CN1058033A

CN1058033A - Printing inks and printing method

Info

Publication number: CN1058033A
Application number: CN91103587A
Authority: CN
Inventors: 马克·P·麦康奈尔; 罗伯特·W·威尔逊; 梅拉尼·N·威尔逊-贝克
Original assignee: LCV INTERNATIONAL Ltd
Current assignee: LCV INTERNATIONAL Ltd
Priority date: 1990-05-03
Filing date: 1991-04-30
Publication date: 1992-01-22
Also published as: PT97554A; NZ237991A; CA2081981A1; YU77891A; EP0527160A1; WO1991017302A1; CS126291A3; AU7766991A; IE911429A1

Abstract

With the printing inks that contains polyvinyl chloride copolymer, softening agent, antioxidant, stablizer and pigment, connect on one deck China ink on transfer sheet 20 by grooved roller 14 one decks, and the style disengaging transfer sheet 20 that will print is bonded on the textile sheet with hot pressing roller 30,32.This printing ink at room temperature can be powdery also can be pasty state or liquid or with on the printing ink that melts to grooved roller tube 14.Last China ink heats with lamp 50 after transfer sheet 20, causes and solidifies.As needs, transfer sheet 20 can flocking, after the China ink, is coated with the powdery binding agent and makes decorative pattern or style can slough the base layer of transfer sheet 20 then from transfer sheet 20 coining to base material after by hot pressing on the China ink layer on the flocking transfer sheet, exposes the decoration flocking.

Description

Printing inks and printing method

The invention relates to the improvement of printing inks, particularly with the method for this printing ink seal decorative pattern on the base material of fabric etc.

Used printing ink in traditional textile printing technology owing to viscosity height, slow, the requirement curing for a long time of stamp speed, thereby is incured loss through delay production, and is particularly all the more so when the style that will print needs several distinct colors.

In addition, many kinds of commonly used printing ink, especially those often produce deleterious waste liquid with the printing ink of China ink on the subliming method, need it from the building site venting with handle, to reduce environmental pollution.

Also have, the colouring of many kinds of printing ink commonly used is limited in one's ability, is difficult to be printed as the sharpness height, color is finished genuine style, and is especially all the more so during the stamp on the fabric darker than the color that will print.

Also meet some difficult problems in stamp production, the style that is printed is nontoxic to the user of product, textiles particularly, the textiles of using as children; In addition, style will keep structural integrity (especially crackle) after long-term dress and/or repeated multiple times cleaning.

One of various tasks of the present invention are to overcome above-mentioned these weavings and the textile material problem and other problem that run in stamp.But the present invention should be understood that also similar the or similar problem that is proposed in other field is had its practicality, for example to the stamp of some wall surface coating.

Here used " printing ink " this speech, being understood that usually can be to the composition and the material of flaky material colouring, but this flaky material generally is not limited to sheet fabric or textile materials.

Printing inks provided by the invention comprises:

[a] polymer support material;

[b] softening agent;

[c] stablizer; With

[d] pigment.

The preferable consumption of polymkeric substance is (not comprise pigment) between 25% to 45%.Polymkeric substance preferably contains the resin of hydroxyl as topcoating, and preferred polymkeric substance comprises polyvinyl chloride (PVC).This carrier substance is advisable with the multipolymer form, and more suitable is the multipolymer of PVC and acrylate or polyvinyl acetate (PVA) (PVA).

Polymkeric substance preferably includes the mixture of multipolymer, and its blending ratio is for example between 60: 40 and 40: 60.

Plasticizer consumption is obviously to be advisable more than usual amounts, and the ratio of preferred consumption and carrier is between 60: 40 and 40: 60.

Softening agent is clearly to the effect that reduces printing inks viscosity, particularly at room temperature being the solid printing inks.

As the comparatively suitable component that softening agent is used, be to contain to be selected from adipic acid ester, phthalic ester, sebate, citrate and the phosphoric acid ester material in forming.

But softening agent preferably contains the second plastifying component, and this component is proper is that to be selected from the polyurethane(s) be the polymeric plasticizer of base-material.

