CN105088864A - Antibacterial paint, antibacterial paper, preparation method of antibacterial paint, and preparation method of antibacterial paper - Google Patents
Antibacterial paint, antibacterial paper, preparation method of antibacterial paint, and preparation method of antibacterial paper Download PDFInfo
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- CN105088864A CN105088864A CN201410193370.1A CN201410193370A CN105088864A CN 105088864 A CN105088864 A CN 105088864A CN 201410193370 A CN201410193370 A CN 201410193370A CN 105088864 A CN105088864 A CN 105088864A
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Abstract
The invention discloses an antibacterial paint, antibacterial paper, a preparation method of the antibacterial paint, and a preparation method of the antibacterial paper. The antibacterial paper comprises a paper layer and an antibacterial paint layer arranged on the surface of the paper layer, wherein the antibacterial paint layer is a mixture layer of antibacterial ingredients and paints, and the antibacterial ingredients contain one or more of chitosan, tea tree essential oil, nanometer zinc oxide, silver nanometer antibacterial powder and nanometer titanium dioxide. Through the manner, the antibacterial paper which is environmental-friendly and has a lasting favorable antibacterial effect can be obtained.
Description
Technical field
The present invention relates to a kind of antibiotic paint, anti-bacteria paper and preparation method thereof.
Background technology
Along with economic development and growth in the living standard, people are concern for the environment hygienic issues more and more.Paper is indispensable articles for daily use during people live, and the mobility of paper is greatly one of approach of spread of germs.
At present, paper industry is generally by using mould inhibitor to prevent to produce in paper manufacturing systems going mouldy of rotten slurry and paper product.But mould inhibitor have impact on paper products quality to a certain extent and human body is healthy.
Summary of the invention
The technical problem that the present invention mainly solves is to provide a kind of antibiotic paint, anti-bacteria paper and preparation method thereof, this antibiotic paint has durable antibiotic effect, and this antibiotic paint is applied to paper products, not only environmental protection can be obtained but also there is the anti-bacteria paper of lasting good antibacterial effect.
For solving the problems of the technologies described above, the technical scheme that the present invention adopts is: provide a kind of antibiotic paint, described antibiotic paint is the mixture of antimicrobial component and coating, and described antimicrobial component is at least one of shitosan, tea tree ethereal oil, nano zine oxide, Nano Silver system antibacterial powder, nano titanium oxide.
Wherein, when described antimicrobial component only includes shitosan, the addition of shitosan is greater than 1% with the ratio of described coating content, is preferably 1-4%; When described antimicrobial component only includes tea tree ethereal oil, the addition of described tea tree ethereal oil is greater than 1% with the ratio of described coating content, is preferably 1-4%; When described antimicrobial component only includes nano zine oxide, the addition of described nano zine oxide is 0.3-0.8% with the ratio of described coating content; When described antimicrobial component only includes Nano Silver system antibacterial powder, the addition of described Nano Silver system antibacterial powder is 0.05-0.3% with the ratio of described coating content; When described antimicrobial component only includes nano titanium oxide, the addition of described nano titanium oxide is 0.3-0.8% with the ratio of described coating content.
Wherein, described antimicrobial component is any one composition of shitosan and nano oxidized Zn composition, tea tree ethereal oil and nano oxidized Zn composition, shitosan and tea tree ethereal oil composition, shitosan and tea tree ethereal oil and nano oxidized Zn composition, nano zine oxide and Nano Silver system antibacterial powder composition, nano zine oxide and nano titanium oxide composition, Nano Silver system antibacterial powder and nano titanium oxide composition, nano zine oxide and Nano Silver system antibacterial powder and nano titanium oxide composition.
Wherein, described nano titanium oxide is 10nm titanium dioxide or 5nm titanium dioxide.
For solving the problems of the technologies described above, another technical solution used in the present invention is: provide a kind of anti-bacteria paper, described anti-bacteria paper comprises paper layer and is coated on the antibiotic paint layer on described paper layer surface, described antibiotic paint layer is the mixture layer of antimicrobial component and coating, and described antimicrobial component is at least one of shitosan, tea tree ethereal oil, nano zine oxide, Nano Silver system antibacterial powder, nano titanium oxide.
