CN110205868A - A kind of plating aluminium profiles tipping paper anti-dropout, prevent adhesion gloss oil and preparation method thereof - Google Patents

A kind of plating aluminium profiles tipping paper anti-dropout, prevent adhesion gloss oil and preparation method thereof Download PDF

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Publication number
CN110205868A
CN110205868A CN201910658926.2A CN201910658926A CN110205868A CN 110205868 A CN110205868 A CN 110205868A CN 201910658926 A CN201910658926 A CN 201910658926A CN 110205868 A CN110205868 A CN 110205868A
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aqueous
parts
tipping paper
gloss oil
dropout
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CN201910658926.2A
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CN110205868B (en
Inventor
何宗修
龚麟
杨正德
王长寿
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Yuxi Tipping Paper Manufacturing Co Ltd
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Yuxi Tipping Paper Manufacturing Co Ltd
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    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/10Coatings without pigments
    • D21H19/14Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/10Coatings without pigments
    • D21H19/14Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/20Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/10Coatings without pigments
    • D21H19/14Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/20Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H19/22Polyalkenes, e.g. polystyrene
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/10Coatings without pigments
    • D21H19/14Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/24Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/10Packing paper

Abstract

The invention discloses a kind of plating aluminium profiles tipping paper anti-dropout, prevent adhesion gloss oil and preparation method thereof, raw materials used proportion in parts by weight is as follows: 30-70 parts of aqueous film-forming resin, 5-20 parts of aqueous not film-forming resin, 1-10 parts of fire resistant resin, 1-10 parts of aqueous high density polyethylene waxes lotion, 0.1-1 parts of aqueous adhesive force promotor, 0.1-0.5 parts of aqueous defoamer, 15-50 parts of pure water, PH regulator is appropriate.Gloss oil of the present invention not only contains adhesion promoter, and it is added to temperature tolerance component, so that it is guaranteed that obtaining adhesion-tight, dimensionally stable, high glaze clear coat resistant to high temperature, solve the mass defects such as loosely easy to fall off, the big, adhesion of the laser boring coefficient of variation of plating aluminium profiles tipping paper varnish coating attachment.Meanwhile the light oil reservoir also has that wear-resisting, anti-roll power is strong, and environmental protection, preparation process are simple, the characteristics such as easy to use.

