CN110205868B - Anti-drop and anti-adhesion gloss oil for aluminized tipping paper and preparation method thereof - Google Patents
Anti-drop and anti-adhesion gloss oil for aluminized tipping paper and preparation method thereof Download PDFInfo
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- CN110205868B CN110205868B CN201910658926.2A CN201910658926A CN110205868B CN 110205868 B CN110205868 B CN 110205868B CN 201910658926 A CN201910658926 A CN 201910658926A CN 110205868 B CN110205868 B CN 110205868B
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/20—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/20—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/22—Polyalkenes, e.g. polystyrene
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/24—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/10—Packing paper
Abstract
The invention discloses an anti-drop and anti-adhesion gloss oil for aluminized tipping paper and a preparation method thereof, wherein the raw materials are as follows by weight: 30-70 parts of water-based film-forming resin, 5-20 parts of water-based non-film-forming resin, 1-10 parts of high-temperature resistant resin, 1-10 parts of water-based high-density polyethylene wax emulsion, 0.1-1 part of water-based adhesion promoter, 0.1-0.5 part of water-based defoamer, 15-50 parts of purified water and a proper amount of pH regulator. The gloss oil disclosed by the invention not only contains an adhesion promoter, but also is added with a temperature-resistant component, so that a high-gloss transparent coating which is firm in adhesion, stable in size and high-temperature resistant is ensured to be obtained, and the quality defects that an aluminized tipping paper gloss oil coating is not firm in adhesion and easy to fall off, and the laser drilling variation coefficient is large, adhesion and the like are overcome. Meanwhile, the gloss oil layer also has the characteristics of wear resistance, strong anti-rolling force, environmental protection, simple preparation process, convenient use and the like.
Description
Technical Field
The invention relates to printing gloss oil, in particular to gloss oil for aluminized tipping paper and a preparation method thereof.
Background
The tipping paper is commonly called 'tipping paper', and is mainly used for rolling and connecting the filter tip and the cigarette. With the continuous improvement of the living standard of people and the transformation of consumption idea and health consciousness, the use of the tipping paper focuses more on the decoration of the tipping paper besides the packaging. The aluminum-plated tipping paper has flashing metallic luster, gives people strong visual impact, and simultaneously gives consideration to the functions of packaging and decoration, thereby being popular with the market and consumers.
The aluminized tipping paper is prepared by taking transfer type bright silver tipping base paper as a printing base material, namely transferring and compounding a metal aluminum layer subjected to vacuum evaporation onto the surface of the tipping white base paper by a transfer method, and performing subsequent processing such as transparent ink printing, varnish application, laser punching and the like by taking the metal aluminum layer as a printing surface. The varnishing is a method for obtaining a bright film layer on the surface of a printed matter by printing once or twice gloss oil on the surface of a duplicate which is completely finished with an image-text printing process by using a solid printing plate or an image-text printing plate and a printing machine. The printing glazing can enhance the light resistance of the printing ink, increase the heat and moisture resistance of the printing ink layer, and play a role in protecting prints and beautifying products. The glazing oil comprises water glazing oil, oily glazing oil, UV glazing oil, alcohol-soluble glazing oil and the like. At present, the most domestic application is the water-based varnish, and the water-based varnish has very good environmental protection performance.
At present, 30% of the drying process of the water-based gloss oil is realized by evaporation, 70% of the drying process is realized by material permeation and absorption, the drying speed is higher, and a film can be formed when the gloss oil contains 20% -30% of water. However, the aluminized tipping paper is essentially different from the general paper-based tipping paper in that the aluminized tipping paper uses a non-absorbent aluminized layer as a printing surface. Therefore, the adhesion of the gloss oil coating is reduced, and the quality defects of the gloss oil coating such as falling off, large variation coefficient of laser drilling and the like are easy to occur. In addition, the tipping paper is wrapped in a small box after being spliced with cigarettes, the cigarette film needs to be subjected to heat sealing under a high-temperature condition, the aluminized tipping paper contains metal aluminum with excellent heat conductivity, and the heat sealing under the high-temperature condition has the quality hidden trouble that adjacent cigarettes are adhered together. Therefore, the gloss oil for aluminum-plated tipping paper is required to have higher temperature resistance.