Wherein, when described antimicrobial component only includes shitosan, the addition of shitosan is greater than 1% (1-4%) with the ratio of described coating content; When described antimicrobial component only includes tea tree ethereal oil, the addition of described tea tree ethereal oil is greater than 1% (1-4%) with the ratio of described coating content; When described antimicrobial component only includes nano zine oxide, the addition of described nano zine oxide is 0.3-0.8% with the ratio of described coating content; When described antimicrobial component only includes Nano Silver system antibacterial powder, the addition of described Nano Silver system antibacterial powder is 0.05-0.3% with the ratio of described coating content; When described antimicrobial component only includes nano titanium oxide, the addition of described nano titanium oxide is 0.3-0.8% with the ratio of described coating content.
Wherein, described antimicrobial component is any one composition of shitosan and nano oxidized Zn composition, tea tree ethereal oil and nano oxidized Zn composition, shitosan and tea tree ethereal oil composition, shitosan and tea tree ethereal oil and nano oxidized Zn composition, nano zine oxide and Nano Silver system antibacterial powder composition, nano zine oxide and nano titanium oxide composition, Nano Silver system antibacterial powder and nano titanium oxide composition, nano zine oxide and Nano Silver system antibacterial powder and nano titanium oxide composition.
Wherein, described nano titanium oxide is 10nm titanium dioxide or 5nm titanium dioxide.
Wherein, two surfaces of described paper layer are all coated with described antibiotic paint layer.
For solving the problems of the technologies described above, a kind of technical scheme in addition provided by the invention is: the preparation method providing a kind of anti-bacteria paper, and described method comprises: prepare paper; Configuration antibiotic paint, described antibiotic paint is the mixture of antimicrobial component and coating, and described antimicrobial component is at least one of shitosan, tea tree ethereal oil, nano zine oxide, Nano Silver system antibacterial powder, nano titanium oxide; At described paper layer surface coating antibiotic paint layer.
Wherein, the step arranging antibiotic paint layer on described paper layer surface comprises: apply antibiotic paint layer by the mode spraying or be coated with on described paper layer surface.
The invention has the beneficial effects as follows: the situation being different from prior art, the present invention utilizes natural antibacterial agent such as shitosan, tea tree ethereal oil, nano inorganic antimicrobial agent such as at least one of nano zine oxide, Nano Silver system antibacterial powder, nano titanium oxide and coating to be mixed to get antibiotic paint.Because above-mentioned natural antibacterial agent and nano inorganic antimicrobial agent and coating all have good compatibility, therefore coating can not be made to produce wadding poly-, do not affect the rheological property of coating, the antibiotic paint obtained not only has lastingly and the antibacterial effect of excellence, and can not bring impact to environment.
Accompanying drawing explanation
Fig. 1 is the structural representation of a kind of anti-bacteria paper that the embodiment of the present invention provides;
Fig. 2 is the structural representation of the another kind of anti-bacteria paper that the embodiment of the present invention provides;
Fig. 3 is the flow chart of the preparation method of a kind of anti-bacteria paper that the embodiment of the present invention provides.
Detailed description of the invention
The invention provides a kind of antibiotic paint, this antibiotic paint is the mixture of antimicrobial component and coating, and wherein, antimicrobial component is at least one of shitosan, tea tree ethereal oil, nano zine oxide, Nano Silver system antibacterial powder, nano titanium oxide.
Wherein, the present invention is by large quantity research, carry out preferably to the addition of single antimicrobial component: when antimicrobial component only includes shitosan, the addition of shitosan and the ratio of coating content are greater than 1% (1-4%), when antimicrobial component only includes tea tree ethereal oil, the addition of tea tree ethereal oil and the ratio of coating content are greater than 1% (1-4%), when antimicrobial component only includes nano zine oxide, the addition of nano zine oxide and the ratio of coating content are 0.3-0.8%, when antimicrobial component only includes Nano Silver system antibacterial powder, the addition of Nano Silver system antibacterial powder and the ratio of coating content are 0.05-0.3%, when antimicrobial component only includes nano titanium oxide, the addition of nano titanium oxide and the ratio of coating content are 0.3-0.8%.
Wherein, the nano titanium oxide mentioned in the embodiment of the present invention is 10nm titanium dioxide or 5nm titanium dioxide.
Certainly, in actual application, can by the composite mode of different antimicrobial component to reach antibacterial effect.When different antimicrobial component is composite, the addition of often kind of antimicrobial component suitably can adjust on its basis separately as addition during antimicrobial component.
