CN109183454A - A kind of heat curing type garment printing ink for screen printing and preparation method thereof - Google Patents
A kind of heat curing type garment printing ink for screen printing and preparation method thereof Download PDFInfo
- Publication number
- CN109183454A CN109183454A CN201811154126.9A CN201811154126A CN109183454A CN 109183454 A CN109183454 A CN 109183454A CN 201811154126 A CN201811154126 A CN 201811154126A CN 109183454 A CN109183454 A CN 109183454A
- Authority
- CN
- China
- Prior art keywords
- curing type
- heat curing
- type garment
- screen printing
- printing ink
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/5214—Polymers of unsaturated compounds containing no COOH groups or functional derivatives thereof
- D06P1/5235—Polyalkenyl halides, e.g. PVC
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
- D06P1/65106—Oxygen-containing compounds
- D06P1/65125—Compounds containing ester groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67333—Salts or hydroxides
- D06P1/6735—Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a kind of heat curing type garment printing ink for screen printing and preparation method thereof, its key points of the technical solution are that including following weight percent composition: plasticizer 45~50%, PVC paste resin 40~45%, stabilizer 1~2%, auxiliary agent 6~10%.The purpose of the present invention is to provide a kind of heat curing type garment printing ink for screen printing, cooperate printing machine fast using rate of drying, are not easy network blocking.
Description
[technical field]
The invention belongs to print technical field of ink, and in particular to a kind of heat curing type garment printing ink for screen printing and its preparation
Method.
[background technique]
Traditional garment printing ink has oiliness and aqueous printing mortar, since there are many dangerous for oiliness printing mortar
Not environmentally etc. factors are eliminated already, on existing market using it is wider be aqueous printing mortar, but with garment printing industry
Development, it is more and more to the production technology quality and style of stamp, in new production technology and special printing quality with aqueous
Printing mortar is unable to reach, as full-automatic decorating machine high-speed production when slow drying speed；High-precision set is printed to be patterned easily
Network blocking；Print that there is the stamp of stereoscopic effect to rise is thick unhappy etc..
[summary of the invention]
The purpose of the present invention is to provide a kind of heat curing type garment printing ink for screen printing, and printing machine is cooperated to use rate of drying
Fastly, it is not easy network blocking.
The present invention also provides a kind of preparation methods of heat curing type garment printing ink for screen printing.
Technical solution of the present invention is as follows:
A kind of heat curing type garment printing ink for screen printing, including following weight percent composition:
Preferably, the plasticizer and the ratio of PVC paste resin are 1:1~1.25.
Preferably, the plasticizer be dioctyl terephthalate DOTP, tri trimellitate (2- ethylhexyl) ester TOTM,
One or more of trioctyl trimellitate (TOTM), fatty acid triglycercide, epoxidized fatty acid methyl esters, epoxy fatty acid ethylester are mixed
Close object.The plasticizer for selecting an environment-friendly type guarantees that a nothing can be selected by every Environmental Safety index in apparel industry
The sanitary grade PVC of poison pastes resin, it is ensured that the vinyl chloride monomer content in PVC paste resin is lower than 1PPM hereinafter, terephthalic acid (TPA) two
Monooctyl ester is excellent in physical property and mechanical performance, is a kind of primary plasticizer of function admirable of PVC plastic, mixes with PVC paste tree
Property it is good, have many advantages, such as it is heat-resisting, cold-resistant, difficult volatilization, it is anti-extraction, softness it is good, shown in product excellent persistence,
Resistance to soap is aqueous and low-temperature pliability, can shorten change and stir the time, improves processing fluidity.
Preferably, the stabilizer is liquid calcium zinc heat stabilizer.A calcium zinc heat stabilizer is selected, to improve ink
Weatherability and printing stability.
Preferably, the auxiliary agent is filler or toner pigment, and the filler is nanometer calcium carbonate, and the toner pigment is titanium
White powder pigment, iron oxide pigment.The filler auxiliary agent for selecting a high oil absorption amount is selected for adjusting the printability state of thermosetting ink
With the toner pigment of plastics grade, for mixing colours.
A kind of preparation method of heat curing type garment printing ink for screen printing, includes the following steps:
1), it is added plasticizer in a mixing bowl, stirring while, is added PVC paste resin, and 500~700 revs/min of revolving speed,
Time: 5~10 minutes；
2), continue to stir and be added stabilizer, 700~1000 revs/min of revolving speed, the time 5~10 minutes.
3), by 2~3 additions of auxiliary agent point after step 2), addition must first be uniformly dispersed every time adds afterwards, turns
Speed: 200~300 revs/min, the time: 10~15 minutes；
4) it is ground 2~3 times after, being dispersed with stirring uniformly through three-roller, obtains a kind of heat curing type garment printing ink for screen printing.