Description

A kind of plating aluminium profiles tipping paper anti-dropout, prevent adhesion gloss oil and preparation method thereof
Technical field
The present invention relates to printing varnish, it is more particularly to a kind of plating aluminium profiles tipping paper gloss oil and preparation method thereof.
Background technique
Tipping paper is commonly called as " cork paper ", is mainly used for filter tip and Cigarette cigarette.Not with living standards of the people Disconnected raising and the transformation of consumption concept and health perception, the purposes of tipping paper more focus on its dicoration other than packaging.Its In, plating aluminium profiles tipping paper has glittering metallic luster, gives people a kind of strong visual impact, has combined packaging and decoration Function, to obtain market and the favor of consumer.
Plating aluminium profiles tipping paper is to lead to the metallic aluminum of vacuum evaporation using transfevent silver lustre tipping base paper as printing element It crosses transfer method transfer and is combined to the white body paper surface of tipping, and carry out transparent ink printing, glazing using metallic aluminum as printing surface The tipping paper that the following process such as oil, laser boring are made.Oil polish is exactly to be fully completed picture and text printing process Duplicate surface prints gloss oil once or twice with printing machine again with printing plate on the spot or picture and text printing plate, printed article surface is made to obtain light The method of bright film layer.The light fastness of ink can be enhanced in printing coating, increases ink layer solar heat protection and moisture protection, plays Protect the effect of trace, beautify product.Oil polish includes water lustering oil, oiliness oil polish, UV oil polish, alcohol-soluble oil polish Etc. kinds.What domestic application was most now is water lustering oil, because it has extraordinary environmental-protecting performance.
Currently, the drying process of water-based gloss oil 30% be by evaporation, 70% by infiltration absorb, rate of drying compared with It fastly, can conjunctiva when gloss oil still contains 20% -30% moisture.But aluminium profiles tipping paper is plated compared with general paper base type tipping paper, Plating aluminium profiles tipping paper is using nonabsorbable aluminium coated as printing surface, and the two has essential distinction.In this way, varnish coating is caused to be adhered to , easily there are the mass defects such as varnish coating falls off, the laser boring coefficient of variation is big in power decline.In addition, after tipping paper cigarette cigarette Capsule packaging is carried out, needs to carry out cigarette film heat-sealing under the high temperature conditions, and plates the metallic aluminium heating conduction that aluminium profiles tipping paper contains Excellent, there are the hidden danger of quality that adjacent Cigarette is sticked together for heat-sealing under the high temperature conditions.Therefore, plating aluminium profiles tipping paper is used The temperature tolerance of gloss oil requires higher.
Summary of the invention
To solve the deficiencies in the prior art, the present invention is intended to provide a kind of adhesion-tight, dimensionally stable, resistant to high temperature aluminizing Type tipping paper anti-dropout, prevent adhesion gloss oil and preparation method thereof.
In order to achieve the above objectives, the present invention uses following technological means: a kind of plating aluminium profiles tipping paper anti-dropout prevents adhesion Gloss oil, raw materials used proportion in parts by weight are as follows: 30-70 parts of aqueous film-forming resin, 5-20 parts of aqueous not film-forming resin, 1-10 parts of fire resistant resin, 1-10 parts of aqueous high density polyethylene waxes lotion is 0.1-1 parts of aqueous adhesive force promotor, aqueous to disappear 0.1-0.5 parts of infusion, 15-50 parts of pure water, PH regulator is appropriate.
Preferably, a kind of plating aluminium profiles tipping paper anti-dropout, prevent adhesion gloss oil, raw materials used to match in parts by weight As follows: 40-60 parts of aqueous film-forming resin, 8-12 parts of aqueous not film-forming resin, 5-10 parts of fire resistant resin, aqueous high density is poly- 4-7 parts of ethylene wax emulsion, 0.5-1 parts of aqueous adhesive force promotor, 0.4-0.5 parts of aqueous defoamer, 17-36 parts of pure water, PH Appropriate regulator.
