CN109464055A - A kind of preparation method of moisturizing soft antibacterial paper handkerchief and the paper handkerchief of preparation - Google Patents
A kind of preparation method of moisturizing soft antibacterial paper handkerchief and the paper handkerchief of preparation Download PDFInfo
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- CN109464055A CN109464055A CN201811423054.3A CN201811423054A CN109464055A CN 109464055 A CN109464055 A CN 109464055A CN 201811423054 A CN201811423054 A CN 201811423054A CN 109464055 A CN109464055 A CN 109464055A
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- paper handkerchief
- preparation
- moisturizing
- soft antibacterial
- emulsion compositions
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- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47K—SANITARY EQUIPMENT NOT OTHERWISE PROVIDED FOR; TOILET ACCESSORIES
- A47K10/00—Body-drying implements; Toilet paper; Holders therefor
- A47K10/02—Towels
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0208—Tissues; Wipes; Patches
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Public Health (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Biomedical Technology (AREA)
- Engineering & Computer Science (AREA)
- Dermatology (AREA)
- Emergency Medicine (AREA)
- Paper (AREA)
Abstract
The present invention discloses a kind of preparation method of moisturizing soft antibacterial paper handkerchief, it is related to daily necessities field, it is poor based on existing paper handkerchief antibacterial effect, have a single function, the problem of paper is easily layered and propose, the present invention is the following steps are included: prepare emulsion compositions, coating, curing；The invention also includes the paper handkerchiefs using the preparation of above-mentioned preparation method, including paper handkerchief and emulsion compositions, the emulsion compositions are mainly made of moisturizer 30%-60%, surfactant 1%-5%, nano zine oxide 1%-10%, softening agent 1%-20%, deionized water 20%-40%；The beneficial effects of the present invention are: preparation process is simple, and cost is relatively low, and flexible towelette obtained has good hydrophily, absorbability, moisture retention, and pliability and fluffy sense preferably, are not easy to be layered, and antibacterial and mouldproof effect is preferable.
Description
Technical field
The present invention relates to daily necessities fields, and in particular to a kind of preparation method of moisturizing soft antibacterial paper handkerchief and the paper of preparation
Towel.
Background technique
With the improvement of living standards and to the deep understanding that ambient enviroment adverse factor adversely affects human body, people's
Consciousness of keeping a public place clean is gradually increased paper and has become necessity for people's lives.
On manpower, the scurf etc. of dust and human body in the sweat and air of people together forms dirt.In dirt
On have accumulated a large amount of microorganism, wherein just having some may be sex pheromone, these bring people's health certain
It threatens.Especially some frequent carry out outdoor activists, due to the limitation of sanitary condition, dirt is more on hand skin, gathers above
A large amount of microorganism is collected, wherein may have some is the microorganisms such as pathogenic bacterium, fungi.And it is commonly used in daily life
Paper hardness it is larger, and easily cause after the symptoms such as dry skin, existing paper handkerchief has a single function, paper is easily layered,
The antibacterial effect of paper is poor simultaneously, easily goes mouldy, and during the preparation process, easily there is a phenomenon where condensations for emulsion compositions.
Summary of the invention
The problem to be solved by the present invention is that existing paper handkerchief antibacterial effect is poor, paper hardness is big, is easily layered.
The present invention adopts the following technical solutions solves above-mentioned technical problem:
The present invention provides a kind of preparation method of moisturizing soft antibacterial paper handkerchief, comprising the following steps:
(1) by 30%-50% moisturizer, 1%-5% surfactant, 5%-20% softening agent, 1%-10% nano oxygen
Change zinc, 20%-40% deionized water are added in reaction kettle, and stirring is configured to emulsion compositions；
(2) the emulsion compositions addition prepared in step (1) is applied on paper handkerchief, the rate of sizing is the 10%- of paper handkerchief
30%；
(3) paper handkerchief after coating is wound, and cures its naturally osmotic, made in paper handkerchief internal moisture and air
Moisture reaches balance, then is cut, packed to get moisturizing soft antibacterial paper handkerchief is arrived.
