CN109440278B - Weaving method of nano antibacterial cool fiber knitted fabric, nano antibacterial cool fiber knitted fabric woven by method and application - Google Patents
Weaving method of nano antibacterial cool fiber knitted fabric, nano antibacterial cool fiber knitted fabric woven by method and application Download PDFInfo
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- CN109440278B CN109440278B CN201811591228.7A CN201811591228A CN109440278B CN 109440278 B CN109440278 B CN 109440278B CN 201811591228 A CN201811591228 A CN 201811591228A CN 109440278 B CN109440278 B CN 109440278B
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- 238000009941 weaving Methods 0.000 title claims abstract description 22
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Classifications
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B1/10—Patterned fabrics or articles
- D04B1/102—Patterned fabrics or articles with stitch pattern
- D04B1/104—Openwork fabric, e.g. pelerine fabrics
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B1/14—Other fabrics or articles characterised primarily by the use of particular thread materials
- D04B1/16—Other fabrics or articles characterised primarily by the use of particular thread materials synthetic threads
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B1/14—Other fabrics or articles characterised primarily by the use of particular thread materials
- D04B1/18—Other fabrics or articles characterised primarily by the use of particular thread materials elastic threads
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
- D10B2201/20—Cellulose-derived artificial fibres
- D10B2201/22—Cellulose-derived artificial fibres made from cellulose solutions
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/10—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyurethanes
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/06—Load-responsive characteristics
- D10B2401/061—Load-responsive characteristics elastic
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/13—Physical properties anti-allergenic or anti-bacterial
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Knitting Of Fabric (AREA)
- Woven Fabrics (AREA)
Abstract
The invention discloses a weaving method of a novel nano antibacterial cool fiber knitted fabric, the nano antibacterial cool fiber knitted fabric woven by the method and application, and the weaving method of the novel nano antibacterial cool fiber knitted fabric comprises the steps of weaving antibacterial cool modified mica polyester filaments, modal/polyester blended yarn and spandex filaments in mesh and plain weave; the mesh tissue is woven by antibacterial cool modified mica polyester filaments and spandex filaments, the plain weave is woven by Modal/polyester blended yarns and spandex filaments, and the two tissues are woven into a variable mesh jacquard weave. The nano antibacterial cool fiber knitted fabric prepared by the method has the advantages of excellent fabric effect, smooth hand feeling, gorgeous color and luster, capability of inhibiting bacteria and wide application prospect.
Description
Technical Field
The invention belongs to the technical field of textile products, and particularly relates to a novel weaving method of nano antibacterial and cool fiber knitted fabric, the nano antibacterial and cool fiber knitted fabric woven by the method and application.
Background
With the improvement of the living standard of substances, the requirements of people on living necessities are continuously improved. Meanwhile, the requirements on the textile are not simple, comfortable and beautiful; but the textile clothing is required to be more fashionable, environment-friendly and diversified in performance. Along with the age that the 21 st century we advocate low carbon and environmental protection, the textile industry also strives to reform and innovate; on the basis of the original textile industry, the innovation of the product is focused, and the development is made to the aspects of more multifunction, low cost and green environmental protection.
Nowadays, products which have health concepts, meet environmental protection requirements and market fashion trends in the textile field are always the favourites of consumers, and cool mineral yarns are generated in the concept, so that the functions of moisture absorption, sweat release and cool feel are required by the current market. Meanwhile, various functional composites are also a trend in the development of new textile materials.
Mica is a widely-distributed rock-making mineral, and has various good characteristics of elasticity, toughness, insulativity, high temperature resistance, acid and alkali resistance, corrosion resistance, strong adhesive force, strong hydration, high refraction brightness and the like. At present, the material is mainly applied to building materials, plastics, papermaking, welding materials, electric insulation and the like at home and abroad. The polyester carrier added with mica has the fiber section subjected to special-shaped treatment, and more capillary channels are arranged among the fibers, so that the fiber is a new generation of cooling and heat dissipation fiber material and has the effects of natural cooling, moisture absorption and quick drying.