In this method, used two kinds of softening agent, wherein a kind ofly reduce the effect of going up ink viscosity in the black process, especially when melt printing ink go up China ink the time, second kind of softening agent is to reduce the hardness that goes up black printing ink.

With polyurethane(s) is the softening agent of base-material, can make printing ink that usual vehicle is had certain oil resistant property put forward.

Preferred printing ink contains oxidation inhibitor, sterically hindered phenol oxidation inhibitor for example, and its protection polymer support is avoided thermooxidative degradation.

Preferred stablizer is the organotin stabilizer with octyl mercaptan tin type.

Printing inks of the present invention preferably contains wax, and content does not preferably comprise pigment less than 4%().General with polyethylene wax, the polyethylene wax of partial oxidation preferably.Significantly outer lubrication is arranged owing to the compatibility of it and PVC is limited in this way, thereby produce resistance to bond, the taxis that printing ink is adhered on the printing roller reduces, particularly on the melting attitude when black.

This printing ink preferably contains lubricant, generally uses epoxidised soybean oil.The effect of this lubricant is the retroaction of offsetting stablizer, and it can cause that compound adheres on the texturing of printing roller, produces uneven stamp.In addition, this lubricant also plays the second certain heat-staple effect.

This printing inks preferably contains thixotropic agent, generally uses calcium base thixotropic agent, for example the partially hydrated mixed carbonate of magnesium and calcium.The effect of this thixotropic agent is to reduce the viscosity of batching under shearing force, makes China ink easily, and can make printing roller institute impression case keep distinct.

As pigment, have been found that the organic and mineral dye of many kinds all can be suitable for.

Also provide a kind of printing ink method for printing according to claim 1 according to the present invention, the stamp step is:

[a] is being added to printing ink on first printing roller under the liquid state;

[b] with this printing ink from first printing roller on transfer sheet;

[c] is being added to printing ink on the printing roller of one or more subsequent handlings under the liquid state;

[d] is added to printing ink on the transfer sheet from above-mentioned each graining roll.

Many distinct colors printing ink can be formed on the styles with such method on the transfer sheet of China ink to the back.

Transfer sheet can be the common paper of continuous reel form.

It can be heavy paper that the present invention is used in the metope wallpaper, and it can directly be attached on the surface that will decorate.

Perhaps the present invention can use light paper when being used in textiles seal decorative pattern.

Preferred printing ink at room temperature is China ink on the powdery, before transfer paper it is melted on by printing roller.

Perhaps this printing ink also fluid at room temperature, for example liquid or pasty state, and preferably each on the transfer sheet Mo Shijun carry out under these conditions, be about to transfer sheet by the ink solidification on the heating zone initiation carrier, for example adopt ir radiation.

In the case, preferably, promptly should go up earlier than light color inks with China ink on the opposite order of light absorption, on the back than dark ink.

Transfer sheet can be flocking, on the printing ink on the transfer sheet of flocking, printing ink has just been permeated in flocking like this, preferably and then coat binding agent after the China ink on this road at the exposed surface of topped flocking, methods such as available spraying, powder are coated with, roller coat, carrier with flocking when stamp finishes is cut into sheet, each sheet passes through hot-pressed printing as a decorative pattern separately between reception material and transfer sheet, the exposed surface that scribbles binding agent is adhered to receive on the material, after peeling transfer sheet off, decorative pattern just appears at the back side of flocking.

But this method also can comprise a procedure again, promptly uses hot-pressed printing between transfer sheet and textile pieces, and style is transferred on the textile sheet.

Perhaps the complete style of above-mentioned generation directly can be transferred on the material of flocking.

Now selected two kinds of prescriptions are elaborated with reference to accompanying drawing, purpose is illustration the present invention, and three kinds of printing methods that use these prescriptions are also elaborated, and this also is that some aspect of the present invention is made an explanation.