Preferably, in the step 3), when auxiliary agent is added, mixture viscosity can be stepped up, control temperature when stirring
Less than or equal to 40 DEG C.
Preferably, it is described 4) in three-roller be equipped with water cooler and cool down, temperature is low during the grinding process for control ink
In 35 DEG C.
The present invention compared with the existing technology, has the advantage that
The invention discloses a kind of heat curing type garment printing ink for screen printing, pastes the easy molecule cohesion of resin, is layered unstable, add
Entering dispersing agent facilitates solid resin emulsification, and under 145-160 DEG C of baking, ink energy rapid curing influences ink setting speed
The main reason for spending is temperature, when PVC paste resin particle disperses in plasticizers, and when heated, Resin Absorbent plasticizer occurs
Cross-linking reaction and solidify, form a PVC film in fabric surface, while it and fiber molecule are firmly combined, be very suitable to complete
The high speed printing of automatic printing machine, ink be at normal temperature will not do certainly it is cured, so in the screen painting of high mesh number not
Can network blocking, be suitble to the printing quality of high-precision chromatography, the ink it is solid containing up to 95% or more, during stamp from be altogether unjustifiable often
Fastly, be suitble to printing that there is the stamp of stereoscopic effect, due to thermosetting ink at normal temperature will not skinning from dry, produce in use
Raw waste material is few, and utilization rate is high；
The invention discloses a kind of preparation methods of heat curing type garment printing ink for screen printing, and raw material sources are extensive, preparation side
Method is simple, and production production process is pollution-free, and stable product quality, use cost are low.
[specific embodiment]
1~5 preparation method for further illustrating heat curing type garment printing ink for screen printing of the invention in conjunction with specific embodiments:
Embodiment 1-2:
1), it is added plasticizer in a mixing bowl, stirring while, is added PVC paste resin, and 500~700 revs/min of revolving speed,
Time: 5~10 minutes；
2), continue to stir and be added stabilizer, 700~1000 revs/min of revolving speed, the time 5~10 minutes.
3), filler and toner pigment are added three times after step 2), is added after must being first uniformly dispersed and adds again every time
Enter, revolving speed: 200~300 revs/min, the time: 10~15 minutes, temperature was controlled at 38 ± 1 DEG C；
4) it is ground 2~3 times after, being dispersed with stirring uniformly through three-roller, temperature control is obtained at 34 ± 1 DEG C when ink is ground
A kind of heat curing type garment printing ink for screen printing.
Embodiment 3-4:
1), it is added plasticizer in a mixing bowl, stirring while, is added PVC paste resin, and 500~700 revs/min of revolving speed,
Time: 5~10 minutes；
2), continue to stir and be added stabilizer, 700~1000 revs/min of revolving speed, the time 5~10 minutes.
3), by 2 additions of filler point after step 2), addition must first be uniformly dispersed every time adds afterwards, revolving speed:
200~300 revs/min, the time: 10~15 minutes, temperature was controlled at 39 ± 1 DEG C；
4) it is ground 2~3 times after, being dispersed with stirring uniformly through three-roller, temperature control is obtained at 33 ± 1 DEG C when ink is ground
A kind of heat curing type garment printing ink for screen printing.
Table 1: each group distribution ratio in Examples 1 to 4:
Table 2: the test of ink performance obtained by Examples 1 to 4:
A kind of heat curing type garment printing ink for screen printing of the invention, the easy molecule cohesion of paste resin are layered unstable, addition point
Powder facilitates solid resin emulsification, under 145-160 DEG C of baking, ink energy rapid curing, when PVC paste resin particle disperses
In plasticizers, when heated, Resin Absorbent plasticizer crosslinks reaction and solidifies, and it is thin to form a PVC in fabric surface
Film, while it and fiber molecule are firmly combined, and are very suitable to the high speed printing of full-automatic decorating machine, ink is at normal temperature will not
It is cured from doing, thus in the screen painting of high mesh number will not network blocking, be suitble to high-precision chromatography printing quality.
Claims (8)
1. a kind of heat curing type garment printing ink for screen printing, it is characterised in that including following weight percent composition:
2. a kind of heat curing type garment printing ink for screen printing according to claim 1, it is characterised in that: the plasticizer with
The ratio of PVC paste resin is 1:1~1.25.
3. a kind of heat curing type garment printing ink for screen printing according to claim 1, it is characterised in that: the plasticizer is pair
Dioctyl phthalate DOTP, tri trimellitate (2- ethylhexyl) ester TOTM, trioctyl trimellitate (TOTM), fatty acid glycerine three
One or more of ester, epoxidized fatty acid methyl esters, epoxy fatty acid ethylester mixture.
