CN109295806A - A kind of polychrome double exposure tipping paper and preparation method thereof with metallic luster - Google Patents
A kind of polychrome double exposure tipping paper and preparation method thereof with metallic luster Download PDFInfo
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- CN109295806A CN109295806A CN201811175144.5A CN201811175144A CN109295806A CN 109295806 A CN109295806 A CN 109295806A CN 201811175144 A CN201811175144 A CN 201811175144A CN 109295806 A CN109295806 A CN 109295806A
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- ethyl alcohol
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/80—Paper comprising more than one coating
- D21H19/82—Paper comprising more than one coating superposed
- D21H19/822—Paper comprising more than one coating superposed two superposed coatings, both being pigmented
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/103—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds of aldehydes, e.g. phenol-formaldehyde resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/14—Printing inks based on carbohydrates
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/52—Cellulose; Derivatives thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/58—Polymers or oligomers of diolefins, aromatic vinyl monomers or unsaturated acids or derivatives thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/60—Polyalkenylalcohols; Polyalkenylethers; Polyalkenylesters
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/62—Macromolecular organic compounds or oligomers thereof obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
Abstract
The invention discloses a kind of polychrome double exposure tipping paper and preparation method thereof with metallic luster, sets gradually aluminize tipping base paper layer, ink layer, light oil reservoir from inside to outside.For tipping paper of the present invention using the aluminium layer for tipping base paper of aluminizing as printing surface, background color uses transparent alcohol ester type ink, and ink can be bonded containing polar hydroxyl group with metallic aluminium, has excellent adhesive force to metallic aluminium, realization directly prints on metallic aluminum；Meanwhile solvent misture is equipped in ink, do not fall off background color layer of ink with metallic aluminum and polychrome double exposure layer of ink adhesion-tight；In addition, the printing ink solvent release property used is good, tipping paper product safety sanitary index is complied with standard.In the case where aluminium layer metallic luster and ink gloss be combined with each other, which has the dicoration and certain antifalsification that metallic luster visual effect is obvious, rich in color, top grade is luxurious, match volume is strong.
Description
Technical field
The present invention relates to ink and tipping paper, be more particularly to a kind of polychrome double exposure tipping paper with metallic luster and
Preparation method.
Background technique
Tipping paper is a kind of special industrial paper, is mainly used for filter tip and Cigarette cigarette, is commonly called as " cork paper ".With
Abundant, the transformation of the consumption concept and health perception of people of modern society's substance and cultural life, also have to cigarette packaging
New requirement, the purposes of tipping paper are not limited solely to simple packaging, more focus on decorative, have tipping paper bigger
Market potential and development space.
Metallic luster printing printing can produce it is a kind of flash of light, it is bright, luxurious, quiet and tastefully laid out, unique, peculiar, magnificent
Visual effect greatly improves the class and grade of commodity packaging, is especially popular in package decoration field, is mainly used for eating
The high-grade outer packing of product, cigarette, wine, medicine, change shape product, clothes, household electrical appliances, toy, craftwork, gift etc..
Metal ink is formulated by tiny sheet metal, and aluminum slice is used for aluminium ink, and copper foil is for gold
Color ink, after ink setting, these thin slices form a thin layer in printing product surface, and sheet metal particle reflected light will produce
The metallic luster such as raw higher gold or silver.Metallic surface effect magnificent in this way can attract the eyeball of consumer, thus
Promote the class and competitiveness of product.In addition, metal ink also has using conveniently, it can print, mention as common ink
The advantages that high efficiency, therefore, metal ink, have obtained the welcome of packages printing industry.But metal ink is lacked there is also many
Point, such as its metallic luster are generated using big sheet metal particle reflected light, and effect is not achieved through vacuum evaporation gold
The metallic luster of mirror surface is formed after belonging to cooling, there are also its process for preparation due to avoiding damage to sheet metal structure and leading to tarnish
Without grinding, gentle agitation can only be leaned on, dispersion unevenly can be such that metallic luster effect substantially reduces, and during storage
It is unstable it is easy precipitate, metal layer of ink is unable to get three-dimensional and strong metal sense multicolor printing without printability.
Tipping paper aluminize using aluminium layer as printing surface, aluminium layer surface is more smooth, there is mirror effect, pore-free, surface absorbency
Can be poor, use more environmentally friendly alcohol ink or water-based ink, because poor adhesive force is also easy to produce layer of ink obscission.Ester soluble ink
With stronger adhesive force, firm layer of ink can be obtained on aluminium layer, to obtain coloury printing, subsequent double exposure process
Must be using the ester soluble ink with system, but ester dissolubility system solvent release is poor, and VOC residual is exceeded in product.Currently, also going out
It coats the method that one layer of primary coat is printed again first on present aluminium layer to overcome attachment fastness and problem of solvent residual, such as discloses
Patent of invention " transfevent tipping paper and preparation method thereof, application number: 201710228740.4 ", provide a kind of elder generation in metal
The clear bottom masking liquid containing resin, then the method for carrying out base gravure ink printing are coated on aluminium layer, it must not be directly in metal with solution
The problem of printing on aluminium layer, but such primary coat technique is arranged exists and increases that production cost, production efficiency is low and dull coloring
Defect.