Prescription 1

Prescription 1 is made up of by following consumption following composition:

Polymer support material 39%

Softening agent 37.5%

Wax 4%

Oxidation inhibitor 0.5%

Stablizer 1.5%

Lubricant 2.5%

Thixotropic agent 15%

The polymer support material:

Polymkeric substance as carrier, preferably the multipolymer in order to vinylchlorid and acrylate or vinyl acetate is the resin surface coating of the hydroxyl of base-material, in prescription 1, used the blend of two kinds of multipolymers, VinnolE/40a and E15/48a that particularly German Wacker-chemieGMBH produces.This material is a white powder, and granularity is less than 4mm, and tamped density is approximately 0.4g/cm ³Its physicals is as follows:

Vinnol		E15/40A	E15/48A
				K value (DIN53276)		39+/-1	48+/-1
Content of vinylchloride (Wacker method)	%W/W	84+/-1	82.4+/-1
				Hydroxy radical content (Wacker method)	%W/W	1.8+/-0.2	1.8+/-0.2
Vicat softening temperature (DIN53460)	℃	About 0.64	0.67

Viscosity.Be dissolved in methylethylketone 25%W/W at 50 ℃ (122 °F)
				DIN 53015 Hoppler viscometers	MPa.s	20+/-5	55+/-10
DIN 53211 4mm cups	S	About 0.14	About 0.23
				DIN ISO 2413 4mm cups	S	About 0.22	About 0.47

Except with the Vinnol this trade mark, other polymer support material can be with the multipolymer of vinyl acetate/vinylchlorid, VYHH for example, VYHD, VYLF, VAGH, VAGD, VROH, VMCH, VMCC, VMCA, these all are to be produced by Britain associating carbonization (UK) company limited.

Softening agent

As softening agent, preferably that usefulness is Unimoll66, and it is the dicyclohexyl phthalate of being made by Bayer A.G, and it provides with white crystalline material, is only limited to the adapted with PVC.

Other can with softening agent comprise adipic acid ester, phthalic ester, sebate, citrate, phosphoric acid ester and other monomeric substance and polymeric material, these all are the PVC carrier systems that are used to do, the REO-MOLTPP that for example available Ciba-Geigy is produced.

Softening agent second component

As the second component softening agent is the UltramollPU that Beyer Co., Ltd produces.Ul-tramoll PU be a kind of be base-material with the high tenacity polyurethane(s), the pulverous polymeric plasticizer of no color or smell, and mix a little P VC as powdering agent.This product aims at PVC and share and design with any ratio, also can mix monomeric plasticizer and other polymeric plasticizer.In addition, use Ultramoll PU that most of usual vehicles are had anti-extracting, this solvent comprises tetrachloroethylene and three oxygen ethene.

The wax component

Preferred wax component is the Irgawax371 that makes with German Ciba-Geigy Marienberg GMBH.This is a kind of polyethylene wax of partial oxidation, because it is limited with the compatibility of PVC, so it has tangible outer lubrication.Concentration has significant anti-adhesion effect at the wax more than 0.2 part, reduces the adhesion trend of melt in the thermometal part of graining roll.

But the releasing agent of also available other wax type comprises the Epolene C10P of Eastman chemical company manufacturing and the Hoechst-wachs PED521 that Hoechst-wachs AG makes.

Antioxidant

Preferred anti-oxidants is the Irganox1076 that has German Ciba-Geigy Marienberg GMBH to make, and this is a kind of sterically hindered phenol oxidation inhibitor, and the base-material that its protection adds inside makes it avoid thermooxidative degradation.Its chemical structure is octadecyl 3-(3,5-di-t-butyl-4-hydroxyphenyl)-propionic ester.

Certainly also available other anti-oxidant oxygen, for example Irganox1010 or the HostanoxDAR24 of Hoechst A.G manufacturing.

Stablizer

Preferably use the organotin stabilizer of octyl mercaptan tin type, by Irgastab 17 MOK of Ciba-GeigyMarienberg GMBH manufacturing.It is colour-fast or do not degrade to use Irgastab 17MOK stablizer can make melting material add man-hour under long period or comparatively high temps.In the life-span that this has just prolonged melting printing ink, make it colour-fast and guarantee every batch of colour consistency of producing material.