The aqueous film-forming resin is aqueous acrylic emulsion, aqueous polyurethane dispersing liquid, aqueous acrylic modified poly- ammonia At least one of ester lotion.
The aqueous defoamer is at least one of modified polyorganosiloxane lotion, polyether silicone lotion.
Wherein, aqueous acrylic emulsion is a kind of acrylic acid copolymer high glaze filming emulsion, translucent milky white liquid, Gu Content 46% ± 1, viscosity (applying 4# glasss/25 DEG C) 80-120 seconds, pH value 8.0-8.5.The ink gloss oil prepared with this product, has Excellent clarity, waterproof glossy pool, quick rate of drying and excellent anti-adhesive properties.This product has extensive compatible Property, it can be used together with other acrylic polymers of prevalence currently on the market.Suitable for preparing aqueous flexible plate and intaglio plate water Property ink gloss oil, aqueous ink used for plastic, water lustering oil, Waterproof gloss oil, aqueous aluminum foil gloss oil, water varnish and aqueous dress Adorn paper ink.
Aqueous polyurethane dispersing liquid is aliphatic anionic modified high-molecular aqueous polyurethane dispersing liquid, solid content 35% ± 1,300~500 mPa.s/25 DEG C of viscosity, pH value (1/10) 7-8, hardness is high hard, and this product film forming is smooth, wear-resisting, warping strength, Resistance to scratch, high temperature resistant is good with paper adhesive property, so that paper jam is had higher printing index after covering with paint, promotes the performance of product.It can be used as Printing ink adhesive can be used for producing high bright rainbow aluminizer paper jam and paper coating varnish.Use suggestion: coating weight 1.5-2.5g, can also be depending on equipment and technique;Upper machine viscosity, 15-20 seconds (applying -4 glasss);85-140 DEG C of drying temperature, machine Fast 50-80m/min.
Aqueous acrylic modified polyaminoester emulsion is the anion aqueous acrylic acid modified poly- ammonia of high-performance one-component of new generation Ester lotion, be the yellowish semi-transparent bright sticky liquid of blue light, solid content 50%, viscosity 1000-1400mPas, elongation percentage 150-200%, PH value 7-8, hardness 1H.
Aqueous not film-forming resin is a kind of non-film-forming hard Styrene And Chloroalkyl Acrylates copolymer emulsion, and appearance is milky half Transparency liquid, solid content 48% ± 1, pH value 8-9, Tg100 DEG C of glass transition temperature.Have with the varnish that this product is prepared faster Rate of drying, very high gloss and the transparency, outstanding water repelling property, anti-stick back performance and low smell, have pigment excellent Wettability, wear-resisting, it has good compatibility with acrylic polymer in the market.Since this product cannot individually form a film, It must be used in mixed way with suitable coalescing agent or with the lesser film forming acrylic emulsion of partial size.
Fire resistant resin is the phenylethylene-maleic anhydride resin of partial esterification, white powder or sheet, acid value 255- 285, weight average molecular weight 7000, Tg125 DEG C of glass transition temperature.The resin high glass transition temperature and softening point, alkali solubility, bloom Pool, the HLB value range (S:MA ratio, esters type, water oil content) of complete series is good with various emulsion system compatibilities, with tradition Surfactant has outstanding compatibility.It is mainly used for heat-resisting varnish/oil polish, heat-resisting emulsion polymer is alkaline-resisting, water-fast Cationic emulsion copolymerization object, water-fast, ultra-fine grain diameter wax emulsion, rosin milk, water-fast floor wax polish cream improves to low The adhesive force of surface-energy material,
Aqueous high density polyethylene waxes lotion, appearance be faint yellow lotion, pH value 8-9, solid content 35%, 137 DEG C of fusing point.This production Product are a kind of to improve the high rigidity wax dispenser that wear-resisting scratch resistance the performances such as prevents adhesion and develops, and use extremely hard high density Polyethylene wax and other former, auxiliary materials are produced through emulsification, and even particle distribution is wear-resisting and anti-blocking properties are good, the stabilization of lotion Performance is splendid.
Aqueous adhesive force promotor is epoxy radicals silicone hydride, and appearance is colourless transparent liquid, specific gravity 1.065, pH value 7-8, molten Xie Xing: water paint and oleaginous system are general.The bonding force of solvent acrylic acid, polyurethane and epoxy coating can be improved in this product;It answers For water paints such as water soluble acrylic acid and polyurethane, as adhesion promoters and crosslinking agent;It is even by the epoxy group of various new Join agent, there are reaction active groups;With good yellowing resistance characteristic.