Summary of the invention
To solve the deficiencies in the prior art, the present invention is intended to provide one kind has, metallic luster visual effect is obvious, color
Abundant, high-grade luxurious polychrome double exposure tipping paper and preparation method thereof.Tipping paper of the present invention is with the aluminium for tipping base paper of aluminizing
Layer is printing surface, and background color uses transparent alcohol ester type ink, and ink can be bonded containing polar hydroxyl group with metallic aluminium, to metal
Aluminium has excellent adhesive force, and realization directly prints on metallic aluminum.
In order to achieve the above objectives, the present invention uses following technological means: a kind of polychrome double exposure tipping with metallic luster
Paper, including tipping base paper layer of aluminizing, ink layer and light oil reservoir 8, the tipping base paper layer of aluminizing successively includes anti-roll from inside to outside
Bent layer 1, the white original paper layer 2 of tipping, composite layer 3, aluminium coated 4 and removing protective layer 5, are hinged with white original paper layer using quantification of 32-
45g/m2Machine glazing be hinged with white body paper；The ink layer includes background color transparent ink layer 6 and double exposure ink layer 7；Background color is transparent
Ink layer 6, double exposure ink layer 7 and light oil reservoir 8 are successively printed on removing protective layer 5.
The background color transparent ink layer is full version layer of ink of the same colour, and raw materials used proportion in parts by weight is as follows: aldehyde ketone
5-20 parts of resin, 1-10 parts of vinyl chloride-vinyl acetate resin, 1-10 parts of pentalyn, 5-25 parts of acetylbutyrylcellulose, transparent pigment
1-15 parts, 1-5 parts of microwax, 20-35 parts of ethyl alcohol, 20-35 parts of ethyl acetate.Preferably, it is raw materials used in parts by weight
It matches as follows: 10-15 parts of aldehyde ketone resin, 5-8 parts of vinyl chloride-vinyl acetate resin, 3-5 parts of pentalyn, acetylbutyrylcellulose 10-
15 parts, 5-8 parts of transparent pigment, 2-4 parts of microwax, 25-30 parts of ethyl alcohol, 25-30 parts of ethyl acetate.
The double exposure ink layer is at least one of of the same colour, two colors, trichromatic diagram case or lines text, and raw materials used press weighs
It is as follows to measure number calculating proportion: 5-20 parts of polyvinyl butyral, 5-25 parts of acetylbutyrylcellulose, 1-10 parts of pigment, crystallite
1-5 parts of wax, 40-70 parts of ethyl alcohol.Preferably, raw materials used proportion in parts by weight is as follows: polyvinyl butyral 10-15
Part, 15-20 parts of acetylbutyrylcellulose, 3-5 parts of pigment, 2-4 parts of microwax, 60-65 parts of ethyl alcohol.
The material of the light oil reservoir includes acrylic acid esters co-polymer, microwax, raw materials used to match in parts by weight
Than as follows: 20-45 parts of acrylic acid esters co-polymer, 1-5 parts of microwax, 50-79 parts of ethyl alcohol.Preferably, it is raw materials used by weight
It is as follows that number calculates proportion: 30-35 parts of acrylic acid esters co-polymer, 1-3 parts of microwax, 62-69 parts of ethyl alcohol.
Wherein, aldehyde ketone resin popular name polyketone resin, ketone resin are that a kind of have high brightness, sunproof neutral, non-soap
Change type cyclohexanone-formaldehyde resin, shallow white particulate or blocks of solid dissolves in common most of solvents, with it is other mostly
Count the compatible of resin.It is mainly used in the systems such as solvent-based ink, coating, general color paste, adhesive, for improving the light of product
Damp degree, adhesive force, quick-drying, levelability, the wetability of pigment and amount of solid content etc..
Vinyl chloride-vinyl acetate resin is the copolymer of vinyl chloride and vinyl acetate, is dissolved completely in organic solvent such as ketone, ester.Solubility is non-
Chang Hao possesses the high tenacity of vinyl chloride and the strong viscosity and plasticity of corrosion resistance and vinyl acetate.To metal especially aluminium
There is superior adherence, also there is excellent adherence to PVC product, paper, fiber, glass, ceramic tile, sandstone, timber.With to face
It is the polymolecularity of material, excellent film forming and solvent release, flexibility, high-wearing feature, chemical resistance, anti-flammability, good molten
Solution property and craftsmanship and extensive adjustable property.Therefore, vinyl chloride-vinyl acetate resin be configure industrial coating preferred adhering resin due to
Its hydroxy functional groups, so that it is with excellent pigment-dispersing, color developing and good polymer compatibility, with PU
The cooperation such as polyurethane resin, alkyd resin, epoxy resin, Lauxite, aldehyde ketone resin, melamine resin, acrylic resin
It uses, makes full use of the characteristic of different resins.