The development and application of the mica fiber serving as a novel fiber in the domestic and foreign markets are just started, and particularly the production and application in the textile field are not developed on a large scale, the developed mica fiber is small in variety and limited in quantity, and most of the mica fibers are in the experimental stage of trial spinning and trial production of the mica fiber, and mica is firstly applied to composite materials for paints, inks, cosmetics and building site safety nets by Dupont and Japanese company in the United states. In recent years, the national Yueyang petrochemical industry general institute, the south China university, the university of Wuhan and the university of Wuhan engineering and other institutions research the use of mica and fiber combination as the enhancement of the system strength of objects. The research and development application of the mica fiber as a novel fiber in the textile field is just started, for example, the mica nylon cool fiber filaments are invented by Taiwan, jiangsu, shanghai and other scientific and technological companies, and the mica fiber is developed; the yarn for knitting of combed cotton/mica fiber is developed by manufacturers, but is not successfully applied to the industrial production of final products in the textile field.
The mica fiber can be blended with cotton, wool, silk, hemp and chemical fiber short fibers, can be spun purely, has the characteristics of health care, antibiosis and cooling, has good dyeing property and wear resistance, can be used for manufacturing various textile products such as underwear, body shaping clothes, socks, bedclothes, automobile cushions and the like, meets the multidirectional requirement that people integrate functions such as comfort, leisure, health care and the like on the textile, further enriches the varieties of textile materials in China, and has good development prospect.
The mechanism of the antibacterial cooling modified mica yarn is that zinc particles and mica sheets with moisture absorption and heat conduction are added in the spinning process by a nano technology, two different carriers of terylene and chinlon have been developed, the excellent heat conductivity of mica is utilized to exert cooling function, the antibacterial function of the nano zinc particles and an electrostatic shell layer at the outer layer are utilized to generate a positive electric field, and the metabolism of bacteria can be effectively inhibited or stopped, so that the antibacterial cooling double-effect is achieved.
Therefore, how to reasonably match the antibacterial and cooling modified mica polyester filaments with other fibers, and a novel and reasonable fabric structure is adopted to research and perfect a mature weaving process, so that the advantages of different fibers are complementary, the organic combination of antibacterial and cooling is achieved, and the taking requirement of low carbon and environmental protection is met. This is a technical problem to be solved at present.
Disclosure of Invention
Aiming at the problems and the defects existing in the prior art, the invention aims to provide a novel nano antibacterial and cool fiber knitted fabric, a weaving method of the novel nano antibacterial and cool fiber knitted fabric and application thereof, antibacterial and cool modified mica polyester filaments and Modal/polyester blended yarn are adopted for interweaving, and spandex filaments are added to increase the elasticity of the fabric, so that the knitted fabric can fully exert various special effects of the novel nano antibacterial and cool polyester filaments through the selection of raw materials and reasonable tissue structure and weaving process route, and the advantages of various components are complemented, so that the functional and comfort properties are far superior to those of common knitwear.
In order to achieve the above purpose, the technical scheme of the invention is as follows:
a novel weaving method of nano antibacterial cool fiber knitted fabric weaves antibacterial cool modified mica polyester filament yarn, modal/polyester blended yarn and spandex yarn in mesh and plain weave.
Based on the scheme, the mesh tissue is woven by antibacterial and cool modified mica polyester filaments and spandex filaments, the plain weave is woven by Modal/polyester blended yarns and spandex filaments, and the two tissues are woven into a variable mesh jacquard weave.
Based on the scheme, the antibacterial and cooling modified mica polyester filament yarn is 75D/72F antibacterial and cooling modified mica polyester filament yarn, the Modal/polyester blended yarn is 11.8tex Modal/polyester blended yarn, and the spandex filament yarn is 30D spandex filament yarn.
Based on the scheme, the weaving method of the novel nano antibacterial cool fiber knitted fabric comprises the following steps of:
weaving by using a DF-CS four-needle-way single-sided circular knitting machine, and threading the yarns: the 1 st, 2 nd, 7 th, 8 th, 13 th and 14 th paths penetrate into 11.8tex Modal/terylene blended yarn, and the yarn feeding length is 240+/-2 mm/100 needles; 3 rd, 4 th, 5 th, 6 th, 9 th, 10 th, 11 th, 12 th, 15 th, 16 th, 17 th, 18 th, 75 th, 72 th and fourth antibacterial cool polyester filaments are penetrated into the yarn, and the yarn feeding length is 240+/-2 mm/100 needles; and in the 1 st to 18 th paths, 30D spandex filaments are added, and the yarn feeding length is 100+/-2 mm/100 needles.