When carrying out composite, preferably adopt following combination as antimicrobial component: any one composition of shitosan and nano oxidized Zn composition, tea tree ethereal oil and nano oxidized Zn composition, shitosan and tea tree ethereal oil composition, shitosan and tea tree ethereal oil and nano oxidized Zn composition, nano zine oxide and Nano Silver system antibacterial powder composition, nano zine oxide and nano titanium oxide composition, Nano Silver system antibacterial powder and nano titanium oxide composition, nano zine oxide and Nano Silver system antibacterial powder and nano titanium oxide composition.
Wherein, in above compounded combination, the addition of often kind of antimicrobial component preferably adopts following proportioning, and following coating content is for 100 parts:
When using shitosan and nano oxidized Zn composition as antimicrobial component, the addition of shitosan is 0.25 part, and the addition of nano zine oxide is 0.3 part; When using tea tree ethereal oil and nano oxidized Zn composition as antimicrobial component, the addition of tea tree ethereal oil is 0.25 part, and the addition of nano zine oxide is 0.35 part; When using shitosan and tea tree ethereal oil composition as antimicrobial component, the addition of shitosan is 0.75 part, and the addition of tea tree ethereal oil is 0.75 part; When using shitosan and tea tree ethereal oil and nano oxidized Zn composition as antimicrobial component, the addition of shitosan is 0.25 part, and the addition of tea tree ethereal oil is 0.3 part, and the addition of nano zine oxide is 0.25 part; When using nano zine oxide and Nano Silver system antibacterial powder composition as antimicrobial component, the addition of nano zine oxide is 0.2 part, and the addition of Nano Silver system antibacterial powder is 0.05 part; When using nano zine oxide and nano titanium oxide composition as antimicrobial component, the addition of nano zine oxide is 0.2 part, and the addition of nano titanium oxide is 0.3 part; When using nano zine oxide and Nano Silver system antibacterial powder and nano titanium oxide composition as antimicrobial component, the addition of nano zine oxide is 0.25 part, and the addition of Nano Silver system antibacterial powder is 0.05 part, and the addition of nano titanium oxide is 0.2 part.
During the addition of above mentioned nano titanium oxide, all for 10nm titanium dioxide, when using 5nm titanium dioxide, its addition can suitably reduce, because 5nm titanium dioxide antibiotic effect is more excellent relative to the antibacterial effect of 10 nano titanium oxides.When such as above-mentioned nano titanium oxide addition is 0.3 part, 5nm titanium dioxide addition is used only to need about 0.2 part, by that analogy.
The antibiotic paint that above-described embodiment provides, it adopts natural antibacterial agent as shitosan, tea tree ethereal oil, nano inorganic antimicrobial agent is as nano zine oxide, Nano Silver system antibacterial powder, the at least one of nano titanium oxide is as antimicrobial component, wherein, except tea tree ethereal oil, all the other antimicrobial components are all powders, good with the compatibility of coating after adding coating, coating can not be made to produce wadding poly-, do not affect the rheological property of coating, thus medical change production technology can use the coating being added with antimicrobial component, organic antibacterial agent is avoided to make coating wad a quilt with cotton because molecular structure is positively charged poly-, with the drawback that the compatibility of coating is poor.
On the basis of the antibiotic paint provided above, the embodiment of the present invention provides a kind of anti-bacteria paper further, refer to Fig. 1, Fig. 1 is the structural representation of a kind of anti-bacteria paper of the embodiment of the present invention, this anti-bacteria paper comprises paper layer and is coated on the antibiotic paint layer on paper layer surface, wherein, antibiotic paint layer is the mixture layer of antimicrobial component and coating, and antimicrobial component is at least one of shitosan, tea tree ethereal oil, nano zine oxide, Nano Silver system antibacterial powder, nano titanium oxide.
Wherein, in the present embodiment, the composition of antimicrobial component and the addition of antimicrobial component refer to the detailed description of above-described embodiment, do not repeat them here.
Wherein, in the present embodiment, as required, two surfaces of paper layer can all be coated with antibiotic paint layer (as shown in Figure 2).
The anti-bacteria paper of the present embodiment, only needs paper face to apply the antibiotic paint of above-described embodiment, therefore effectively can control the manufacturing cost of this anti-bacteria paper.