Pentalyn be by rosin or pale rosin after modified with pentaerythrite lactate synthesis, at vacuum
Irregular transparent cake, sheet or granular solids are made after reason, are widely applied as tackifier in adhesive industry.Have product
There is outstanding heat-resisting, anti-aging and good stability, compatibility and dissolubility are good, and excellent surface drag and good color are protected
Holding property.Outstanding viscosity, internal cohesiveness, excellent heat resistance is well compatible with wax and EVA polymer, and outstanding is anti-oxidant
Property, it is mainly used in hot melt adhesive, pressure sensitive adhesive and rubber industry.
Acetylbutyrylcellulose abbreviation CAB is used as auxiliary agent, modified resin or main film forming substance in ink and coating
When, levelability can be improved, mitigate pitfall, shorten drying time, reduce pressure viscosity, metallic pigments stable carrier, abrasiveness, ultraviolet light
Stability, improvement pulverability, the resistance to bursting by freezing of enhancing, mitigates solvent crackle, improvement slip, reduces the migration of plasticizer yellowing-resistant
Property, viscosity control, pigment grind medium, control aluminium orientation, solvent resistant back dissolving function again.
Microwax is micronized polyethylene wax micro mist, this product white powder, with viscosity is low, softening point is high, color is white, gloss
Degree is high, lubricity is good, higher hardness, wearability is good, prevents adhesion and stain resistant, anti-precipitating, resistance to marring, mar-resistance and flat
Sliding feel, the extremely excellent property of dispersibility.Its is fast light and chemical property is good, can use the carrier of pigment, can improve paint, oil
The wearability of ink improves the dispersibility of pigment and filler, prevents pigment from sinking to the bottom.Applied to woodcare paint, industrial paint, powdery paints with
And the ink areas such as inner print, table print, silk screen, relief printing plate, intaglio plate.
Polyvinyl butyral PVB is a kind of supporter being often used, it has binding force, the high optical clarity of strength
Degree is easily sticked in a variety of different surfaces, high tenacity and elastomeric resin.Structure is white powder, relative density 1.08~
1.10, dissolve in methanol, ethyl alcohol, ketone, alkyl halide, aromatic hydrocarbon solvent.Because containing high hydroxyl, to the dispersibility that pigment has had,
It is therefore widely used in printing ink and coating, produces alcohol-soluble printing ink with PVB, nontoxic, environmental protection meets state food
Pack safety standard requirement.
Wherein, acrylic acid esters co-polymer is thermoplastic acrylic resin, by acrylic acid, methacrylic acid and its derivative
Object, one kind thermoplastic resin as made of esters, nitrile, amide Type of Collective.It can be repeatedly by thermal softening and cooled and solidified.Generally
Chain macromolecule compound can be homopolymer, be also possible to copolymer, have preferable physical mechanical property, weatherability, resistance to
It is high to protect light colour retention for chemicals and excellent water resistance.The hot acrylic resin molecular weight of heat of coatings industry is generally 75
000~120 000, common nitrocellulose, cellulose acetate-butyrate and superchlorinated polyvinyl chloride resin etc. spell use with it, to improve film
Performance.Acrylic resin is used widely in solvent-based ink, most of to dissolve in aromatic hydrocarbons, in esters equal solvent, also
It is some to dissolve in alcohols solvent, it is mainly used for the manufacture of photogravure ink and flexographic plate printing ink.Since it is with clear, colorless
Feature, and be used to manufacture finishing oil.
Ethyl alcohol is a kind of organic matter, is commonly called as alcohol, is the saturated monohydroxy alcohol with a hydroxyl, is under room temperature, normal pressure
A kind of inflammable, volatile colourless transparent liquid, its aqueous solution has the smell of aroma, and slightly stimulates.There are smells of wine
With the pungent flavour of stimulation, micro-sweet.Ethyl alcohol has many uses, and acetic acid, beverage, essence, coating, ink etc. can be manufactured with ethyl alcohol.
Ethyl acetate is colorless clear liquid, is nitrocellulose, ethyl cellulose, cellulose acetate and neoprene
Quick-drying solvent, and the low-toxic solvent industrially used.
A kind of preparation method of the polychrome double exposure tipping paper with metallic luster of the present invention the following steps are included:
One, prepared by ink
1. prepared by background color transparent ink
A, load weighted solvent according to the ratio is added to the container 3~5min of stirring at normal temperature, mixing speed 60-100r/min,
Obtain mixed liquor A；
B, under the conditions of 60-100r/min is stirred at low speed, sequentially added into mixed liquor A according to the ratio load weighted aldehyde ketone resin,
Vinyl chloride-vinyl acetate resin, pentalyn, acetylbutyrylcellulose are adhered on casing wall, agitating shaft etc. when cleaning feeds intake after finishing
Material be integrated in the cylinder that feeds intake to thrown material is molten, step up mixing speed to 600-1000r/min, stirring at normal temperature 2
~4h makes film-forming resin dissolution completely, obtains mixed liquid B；
C, load weighted microwax according to the ratio is added in mixed liquid B, stirs 0.5~1h, mixing speed 600-1000r/
Min, until being completely dispersed uniformly, the ethyl alcohol for being 1:1 with ratio and ethyl acetate mixed solvent are supplied to 100 parts, and mixed liquor is obtained
C；
D, under the conditions of 60-100r/min is stirred at low speed, load weighted transparent pigment according to the ratio is added into mixed liquor C, gradually
Mixing speed is promoted to 600-1000r/min, 8h is standing and soaking after stirring at normal temperature 0.5-1h, finely dispersed ink will be mixed
Turn sand milling process to be sanded to fineness≤20 μm, 200 mesh net filtrations obtain background color transparent ink.