Based on the scheme, the fabric woven by the method comprises the following steps of: yarn tension 5.0-6.9 cN; gram weight of blank: 160g/m 2, density: transverse density 41 wales/25.4 mm, longitudinal density 68 courses/25.4 mm, lower machine breadth: (75 cm. Times.2). + -.5 cm.
The novel nano antibacterial cool fiber knitted fabric is woven by the method.
On the basis of the scheme, the novel nano antibacterial cool fiber knitted fabric is continuously composed of a plurality of units, and each unit comprises 18 wefts; wherein,
The 1 st, 2 nd, 7 th, 8 th, 13 th and 14 th weft materials are 11.8tex Modal/terylene blended yarn and 30D spandex filaments; the 11.8tex Modal/terylene blended yarn and the 30D spandex filament are woven into a Modal/terylene blended yarn floating point; the whole weft routes of the 1 st weft route, the 2 nd weft route, the 7 th weft route, the 8 th weft route, the 13 th weft route and the 14 th weft route are composed of the modal/terylene mixed yarn floating points;
the 3 rd, 4 th, 5 th, 6 th, 9 th, 10 th, 11 th, 12 th, 15 th, 16 th, 17 th and 18 th weft materials are selected from 75D/72F antibacterial and cooling modified mica polyester filaments and 30D spandex filaments;
Each interval 7 paths on the 3 rd to 6 th weft paths are respectively provided with a bacteriostatic cooling modified mica polyester filament loop floating point, and the bacteriostatic cooling modified mica polyester filament loop floating point is woven by 75D/72F bacteriostatic cooling modified mica polyester filaments and 30D spandex filaments; the rest positions are all loop floating points of the antibacterial cool modified mica polyester filament yarn;
Each of the 3 paths on the 9 th to 12 th weft paths is provided with a bacteriostatic and cool modified mica polyester filament tuck floating point, and a path is arranged between the path on which the bacteriostatic and cool modified mica polyester filament tuck floating point on the 9 th to 12 th weft paths and the path on which the bacteriostatic and cool modified mica polyester filament tuck floating point on the 3 rd to 6 th weft paths closest to the path; the rest positions are all loop floating points of the antibacterial cool modified mica polyester filament yarn;
Each interval 7 paths on the 15 th to 18 th weft paths are respectively provided with a bacteriostatic cool modified mica polyester filament tuck floating point; one warp path is arranged between the warp path of the floating point of the bacteriostatic and cool modified mica polyester filament yarn collection circle on the 15 th-18 th weft and the warp path of the floating point of the bacteriostatic and cool modified mica polyester filament yarn collection circle on the 9 th-12 th weft which is nearest to the warp path, and the rest positions form the floating point of the bacteriostatic and cool modified mica polyester filament yarn collection circle.
Compared with the prior art, the invention has the following advantages and positive effects:
Through the selection of raw materials, reasonable tissue structure and weaving process route, the antibacterial and cool modified mica polyester filament yarn and Modal/polyester blended yarn and spandex yarn interweaved knitted fabric is adopted, so that the fabric has excellent effect, smooth hand feeling, gorgeous color and luster, antibacterial effect and wide application prospect.
1. The invention relates to a bacteriostatic cool modified mica yarn, which is characterized in that zinc particles and mica sheets with moisture absorption and heat conduction are added in the spinning process by a nano technology, two different carriers of terylene and chinlon are developed, the excellent heat conductivity of mica is utilized to exert a cool function, and the bacteriostatic function of nano zinc particles and an electrostatic shell layer on the outer layer are utilized to generate a positive electric field, so that the metabolism of bacteria can be effectively inhibited or stopped, and the bacteriostatic and cool double effects are achieved.
2. The knitted fabric adopts the novel nano antibacterial and cool modified mica polyester filament yarn and the Modal/polyester blended yarn for interweaving, and simultaneously the spandex filament yarn is added to increase the elasticity of the fabric, so that the knitted fabric can fully exert various special effects of the novel antibacterial and cool modified mica polyester filament yarn through the selection of raw materials, reasonable tissue structure and weaving process route, and the advantages of various components are complementary, and the functionality and the comfort are far superior to those of common knitted fabrics.
3. The mesh weave and the plain weave are woven, the mesh weave adopts antibacterial cool modified mica polyester filaments and spandex filaments for weaving, the plain weave adopts Modal/polyester blended yarns and spandex filaments for weaving, and the two kinds of weave form a variable mesh jacquard weave. In the mesh structure, holes are formed at the tuck-stitch part, so that the mica fibers are finally presented on the fabric and have peak-valley effect, and therefore, excellent heat conduction and water absorption effects of the mica fibers are better exerted, and the plain weave structure uses the Modal/terylene blended yarn, so that the fabric finally presents a horizontal effect, and the three-dimensional sense and visual aesthetic feeling of the fabric are improved.