But also can make the PVC stablizer, the Tinstab ZT903 that for example Hostastab SNS10 of Hoechst AG manufacturing, or Dutch Haagen Chemie b.v. produces with other tin octylate.

Lubricant

The Reoplast 392 that preferred lubricant is to use Ciba-Geigy Marienberge GMBH to make, this is a trade mark as the epoxy soybean oil of PVC internal lubricant.Reoplast 392 has offset the retroaction of octyl tin stabilizer, and it can make batching adhere in the texturing trace of grain roller, thereby produces uneven stamp on transfer paper.It has not only made internal lubricant, also can be used as second thermo-stabilizer, and therefore the advantage of strengthening main thermo-stabilizer is arranged.

In a word, also available other epoxy soybean oil production.

The thixotropic agent component

That be preferably used as the thixotropic agent component is Britain Microfine Minerals ﹠amp; The Ultracarb U5 that Chemicals company limited makes, this material is a kind of natural magnesium filler salt, also has flame retardant resistance.

, reduce the viscosity of printing ink under shearing force, and after transfer, keep high viscosity the fused thixotropic transformation of having prepared burden with Ultracrb US, make the style of transfer keep clear.

But also can be with filler like other numerous species.

Pigment

The pigment of now existing many kinds of organic or inorganics is considered to be applicable to system of the present invention, though following two class pigment dyestuffs have demonstrated preferable performance: bright, photostabilization, thermostability, little, the low ash content of toxicity and color matching are easily.This two classes pigment is the Hostaprint that Hoechst AG makes, and the Microlith C-K of Ciba-Giegy manufacturing.

In addition, a kind of pigment that is used for production " metallic appearance " is the Silvet EX592﹠amp that Scotland Silberlene company limited makes; 972.

For producing " fluorescent effect ", can prepare burden with the various Radglow that Ciba-Geigy makes, P-18, PS-10, R-18 and R-19 are specifically arranged.

All preferred formulations all are powdery products in the prescription 1, as needs, particularly relate to color matching when material, wax and/or lubricant, can be with liquid, but preferably clad can be miscible at PVC with it solid ingredient in, several batchings of this prescription are mixed in dry state.

Prescription 2

Polymer support material 40%

Softening agent 34%

Wax 2%

Antioxidant/lubricant 11.5%

Stablizer 1%

Thixotropic agent 11.5%

The 2 used preferred formulations of filling a prescription are as follows:

The polymer support material

The Ucar Vinylite that past attempts is made with Union Carbide Corp is as the polymer support material, and this material is a kind of vinylchlorid/vinyl acetate copolymer, and ratio is about 86%/14%.With this product is that the coating of base-material is thermoplastic, non-oxide reaction and non-thermal response, does not have obvious color, odorless, tasteless.Their physicals is as follows:

VCI/VA % 86/1d

Logarithmic viscosity number (ASTMD-1243) 0.5

Proportion (ASTMD-792) 1.35

Second-order transition temperature ℃ 72

Average molecular mass Mn 20,000

Soltion viscosity CP 600 in the time of 25 ℃

Granularity 98% weight is by 20 orders

Loose density 385-545kg/m ³

Perhaps can use the VinnolH15/45 of Wacker-Chemie GMBH manufacturing, H15/50, H14/36.

Softening agent

The Bisoflex DOP that makes with Britain B P Chemicals Limited is as softening agent.Bisoflex DOP is the common plasticizer of a kind of known PVC of being used for, and molecular weight is 390, and the specific refractory power of n20.D is that the density under 1.487,20 ℃ is 0.983kg/L, and the boiling point under the 5mbar is 220 ℃.

But also available other softening agent comprises DINP, DIDP, DIDP, DOA, or DIDA.

The expense of Bisoflex DOP is about 24%(and does not comprise pigment).