2. prepared by double exposure ink.
A, load weighted ethyl alcohol according to the ratio is added to the container, under the conditions of 60-100r/min is stirred at low speed, is sequentially added
Load weighted polyvinyl butyral, acetylbutyrylcellulose according to the ratio are adhered to casing wall, agitating shaft when cleaning feeds intake after finishing
Material Deng on is integrated in the cylinder that feeds intake to thrown material is molten, steps up mixing speed to 600-1000r/min, room temperature stirs
2~4h is mixed, makes resin dissolution completely, obtains mixed liquor D；
B, load weighted microwax according to the ratio is added in mixed liquor D, stirs 0.5~1h, mixing speed 600-1000r/
Min is supplied to 100 parts with ethyl alcohol until being completely dispersed uniformly, obtains mixed liquor E；
C, under the conditions of 60-100r/min is stirred at low speed, load weighted pigment according to the ratio is added into mixed liquor E, steps up
Mixing speed is standing and soaking 8h after stirring at normal temperature 0.5-1h, will mix finely dispersed ink and turn sand to 600-1000r/min
Grinder sequence is sanded to fineness≤20 μm, and 200 mesh net filtrations obtain double exposure ink.
3. prepared by gloss oil.
A, load weighted ethyl alcohol according to the ratio is added to the container, under the conditions of 60-100r/min is stirred at low speed, is added by matching
Than load weighted acrylic acid esters co-polymer, the material that is adhered on casing wall, agitating shaft etc. when cleaning feeds intake after finishing is in feeding intake
It is integrated in cylinder to thrown material is molten, stepping up mixing speed to 600-1000r/min, 2~4h of stirring at normal temperature makes resin
Dissolution completely, obtains mixed liquor F；
B, load weighted microwax according to the ratio is added in mixed liquor F, stirs 0.5~1h, mixing speed 600-1000r/
Min is supplied with ethyl alcohol to 100 parts, 200 mesh net filtrations obtain gloss oil until being completely dispersed uniformly.
Two, it prints
1. the background color transparent ink prepared is used mixed proportion in the environment of 22-28 DEG C of temperature, relative humidity 50-60%
It is 2# glasss English to 12s-18s for the ethyl alcohol and ethyl acetate solvent diluted viscosity of 1:1, by using 80 lines/cm galley, dry
Dry 130-150 DEG C of temperature, printing speed 180-200m/min, 0.5-0.8g/m2The printing technology of dry-coated amount, in 32-45g/m2
Tipping base paper of aluminizing aluminium layer surface carry out background color printing.
2. the double exposure ink prepared is diluted in the environment of 22-28 DEG C of temperature, relative humidity 50-60% with ethyl alcohol
Viscosity is 2# glasss English to 12s-18s, by using 90 lines/cm pattern or alphabet, 70-80 DEG C of drying temperature, printing speed
180-200m/min, 0.1-0.3g/m2The printing technology of dry-coated amount, in 32-45g/m2Tipping paper of aluminizing background color ink surface
Carry out overlapping printing.
3. the gloss oil that will be prepared, in the environment of 22-28 DEG C of temperature, relative humidity 50-60%, with ethyl alcohol diluted viscosity
It is 2# glasss English to 12s-18s, by using 80 lines/cm galley, 130-150 DEG C of drying temperature, printing speed 180-200m/
Min, 0.1-0.3g/m2The printing technology of dry-coated amount, in 32-45g/m2The layer of ink surface of tipping paper of aluminizing carry out overlapping print
Brush, drying winding.
Three, it cuts, punch, examine and packs
Tipping paper semi-finished product through printing are placed on laser-beam drilling machine by regulatory specifications splitting winding and are carried out single laser and beat
Hole, to increase the air permeability of product, sample detection index of correlation after winding is packed after qualified to get with the more of metallic luster
Color double exposure tipping paper.
The invention has the following advantages:
A kind of polychrome double exposure tipping paper with metallic luster of the present invention is printing with the aluminium layer for tipping base paper of aluminizing
Face, background color use transparent alcohol ester type ink, and ink can be bonded containing polar hydroxyl group with metallic aluminium, have to metallic aluminium excellent
Good adhesive force, realization directly print on metallic aluminum；Meanwhile solvent misture is equipped in ink, make background color layer of ink and metal
Aluminium layer and polychrome double exposure layer of ink adhesion-tight are not fallen off, and light oil reservoir can make entirely to print ink blast, and are prevented and treated ink layer and fallen off.
Polychrome double exposure tipping paper prepared by the present invention with metallic luster, the printing ink solvent release property of use is good, tipping
Paper product safety and sanitation index complies with standard.
Polychrome double exposure tipping paper prepared by the present invention with metallic luster, has that metallic luster visual effect is obvious, color
The dicoration and certain antifalsification that coloured silk is abundant, top grade is luxurious, match volume is strong.