4. The novel nano antibacterial cool fiber knitted fabric has excellent contact cool feeling effect, has obvious instant cool feeling, and has excellent moisture absorption and quick drying performance; the addition of zinc particles endows the fabric with excellent antibacterial effect, and the antibacterial rate of staphylococcus aureus, escherichia coli and candida albicans reaches the AAA grade, so that the human health can be effectively maintained.
The functional indexes of the knitted fabric of the invention exceed the current product level, so the knitted fabric of the invention fills up the market blank, widens the application range of novel fibers, endows the textile with cooling comfort and bacteriostasis, integrates multiple functions, improves the added value of the textile, and meets the requirements of the current society on the comfort and the functionality of the textile.
Drawings
FIG. 1 is a needle arrangement;
Fig. 2 is a jacquard schematic diagram of the surface of the fabric (note: "×" represents the circle floating point of the antibacterial and cooling modified mica polyester filament yarn set, space represents the circle floating point of the antibacterial and cooling modified mica polyester filament yarn set, and "/" represents the modal/polyester blended yarn floating point);
figure 3 surface jacquard weave a unit diagram (note: "×" indicates circle floating point of antibacterial and cooling modified mica polyester filament yarn, space indicates circle floating point of antibacterial and cooling modified mica polyester filament yarn, and "/" indicates modal/polyester blended yarn floating point);
FIG. 4 is a triangle arrangement diagram (note: "Λ" -looping triangle, -Tucking triangle).
Detailed Description
The terms used in the present invention generally have meanings commonly understood by those of ordinary skill in the art unless otherwise indicated.
The invention will be described in further detail below in connection with specific embodiments and with reference to the data. The following examples are intended to illustrate the invention and are not intended to limit the scope of the invention in any way.
Referring to fig. 1-4, the novel nano antibacterial cool fiber knitted fabric is woven by adopting a mesh weave and a plain weave, wherein the mesh weave is woven by adopting antibacterial cool modified mica polyester filaments and spandex filaments, the plain weave is woven by using a modal/polyester blended yarn and the spandex filaments, and the two weaves are woven into a variable mesh jacquard weave. In the mesh structure, holes are formed at the tuck-stitch part, so that the mica fibers are finally presented on the fabric and have peak-valley effect, and therefore, excellent heat conduction and water absorption effects of the mica fibers are better exerted, and the plain weave structure uses the Modal/terylene blended yarn, so that the fabric finally presents a horizontal effect, and the three-dimensional sense and visual aesthetic feeling of the fabric are improved.
The novel nano bacteriostatic cool fiber knitted fabric of the invention is formed by a plurality of units continuously (as shown in figure 2), wherein each unit comprises 18 wefts (figure 3, which takes the transverse direction as a dimension path and the longitudinal direction as a path, the warps and wefts are only used for illustrating jacquard patterns of the fabric of the invention, and the technical scheme of the invention is not limited in any way), wherein,
The 1 st, 2 nd, 7 th, 8 th, 13 th and 14 th weft materials are 11.8tex Modal/terylene blended yarn and 30D spandex filaments; the 11.8tex Modal/terylene blended yarn and the 30D spandex filament are woven into a Modal/terylene blended yarn floating point; the whole weft routes of the 1 st weft route, the 2 nd weft route, the 7 th weft route, the 8 th weft route, the 13 th weft route and the 14 th weft route are composed of the modal/terylene mixed yarn floating points;
the 3 rd, 4 th, 5 th, 6 th, 9 th, 10 th, 11 th, 12 th, 15 th, 16 th, 17 th and 18 th weft materials are selected from 75D/72F antibacterial and cooling modified mica polyester filaments and 30D spandex filaments;
Each interval 7 paths on the 3 rd to 6 th weft paths are respectively provided with a bacteriostatic cooling modified mica polyester filament loop floating point, and the bacteriostatic cooling modified mica polyester filament loop floating point is woven by 75D/72F bacteriostatic cooling modified mica polyester filaments and 30D spandex filaments; the rest positions are all loop floating points of the antibacterial cool modified mica polyester filament yarn;
Each of the 3 paths on the 9 th to 12 th weft paths is provided with a bacteriostatic and cool modified mica polyester filament tuck floating point, and a path is arranged between the path on which the bacteriostatic and cool modified mica polyester filament tuck floating point on the 9 th to 12 th weft paths and the path on which the bacteriostatic and cool modified mica polyester filament tuck floating point on the 3 rd to 6 th weft paths closest to the path; the rest positions are all loop floating points of the antibacterial cool modified mica polyester filament yarn;
Each interval 7 paths on the 15 th to 18 th weft paths are respectively provided with a bacteriostatic cool modified mica polyester filament tuck floating point; one warp path is arranged between the warp path of the floating point of the bacteriostatic and cool modified mica polyester filament yarn collection circle on the 15 th-18 th weft and the warp path of the floating point of the bacteriostatic and cool modified mica polyester filament yarn collection circle on the 9 th-12 th weft which is nearest to the warp path, and the rest positions form the floating point of the bacteriostatic and cool modified mica polyester filament yarn collection circle.