Softening agent/second component

Plasticizers as second component is the PerchemMF that makes with Britain AKZO chemistry company limited, its expense is approximately 10%, PerchemMF is a kind of finely divided hydrogenated castor oil, generally is used as paint, the rheology control agent of polyester glue coating, printing inks, makeup etc.Especially when prescription used in 2, this product can make batching have lower fusing point and viscosity, and the pigment solids of suspension can have bigger per-cent, but also can be with the hydrogenated castor oil of other trade mark.

Antioxidant

Preferred anti-oxidants is to use Hercolyn D, and consumption is about 11.5%(except that pigment).Hercolyn D is that Dutch Hercules BV makes, and it is that a kind of hercolyn D, acid number are 4-8.

This material has excellent wettability also as lubricant to other component.

Stablizer

Preferred stablizer is organotin, fill a prescription Irgastab17MOK in 1 preferably.But also think and to use other stablizer.

The wax component

The wax component is approximately used 2% of gross weight, and preferred wax is a kind of Epolene C10P of equal proportion and the mixture of Irgawax 371 normally, in prescription 1 more detailed explanation is arranged.

The thixotroping component

Preferred thixotropic agent is Ultracarb U5, and consumption is about 40% weight.

Pigment

Prescription 2 can be with the similar pigment of prescription described in 1, but PV that makes with Hoechst AG and firm PV, and the Cromopthal and the Irgalite of Ciba-Geigy manufacturing, obtained good effect.

Prescription 1 batching is solid-state mixing, and 2 the batching of filling a prescription is to mix under heating up, and their form pasty state under this temperature, are exactly the material of colouring usefulness described below after mixing fully.But the prescription 2 that stamp is used preferably heats when preparation, and this helps thoroughly to mix and later curing.

Illustrate how to use above-mentioned two kinds of prescriptions to carry out the production process of stamp referring now to accompanying drawing at (particularly on textiles) on the sheet stock.

Fig. 1 simple declaration carry out a machine of stamp with first kind of prescription, be used for illustrating a kind of method of carrying out some aspect of the present invention, be the example that is used for illustrating the object of the invention.

In this machine shown in Figure 1, a plurality of operations are arranged, the process number purpose repeatedly depends on the kind number that will go up black color.Fig. 1 has enumerated A, B, C and D four procedures, but to be interpreted as with these several procedures be relevant with the style that will print.

Each operation of A, B, C and D has a mixing section (preferably seeing Fig. 2), and mixing section has will fill a prescription 1 compound of a pair of pressure roller 6,8 to add wherein gap, and roll-in is to thoroughly mixing, and makes this batching fusion.Remove fused printing ink by traction section 10, and it is transferred to heat channel roller 14, the recess (the about 1.5mm of the degree of depth) of the ink transfer that makes thawing with the method for routine texturing sample to this roller 16.Facing to the whole length of grooved roller scraper plate 18 arranged, its effect is to guarantee that the not recessed part of roller 14 always not have the printing ink of thawing.

Transferred material generally is advisable with the continuous reel 10 of paper; It is pulled out and lick China ink between grooved roller 14 and pressure upper inking roller 24 from feed roller 22, this transfer paper is brought into grooved roller contact, when it by between the roller 14 and 24 time, printing ink just from the impression groove 16 on transfer paper.Printing ink with this prescription can successfully all shift on the transfer sheet of per 2 meters heavy 28 common paper that restrain.

Similarly transfer sheet is installed on the grooved roller of order operation 14b, 14c, 14d, several further colors, like this, before sheet is rolled to roller 28, can be stored when needs on transfer sheet by last, just stamp desired color matching style.

When needs, transfer sheet 20 stretches by between the

heat roller tube

30 and 32 from roller 28, and at this, transfer sheet is brought into the (see figure 3) that contacts with the reel 34 of fabric, from transfer sheet stencil style.In this way successfully printing on the textile materials by several procedures of A, B, C and D at the style on the transfer sheet, and the transfer sheet of will giving up is rolled on collecting drum 36.

Then, the textile materials 34 that stamps style was passed through a series of deflector rolls 38 before pulling out.