Disclosure of Invention
In order to solve the defects of the prior art, the invention aims to provide the anti-falling and anti-adhesion gloss oil for the aluminized tipping paper which is firm in adhesion, stable in size and high-temperature resistant and the preparation method thereof.
In order to achieve the purpose, the invention adopts the following technical means: an anti-drop and anti-adhesion gloss oil for aluminized tipping paper comprises the following raw materials in parts by weight: 30-70 parts of water-based film-forming resin, 5-20 parts of water-based non-film-forming resin, 1-10 parts of high-temperature resistant resin, 1-10 parts of water-based high-density polyethylene wax emulsion, 0.1-1 part of water-based adhesion promoter, 0.1-0.5 part of water-based defoamer, 15-50 parts of purified water and a proper amount of pH regulator.
Preferably, the anti-drop and anti-adhesion gloss oil for the aluminized tipping paper comprises the following raw materials in parts by weight: 40-60 parts of water-based film-forming resin, 8-12 parts of water-based non-film-forming resin, 5-10 parts of high-temperature resistant resin, 4-7 parts of water-based high-density polyethylene wax emulsion, 0.5-1 part of water-based adhesion promoter, 0.4-0.5 part of water-based defoamer, 17-36 parts of purified water and a proper amount of pH regulator.
The waterborne film-forming resin is at least one of waterborne acrylic emulsion, waterborne polyurethane dispersion and waterborne acrylic modified polyurethane emulsion.
The aqueous defoaming agent is at least one of modified polysiloxane emulsion and polyether siloxane emulsion.
Wherein the water-based acrylic emulsion is acrylic acid copolymerization high-gloss film-forming emulsion, is semitransparent milky liquid, has the solid content of 46% +/-1, the viscosity (coated in a 4# cup at 25 ℃) of 80-120 seconds and the pH value of 8.0-8.5. The ink varnish prepared by the product has excellent definition, high water resistance and luster, high drying speed and excellent anti-adhesion performance. The product has wide compatibility and can be used together with other acrylic polymers which are popular in the market at present. The method is suitable for preparing water-based flexible and gravure water-based ink varnish, water-based plastic ink, water-based varnish, water-based waterproof varnish, water-based aluminum foil varnish, water-based varnish and water-based decorative paper ink.
The aqueous polyurethane dispersion is aliphatic anionic modified high-molecular aqueous polyurethane dispersion, the solid content is 35% +/-1, the viscosity is 300-500 mPa.s/25 ℃, the pH value (1/10) is 7-8, the hardness is high, the product is smooth in film forming, wear-resistant, bending-resistant, scratch-resistant, high-temperature resistant and good in bonding performance with paper, the paperboard has a high printing index after being coated, and the performance of the product is improved. Can be used as printing ink binder for producing high-brightness rainbow aluminized film card paper and paper finishing varnish. Use recommendations: the coating weight is 1.5-2.5g, and can also be determined according to equipment and a process; machine viscosity, 15-20 seconds (smear-4 cups); the drying temperature is 85-140 ℃, and the machine speed is 50-80 m/min.
The waterborne acrylic modified polyurethane emulsion is a new generation of high-performance single-component anionic waterborne acrylic modified polyurethane emulsion, is a yellowish semitransparent blue light transparent viscous liquid, has the solid content of 50 percent, the viscosity of 1000-1400mPas, the elongation of 150-200 percent, the pH value of 7-8 and the hardness of 1H.
The water-based non-film-forming resin is a non-film-forming hard styrene-acrylic acid copolymer emulsion, the appearance of the emulsion is milky semitransparent liquid, the solid content is 48 +/-1, the pH value is 8-9, and the glass transition temperature Tg is 100 ℃. The varnish prepared by the product has the advantages of high drying speed, high gloss and transparency, excellent water resistance, back adhesion resistance and low odor, excellent wettability to pigment, wear resistance and good compatibility with acrylic polymers on the market. Since the product cannot be formed into a film alone, it must be used with a suitable film-forming aid or in admixture with a film-forming acrylic emulsion of relatively small particle size.