The anti-bacteria paper of the embodiment of the present invention; because using above antibiotic paint; and the antimicrobial component that antibiotic paint adopts is all environmentally friendly antiseptics, its antibacterial mechanisms directly destroys bacterial structure by producing active oxygen, can avoid the drug resistance that bacterium produces because of autoprotection mechanism.And use the anti-bacteria paper of this antibiotic paint, be carry out sterilization by antiseptic sustained release activity oxygen instead of by the quantity of effect antiseptic own, thus there is permanent anti-microbial property.And this anti-bacteria paper is all just can produce anti-microbial property under field conditions (factors), does not need through special treatment, as ultra violet lamp etc.
In order to verify the antibacterial effect of embodiment of the present invention anti-bacteria paper, the embodiment of the present invention detects for staphylococcus aureus and colibacillary anti-microbial property the anti-bacteria paper of Different adding amount antimicrobial component, obtain following antibacterial experiment result (be 100 part notes with coating content, addition is the ratio with coating content):
Table 1: the anti-bacteria paper antibacterial experiment result of different antimicrobial component coating
Continued 1: the anti-bacteria paper antibacterial experiment result of different antimicrobial component coating
In addition, the embodiment of the present invention also provides a kind of preparation method of anti-bacteria paper, and the preparation method of the anti-bacteria paper of the present embodiment comprises:
S101: prepare paper;
S102: configuration antibiotic paint, antibiotic paint is the mixture of antimicrobial component and coating, and antimicrobial component is at least one of shitosan, tea tree ethereal oil, nano zine oxide, Nano Silver system antibacterial powder, nano titanium oxide;
Wherein, the concrete composition of the present embodiment antimicrobial component and individual constituent content refer to the detailed description of above-described embodiment, do not repeat them here.
S103: at paper layer surface coating antibiotic paint layer;
Wherein, antibiotic paint layer can be applied by the mode spraying or be coated with on paper layer surface.In actual application, can as required only at a surface coating antibiotic paint layer of paper, or all apply antibiotic paint layer on two of paper relative surfaces.
By the detailed description of above embodiment, be appreciated that the present invention's natural antibacterial agent such as shitosan, tea tree ethereal oil, nano inorganic antimicrobial agent such as at least one of nano zine oxide, Nano Silver system antibacterial powder, nano titanium oxide and coating are mixed to get antibiotic paint.Because above-mentioned natural antibacterial agent and nano inorganic antimicrobial agent and coating all have good compatibility, therefore coating can not be made to produce wadding poly-, do not affect the rheological property of coating, the antibiotic paint obtained not only has lastingly and the antibacterial effect of excellence, and can not bring impact to environment.
Because the antimicrobial component that antibiotic paint of the present invention adopts is all environmentally friendly antiseptics, its antibacterial mechanisms directly destroys bacterial structure by producing active oxygen, can avoid the drug resistance that bacterium produces because of autoprotection mechanism.And use the anti-bacteria paper of this antibiotic paint, be carry out sterilization by antiseptic sustained release activity oxygen instead of by the quantity of effect antiseptic own, thus there is permanent anti-microbial property.And this anti-bacteria paper is all just can produce anti-microbial property under field conditions (factors), does not need through special treatment, as ultra violet lamp etc.
On the other hand, anti-bacteria paper of the present invention, only needs paper painting coating to be antibiotic paint, effectively can control the production cost of this paper.
The foregoing is only embodiments of the present invention; not thereby the scope of the claims of the present invention is limited; every utilize description of the present invention and accompanying drawing content to do equivalent structure or equivalent flow process conversion; or be directly or indirectly used in other relevant technical fields, be all in like manner included in scope of patent protection of the present invention.
Claims (11)
1. an antibiotic paint, is characterized in that, described antibiotic paint is the mixture of antimicrobial component and coating, and described antimicrobial component is at least one of shitosan, tea tree ethereal oil, nano zine oxide, Nano Silver system antibacterial powder, nano titanium oxide.
2. antibiotic paint according to claim 1, is characterized in that, when described antimicrobial component only includes shitosan, the addition of shitosan is greater than 1% with the ratio of described coating content; When described antimicrobial component only includes tea tree ethereal oil, the addition of described tea tree ethereal oil is greater than 1% with the ratio of described coating content; When described antimicrobial component only includes nano zine oxide, the addition of described nano zine oxide is 0.3-0.8% with the ratio of described coating content; When described antimicrobial component only includes Nano Silver system antibacterial powder, the addition of described Nano Silver system antibacterial powder is 0.05-0.3% with the ratio of described coating content; When described antimicrobial component only includes nano titanium oxide, the addition of described nano titanium oxide is 0.3-0.8% with the ratio of described coating content.