Detailed description of the invention
Fig. 1 is tipping paper structural schematic diagram of the present invention.
In figure: anti-curl layers 1, the white original paper layer 2 of tipping, composite layer 3, aluminium coated 4 remove protective layer 5, background color clean oil
Layer of ink 6, double exposure ink layer 7, light oil reservoir 8.
Specific embodiment
Embodiment 1
A kind of polychrome double exposure tipping paper with metallic luster, including tipping base paper layer of aluminizing, ink layer and light oil reservoir 8, it is described
Tipping base paper layer of aluminizing successively includes anti-curl layers 1, the white original paper layer 2 of tipping, composite layer 3, aluminium coated 4 and removing from inside to outside
Protective layer 5, the ink layer include background color transparent ink layer 6 and double exposure ink layer 7；Background color transparent ink layer 6, double exposure ink layer
7 and light oil reservoir 8 be successively printed on removing protective layer 5 on.
Implement by following technical scheme:
(1) printing element is quantification of 45g/m2Base paper for tipping paper of aluminizing；
(2) background color transparent ink, specific formula are calculated by weight as: 10 parts of aldehyde ketone resin, 7 parts of vinyl chloride-vinyl acetate resin, rosin season penta
Four 3 parts of alcohol esters, 15 parts of acetylbutyrylcellulose, transparent pigment yellow 5 parts, 2 parts of microwax, 29 parts of ethyl alcohol, 29 parts of ethyl acetate；
(3) double exposure ink of the same colour, specific formula are calculated by weight as: 10 parts of polyvinyl butyral, acetylbutyrylcellulose
20 parts, pigment red 3 part, 2 parts of microwax, 65 parts of ethyl alcohol；
(4) gloss oil, specific formula are calculated by weight as: 30 parts of acrylic acid esters co-polymer, 1 part of microwax, 69 parts of ethyl alcohol.
Follow the steps below production:
One, prepared by ink
1. prepared by background color transparent ink
A, load weighted solvent according to the ratio is added to the container 3~5min of stirring at normal temperature, mixing speed 60-100r/min is obtained
Mixed liquor A；
B, under the conditions of 60-100r/min is stirred at low speed, sequentially added into mixed liquor A according to the ratio load weighted aldehyde ketone resin,
Vinyl chloride-vinyl acetate resin, pentalyn, acetylbutyrylcellulose are adhered on casing wall, agitating shaft etc. when cleaning feeds intake after finishing
Material be integrated in the cylinder that feeds intake to thrown material is molten, step up mixing speed to 600-1000r/min, stirring at normal temperature 2
~4h makes film-forming resin dissolution completely, obtains mixed liquid B；
C, load weighted microwax according to the ratio is added in mixed liquid B, stirs 0.5~1h, mixing speed 600-1000r/
Min, until being completely dispersed uniformly, the ethyl alcohol for being 1:1 with ratio and ethyl acetate mixed solvent are supplied to 100 parts, and mixed liquor is obtained
C；
D, under the conditions of 60-100r/min is stirred at low speed, load weighted transparent pigment according to the ratio is added into mixed liquor C, gradually
Mixing speed is promoted to 600-1000r/min, 8h is standing and soaking after stirring at normal temperature 0.5-1h, finely dispersed ink will be mixed
Turn sand milling process to be sanded to fineness≤20 μm, 200 mesh net filtrations obtain background color transparent ink.
2. prepared by double exposure ink
A, load weighted ethyl alcohol according to the ratio is added to the container, under the conditions of 60-100r/min is stirred at low speed, is sequentially added by matching
Than load weighted polyvinyl butyral, acetylbutyrylcellulose, it is adhered on casing wall, agitating shaft etc. when cleaning feeds intake after finishing
Material be integrated in the cylinder that feeds intake to thrown material is molten, step up mixing speed to 600-1000r/min, stirring at normal temperature 2
~4h makes resin dissolution completely, obtains mixed liquor D；
B, load weighted microwax according to the ratio is added in mixed liquor D, stirs 0.5~1h, mixing speed 600-1000r/
Min is supplied to 100 parts with ethyl alcohol until being completely dispersed uniformly, obtains mixed liquor E；
C, under the conditions of 60-100r/min is stirred at low speed, load weighted pigment according to the ratio is added into mixed liquor E, steps up
Mixing speed is standing and soaking 8h after stirring at normal temperature 0.5-1h, will mix finely dispersed ink and turn sand to 600-1000r/min
Grinder sequence is sanded to fineness≤20 μm, and 200 mesh net filtrations obtain double exposure ink.
3. prepared by gloss oil
A, load weighted ethyl alcohol according to the ratio is added to the container, under the conditions of 60-100r/min is stirred at low speed, addition claims according to the ratio
Measured acrylic acid esters co-polymer, the material being adhered on casing wall, agitating shaft etc. when cleaning feeds intake after finishing is in the cylinder that feeds intake
It is integrated to thrown material is molten, stepping up mixing speed dissolves resin to 600-1000r/min, 2~4h of stirring at normal temperature
Completely, mixed liquor F is obtained；
B, load weighted microwax according to the ratio is added in mixed liquor F, stirs 0.5~1h, mixing speed 600-1000r/
Min is supplied with ethyl alcohol to 100 parts, 200 mesh net filtrations obtain gloss oil until being completely dispersed uniformly.