Machine shown in Figure 4 and the machine of Fig. 1 are similar, the illustrated difference just and in the past that will illustrate later on, and for for simplicity, what represent among the figure is single operation.

The machine of Fig. 2 is applicable to prescription 2, is pasty state during this batching heating, or full-bodied liquid.Printing ink is contained among the groove 12a, grooved roller 14 in this groove on the China ink, scrape deflashing with scraper plate 18.With hot-rolling 24 printing ink is printed on the transfer sheet 20 from notch board 16.The coating of last China ink is passed through for 50 times at the superpower infrared lamp, heats this coatingsurface and it is caused solidify and solidify.Equally, transfer sheet 20 is all further shone heating with infrared lamp and is made ink deposition on transfer sheet, to guarantee abundant curing by after B, C and each operation of D, make the style that is set on the transfer sheet, any trend that fogs reduces to minimum at every turn by each order roller the time.

The application of Fig. 5 simple declaration the present invention in the ornament of preparation as applique.

As shown in Figure 5, flocking transfer sheet 20b has base material 21a and one deck flock coating of the material of one deck such as paper etc., passes through between the grooved roller 14 of heating and pressure roller 24, and last China ink arrives cashmere-planted layer 21b, this generally and Fig. 1,2 and 3 described methods similar.

On per pass after the black operation, last black surface is coated with polyester adhesive, the Turbitrans Elastomelt95F that for example German CHT makes, this binding agent is advisable with powdery, so that powder adheres on the thermoplastic printing ink.When therefore this printing technology finished, because the outside surface of flocked strip has an adhesive layer, required style just was imprinted on the flocked strip.

Then can be from the flocked strip applique, and can print to applique as required on (for example) textiles, its method is that the one side with coating adhesive is layered on the textiles, and facing to the abundant heating and pressurizing of ply of paper 21a, make binder activating and flocking is adhered on the textiles, the paper 20b with the back side after adhesive cures peels off.

Perhaps also can be with the described transfer sheet 20 of Fig. 1 to 4, the style that shape is complete prints to flocked surface, so just has complete a series of styles to be imprinted on simultaneously on the cashmere-planted layer, sees through the printing ink of flocked fiber 21b, be seeped into following substrate layer 21a, and on stamp, be coated with one deck hot-melt adhesive.At subsequent processing, flocked strip impression applique sticks with hot-press method, peels off back layer 21a then.

Can obtain the printing textile of shades of colour and style with the present invention, it has fastness and weather resistance, particularly can anti-various cleaning conditions, and also the PRINTED FABRIC feel is soft and nontoxic.

Below list the trade mark that occurred in this specification sheets:

VINNOL（Wacker-Chemie GMBH）

UNIMOLL（Bayer AG）

REOMOL（Ciba-Geigy）

ULTRAMOLL（Bayer AG）

IRGAWAX（Ciba-Geigy Marienberg GMBH）

EPOLENE（Eastman Chemical Corporation）

IRGANOX（Ciba-Geigy Marienberg GMBH）

IRGASTAB（Ciba-Geigy Marienberg GMCH）

HOSTASTAB（Hoechst AG）

TINSTAB（Haagcn Chemie b.v.）

REOPLAST（Ciba-Geigy Marienberg）

ULTRACARB（Microfine Mincrals & Chemicals Limited）

HOSTAPRINT（Hocchst A.G.）

MICROLITH（Ciba-Geigy）

SILVET（Silberlene Limitcd）

RADGLOW（Ciba-Geigy）

UCAR（Union Carbide Corporoation）

BISOFLEX（BP Chemicals Limited）

PERCHEN（AKZO Chemicals Limited）

HERCOLYND（Hercules BV）

CROMOPTHAL（Ciba-Geigy）

IRGALITE（Ciba-Geigy）

FASTION（Hoechst AG）

Superincumbent specification sheets or following claim or disclosed in the accompanying drawings feature, indicated various specific forms or word or means are finished desired function, or method or obtain disclosed result's technology, can be separately or the combination of these features be used and realize various task of the present invention.