The specific weaving process is as follows:
The first and the second devices are selected
Selection of machine types: DF-CS four-needle-way single-sided large circle machine
Number of machine: 28 needle/25.4 mm
Cylinder diameter: 762mm (30 inch)
Number of needles: 2640 pieces
Total number of routes: 90F
(II) weaving process
1. Knitting needle arrangement: see fig. 1.
2. The pattern design is shown in fig. 2 and 3.
(1) The triangle arrangement is shown in fig. 4.
(2) Threading mode:
the 1 st, 2 nd, 7 th, 8 th, 13 th and 14 th paths are penetrated into 11.8tex Modal/terylene blended yarn and 30D spandex yarn;
The 3 rd, 4 th, 5 th, 6 th, 9 th, 10 th, 11 th, 12 th, 15 th, 16 th, 17 th and 18 th paths penetrate into 75D/72F antibacterial and cooling modified mica polyester filaments and +30D spandex filaments;
(3) The incoming length of the knitted fabric is as follows:
240+ -2 mm/100 needles on paths 1,2, 7, 8, 13 and 14;
3 rd, 4 th, 5 th, 6 th, 9 th, 10 th, 11 th, 12 th, 15 th, 16 th, 17 th, 18 th, 240 th + -2 mm/100 th needles;
1 st to 18 th paths, and 100+/-2 mm/100 needles of spandex.
4 Process parameters
Through multiple tests, the optimization and proper adjustment are carried out within the following ranges according to the raw material proportion, the yarn linear density and the specification and the application of the fabric:
(1) Yarn tension 5.0-6.9cN (common yarn 4-5.5 cN); if the flower shape is complex, about 6.05cN is preferable.
(2) Gram weight of blank: 160g/m 2.
(3) Transverse density 41 columns/25.4 mm, longitudinal density 68 columns/25.4 mm.
(4) Width of machine: (75 cm. Times.2). + -.5 cm.
(III) knitting gist
(1) The needle arrangement and triangle change are strictly carried out according to the technological requirements, so that the fabric is prevented from being misplaced.
(2) The tension of each path of yarns is regulated, so that holes in the material cloth are prevented.
(3) The arrangement of the yarns is separated, and the wrong yarns are prevented.
The detection result shows that the main technical indexes of the novel nano antibacterial cool fiber knitted fabric not only meet the requirements of B-class (direct contact skin-class) products in GB18401-2010 national basic textile product safety technical specification, but also reach the technical requirements of related indexes of high-class products of FZ/T73024-2014 chemical fiber knitted underwear and FZ/T73022-2012 knitted thermal underwear, and the novel nano antibacterial cool fiber knitted fabric has the effects of good color fastness, fuzzing resistance, air permeability and the like. The effect comparison is shown in the following table:
Table 1 comparison of moisture absorption and quick drying effects
As can be seen from the results in Table 1, the antibacterial cool fiber fabric has shorter dripping diffusion time and faster evaporation rate than the special-shaped moisture-absorption quick-drying fiber fabric, and has excellent moisture-absorption quick-drying performance.
The antibacterial performance of the fabric disclosed by the invention is tested, and the antibacterial performance is tested according to FZ/T73023-2012 antibacterial knitwear by reference standards, and the result is as follows:
Table 2 antibacterial property index test
The results in Table 2 show that the fabric provided by the invention has excellent antibacterial effect due to the addition of zinc particles, and the antibacterial rate of staphylococcus aureus, escherichia coli and candida albicans reaches the AAA grade, so that the health of a human body can be effectively maintained.