Modified polyorganosiloxane is milky creamy liquids, belongs to waterborne organic silicon defoaming agent, effective component 100%.The product With high foam inhibition ability, especially showed in ink grinding system it is splendid, can be with acrylic acid, epoxy, polyester, polyurethane It is compatible with polyethylene system.
Polyether silicone lotion is white opacity liquid, belongs to waterborne organic silicon defoaming agent, effective component 26%.The product Suitable for emulsion acrylic polyurethane coating systems, with the paint stage have extremely strong defoaming, can be common to varnish and Colored paint formulation, furniture lacquer and veneering coating.Coating, additive amount 0.1-0.5% can be added in the form of original-pack object.
PH value adjustment agent is dimethylethanolamine, and abbreviation DMEA is colourless volatile liquid, there is ammonia taste, boiling point 134.6 DEG C, it is miscible with water, it is miscible in ether, aromatic hydrocarbons, is used for ion exchange resin;As water soluble paint cosolvent, polyurethane paint is solid Agent;Flocculant with the reaction product of acrylic acid microorganism as city purified water field.This product to eyes, skin, mucous membrane and The upper respiratory tract has severe irritation effect, can cause skin burn, and larynx, bronchial inflammation, oedema, spasm can be caused after sucking, changes The property learned pneumonia, pulmonary edema etc.;There is sensitization to skin.
A kind of plating aluminium profiles tipping paper anti-dropout of the present invention, the preparation method for the gloss oil that prevents adhesion the following steps are included: (1) Load weighted pure water is added in dissolution axe according to the ratio, and low whipping speed is added under conditions of being 60-100r/min to be claimed according to the ratio Measured fire resistant resin stirs 5~10min, makes the fire resistant resin being added to obtain complete wetting as uniform pulpous state Object.Appropriate PH regulator is added into slurry under stirring, so that system PH is reached 10 or more, steps up mixing speed To 600-1000r/min, 4~5h of stirring at normal temperature, makes the dissolution of SMA resin completely, obtain mixed liquor A.
(2) it under the conditions of 60-100r/min is stirred at low speed, is sequentially added into mixed liquor A load weighted aqueous according to the ratio Film-forming resin, aqueous not film-forming resin, step up mixing speed to 600-1000r/min, 1~2h of stirring at normal temperature after finishing, Keep emulsion dispersion uniformly complete, obtains mixed liquid B.
(3) load weighted aqueous high density polyethylene waxes lotion, aqueous adhesive force according to the ratio are added in mixed liquid B to promote 0.5~1h, mixing speed 100-300r/min are stirred in agent, aqueous defoamer, until being completely dispersed uniformly, with PH regulator Regulation system PH reaches 10 or more, 200 mesh net filtrations, must plate that aluminium profiles tipping paper anti-dropout, prevent adhesion gloss oil.
The gloss oil that will be prepared, in the environment of 22-28 DEG C of temperature, relative humidity 50-60%, with ethyl alcohol: pure water 1: 1 diluent diluted viscosity is 2# glasss English to 12s-18s(), by using 80 lines/cm galley, drying temperature 130-150 DEG C, printing speed 180-200m/min, 0.1-0.3g/m2The printing technology of dry-coated amount, in 32-45g/m2Plating aluminium profiles tipping paper Layer of ink surface oil polish, drying winding.
The invention has the following advantages: a kind of plating aluminium profiles tipping paper anti-dropout of the present invention, prevent adhesion gloss oil, Not only contain adhesion promoter, but also be added to temperature tolerance component, so that it is guaranteed that obtaining adhesion-tight, dimensionally stable, resistance to height The high glaze clear coat of temperature solves plating aluminium profiles tipping paper varnish coating and adheres to loosely easy to fall off, the laser boring coefficient of variation Greatly, the mass defects such as adhesion.
Light oil reservoir prepared by the present invention also has that wear-resisting, anti-roll power is strong, and environmental protection, preparation process are simple, easy to use Etc. characteristics.
Specific embodiment
Embodiment 1
A kind of plating aluminium profiles tipping paper anti-dropout, prevent adhesion gloss oil, implements by following technical scheme:
Specific formula is calculated by weight as: 45 parts of aqueous acrylic emulsion, 10 parts of Styrene And Chloroalkyl Acrylates copolymer emulsion, and benzene second 8 parts of alkene-copolymer-maleic anhydride, 5 parts of aqueous high density polyethylene waxes lotion, 1 part of epoxy radicals silicone hydride, modified polyorganosiloxane lotion 0.5 part, 30.5 parts of pure water, appropriate dimethylethanolamine.
It follows the steps below production: (1) load weighted pure water according to the ratio being added in dissolution axe, low whipping speed To be added load weighted styrene-maleic anhydride copolymer according to the ratio under conditions of 60-100r/min, 5~10min is stirred, Make the styrene-maleic anhydride copolymer being added to obtain complete wetting as uniform slurry.To slurry under stirring Appropriate dimethylethanolamine is added in shape object, system PH is made to reach 10 or more, steps up mixing speed to 600-1000r/ Min, 4~5h of stirring at normal temperature make the dissolution of styrene-maleic anhydride copolymer resin completely, obtain mixed liquor A.
(2) it under the conditions of 60-100r/min is stirred at low speed, is sequentially added into mixed liquor A load weighted aqueous according to the ratio Acrylic emulsion, Styrene And Chloroalkyl Acrylates copolymer emulsion step up mixing speed to 600-1000r/min after finishing, room temperature stirs 1~2h is mixed, keeps emulsion dispersion uniformly complete, obtains mixed liquid B.
(3) be added in mixed liquid B according to the ratio load weighted aqueous high density polyethylene waxes lotion, epoxy radicals silicone hydride, change Property polysiloxane emulsion, stir 0.5~1h, mixing speed 100-300r/min, until be completely dispersed uniformly, use dimethyl Ethanol amine regulation system PH reaches 10 or more, 200 mesh net filtrations, must plate that aluminium profiles tipping paper anti-dropout, prevent adhesion gloss oil.
The gloss oil that will be prepared, in the environment of 22-28 DEG C of temperature, relative humidity 50-60%, with ethyl alcohol: pure water 1: 1 diluent diluted viscosity is 2# glasss English to 12s-18s(), by using 80 lines/cm galley, drying temperature 130-150 DEG C, printing speed 180-200m/min, 0.1-0.3g/m2The printing technology of dry-coated amount, in 32-45g/m2Plating aluminium profiles tipping paper Layer of ink surface oil polish, drying winding.It crosses pasta to be bonded two-by-two, 4kg weight is put on pile, be placed in 150 DEG C of baking ovens and stand Observe that coating is non-discolouring and adhesion after 48h.Pasta tipping paper is crossed to beat with pitch of holes 1mm, Kong Zhongxin away from side 21.5mm, two rows of laser Hole meets tipping paper standard requirements through the detection air permeability coefficient of variation less than 4%.
Embodiment 2
A kind of plating aluminium profiles tipping paper anti-dropout, prevent adhesion gloss oil, and specific formula is calculated by weight as: aqueous polyurethane dispersion 58 parts of liquid, 5 parts of Styrene And Chloroalkyl Acrylates copolymer emulsion, 2 parts of styrene-maleic anhydride copolymer, aqueous high density polyethylene waxes cream 1 part of liquid, 0.5 part of epoxy radicals silicone hydride, 0.3 part of modified polyorganosiloxane lotion, 17.5 parts of pure water, appropriate dimethylethanolamine.
It is specific that the preparation method is the same as that of Example 1.
Embodiment 3
A kind of plating aluminium profiles tipping paper anti-dropout, prevent adhesion gloss oil, and specific formula is calculated by weight as: aqueous acrylic modified 30 parts of polyaminoester emulsion, 20 parts of Styrene And Chloroalkyl Acrylates copolymer emulsion, 10 parts of styrene-maleic anhydride copolymer, aqueous high density 10 parts of polythene wax emulsion, 0.1 part of epoxy radicals silicone hydride, 0.5 part of polyether silicone lotion, 15 parts of pure water, dimethylethanolamine In right amount.
It is specific that the preparation method is the same as that of Example 1.
Embodiment 4
A kind of plating aluminium profiles tipping paper anti-dropout, prevent adhesion gloss oil, and specific formula is calculated by weight as: aqueous acrylic modified 70 parts of polyaminoester emulsion, 12 parts of Styrene And Chloroalkyl Acrylates copolymer emulsion, 5 parts of styrene-maleic anhydride copolymer, aqueous high density 7 parts of polythene wax emulsion, 0.8 part of epoxy radicals silicone hydride, 0.4 part of polyether silicone lotion, 50 parts of pure water, dimethylethanolamine is suitable Amount.
It is specific that the preparation method is the same as that of Example 1.