It preferably, further include 0.1% defoaming agent in the emulsion compositions.
Preferably, the defoaming agent is polyethers defoaming agent or organic silicon defoaming agent.
Preferably, the moisturizer is polyhydroxy alcohols.
Preferably, the softening agent is polysiloxanes.
Preferably, the surfactant is neopelex, sodium cetanesulfonate, polyoxyethylene polyols
One of ether, polyoxyethylene aliphatic alcohol ether, polyoxyethylene nonylphenol ether are a variety of.
Preferably, every square metre of the paper obtained is evenly distributed with 0.1-0.5g polysiloxanes, 0.2-0.6g polyhydroxy
Alcohols, 0.02-0.1g surfactant.
Preferably, mixing time is 1-2h in the step (1).
Preferably, the curing time is for 24 hours in the step (3).
The present invention also provides one kind moisturizing soft antibacterial paper handkerchief as made from above-mentioned preparation method.
The beneficial effects of the present invention are:
(1) preparation process of the invention is simple, and cost is relatively low, and paper handkerchief obtained has good hydrophily, absorbability, together
When pliability and it is fluffy sense preferably, be not easy to be layered；
(2) it uses nano zine oxide for bacteriostatic agent in preparation process of the present invention, imitates paper handkerchief with good antibacterial and mouldproof
Fruit.
Specific embodiment
The present invention is described in further details below with reference to embodiment.
Test material and reagent as used in the following examples etc., unless otherwise specified, commercially obtain,
Middle nano zine oxide can also be commercially available from domestic and international market.
Embodiment 1
A kind of preparation method of moisturizing soft antibacterial paper handkerchief, comprising the following steps:
(1) 49.9% deionized water, 5% polyoxyethylene polyols ether, 10% polysiloxanes, 30% glycerine, 5% are received
Rice zinc oxide is added in reaction kettle, after stirring 1h, 0.1% polyethers defoaming agent is added, is configured to emulsion compositions；Due to cream
There is surfactant in liquid composition, rear extended meeting generates many foams, therefore need to attach defoaming agent；
(2) the emulsion compositions addition prepared in step (1) is applied on paper handkerchief, the rate of sizing is the 20% of paper handkerchief；
(3) paper handkerchief after coating is wound, and makes the curing of its naturally osmotic for 24 hours, make paper handkerchief internal moisture and air
In moisture reach balance, then cut, packed to get to moisturizing soft antibacterial paper handkerchief.
Wherein, the coating method of emulsion compositions is the prior art.
Embodiment 2
A kind of preparation method of moisturizing soft antibacterial paper handkerchief, comprising the following steps:
(1) 49.9% deionized water, 5% polyoxyethylene polyols ether, 10% polysiloxanes, 30% glycerine, 5% are received
Rice zinc oxide is added in reaction kettle, after stirring 1h, 0.1% polyethers defoaming agent is added, is configured to emulsion compositions；
(2) the emulsion compositions addition prepared in step (1) is applied on paper handkerchief, the rate of sizing is the 10% of paper handkerchief；
(3) paper handkerchief after coating is carried out, winding, and makes the curing of its naturally osmotic for 24 hours, make paper handkerchief internal moisture and air
In moisture reach balance, then cut, packed to get to soft soft antibacterial paper handkerchief.
Wherein, the coating method of emulsion compositions is the prior art.
The bacteriostasis rate of product in embodiment 1 and embodiment 2 is detected, submitted sample and control sample are cut into
50mm × 50mm size is detected according to GB T 31402-2015 plastics frosting Anti-microbial Performance Tests method.