The fabric and the coumart cool yarn are compared and analyzed, a KES-F7 precise instant thermophysical property tester is adopted for testing, the fabric is placed on a cold plate of the tester, when the temperature of the fabric is the same as that of the cold plate, a hot plate is rapidly placed on a sample, the heat of the hot plate can be transmitted to the cold plate through the fabric, the maximum heat loss of the fabric can be measured at the instant of contact, namely, the Qmax value is represented by the instant cool heat flow (W/cm < 2 >) of the fabric, the Q-max value is the maximum value of the instant heat loss of the skin when a human body is simulated to contact the fabric, and is also the maximum heat flow instantly taken away by the unit area of the fabric, the value is an index of the instant cool property of the fabric, the larger the Q-max value represents more heat can be taken away, and the test result is as follows:
table 3 cool feeling index test
As can be seen from the results in Table 3, the fabric of the invention has excellent contact cold effect (standard requirement (W/cm < 2 >) which is not less than 0.14, is superior to the Kusima cold fiber, has obvious instant cold feel, and is suitable for developing spring and summer products.
The ultraviolet-proof property of the fabric is tested, and the fabric is tested according to the standard GB/T18830-2009 "evaluation of ultraviolet-proof property of textiles", and the test result is as follows:
Table 4 uv resistance test
Sequence number | Checking item names | Unit (B) | Technical requirements | Test results |
1 | UPF ultraviolet protection coefficient | / | / | >50 |
2 | UVA average transmittance | % | / | 3.4 |
3 | UVB average transmittance | % | / | 0.8 |
From the results in table 4, it can be seen that the novel nano antibacterial cool fiber knitted fabric UPF of the invention belongs to 50+, and the UVA is less than 5%, which can be identified as an 'anti-ultraviolet product', and has excellent anti-ultraviolet performance.
The above description is only a preferred embodiment of the present invention, and is not intended to limit the invention in any way, and any person skilled in the art may make modifications or alterations to the disclosed technical content to the equivalent embodiments. However, any simple modification, equivalent variation and variation of the above embodiments according to the technical substance of the present invention still fall within the protection scope of the technical solution of the present invention.
Claims (2)
1. A novel weaving method of nano antibacterial cool fiber knitted fabric is characterized in that: weaving antibacterial and cool modified mica polyester filaments, modal/polyester blended yarns and spandex filaments in a mesh weave and a plain weave;
The antibacterial cool modified mica polyester filament yarn is prepared by adding zinc particles and mica sheets with moisture absorption and heat conduction in the spinning process by a nano technology;
The mesh tissue is woven by antibacterial cool modified mica polyester filaments and spandex filaments, the plain weave is woven by Modal/polyester blended yarns and spandex filaments, and the two tissues are woven into a variable mesh jacquard weave;
the antibacterial and cooling modified mica polyester filament yarn is 75D/72F antibacterial and cooling modified mica polyester filament yarn, the Modal/polyester blended yarn is 11.8tex Modal/polyester blended yarn, and the spandex filament yarn is 30D spandex filament yarn;
the weaving method of the novel nano antibacterial cool fiber knitted fabric comprises the following steps:
Weaving by using a DF-CS four-needle-way single-sided circular knitting machine, and threading the yarns: the 1 st, 2 nd, 7 th, 8 th, 13 th and 14 th paths penetrate into 11.8tex Modal/terylene blended yarn, and the yarn feeding length is 240+/-2 mm/100 needles; the 3 rd, 4 th, 5 th, 6 th, 9 th, 10 th, 11 th, 12 th, 15 th, 16 th, 17 th and 18 th paths penetrate into 75D/72F antibacterial and cooling modified mica polyester filaments, and the yarn feeding length is 240+/-2 mm/100 needles; the 1 st to 18 th paths, adding 30D spandex filaments, wherein the yarn feeding length is 100+/-2 mm/100 needles;