Claims (6)

1. a kind of plating aluminium profiles tipping paper anti-dropout, prevent adhesion gloss oil, which is characterized in that raw materials used to match in parts by weight Than as follows: 30-70 parts of aqueous film-forming resin, 5-20 parts of aqueous not film-forming resin, 1-10 parts of fire resistant resin, aqueous high density is poly- 1-10 parts of ethylene wax emulsion, 0.1-1 parts of aqueous adhesive force promotor, 0.1-0.5 parts of aqueous defoamer, 15-50 parts of pure water, PH Appropriate regulator;The aqueous not film-forming resin is Styrene And Chloroalkyl Acrylates copolymer emulsion;The fire resistant resin is styrene- Copolymer-maleic anhydride;The aqueous adhesive force promotor is epoxy radicals silicone hydride.
2. according to claim 1 a kind of plating aluminium profiles tipping paper anti-dropout, prevent adhesion gloss oil, which is characterized in that institute It is matched in parts by weight with raw material as follows: 40-60 parts of aqueous film-forming resin, 8-12 parts of aqueous not film-forming resin, high temperature resistant 5-10 parts of resin, 4-7 parts of aqueous high density polyethylene waxes lotion, 0.5-1 parts of aqueous adhesive force promotor, aqueous defoamer 0.4- 0.5 part, 17-36 parts of pure water, PH regulator is appropriate.
3. a kind of plating aluminium profiles tipping paper anti-dropout according to claim 1 or described in 2, prevent adhesion gloss oil, it is characterised in that: The aqueous film-forming resin is aqueous acrylic emulsion, aqueous polyurethane dispersing liquid, in aqueous acrylic modified polyaminoester emulsion At least one.
4. a kind of plating aluminium profiles tipping paper anti-dropout according to claim 1 or described in 2, prevent adhesion gloss oil, it is characterised in that: The aqueous defoamer is at least one of modified polyorganosiloxane lotion, polyether silicone lotion.
5. a kind of plating aluminium profiles tipping paper anti-dropout according to claim 1 or described in 2, prevent adhesion gloss oil, it is characterised in that: The PH regulator is dimethylethanolamine.
6. a kind of side for preparing plating aluminium profiles tipping paper anti-dropout, the gloss oil that prevents adhesion described in any one of Claims 1 to 5 Method, which comprises the following steps:
(1) load weighted pure water according to the ratio is added in dissolution axe, low whipping speed adds under conditions of being 60-100r/min Enter load weighted fire resistant resin according to the ratio, stir 5~10min, becomes the fire resistant resin being added to obtain complete wetting Uniform slurry;Appropriate PH regulator is added into slurry under stirring, so that system PH is reached 10 or more, gradually mentions Mixing speed is risen to 600-1000r/min, 4~5h of stirring at normal temperature, makes fire resistant resin dissolution completely, obtains mixed liquor A;
(2) under the conditions of 60-100r/min is stirred at low speed, load weighted waterborne film-forming according to the ratio is sequentially added into mixed liquor A Resin, aqueous not film-forming resin, mixing speed is stepped up after finishing to 600-1000r/min, 1~2h of stirring at normal temperature makes cream Liquid is uniformly dispersed completely, obtains mixed liquid B;
(3) be added in mixed liquid B according to the ratio load weighted aqueous high density polyethylene waxes lotion, aqueous adhesive force promotor, Aqueous defoamer stirs 0.5~1h, mixing speed 100-300r/min, until being completely dispersed uniformly, with PH regulator tune Section PH reaches 10 or more, 200 mesh net filtrations, must plate that aluminium profiles tipping paper anti-dropout, prevent adhesion gloss oil.
CN201910658926.2A 2019-07-22 2019-07-22 Anti-drop and anti-adhesion gloss oil for aluminized tipping paper and preparation method thereof Active CN110205868B (en)

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WO2022070067A1 (en) * 2020-10-01 2022-04-07 Seal Chemistry (Pty) Ltd High-release barrier coated paper wrapper for candies and gum which exclude the use of hot wax and a method for preparation thereof

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WO2017216767A1 (en) * 2016-06-17 2017-12-21 HICKMAN, Stuart Roy Micro-porous coating compositions
CN108774915A (en) * 2018-06-29 2018-11-09 湖北黄鹤楼特色包装材料有限公司 A kind of high temperature resistant prevents adhesion finishing oil
CN109295806A (en) * 2018-10-10 2019-02-01 玉溪接装纸制造有限公司 A kind of polychrome double exposure tipping paper and preparation method thereof with metallic luster

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111501404A (en) * 2020-04-28 2020-08-07 曲靖麒麟福牌印刷有限公司 High-temperature-resistant antibacterial tipping paper gloss oil and preparation method thereof
WO2022070067A1 (en) * 2020-10-01 2022-04-07 Seal Chemistry (Pty) Ltd High-release barrier coated paper wrapper for candies and gum which exclude the use of hot wax and a method for preparation thereof

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