3. antibiotic paint according to claim 1, it is characterized in that, described antimicrobial component is any one composition of shitosan and nano oxidized Zn composition, tea tree ethereal oil and nano oxidized Zn composition, shitosan and tea tree ethereal oil composition, shitosan and tea tree ethereal oil and nano oxidized Zn composition, nano zine oxide and Nano Silver system antibacterial powder composition, nano zine oxide and nano titanium oxide composition, Nano Silver system antibacterial powder and nano titanium oxide composition, nano zine oxide and Nano Silver system antibacterial powder and nano titanium oxide composition.
4. the antibiotic paint according to any one of claim 1-3, is characterized in that, described nano titanium oxide is 10nm titanium dioxide or 5nm titanium dioxide.
5. an anti-bacteria paper, it is characterized in that, described anti-bacteria paper comprises paper layer and is coated on the antibiotic paint layer on described paper layer surface, described antibiotic paint layer is the mixture layer of antimicrobial component and coating, and described antimicrobial component is at least one of shitosan, tea tree ethereal oil, nano zine oxide, Nano Silver system antibacterial powder, nano titanium oxide.
6. anti-bacteria paper according to claim 5, is characterized in that, when described antimicrobial component only includes shitosan, the addition of shitosan is greater than 1% with the ratio of described coating content; When described antimicrobial component only includes tea tree ethereal oil, the addition of described tea tree ethereal oil is greater than 1% with the ratio of described coating content; When described antimicrobial component only includes nano zine oxide, the addition of described nano zine oxide is 0.3-0.8% with the ratio of described coating content; When described antimicrobial component only includes Nano Silver system antibacterial powder, the addition of described Nano Silver system antibacterial powder is 0.05-0.3% with the ratio of described coating content; When described antimicrobial component only includes nano titanium oxide, the addition of described nano titanium oxide is 0.3-0.8% with the ratio of described coating content.
7. anti-bacteria paper according to claim 5, it is characterized in that, described antimicrobial component is any one composition of shitosan and nano oxidized Zn composition, tea tree ethereal oil and nano oxidized Zn composition, shitosan and tea tree ethereal oil composition, shitosan and tea tree ethereal oil and nano oxidized Zn composition, nano zine oxide and Nano Silver system antibacterial powder composition, nano zine oxide and nano titanium oxide composition, Nano Silver system antibacterial powder and nano titanium oxide composition, nano zine oxide and Nano Silver system antibacterial powder and nano titanium oxide composition.
8. the anti-bacteria paper according to any one of claim 5-7, is characterized in that, described nano titanium oxide is 10nm titanium dioxide or 5nm titanium dioxide.
9. the anti-bacteria paper according to any one of claim 5-7, is characterized in that, two surfaces of described paper layer are all coated with described antibiotic paint layer.
10. a preparation method for anti-bacteria paper, is characterized in that, described method comprises:
Prepare paper;
Configuration antibiotic paint, described antibiotic paint is the mixture of antimicrobial component and coating, and described antimicrobial component is at least one of shitosan, tea tree ethereal oil, nano zine oxide, Nano Silver system antibacterial powder, nano titanium oxide;
At described paper layer surface coating antibiotic paint layer.
11. preparation methods according to claim 10, is characterized in that, comprise in the step of described paper layer surface coating antibiotic paint layer:
Antibiotic paint layer is applied on described paper layer surface by the mode spraying or be coated with.