The fabric woven by the method comprises the following steps: yarn tension 5.0-6.9 cN; gram weight of blank: 160g/m 2, density: transverse density 41 wales/25.4 mm, longitudinal density 68 courses/25.4 mm, lower machine breadth: (75 cm. Times.2). + -.5 cm;
The novel nano antibacterial cool fiber knitted fabric is formed by a plurality of units continuously, and each unit comprises 18 wefts; wherein,
The 1 st, 2 nd, 7 th, 8 th, 13 th and 14 th weft materials are 11.8tex Modal/terylene blended yarn and 30D spandex filaments; the 11.8tex Modal/terylene blended yarn and the 30D spandex filament are woven into a Modal/terylene blended yarn floating point; the whole weft routes of the 1 st weft route, the 2 nd weft route, the 7 th weft route, the 8 th weft route, the 13 th weft route and the 14 th weft route are composed of the modal/terylene mixed yarn floating points;
the 3 rd, 4 th, 5 th, 6 th, 9 th, 10 th, 11 th, 12 th, 15 th, 16 th, 17 th and 18 th weft materials are selected from 75D/72F antibacterial and cooling modified mica polyester filaments and 30D spandex filaments;
Each of the 3 rd to 6 th weft paths is provided with 7 warp paths at intervals, each warp path is provided with a bacteriostatic cooling modified mica polyester filament loop floating point, and the bacteriostatic cooling modified mica polyester filament loop floating point is woven by 75D/72F bacteriostatic cooling modified mica polyester filaments and 30D spandex filaments; the rest positions are all loop floating points of the antibacterial cool modified mica polyester filament yarn;
Each 9 th to 12 th weft paths are respectively provided with a bacteriostatic and cool modified mica polyester filament loop floating point at intervals of 3 paths, and a path is arranged between the path where the bacteriostatic and cool modified mica polyester filament loop floating point is positioned on the 9 th to 12 th weft paths and the path where the bacteriostatic and cool modified mica polyester filament loop floating point is positioned on the 3 rd to 6 th weft paths closest to the path; the rest positions are all loop floating points of the antibacterial cool modified mica polyester filament yarn;
Each of the 15 th to 18 th weft paths is provided with 7 warp paths at intervals, and each warp path is provided with a bacteriostatic cool modified mica polyester filament loop-collecting floating point; one warp path is arranged between the warp path of the bacteriostatic and cool modified mica polyester filament loop floating point on the 15 th-18 th weft and the warp path of the bacteriostatic and cool modified mica polyester filament loop floating point on the 9 th-12 th weft which is nearest to the warp path, and the rest positions form the bacteriostatic and cool modified mica polyester filament loop floating point.
2. A novel nano antibacterial cool fiber knitted fabric is characterized in that: woven by the method of claim 1.
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---|---|---|---|---|
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Citations (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101613907A (en) * | 2008-06-25 | 2009-12-30 | 福建凤竹纺织科技股份有限公司 | Ice-cold fiber knitted fabric and manufacture method thereof |
CN102031581A (en) * | 2009-09-25 | 2011-04-27 | 上海德福伦化纤有限公司 | Method for producing super-refreshing cool-feel health care polyester fiber |
CN102433674A (en) * | 2011-10-26 | 2012-05-02 | 青岛雪达集团有限公司 | Mica fiber comfortable ecological knitted fabric and knitting method thereof |
CN102517773A (en) * | 2005-04-18 | 2012-06-27 | 郡是株式会社 | Fiber highly cool to touch |
CN103173916A (en) * | 2013-03-08 | 2013-06-26 | 高密市富源印染有限公司 | Blending silky single jersey cloth of polyester fiber and modal fiber and preparation method thereof |