Two, it prints
The background color transparent ink that will be prepared is with mixed proportion in the environment of 22-28 DEG C of temperature, relative humidity 50-60%
The ethyl alcohol and ethyl acetate solvent diluted viscosity of 1:1 is 2# glasss English to 12s-18s, by using 80 lines/cm galley, drying
130-150 DEG C of temperature, printing speed 180-200m/min, 0.5-0.8g/m2The printing technology of dry-coated amount, in 45g/m2Aluminize
The aluminium layer surface of tipping base paper carries out background color printing.
The double exposure ink that will be prepared is diluted viscous in the environment of 22-28 DEG C of temperature, relative humidity 50-60% with ethyl alcohol
Degree is 2# glasss English to 12s-18s, by using 90 lines/cm pattern plate, 70-80 DEG C of drying temperature, printing speed 180-200m/
Min, 0.1-0.3g/m2The printing technology of dry-coated amount, in 45g/m2The background color ink surface of tipping paper of aluminizing carry out overlapping printing.
The gloss oil that will be prepared, in the environment of 22-28 DEG C of temperature, relative humidity 50-60%, extremely with ethyl alcohol diluted viscosity
12s-18s is 2# glasss English, by using 80 lines/cm galley, 130-150 DEG C of drying temperature, printing speed 180-200m/
Min, 0.1-0.3g/m2The printing technology of dry-coated amount, in 45g/m2The layer of ink surface of tipping paper of aluminizing carry out overlapping printing, dry
Dry winding.
Three, it cuts, punch, examine and packs
Tipping paper semi-finished product through printing are placed on laser-beam drilling machine by regulatory specifications splitting winding and are carried out single laser and beat
Hole, to increase the air permeability of product, sample detection index of correlation after winding is packed after qualified to get with the more of metallic luster
Color double exposure tipping paper.The tipping paper is using transparent pigment Huang as background color ink, double exposure red pattern ink and transparent varnish, each layer of ink attachment
Do not fall off securely, appearance flashes golden metallic luster, with rich in color, top grade is luxurious, match volume is strong dicoration and
Certain antifalsification, and product safety sanitary index complies with standard.
Embodiment 2
A kind of polychrome double exposure tipping paper with metallic luster is implemented by following technical scheme:
(1) printing element is quantification of 36g/m2Base paper for tipping paper of aluminizing；
(2) background color transparent ink, specific formula are calculated by weight as: 13 parts of aldehyde ketone resin, 5 parts of vinyl chloride-vinyl acetate resin, rosin season penta
Four 4 parts of alcohol esters, 13 parts of acetylbutyrylcellulose, transparent pigment yellow 6 parts, 3 parts of microwax, 26.5 parts of ethyl alcohol, ethyl acetate 26.5
Part；
(3) double exposure ink of the same colour, specific formula are calculated by weight as: 13 parts of polyvinyl butyral, acetylbutyrylcellulose
17 parts, pigment red 4 part, 3 parts of microwax, 63 parts of ethyl alcohol；Two color double exposure ink, specific formula are calculated by weight as: polyethylene
13 parts of butyral, 17 parts of acetylbutyrylcellulose, pigment coffee-like 4 parts, 3 parts of microwax, 63 parts of ethyl alcohol；
(4) gloss oil, specific formula are calculated by weight as: 33 parts of acrylic acid esters co-polymer, 2 parts of microwax, 65 parts of ethyl alcohol.
According to the following examples 1 the step of produced.
Embodiment 3
A kind of polychrome double exposure tipping paper with metallic luster is implemented by following technical scheme:
(1) printing element is quantification of 32g/m2Base paper for tipping paper of aluminizing；
(2) background color transparent ink, specific formula are calculated by weight as: 15 parts of aldehyde ketone resin, 8 parts of vinyl chloride-vinyl acetate resin, rosin season penta
Four 5 parts of alcohol esters, 10 parts of acetylbutyrylcellulose, transparent pigment yellow 8 parts, 4 parts of microwax, 25 parts of ethyl alcohol, 25 parts of ethyl acetate；
(3) double exposure ink of the same colour, specific formula are calculated by weight as: 15 parts of polyvinyl butyral, acetylbutyrylcellulose
15 parts, 5 parts of paratonere, 4 parts of microwax, 61 parts of ethyl alcohol；Two color double exposure ink, specific formula are calculated by weight as: polyethylene
15 parts of butyral, 15 parts of acetylbutyrylcellulose, pigment coffee-like 5 parts, 4 parts of microwax, 61 parts of ethyl alcohol；Three color double exposure oil
Ink, specific formula are calculated by weight as: 15 parts of polyvinyl butyral, 15 parts of acetylbutyrylcellulose, 5 parts of pigment blue, micro-
4 parts of brilliant wax, 61 parts of ethyl alcohol；
(4) gloss oil, specific formula are calculated by weight as: 35 parts of acrylic acid esters co-polymer, 3 parts of microwax, 62 parts of ethyl alcohol.
