the appearance is glittering golden and metallic, the tipping paper has the decoration and certain anti-counterfeiting performance which are rich in color, high-grade and luxury, and strong in three-dimensional texture, and the safety and sanitation indexes of the product meet the standard.
Example 2
A multicolor overprinting tipping paper with metallic luster is implemented according to the following technical scheme:
(1) the basis weight of the printing substrate was 36g/m2The aluminized base tipping paper of (1);
(2) the specific formula of the ground color transparent ink comprises the following components in parts by weight: 13 parts of aldehyde ketone resin, 5 parts of vinyl chloride-acetate resin, 4 parts of rosin pentaerythritol ester, 13 parts of cellulose acetate butyrate, 6 parts of transparent pigment yellow, 3 parts of microcrystalline wax, 26.5 parts of ethanol and 26.5 parts of ethyl acetate;
(3) the specific formula of the ink for overprinting comprises the following components in parts by weight: 13 parts of polyvinyl butyral, 17 parts of cellulose acetate butyrate, 4 parts of pigment red, 3 parts of microcrystalline wax and 63 parts of ethanol; the bicolor overprinting ink comprises the following specific components in parts by weight: 13 parts of polyvinyl butyral, 17 parts of cellulose acetate butyrate, 4 parts of pigment coffee, 3 parts of microcrystalline wax and 63 parts of ethanol;
(4) the gloss oil comprises the following specific formula in parts by weight: 33 parts of acrylate copolymer, 2 parts of microcrystalline wax and 65 parts of ethanol.
The production was carried out according to the procedure of example 1 below.
Example 3
A multicolor overprinting tipping paper with metallic luster is implemented according to the following technical scheme:
(1) the basis weight of the printing substrate was 32g/m2The aluminized base tipping paper of (1);
(2) the specific formula of the ground color transparent ink comprises the following components in parts by weight: 15 parts of aldehyde ketone resin, 8 parts of vinyl chloride-acetate resin, 5 parts of rosin pentaerythritol ester, 10 parts of cellulose acetate butyrate, 8 parts of transparent pigment yellow, 4 parts of microcrystalline wax, 25 parts of ethanol and 25 parts of ethyl acetate;
(3) the specific formula of the ink for overprinting comprises the following components in parts by weight: 15 parts of polyvinyl butyral, 15 parts of cellulose acetate butyrate, 5 parts of pigment red, 4 parts of microcrystalline wax and 61 parts of ethanol; the bicolor overprinting ink comprises the following specific components in parts by weight: 15 parts of polyvinyl butyral, 15 parts of cellulose acetate butyrate, 5 parts of pigment coffee, 4 parts of microcrystalline wax and 61 parts of ethanol; the three-color overprinting ink comprises the following specific formula in parts by weight: 15 parts of polyvinyl butyral, 15 parts of cellulose acetate butyrate, 5 parts of pigment blue, 4 parts of microcrystalline wax and 61 parts of ethanol;
(4) the gloss oil comprises the following specific formula in parts by weight: 35 parts of acrylate copolymer, 3 parts of microcrystalline wax and 62 parts of ethanol.
The procedure of example 1 was followed.
Claims (5)
1. The multicolor overprinting tipping paper with metallic luster is characterized by comprising an aluminum-plated tipping base paper layer, an ink layer and a gloss oil layer (8), wherein the aluminum-plated tipping base paper layer sequentially comprises an anti-curling layer (1), a tipping white base paper layer (2), a composite adhesive layer (3), an aluminum-plated layer (4) and a stripping protective layer (5) from inside to outside, and the quantitative tipping white base paper layer is 32-45g/m2The single side of the base paper is polished and connected with white base paper; the printing ink layer comprises a bottom color transparent printing ink layer (6) and an overprint printing ink layer (7); the bottom color transparent ink layer (6), the overprint ink layer (7) and the gloss oil layer (8) are sequentially printed on the stripping protective layer (5); the bottom color transparent ink layer (6) is a full-color ink layer, and the raw materials are as follows according to the weight portion: 5-20 parts of aldehyde ketone resin, 1-10 parts of vinyl chloride-acetate resin, 1-10 parts of rosin pentaerythritol ester, 5-25 parts of cellulose acetate butyrate, 1-15 parts of transparent pigment, 1-5 parts of microcrystalline wax, 20-35 parts of ethanol and 20-35 parts of ethyl acetate;
the overprint ink layer (7) is at least one of a one-color, two-color, three-color pattern or line character, and the used raw materials are as follows according to the weight part: 5-20 parts of polyvinyl butyral, 5-25 parts of cellulose acetate butyrate, 1-10 parts of pigment, 1-5 parts of microcrystalline wax and 40-70 parts of ethanol.