The high-temperature resistant resin is partially esterified styrene-maleic anhydride resin which is in a white powder or sheet shape, has an acid value of 255-285, a weight average molecular weight of 7000 and a glass transition temperature Tg of 125 ℃. The resin has high glass transition temperature and softening point, alkali solubility, high gloss, complete series of HLB value ranges (S: MA ratio, ester type and water-oil degree), good compatibility with various emulsion systems and excellent compatibility with the conventional surfactant. Is mainly used for heat-resistant varnish/varnish, heat-resistant emulsion polymer, alkali-resistant and water-resistant cationic emulsion polymer, water-resistant wax emulsion with superfine grain diameter, rosin emulsion and water-resistant floor varnish, improves the adhesive force to low-surface-energy materials,
the aqueous high-density polyethylene wax emulsion is light yellow emulsion, has the appearance of 8-9 of pH value, 35 percent of solid content and 137 ℃ of melting point. The product is a high-hardness wax dispersoid developed for improving the performances of wear resistance, scratch resistance, adhesion resistance and the like, and the extremely hard high-density polyethylene wax, other raw materials and auxiliary materials are used for emulsification production, so that the particle distribution is uniform, the wear resistance and the adhesion resistance are good, and the emulsion stability is excellent.
The water-based adhesion promoter is epoxy silane, is colorless transparent liquid in appearance, has the specific gravity of 1.065, the pH value of 7-8 and the solubility: the water paint and the oil system are commonly used. The product can improve the adhesive force of acrylic acid, polyurethane and epoxy paint; the adhesive is applied to water-based coatings such as water-based acrylic acid, polyurethane and the like, and is used as an adhesion promoter and a cross-linking agent; the epoxy resin is prepared by a plurality of novel epoxy coupling agents with reactive groups; has good yellowing resistance.
The modified polysiloxane is milky creamy liquid, belongs to a water-based organic silicon defoamer and comprises 100 percent of effective components. The product has very high foam inhibition capability, performs very well especially in ink grinding systems, and is compatible with acrylic, epoxy, polyester, polyurethane and polyethylene systems.
The polyether siloxane emulsion is white turbid liquid, belongs to a water-based organic silicon defoamer and contains 26 percent of effective components. The product is suitable for emulsion acrylic polyurethane coating systems, has extremely strong defoaming property in the paint preparation stage, and can be generally used in varnish and paint formulas, furniture paints and wood veneer coatings. The coating can be added in the form of original articles, and the addition amount is 0.1-0.5%.
The pH value regulator is dimethylethanolamine, DMEA for short, is colorless volatile liquid with ammonia smell and boiling point of 134.6 ℃, is miscible with water, can be dissolved in ether and aromatic hydrocarbon, is used for ion exchange resin, is used as a water-soluble paint cosolvent and a polyurethane paint curing agent, and is used as a flocculating agent for urban water purification fields by using a reaction product of the dimethylethanolamine and the DMEA with acrylic acid microorganisms. The product has severe irritation to eyes, skin, mucosa and upper respiratory tract, and can cause skin burn, and inflammation, edema, spasm, chemical pneumonia, pulmonary edema, etc. of larynx and bronchus after inhalation; has skin sensitizing effect.
The invention relates to a preparation method of anti-drop and anti-adhesion gloss oil for aluminized tipping paper, which comprises the following steps: (1) adding purified water weighed according to the proportion into a dissolving kettle, adding high-temperature-resistant resin weighed according to the proportion under the condition that the stirring speed is 60-100r/min, and stirring for 5-10 min to enable the added high-temperature-resistant resin to be completely wetted to form uniform slurry. Adding a proper amount of pH regulator into the slurry under the stirring state to enable the pH of the system to reach more than 10, gradually increasing the stirring speed to 600-.
(2) Under the condition of low-speed stirring at 60-100r/min, sequentially adding the aqueous film-forming resin and the aqueous non-film-forming resin which are weighed according to the proportion into the mixed solution A, gradually increasing the stirring speed to 600-1000r/min after the addition, and stirring at normal temperature for 1-2 h to uniformly and completely disperse the emulsion to obtain the mixed solution B.