It is produced according to the step of embodiment 1.
Claims (6)
1. a kind of polychrome double exposure tipping paper with metallic luster, which is characterized in that including tipping base paper layer of aluminizing, ink layer and
Light oil reservoir (8), the tipping base paper layer of aluminizing successively include anti-curl layers (1), are hinged with white original paper layer (2), are compound from inside to outside
Glue-line (3), aluminium coated (4) and removing protective layer (5) are hinged with white original paper layer using quantification of 32-45g/m2Machine glazing tipping
White body paper；The ink layer includes background color transparent ink layer (6) and double exposure ink layer (7)；Background color transparent ink layer (6), double exposure
Ink layer (7) and light oil reservoir (8) are successively printed in removing protective layer (5).
2. a kind of polychrome double exposure tipping paper with metallic luster according to claim 1, which is characterized in that the bottom
Color transparent ink layer is full version layer of ink of the same colour, and raw materials used proportion in parts by weight is as follows: 5-20 parts of aldehyde ketone resin, chlorine vinegar
1-10 parts of resin, 1-10 parts of pentalyn, 5-25 parts of acetylbutyrylcellulose, 1-15 parts of transparent pigment, microwax 1-5
Part, 20-35 parts of ethyl alcohol, 20-35 parts of ethyl acetate；
The double exposure ink layer is at least one of of the same colour, two colors, trichromatic diagram case or lines text, it is raw materials used by weight
It is as follows that number calculates proportion: 5-20 parts of polyvinyl butyral, 5-25 parts of acetylbutyrylcellulose, 1-10 parts of pigment, microwax 1-5
Part, 40-70 parts of ethyl alcohol.
3. a kind of polychrome double exposure tipping paper with metallic luster according to claim 2, which is characterized in that the bottom
The raw materials used proportion in parts by weight of color transparent ink layer is as follows: 10-15 parts of aldehyde ketone resin, 5-8 parts of vinyl chloride-vinyl acetate resin, rosin
3-5 parts of pentaerythritol ester, 10-15 parts of acetylbutyrylcellulose, 5-8 parts of transparent pigment, 2-4 parts of microwax, 25-30 parts of ethyl alcohol,
25-30 parts of ethyl acetate；
The raw materials used proportion in parts by weight of the double exposure ink layer is as follows: 10-15 parts of polyvinyl butyral, acetic acid fourth
15-20 parts of acid cellulose, 3-5 parts of pigment, 2-4 parts of microwax, 60-65 parts of ethyl alcohol.
4. a kind of polychrome double exposure tipping paper with metallic luster according to claim 2 or 3, original used in the light oil reservoir
Material matches as follows in parts by weight: 20-45 parts of acrylic acid esters co-polymer, 1-5 parts of microwax, 50-79 parts of ethyl alcohol.
5. a kind of polychrome double exposure tipping paper with metallic luster according to claim 4, the light oil reservoir are raw materials used
It matches in parts by weight as follows: 30-35 parts of acrylic acid esters co-polymer, 1-3 parts of microwax, 62-69 parts of ethyl alcohol.
6. the preparation side of described in any item a kind of polychrome double exposure tipping papers with metallic luster according to claim 1-5
Method, which comprises the following steps:
One, prepared by ink
1. prepared by background color ink
A, load weighted ethyl alcohol, ethyl acetate solvent according to the ratio are added to the container 3~5min of stirring at normal temperature, mixing speed is
60-100r/min obtains mixed liquor A；
B, under the conditions of 60-100r/min is stirred at low speed, sequentially added into mixed liquor A according to the ratio load weighted aldehyde ketone resin,
Vinyl chloride-vinyl acetate resin, pentalyn, acetylbutyrylcellulose are adhered on casing wall, agitating shaft etc. when cleaning feeds intake after finishing
Material be integrated in the cylinder that feeds intake to thrown material is molten, step up mixing speed to 600-1000r/min, stirring at normal temperature 2
~4h makes film-forming resin dissolution completely, obtains mixed liquid B；
C, load weighted microwax according to the ratio is added in mixed liquid B, stirs 0.5~1h, mixing speed 600-1000r/
Min, until being completely dispersed uniformly, then the ethyl alcohol and ethyl acetate mixed solvent that are 1:1 with ratio are supplied to 100 parts, must be mixed
Liquid C；
D, under the conditions of 60-100r/min is stirred at low speed, load weighted transparent pigment according to the ratio is added into mixed liquor C, gradually
Mixing speed is promoted to 600-1000r/min, 8h is standing and soaking after stirring at normal temperature 0.5-1h, finely dispersed ink will be mixed
Turn sand milling process to be sanded to fineness≤20 μm, 200 mesh net filtrations obtain background color transparent ink；
2. prepared by double exposure ink
A, load weighted ethyl alcohol according to the ratio is added to the container, under the conditions of 60-100r/min is stirred at low speed, is sequentially added by matching
Than load weighted polyvinyl butyral, acetylbutyrylcellulose, it is adhered on casing wall, agitating shaft etc. when cleaning feeds intake after finishing