2. The multi-color overprinting tipping paper with metallic luster according to claim 1, characterized in that the base color transparent ink layer is prepared from the following raw materials in parts by weight: 10-15 parts of aldehyde ketone resin, 5-8 parts of vinyl chloride-acetate resin, 3-5 parts of rosin pentaerythritol ester, 10-15 parts of cellulose acetate butyrate, 5-8 parts of transparent pigment, 2-4 parts of microcrystalline wax, 25-30 parts of ethanol and 25-30 parts of ethyl acetate;
the overprint ink layer comprises the following raw materials in parts by weight: 10-15 parts of polyvinyl butyral, 15-20 parts of cellulose acetate butyrate, 3-5 parts of pigment, 2-4 parts of microcrystalline wax and 60-65 parts of ethanol.
3. The multicolor overprinting tipping paper with metallic luster according to claim 1 or 2, wherein the gloss oil layer comprises the following raw materials in parts by weight: 20-45 parts of acrylate copolymer, 1-5 parts of microcrystalline wax and 50-79 parts of ethanol.
4. The multi-color overprinting tipping paper with metallic luster according to claim 3, wherein the gloss oil layer comprises the following raw materials in parts by weight: 30-35 parts of acrylate copolymer, 1-3 parts of microcrystalline wax and 62-69 parts of ethanol.
5. A method of producing a multi-colour, overlapping tipping paper with metallic sheen according to any one of claims 1 to 4, characterised in that it comprises the steps of:
firstly, preparing ink
Preparation of ground color ink
a. Adding the ethanol and the ethyl acetate solvent which are weighed according to the proportion into a container, and stirring at the normal temperature for 3-5 min at the stirring speed of 60-100r/min to obtain a mixed solution A;
b. under the condition of low-speed stirring at 60-100r/min, sequentially adding aldehyde ketone resin, vinyl chloride-acetate copolymer, rosin pentaerythritol ester and cellulose acetate butyrate which are weighed according to the proportion into the mixed solution A, cleaning the fed materials after feeding, putting the materials adhered to the wall of the cylinder and a stirring shaft into a feeding cylinder until the fed materials are dissolved into a whole, gradually increasing the stirring speed to 600-agent addition for 1000r/min, and stirring at normal temperature for 2-4 h to completely dissolve the film-forming resin to obtain mixed solution B;
c. adding microcrystalline wax weighed according to the proportion into the mixed solution B, stirring for 0.5-1h at the stirring speed of 600-: 1, adding the mixed solvent of ethanol and ethyl acetate to 100 parts to obtain mixed solution C;
d. under the condition of low-speed stirring at 60-100r/min, adding the weighed transparent pigment in proportion into the mixed solution C, gradually increasing the stirring speed to 600-1000r/min, stirring at normal temperature for 0.5-1h, standing and soaking for 8h, performing sand grinding on the uniformly mixed and dispersed ink until the fineness is less than or equal to 20 mu m, and filtering by a 200-mesh screen to obtain the bottom color transparent ink;
preparation of overprinting ink
a. Adding ethanol weighed according to a ratio into a container, sequentially adding polyvinyl butyral and cellulose acetate butyrate weighed according to the ratio under the low-speed stirring condition of 60-100r/min, cleaning the materials adhered to the wall of the tank and a stirring shaft when the materials are fed, putting the materials into the feeding tank until the materials are dissolved into a whole, gradually increasing the stirring speed to 600-1000r/min, and stirring at normal temperature for 2-4 h to completely dissolve resin to obtain a mixed solution D;
b. adding microcrystalline wax weighed according to the proportion into the mixed solution D, stirring for 0.5-1h at the stirring speed of 600-1000r/min until the microcrystalline wax is completely and uniformly dispersed, and supplementing 100 parts of ethanol to obtain mixed solution E;
c. under the condition of low-speed stirring at 60-100r/min, adding pigment weighed according to the proportion into the mixed solution E, gradually increasing the stirring speed to 600-1000r/min, stirring at normal temperature for 0.5-1h, standing and soaking for 8h, performing sand grinding on the uniformly mixed and dispersed ink until the fineness is less than or equal to 20 mu m, and filtering by a 200-mesh screen to obtain overprint ink;