Testing result is as shown in table 1:
As can be seen from Table 1, when containing 5% or 8% nano zine oxide in paper handkerchief, paper handkerchief obtained has good anti-
Bacterium effect.The selection of bacteriostatic agent should consider fungistatic effect, also to consider the compatibility with emulsion compositions, prevent colloidal sol
Condensation.A variety of bacteriostatic agents, such as polyhexamethylene guanide, Bronopol, isothiazolinone are used in experimentation, it is above-mentioned antibacterial
There is condensation phenomenon after mixing with the emulsion compositions of the colloidal sol containing many kinds of substance such as polysiloxanes in agent, in the present embodiment with
It is preferable with the emulsion compositions compatibility of the colloidal sol containing many kinds of substance such as polysiloxanes for nano zine oxide, while having preferably
Fungistatic effect, and paper handkerchief is not susceptible to go mouldy, and wherein the partial size of nano zine oxide is 15nm.
Embodiment 3
The influence of polysiloxanes, glycerine, polyoxyethylene glycerol ether content to product physical property in emulsion compositions:
Table 2 is influence of the polysiloxane level to product physical property
From Table 2, it can be seen that polysiloxane level influences the pliability and intensity of paper handkerchief, when its content is greater than 14%
When, the lateral tensile index of paper will be less than 1.2Nm/g, and paper is easily broken in use；When content is less than 6%
When, pliability will be greater than 56mN, while paper handkerchief can seem stiffening and coarse；Therefore, polysiloxane level should be in 6%- in paper handkerchief
Between 14%.When content is between 10%-12%, the pliability of paper handkerchief will in 40mN hereinafter, and lateral tensile index will be big
In 1.5Nm/g.
Table 3 is influence of the glycerol content to product physical property
By the processed obtained paper handkerchief of sili-cone surfaces, the hydroxyl value on paper fibre element surface itself can reduce, make
Hyarogen-bonding weakens between obtaining cellulosic molecule, and the adsorption capacity between each layer paper handkerchief can reduce, and paper handkerchief is easy layering；Polyalcohol
Hyarogen-bonding is easily formed between hydroxyl and hydrone, therefore polynary alcohol and water has fabulous compatibility and water imbibition, potentially acts as
Moisturizer；Polyalcohol can absorb the moisture in environment, and saves it in the surface of paper, and paper is made to have damp, soft and moist
Property gets a promotion；Meanwhile polyalcohol, in paper surface, the hydroxyl value of paper surface increases naturally, the absorption between each layer paper handkerchief
Power will be improved, and paper is made to be not easy to be layered.
When glycerine is when paper surface content is less than 30%, paper hygroscopicity is poor, soft and moist property is bad, and easily layering；When
Glycerine is excessive in paper surface content, and when more than 60%, adsorption capacity rises and is closely adsorbed on one between each layer paper handkerchief
It rises, so that paper handkerchief loses original fluffy sense.
Table 4 is influence of the polyoxyethylene glycerol ether to product physical property
Since polysiloxane soft agent reduces the surface tension of paper fibre element, so that water is not easy to spread in paper surface
The hydrophily of exhibition, paper reduces, and therefore, surfactant is added in the lotion containing polysiloxane soft agent, and add poly-
The effect of ethylene oxide glycerin ether is best.
When the content of polyoxyethylene glycerol ether is less than 1%, the hydrophilicity of paper handkerchief cannot preferably improve, and be more than
When 4%, the absorption speed of paper handkerchief is without improved space.
The above is only the preferred embodiment of the present invention, protection scope of the present invention is not limited merely to above-described embodiment,
It is within the scope of the invention with present inventive concept without the various process programs of substantial differences.
Claims (10)
1. a kind of preparation method of moisturizing soft antibacterial paper handkerchief, it is characterised in that: the following steps are included:
(1) by 30%-60% moisturizer, 1%-5% surfactant, 5%-20% softening agent, 1%-10% nano zine oxide,
20%-40% deionized water is added in reaction kettle, and stirring is configured to emulsion compositions；
(2) the emulsion compositions addition prepared in step (1) is applied on paper handkerchief, the rate of sizing is the 10%-30% of paper handkerchief；
(3) paper handkerchief after coating is wound, and cures its naturally osmotic, make the moisture in paper handkerchief internal moisture and air
Reach balance, then is cut, packed to get moisturizing soft antibacterial paper handkerchief is arrived.