Material be integrated in the cylinder that feeds intake to thrown material is molten, step up mixing speed to 600-1000r/min, stirring at normal temperature 2
~4h makes resin dissolution completely, obtains mixed liquor D；
B, load weighted microwax according to the ratio is added in mixed liquor D, stirs 0.5~1h, mixing speed 600-1000r/
Min is supplied to 100 parts with ethyl alcohol until being completely dispersed uniformly, obtains mixed liquor E；
C, under the conditions of 60-100r/min is stirred at low speed, load weighted pigment according to the ratio is added into mixed liquor E, steps up
Mixing speed is standing and soaking 8h after stirring at normal temperature 0.5-1h, will mix finely dispersed ink and turn sand to 600-1000r/min
Grinder sequence is sanded to fineness≤20 μm, and 200 mesh net filtrations obtain double exposure ink；
3. prepared by gloss oil
A, load weighted ethyl alcohol according to the ratio is added to the container, under the conditions of 60-100r/min is stirred at low speed, addition claims according to the ratio
Measured acrylic acid esters co-polymer, the material being adhered on casing wall, agitating shaft etc. when cleaning feeds intake after finishing is in the cylinder that feeds intake
It is integrated to thrown material is molten, stepping up mixing speed keeps resin molten to 600-1000r/min, 2~4h of stirring at normal temperature
Solution completely, obtains mixed liquor F；
B, load weighted microwax according to the ratio is added in mixed liquor F, stirs 0.5~1h, mixing speed 600-1000r/
Min until being completely dispersed uniformly, then is supplied with ethyl alcohol to 100 parts, and 200 mesh net filtrations obtain gloss oil；
Two, it prints
1. the background color transparent ink prepared is used mixed proportion in the environment of 22-28 DEG C of temperature, relative humidity 50-60%
For 1:1 ethyl alcohol and ethyl acetate solvent diluted viscosity to English 2# glasss of 12s-18s, by using 80 lines/cm galley, dry
Dry 130-150 DEG C of temperature, printing speed 180-200m/min, 0.5-0.8g/m2The printing technology of dry-coated amount, in 32-45g/m2
Tipping base paper of aluminizing aluminium layer surface carry out background color printing, formed background color transparent ink layer；
2. the double exposure ink that will be prepared, in the environment of 22-28 DEG C of temperature, relative humidity 50-60%, with ethyl alcohol diluted viscosity
To English 2# glasss of 12s-18s, by using 90 lines/cm pattern or alphabet, 70-80 DEG C of drying temperature, printing speed 180-
200m/min, 0.1-0.3g/m2The printing technology of dry-coated amount, in 32-45g/m2Tipping paper of aluminizing background color ink surface carry out
Overlapping printing, forms double exposure ink layer；
3. the gloss oil that will be prepared, in the environment of 22-28 DEG C of temperature, relative humidity 50-60%, with ethyl alcohol diluted viscosity to English
2# glasss of 12s-18s of formula by using 80 lines/cm galley, 130-150 DEG C of drying temperature, print speed 180-200m/min,
0.1-0.3g/m2The printing technology of dry-coated amount, in 32-45g/m2The layer of ink surface of tipping paper of aluminizing carry out overlapping printing, shape
At light oil reservoir, drying winding；
Three, it cuts, punch, examining and packaging, the tipping paper semi-finished product through printing are placed in sharp by regulatory specifications splitting winding
Single laser boring is carried out on light puncher, to increase the air permeability of product, sample detection index of correlation after winding is wrapped after qualified
Dress is to get the polychrome double exposure tipping paper with metallic luster.
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| CN110424189A (en) * | 2019-08-19 | 2019-11-08 | 玉溪接装纸制造有限公司 | A kind of quick-fried pearl type tipping paper and preparation method thereof with laser effect |
| CN110499071A (en) * | 2019-08-22 | 2019-11-26 | 青岛嘉泽包装有限公司 | A kind of ink and preparation method thereof and the application in temperature sensing color changing cigarette tipping paper |
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| CN113818280A (en) * | 2021-09-29 | 2021-12-21 | 福建中烟工业有限责任公司 | Cigarette tipping paper, preparation method thereof, tobacco product and application |
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| CN110424189B (en) * | 2019-08-19 | 2021-05-25 | 玉溪接装纸制造有限公司 | Bead blasting tipping paper with laser effect and preparation method thereof |
| CN110499071A (en) * | 2019-08-22 | 2019-11-26 | 青岛嘉泽包装有限公司 | A kind of ink and preparation method thereof and the application in temperature sensing color changing cigarette tipping paper |
| CN111501405A (en) * | 2020-04-28 | 2020-08-07 | 安徽集友纸业包装有限公司 | Anti-counterfeiting cigarette tipping paper, preparation method thereof, filter element and smoking product |
| CN111548674A (en) * | 2020-05-08 | 2020-08-18 | 宁波佐图文化用品有限公司 | Water-based ink with three-dimensional effect and preparation method thereof |
| WO2022103716A1 (en) * | 2020-11-12 | 2022-05-19 | Sun Chemical Corporation | Titanium dioxide-free cigarette tipping inks |
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