preparation of gloss oil
a. Adding ethanol weighed according to the proportion into a container, adding the acrylate copolymer weighed according to the proportion under the low-speed stirring condition of 60-100r/min, cleaning the materials adhered to the wall of the cylinder and a stirring shaft when the materials are fed after feeding until the materials are dissolved into a whole, gradually increasing the stirring speed to 600 plus materials for 1000r/min, and stirring at normal temperature for 2-4 h to completely dissolve resin to obtain a mixed solution F;
b. adding the microcrystalline wax weighed according to the proportion into the mixed solution F, stirring for 0.5-1h at the stirring speed of 600-1000r/min until the microcrystalline wax is completely dispersed uniformly, then supplementing 100 parts of ethanol, and filtering by using a 200-mesh screen to obtain gloss oil;
printing
Firstly, mixing the prepared bottom color transparent ink in an environment with the temperature of 22-28 ℃ and the relative humidity of 50-60% according to the mixing ratio of 1: 1, diluting the viscosity to 12s-18s in British 2# cup by using a printing plate with 80 lines/cm, drying at 130-150 ℃, and printing at a speed of 180-200m/min, wherein the viscosity is 0.5-0.8g/m2Printing process with dry coating amount of 32-45g/m2Performing ground color printing on the surface of the aluminum layer of the aluminum-plated tipping base paper to form a ground color transparent ink layer;
secondly, diluting the prepared overprinting ink with ethanol to 12s-18s in an English 2# cup in an environment with the temperature of 22-28 ℃ and the relative humidity of 50-60 percent, adopting a pattern or a letter master plate with 90 lines/cm, the drying temperature of 70-80 ℃, the printing speed of 180 DEG and the like for 200m/min, and the printing speed of 0.1-0.3g/m2Printing process with dry coating amount of 32-45g/m2The surface of the bottom color ink of the aluminized tipping paper is printed in an overlapping mode to form an overprint ink layer;
thirdly, diluting the prepared gloss oil with ethanol to reach the viscosity of British 2# cup of 12s-18s at the temperature of 22-28 ℃ and the relative humidity of 50-60 percent, and adopting a printing plate of 80 lines/cm, the drying temperature of 130 ℃, the printing speed of 180-0.3 g/m for 200m/min2Printing process with dry coating amount of 32-45g/m2The surface of the ink layer of the aluminized tipping paper is printed in an overlapping way to form a gloss oil layer, and the gloss oil layer is dried and wound;
cutting, punching, inspecting and packaging, cutting and rolling the printed semi-finished tipping paper according to specified specifications, placing the semi-finished tipping paper on a laser drilling machine for single-row laser drilling to increase the air permeability of the product, sampling and detecting relevant indexes after rolling, and packaging after qualification to obtain the multicolor overprinting tipping paper with metallic luster.
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| CN110205868B (en) * | 2019-07-22 | 2021-09-28 | 玉溪接装纸制造有限公司 | Anti-drop and anti-adhesion gloss oil for aluminized tipping paper and preparation method thereof |
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| CN111501405B (en) * | 2020-04-28 | 2023-03-24 | 安徽集友纸业包装有限公司 | Anti-counterfeiting cigarette tipping paper, preparation method thereof, filter element and smoking product |
| CN111548674A (en) * | 2020-05-08 | 2020-08-18 | 宁波佐图文化用品有限公司 | Water-based ink with three-dimensional effect and preparation method thereof |
| EP4225859B1 (en) * | 2020-11-12 | 2024-01-31 | Sun Chemical Corporation | Titanium dioxide-free cigarette tipping inks |
| CN113818280B (en) * | 2021-09-29 | 2022-11-29 | 福建中烟工业有限责任公司 | Cigarette tipping paper, preparation method thereof, tobacco product and application |
| CN113931004A (en) * | 2021-11-19 | 2022-01-14 | 增和包装股份有限公司 | Improved process for softness of ester-soluble ink tipping paper |
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