2. the preparation method of moisturizing soft antibacterial paper handkerchief according to claim 1, it is characterised in that: the emulsion compositions
In further include 0.1% defoaming agent.
3. the preparation method of moisturizing soft antibacterial paper handkerchief according to claim 2, it is characterised in that: the defoaming agent is poly-
Ethers defoaming agent or organic silicon defoaming agent.
4. the preparation method of moisturizing soft antibacterial paper handkerchief according to claim 1, it is characterised in that: the moisturizer is more
Hydroxy alcohols.
5. the preparation method of moisturizing soft antibacterial paper handkerchief according to claim 1, it is characterised in that: the softening agent is poly-
Siloxanes.
6. the preparation method of moisturizing soft antibacterial paper handkerchief according to claim 1, it is characterised in that: the surfactant
For neopelex, sodium cetanesulfonate, polyoxyethylene polyols ether, polyoxyethylene aliphatic alcohol ether, polyoxyethylene
One of nonyl phenolic ether is a variety of.
7. the preparation method of moisturizing soft antibacterial paper handkerchief according to claim 1, it is characterised in that: the paper obtained is every
Square metre it is evenly distributed with 0.1-0.5g polysiloxanes, 0.2-0.6g polyhydroxy alcohols, 0.02-0.1g surfactant.
8. the preparation method of moisturizing soft antibacterial paper handkerchief according to claim 1, it is characterised in that: in the step (1)
Mixing time is 1-2h.
9. the preparation method of moisturizing soft antibacterial paper handkerchief according to claim 1, it is characterised in that: in the step (3)
Curing time is for 24 hours.
10. the moisturizing using the preparation method preparation of the moisturizing soft antibacterial paper handkerchief of any of claims 1-9 is soft
Antibacterial facial tissue.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201811423054.3A CN109464055A (en) | 2018-11-27 | 2018-11-27 | A kind of preparation method of moisturizing soft antibacterial paper handkerchief and the paper handkerchief of preparation |
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| CN201811423054.3A CN109464055A (en) | 2018-11-27 | 2018-11-27 | A kind of preparation method of moisturizing soft antibacterial paper handkerchief and the paper handkerchief of preparation |
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| CN109464055A true CN109464055A (en) | 2019-03-15 |
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| CN201811423054.3A Pending CN109464055A (en) | 2018-11-27 | 2018-11-27 | A kind of preparation method of moisturizing soft antibacterial paper handkerchief and the paper handkerchief of preparation |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113693063A (en) * | 2021-08-09 | 2021-11-26 | 广州市拓瑞科技有限公司 | Efficient antibacterial cream and preparation method thereof |
| CN114345492A (en) * | 2021-12-27 | 2022-04-15 | 深圳市金阳盛城市服务集团有限公司 | Intelligent garbage treatment equipment and garbage treatment method |
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| CN107926941A (en) * | 2017-11-15 | 2018-04-20 | 惠州市环美盛新材料有限公司 | A kind of zinc oxide antibacterial mildew inhibitor and its preparation method and application |
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Patent Citations (8)
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| CN101633781A (en) * | 2008-07-22 | 2010-01-27 | 道康宁（上海）有限公司 | Emulsion composition, method for softening fiber structure and fiber containing base material |
| CN103061204A (en) * | 2012-10-26 | 2013-04-24 | 福建恒安集团有限公司 | Soft paper subjected to surface preparation |
| CN103417154A (en) * | 2013-07-26 | 2013-12-04 | 广州联庄科技有限公司 | Mobile-phone antibacterial cleaning wet tissue |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN113693063A (en) * | 2021-08-09 | 2021-11-26 | 广州市拓瑞科技有限公司 | Efficient antibacterial cream and preparation method thereof |
| CN114345492A (en) * | 2021-12-27 | 2022-04-15 | 深圳市金阳盛城市服务集团有限公司 | Intelligent garbage treatment equipment and garbage treatment method |
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Application publication date: 20190315 |
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