(3) And adding the aqueous high-density polyethylene wax emulsion, the aqueous adhesion promoter and the aqueous defoaming agent which are weighed according to the proportion into the mixed solution B, stirring for 0.5-1 h at the stirring speed of 100-300r/min until the mixture is completely and uniformly dispersed, adjusting the pH of the system to be more than 10 by using a pH regulator, and filtering by using a 200-mesh screen to obtain the anti-falling and anti-adhesion gloss oil for the aluminized tipping paper.
And (2) mixing the prepared gloss oil with ethanol at the temperature of 22-28 ℃ and the relative humidity of 50-60 percent: diluting with 1:1 pure water to 12s-18s (British 2# cup), drying at 130 deg.C and 150 deg.C by using 80 lines/cm printing plate, and printing at 180 deg.C and 200m/min at 0.1-0.3g/m2Printing process with dry coating amount of 32-45g/m2The surface of the ink layer of the aluminized tipping paper is polished with oil, dried and rolled.
The invention has the following beneficial effects: the anti-drop and anti-adhesion gloss oil for the aluminized tipping paper disclosed by the invention contains the adhesion promoter and is added with the temperature-resistant component, so that a high-gloss transparent coating with firm adhesion, stable size and high temperature resistance is ensured to be obtained, and the quality defects that the aluminized tipping paper gloss oil coating is not firm in adhesion and easy to drop, the laser drilling variation coefficient is large, adhesion is caused and the like are overcome.
The gloss oil layer prepared by the invention also has the characteristics of wear resistance, strong anti-rolling force, environmental protection, simple preparation process, convenient use and the like.
Detailed Description
Example 1
An anti-drop and anti-adhesion gloss oil for aluminized tipping paper is implemented according to the following technical scheme:
the specific formula comprises the following components in parts by weight: 45 parts of water-based acrylic emulsion, 10 parts of styrene-acrylic acid copolymer emulsion, 8 parts of styrene-maleic anhydride copolymer, 5 parts of water-based high-density polyethylene wax emulsion, 1 part of epoxy silane, 0.5 part of modified polysiloxane emulsion, 30.5 parts of purified water and a proper amount of dimethylethanolamine.
The production is carried out according to the following steps: (1) adding purified water weighed according to the proportion into a dissolving kettle, adding the styrene-maleic anhydride copolymer weighed according to the proportion under the condition of stirring speed of 60-100r/min, and stirring for 5-10 min to ensure that the added styrene-maleic anhydride copolymer is completely wetted to form uniform slurry. Adding a proper amount of dimethylethanolamine into the slurry under the stirring state to enable the pH of the system to reach more than 10, gradually increasing the stirring speed to 600-1000r/min, and stirring at normal temperature for 4-5 h to completely dissolve the styrene-maleic anhydride copolymer resin to obtain a mixed solution A.
(2) Under the condition of low-speed stirring at 60-100r/min, sequentially adding the water-based acrylic emulsion and the styrene-acrylic acid copolymer emulsion which are weighed according to the proportion into the mixed solution A, gradually increasing the stirring speed to 600-1000r/min after the addition, and stirring at normal temperature for 1-2 h to ensure that the emulsion is uniformly and completely dispersed to obtain the mixed solution B.
(3) And adding the aqueous high-density polyethylene wax emulsion, the epoxy silane and the modified polysiloxane emulsion which are weighed according to the proportion into the mixed solution B, stirring for 0.5-1 h at the stirring speed of 100-300r/min until the mixture is completely and uniformly dispersed, adjusting the pH of the system to be more than 10 by using dimethylethanolamine, and filtering by using a 200-mesh screen to obtain the anti-falling and anti-adhesion gloss oil for the aluminized tipping paper.