CN103194847A (en) * | 2013-03-19 | 2013-07-10 | 上海嘉乐股份有限公司 | Antibacterial, moisture-absorbent and warming knitted fabric and manufacturing method thereof |
JP2014189937A (en) * | 2013-03-28 | 2014-10-06 | Unitika Trading Co Ltd | Functional fiber |
JP2015094034A (en) * | 2013-11-08 | 2015-05-18 | ユニチカトレーディング株式会社 | Heat-retaining cloth |
CN104878517A (en) * | 2015-06-18 | 2015-09-02 | 青岛雪达集团有限公司 | Cool fibrous comfortable ecological knitted fabric and knitting method thereof |
CN106192179A (en) * | 2016-08-26 | 2016-12-07 | 青岛雪达集团有限公司 | A kind of vinegar green grass or young crops fiber functional knitting fabric and method for weaving |
CN107287746A (en) * | 2017-08-24 | 2017-10-24 | 宁波大千纺织品有限公司 | A kind of close comfortable well-pressed type knitted side preparation method for material |
CN107841820A (en) * | 2017-11-06 | 2018-03-27 | 福建凤竹纺织科技股份有限公司 | A kind of production technology of ice coffee fiber knitted fabric |
CN108277570A (en) * | 2018-02-12 | 2018-07-13 | 武汉汉麻生物科技有限公司 | A kind of functionally graded layer looped fabric and preparation method thereof |
CN209397348U (en) * | 2018-12-25 | 2019-09-17 | 青岛雪达集团有限公司 | A kind of antibacterial cool fiber knitted fabric of novel nano |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP6607951B2 (en) * | 2015-09-28 | 2019-11-20 | 旭化成株式会社 | Multi-layer structure circular knitted fabric |
WO2017210589A2 (en) * | 2016-06-03 | 2017-12-07 | Mission Product Holdings, Inc. | Wet-activated cooling fabric |
-
2018
- 2018-12-25 CN CN201811591228.7A patent/CN109440278B/en active Active
Patent Citations (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102517773A (en) * | 2005-04-18 | 2012-06-27 | 郡是株式会社 | Fiber highly cool to touch |
CN101613907A (en) * | 2008-06-25 | 2009-12-30 | 福建凤竹纺织科技股份有限公司 | Ice-cold fiber knitted fabric and manufacture method thereof |
CN102031581A (en) * | 2009-09-25 | 2011-04-27 | 上海德福伦化纤有限公司 | Method for producing super-refreshing cool-feel health care polyester fiber |
CN102433674A (en) * | 2011-10-26 | 2012-05-02 | 青岛雪达集团有限公司 | Mica fiber comfortable ecological knitted fabric and knitting method thereof |
CN103173916A (en) * | 2013-03-08 | 2013-06-26 | 高密市富源印染有限公司 | Blending silky single jersey cloth of polyester fiber and modal fiber and preparation method thereof |
CN103194847A (en) * | 2013-03-19 | 2013-07-10 | 上海嘉乐股份有限公司 | Antibacterial, moisture-absorbent and warming knitted fabric and manufacturing method thereof |
JP2014189937A (en) * | 2013-03-28 | 2014-10-06 | Unitika Trading Co Ltd | Functional fiber |
JP2015094034A (en) * | 2013-11-08 | 2015-05-18 | ユニチカトレーディング株式会社 | Heat-retaining cloth |
CN104878517A (en) * | 2015-06-18 | 2015-09-02 | 青岛雪达集团有限公司 | Cool fibrous comfortable ecological knitted fabric and knitting method thereof |
CN106192179A (en) * | 2016-08-26 | 2016-12-07 | 青岛雪达集团有限公司 | A kind of vinegar green grass or young crops fiber functional knitting fabric and method for weaving |
CN107287746A (en) * | 2017-08-24 | 2017-10-24 | 宁波大千纺织品有限公司 | A kind of close comfortable well-pressed type knitted side preparation method for material |
CN107841820A (en) * | 2017-11-06 | 2018-03-27 | 福建凤竹纺织科技股份有限公司 | A kind of production technology of ice coffee fiber knitted fabric |
CN108277570A (en) * | 2018-02-12 | 2018-07-13 | 武汉汉麻生物科技有限公司 | A kind of functionally graded layer looped fabric and preparation method thereof |
CN209397348U (en) * | 2018-12-25 | 2019-09-17 | 青岛雪达集团有限公司 | A kind of antibacterial cool fiber knitted fabric of novel nano |
Non-Patent Citations (6)
Title |
---|
《纺织品技术规则与国际贸易》编委会.《纺织品技术规则与国际贸易》.中国纺织出版社,2004,(第1版),第566页. * |
凉爽型防紫外线涤纶针织面料的开发与性能评价;张海霞;张喜昌;吉荣昌;万国然;;河南工程学院学报(自然科学版)(第01期);全文 * |
吸湿散热针织面料的开发及性能研究;周礼标;龙海如;陈茂胜;;针织工业;20120828(第08期);全文 * |
多组分双层弹力针织面料的开发与服用性能测试;赵晓红;;印染助剂(第09期);全文 * |
天然植物源金樱子抑菌黏胶纤维及面料开发;张世安;于湖生;关燕;王显其;张洪宾;位国栋;;针织工业;20160828(第08期);全文 * |
智能调温商务休闲针织面料的研发;张世安;王显其;关燕;李良;位国栋;马君志;;针织工业(第01期);全文 * |
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