4. a kind of heat curing type garment printing ink for screen printing according to claim 1, it is characterised in that: the stabilizer is liquid
Body calcium zinc heat stabilizer.
5. a kind of heat curing type garment printing ink for screen printing according to claim 1, it is characterised in that: the auxiliary agent is filler
Or toner pigment, the filler are nanometer calcium carbonate, the toner pigment is titanium white powder pigment, iron oxide pigment.
6. a kind of preparation method of heat curing type garment printing ink for screen printing, it is characterised in that include the following steps:
1), it is added plasticizer in a mixing bowl, stirring while, is added PVC paste resin, and 500~700 revs/min of revolving speed, the time:
50~10 minutes；
2), continue to stir and be added stabilizer and diluent, 700~1000 revs/min of revolving speed, the time 5~10 minutes.
3), by 2~3 additions of auxiliary agent point after step 2), addition must first be uniformly dispersed every time adds afterwards, revolving speed: 200
~300 revs/min, the time: 10~15 minutes；
4) it is ground 2~3 times after, being dispersed with stirring uniformly through three-roller, obtains a kind of heat curing type garment printing ink for screen printing.
7. a kind of preparation method of heat curing type garment printing ink for screen printing according to claim 6, it is characterised in that: described
In step 3), when auxiliary agent is added, mixture viscosity can be stepped up, and control temperature when stirring is less than or equal to 40 DEG C.
8. a kind of preparation method of heat curing type garment printing ink for screen printing according to claim 6, it is characterised in that: described
4) three-roller in is equipped with water cooler to cool down, and temperature is lower than 35 DEG C to control ink during the grinding process.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811154126.9A CN109183454A (en) | 2018-09-30 | 2018-09-30 | A kind of heat curing type garment printing ink for screen printing and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811154126.9A CN109183454A (en) | 2018-09-30 | 2018-09-30 | A kind of heat curing type garment printing ink for screen printing and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109183454A true CN109183454A (en) | 2019-01-11 |
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ID=64907084
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811154126.9A Pending CN109183454A (en) | 2018-09-30 | 2018-09-30 | A kind of heat curing type garment printing ink for screen printing and preparation method thereof |
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| Country | Link |
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| CN (1) | CN109183454A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112876892A (en) * | 2021-03-12 | 2021-06-01 | 佛山市索菲雅网印科技有限公司 | Silk-screen printing coating and preparation method thereof |
| CN114188071A (en) * | 2021-12-10 | 2022-03-15 | 洋紫荆油墨(中山)有限公司 | Thermosetting conductive slurry and preparation method and application thereof |
| CN114316672A (en) * | 2021-12-10 | 2022-04-12 | 洋紫荆油墨(中山)有限公司 | Thermosetting insulating oil and preparation method and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0051560A1 (en) * | 1980-10-03 | 1982-05-12 | Ciba-Geigy Ag | Monoazopigments containing heterocyclic nuclei, their preparation and use |
| CN1058033A (en) * | 1990-05-03 | 1992-01-22 | Lcv国际有限公司 | Printing inks and printing method |
| CN102848763A (en) * | 2012-09-13 | 2013-01-02 | 广州市优伟家居用品有限公司 | Production method of bicolor printing outdoors tablecloth |
-
2018
- 2018-09-30 CN CN201811154126.9A patent/CN109183454A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0051560A1 (en) * | 1980-10-03 | 1982-05-12 | Ciba-Geigy Ag | Monoazopigments containing heterocyclic nuclei, their preparation and use |
| CN1058033A (en) * | 1990-05-03 | 1992-01-22 | Lcv国际有限公司 | Printing inks and printing method |
| CN102848763A (en) * | 2012-09-13 | 2013-01-02 | 广州市优伟家居用品有限公司 | Production method of bicolor printing outdoors tablecloth |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112876892A (en) * | 2021-03-12 | 2021-06-01 | 佛山市索菲雅网印科技有限公司 | Silk-screen printing coating and preparation method thereof |
| CN114188071A (en) * | 2021-12-10 | 2022-03-15 | 洋紫荆油墨(中山)有限公司 | Thermosetting conductive slurry and preparation method and application thereof |
| CN114316672A (en) * | 2021-12-10 | 2022-04-12 | 洋紫荆油墨(中山)有限公司 | Thermosetting insulating oil and preparation method and application thereof |
| CN114188071B (en) * | 2021-12-10 | 2024-09-24 | 洋紫荆油墨(中山)有限公司 | Thermosetting conductive paste and preparation method and application thereof |
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190111 |
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