Claims

1, a kind of printing inks contains

[a] polymer support material;

[b] softening agent;

[c] stablizer and

[d] pigment.

2, according to the printing inks of claim 1, wherein the consumption of polymkeric substance is (not comprise pigment) between 25% to 45%.

3, according to a kind of printing ink of claim 1, wherein polymkeric substance contains PVC.

4, according to a kind of printing ink of claim 1, wherein polymkeric substance contains the multipolymer of PVC and two olefin(e) acid esters.

5, according to a kind of printing ink of claim 1, wherein polymkeric substance contains the copolymerization fat of PVC and polyvinyl acetate (PVA).

6, according to a kind of printing ink of claim 1 or 2, wherein polymkeric substance contains the mixture that ratio is the multipolymer between 80: 20 to 20: 80.

7, according to a kind of printing inks of claim 1, wherein plasticizer consumption is obviously more than usual amounts.

8, according to a kind of printing ink of claim 7, wherein the ratio of the consumption of softening agent and carrier substance is between 60: 40 to 40: 60.

9, according to a kind of printing ink of claim 1, wherein softening agent contains two kinds of plasticised mass, and described first kind of softening agent plays a part to reduce ink viscosity in the process of last China ink; Second kind is to reduce the printing ink hardness that goes up China ink.

10, according to a kind of printing ink of claim 1, wherein softening agent contains a kind of material that is selected from adipic acid ester, phthalic ester, sebate, citrate and the phosphate ester components.

11, according to a kind of printing ink of claim 1, wherein to contain with polyethylene be the polymeric plasticiser of main base-material to softening agent.

12, according to a kind of printing ink of claim 1, contain a kind of antioxidant.

13, according to a kind of printing ink of claim 1, wherein stablizer is a kind of organotin stabilizer.

14, according to a kind of printing ink of claim 13, wherein stablizer is a kind of octyl mercaptan tin.

15, according to a kind of printing ink of claim 1, also contain a kind of wax.

16, according to a kind of printing ink of claim 15, wherein wax is a kind of polyethylene wax.

17, according to a kind of printing ink of claim 1, also contain a kind of lubricant.

18, according to a kind of printing ink of claim 17, wherein lubricant is a kind of epoxy soybean oil.

19, according to a kind of printing ink of claim 1, also contain a kind of thixotropic agent.

20, according to a kind of printing ink of claim 19, wherein thixotropic agent contains a kind of magnesiumcarbonate.

21, according to a kind of printing ink of claim 19, remove outside the pigment, wherein the consumption of thixotropic agent is between 10% to 20%.

22, according to a kind of printing ink of claim 1, wherein all components at room temperature is Powdered.

23, a kind of printing ink method for printing on textiles with claim 1 the steps include:

[a] with printing ink under the liquid condition to first printing roller;

[b] moves on to this printing ink on the transfer sheet from described printing roller;

[c] with printing ink under the liquid condition to one or more follow-up printing rollers;

[d] with printing ink from above-mentioned each graining roll on transfer sheet.

24, according to a kind of method of claim 23, wherein transfer sheet is a successive reel form.

25, according to a kind of method of claim 24, wherein transfer sheet is a paper.

26, according to a kind of method of claim 23, wherein printing ink at room temperature is pulverous, and China ink melted before transfer sheet on by printing roller.

27, according to a kind of method of claim 23, wherein printing ink at room temperature is liquid, and after last China ink is on transfer sheet, this sheet stock by one heating process, is caused the ink solidification on transfer sheet.

28, according to a kind of method of claim 23, wherein transfer sheet is flocking, and on the transfer sheet of flocking, permeating in this flocking on the China ink.

29, according to a kind of method of claim 28, after flocking, be coated with a layer binder at last black outside surface at last China ink.

30,, comprise that another step is that the method with heating and pressurizing is transferred to style on the textiles between transfer sheet and textiles according to a kind of method of claim 23.

31, a kind of printing ink, any in two kinds of prescriptions as previously described basically.

32, a kind of on textiles method for printing, basically by foregoing and implement with reference to accompanying drawing.