And (2) mixing the prepared gloss oil with ethanol at the temperature of 22-28 ℃ and the relative humidity of 50-60 percent: diluting with 1:1 pure water to 12s-18s (British 2# cup), drying at 130 deg.C and 150 deg.C by using 80 lines/cm printing plate, and printing at 180 deg.C and 200m/min at 0.1-0.3g/m2Printing process with dry coating amount of 32-45g/m2The surface of the ink layer of the aluminized tipping paper is polished with oil, dried and rolled. The oil-coated surfaces are attached two by two, a weight of 4kg is placed on the paper stack, and the paper stack is placed in a drying oven at 150 ℃ for standing for 48 hours, and then the coating is observed not to discolor or adhere. The oil-surface-passing tipping paper is subjected to laser drilling in two rows with the hole spacing of 1mm and the hole center-to-edge distance of 21.5mm, and the air permeability coefficient of variation detected is less than 4%, so that the standard requirement of the tipping paper is met.
Example 2
An anti-drop and anti-adhesion gloss oil for aluminized tipping paper comprises the following specific formula in parts by weight: 58 parts of aqueous polyurethane dispersion liquid, 5 parts of styrene-acrylic acid copolymer emulsion, 2 parts of styrene-maleic anhydride copolymer, 1 part of aqueous high-density polyethylene wax emulsion, 0.5 part of epoxy silane, 0.3 part of modified polysiloxane emulsion, 17.5 parts of purified water and a proper amount of dimethylethanolamine.
The specific preparation method is the same as that of example 1.
Example 3
An anti-drop and anti-adhesion gloss oil for aluminized tipping paper comprises the following specific formula in parts by weight: 30 parts of waterborne acrylic modified polyurethane emulsion, 20 parts of styrene-acrylic copolymer emulsion, 10 parts of styrene-maleic anhydride copolymer, 10 parts of waterborne high-density polyethylene wax emulsion, 0.1 part of epoxy silane, 0.5 part of polyether siloxane emulsion, 15 parts of purified water and a proper amount of dimethylethanolamine.
The specific preparation method is the same as that of example 1.
Example 4
An anti-drop and anti-adhesion gloss oil for aluminized tipping paper comprises the following specific formula in parts by weight: 70 parts of waterborne acrylic modified polyurethane emulsion, 12 parts of styrene-acrylic copolymer emulsion, 5 parts of styrene-maleic anhydride copolymer, 7 parts of waterborne high-density polyethylene wax emulsion, 0.8 part of epoxy silane, 0.4 part of polyether siloxane emulsion, 50 parts of purified water and a proper amount of dimethylethanolamine.
The specific preparation method is the same as that of example 1.
Claims (4)
1. An anti-drop and anti-adhesion gloss oil for aluminized tipping paper is characterized in that the anti-drop and anti-adhesion gloss oil comprises the following raw materials in parts by weight: 40-60 parts of water-based film-forming resin, 8-12 parts of water-based non-film-forming resin, 5-10 parts of high-temperature-resistant resin and 4-7 parts of water-based high-density polyethylene wax emulsion, wherein the appearance of the water-based high-density polyethylene wax emulsion is light yellow emulsion, the pH value of the water-based high-density polyethylene wax emulsion is 8-9, the solid content of the water-based high-density polyethylene wax emulsion is 35%, the melting point of the water-based high-density polyethylene wax emulsion is 137 ℃, 0.5-1 part of water-based adhesion promoter, 0.4-0.5 part of water-based defoaming agent, 17-36 parts of purified water and a proper amount of pH regulator; the waterborne film-forming resin is at least one of waterborne polyurethane dispersion and waterborne acrylic modified polyurethane emulsion; the water-based non-film-forming resin is a non-film-forming hard styrene-acrylic acid copolymer emulsion, the appearance of the emulsion is milky semitransparent liquid, the solid content is 48 +/-1, the pH value is 8-9, and the glass transition temperature Tg is 100 ℃; the high-temperature resistant resin is a styrene-maleic anhydride copolymer; the water-based adhesion promoter is epoxy silane.
2. An anti-drop and anti-adhesion gloss oil for aluminized tipping paper according to claim 1, characterized in that: the aqueous defoaming agent is at least one of modified polysiloxane emulsion and polyether siloxane emulsion.
3. An anti-drop and anti-adhesion gloss oil for aluminized tipping paper according to claim 1, characterized in that: the pH regulator is dimethylethanolamine.