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| CN201410193370.1A CN105088864A (en) | 2014-05-07 | 2014-05-07 | Antibacterial paint, antibacterial paper, preparation method of antibacterial paint, and preparation method of antibacterial paper |
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| CN106245424A (en) * | 2016-08-29 | 2016-12-21 | 赵哲 | A kind of preparation method of anti-bacteria paper |
| CN107162542A (en) * | 2017-06-09 | 2017-09-15 | 郭发亮 | A kind of natural paint formula |
| CN107641352A (en) * | 2017-10-27 | 2018-01-30 | 桂林市漓江机电制造有限公司 | A kind of UV antibiotic paints of color inhibition |
| CN107641456A (en) * | 2017-10-27 | 2018-01-30 | 桂林市漓江机电制造有限公司 | A kind of antibiotic paint for efficiently removing formaldehyde and preparation method thereof |
| CN107964320A (en) * | 2017-08-16 | 2018-04-27 | 合肥卓立雅工程材料科技有限公司 | A kind of metro shield section of jurisdiction high-efficiency environment friendly anti-corrosive and waterproof paint and preparation method thereof |
| CN108716165A (en) * | 2018-06-20 | 2018-10-30 | 广州市宝绅纸塑有限公司 | A kind of wrapping paper high-effect anti-mould antiseptic and the preparation method and application thereof |
| CN109464055A (en) * | 2018-11-27 | 2019-03-15 | 旌德县万方日用品有限公司 | A kind of preparation method of moisturizing soft antibacterial paper handkerchief and the paper handkerchief of preparation |
| CN109662531A (en) * | 2019-01-26 | 2019-04-23 | 夏仙龙 | A kind of sandwich type summer sleeping mat based on summer sleeping mat dedicated paper |
| CN109927353A (en) * | 2019-03-01 | 2019-06-25 | 华亚工业塑胶（太仓）有限公司 | High anti-microbial property chliorinated polyvinyl chloride industry pipe, production technology and installation method |
| CN111270553A (en) * | 2020-03-31 | 2020-06-12 | 常德集智生物科技有限公司 | Broad-spectrum antiviral bactericidal paper and application |
| CN111472199A (en) * | 2020-03-31 | 2020-07-31 | 常德集智生物科技有限公司 | Currency broad-spectrum antiviral and bactericidal nano material and preparation method and use method thereof |
| CN111660391A (en) * | 2020-06-17 | 2020-09-15 | 深圳市绿泰环保科技有限公司 | Preparation method of wood mildew preventive |
| WO2023075736A1 (en) * | 2021-10-27 | 2023-05-04 | Atatürk Üni̇versi̇tesi̇ Rektörlüğü | An antibacterial masterbatch |
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Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106245424A (en) * | 2016-08-29 | 2016-12-21 | 赵哲 | A kind of preparation method of anti-bacteria paper |
| CN106245424B (en) * | 2016-08-29 | 2018-01-09 | 赵哲 | A kind of preparation method of anti-bacteria paper |
| CN107162542A (en) * | 2017-06-09 | 2017-09-15 | 郭发亮 | A kind of natural paint formula |
| CN107964320A (en) * | 2017-08-16 | 2018-04-27 | 合肥卓立雅工程材料科技有限公司 | A kind of metro shield section of jurisdiction high-efficiency environment friendly anti-corrosive and waterproof paint and preparation method thereof |
| CN107641352A (en) * | 2017-10-27 | 2018-01-30 | 桂林市漓江机电制造有限公司 | A kind of UV antibiotic paints of color inhibition |
| CN107641456A (en) * | 2017-10-27 | 2018-01-30 | 桂林市漓江机电制造有限公司 | A kind of antibiotic paint for efficiently removing formaldehyde and preparation method thereof |
| CN108716165A (en) * | 2018-06-20 | 2018-10-30 | 广州市宝绅纸塑有限公司 | A kind of wrapping paper high-effect anti-mould antiseptic and the preparation method and application thereof |
| CN109464055A (en) * | 2018-11-27 | 2019-03-15 | 旌德县万方日用品有限公司 | A kind of preparation method of moisturizing soft antibacterial paper handkerchief and the paper handkerchief of preparation |
| CN109662531A (en) * | 2019-01-26 | 2019-04-23 | 夏仙龙 | A kind of sandwich type summer sleeping mat based on summer sleeping mat dedicated paper |
| CN109927353A (en) * | 2019-03-01 | 2019-06-25 | 华亚工业塑胶（太仓）有限公司 | High anti-microbial property chliorinated polyvinyl chloride industry pipe, production technology and installation method |
| CN111270553A (en) * | 2020-03-31 | 2020-06-12 | 常德集智生物科技有限公司 | Broad-spectrum antiviral bactericidal paper and application |
| CN111472199A (en) * | 2020-03-31 | 2020-07-31 | 常德集智生物科技有限公司 | Currency broad-spectrum antiviral and bactericidal nano material and preparation method and use method thereof |
| CN111660391A (en) * | 2020-06-17 | 2020-09-15 | 深圳市绿泰环保科技有限公司 | Preparation method of wood mildew preventive |
| WO2023075736A1 (en) * | 2021-10-27 | 2023-05-04 | Atatürk Üni̇versi̇tesi̇ Rektörlüğü | An antibacterial masterbatch |
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Application publication date: 20151125 |