4. A method for preparing the anti-drop and anti-adhesion gloss oil for the aluminized tipping paper of any one of claims 1 to 3, characterized by comprising the following steps:
(1) adding purified water weighed according to a ratio into a dissolving kettle, adding high-temperature-resistant resin weighed according to the ratio under the condition that the stirring speed is 60-100r/min, and stirring for 5-10 min to completely wet the added high-temperature-resistant resin into uniform slurry; adding a proper amount of pH regulator into the slurry under the stirring state to enable the pH of the system to reach more than 10, gradually increasing the stirring speed to 600-;
(2) under the condition of low-speed stirring at 60-100r/min, sequentially adding the aqueous film-forming resin and the aqueous non-film-forming resin which are weighed according to the proportion into the mixed solution A, gradually increasing the stirring speed to 600-1000r/min after the addition, and stirring at normal temperature for 1-2 h to uniformly and completely disperse the emulsion to obtain a mixed solution B;
(3) and adding the aqueous high-density polyethylene wax emulsion, the aqueous adhesion promoter and the aqueous defoaming agent which are weighed according to the proportion into the mixed solution B, stirring for 0.5-1 h at the stirring speed of 100-300r/min until the mixture is completely and uniformly dispersed, adjusting the pH to be more than 10 by using a pH regulator, and filtering by using a 200-mesh screen to obtain the anti-drop and anti-adhesion gloss oil for the aluminized tipping paper.
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| CN111501404A (en) * | 2020-04-28 | 2020-08-07 | 曲靖麒麟福牌印刷有限公司 | High-temperature-resistant antibacterial tipping paper gloss oil and preparation method thereof |
| ZA202006089B (en) * | 2020-10-01 | 2023-01-25 | Seal Chemistry Pty Ltd | High-release barrier coated paper wrapper for candies and gum which exclude the use of hot wax and a method for preparation thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001275641A (en) * | 2000-03-30 | 2001-10-09 | Japan Tobacco Inc | Device for inspecting and excluding filter-tipped cigarette |
| CN101879819A (en) * | 2010-06-13 | 2010-11-10 | 高邮市卫星卷烟材料有限公司 | Production method of hot stamping foil |
| CN105694602A (en) * | 2014-11-27 | 2016-06-22 | 合众（佛山）化工有限公司 | Preparation method of highlight high-temperature-resistant waterborne glazing oil |
| WO2017216767A1 (en) * | 2016-06-17 | 2017-12-21 | HICKMAN, Stuart Roy | Micro-porous coating compositions |
| CN108774915A (en) * | 2018-06-29 | 2018-11-09 | 湖北黄鹤楼特色包装材料有限公司 | A kind of high temperature resistant prevents adhesion finishing oil |
| CN109295806A (en) * | 2018-10-10 | 2019-02-01 | 玉溪接装纸制造有限公司 | A kind of polychrome double exposure tipping paper and preparation method thereof with metallic luster |
-
2019
- 2019-07-22 CN CN201910658926.2A patent/CN110205868B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001275641A (en) * | 2000-03-30 | 2001-10-09 | Japan Tobacco Inc | Device for inspecting and excluding filter-tipped cigarette |
| CN101879819A (en) * | 2010-06-13 | 2010-11-10 | 高邮市卫星卷烟材料有限公司 | Production method of hot stamping foil |
| CN105694602A (en) * | 2014-11-27 | 2016-06-22 | 合众（佛山）化工有限公司 | Preparation method of highlight high-temperature-resistant waterborne glazing oil |
| WO2017216767A1 (en) * | 2016-06-17 | 2017-12-21 | HICKMAN, Stuart Roy | Micro-porous coating compositions |
| CN108774915A (en) * | 2018-06-29 | 2018-11-09 | 湖北黄鹤楼特色包装材料有限公司 | A kind of high temperature resistant prevents adhesion finishing oil |
| CN109295806A (en) * | 2018-10-10 | 2019-02-01 | 玉溪接装纸制造有限公司 | A kind of polychrome double exposure tipping paper and preparation method thereof with metallic luster |
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| CN110205868A (en) | 2019-09-06 |
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