CN109422505A - A kind of environmental-protection flame-retardant mortar and its preparation method and application - Google Patents

A kind of environmental-protection flame-retardant mortar and its preparation method and application Download PDF

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Publication number
CN109422505A
CN109422505A CN201710776891.3A CN201710776891A CN109422505A CN 109422505 A CN109422505 A CN 109422505A CN 201710776891 A CN201710776891 A CN 201710776891A CN 109422505 A CN109422505 A CN 109422505A
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CN
China
Prior art keywords
mass parts
powder
environmental
retardant
protection flame
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Pending
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CN201710776891.3A
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Chinese (zh)
Inventor
张优雨
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Chengdu Yue Sheng Technology Co Ltd
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Chengdu Yue Sheng Technology Co Ltd
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Priority to CN201710776891.3A priority Critical patent/CN109422505A/en
Publication of CN109422505A publication Critical patent/CN109422505A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/28Fire resistance, i.e. materials resistant to accidental fires or high temperatures

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Fireproofing Substances (AREA)

Abstract

The invention discloses a kind of environmental-protection flame-retardant mortars, are made of the water of the general ash of 200-400 mass parts, the fire prevention powder, the talcum powder of 2-5 mass parts and 300-860 mass parts of the fine sand of 300-900 mass parts, the rubber powder of 10-50 mass parts, the wood-fibred of 1-5 mass parts, the cellulose ether of 1-5 mass parts, 20-60 mass parts.Said components are mixed evenly when preparation, when use, is evenly coated on insulation board, can not only be effectively fire-retardant, it is easy for construction, and also itself can effectively be combined with finishing mucilage, avoid boundary defect.

Description

A kind of environmental-protection flame-retardant mortar and its preparation method and application
Technical field
The present invention relates to a kind of fire proofing materials, more specifically to a kind of environmental-protection flame-retardant mortar and preparation method thereof And application.
Background technique
Fire has become one of the disaster for endangering human life and property safety, and various bamboo-wood structure buildings are easy Combustion is built, and various concrete and structural steelwork are not explosions, exactly lose intensity and collapse in 300 DEG C or more of high temperature, Therefore people develop a variety of inorganic and organic fire prevention coating, are sprayed on the table of civil structure building, concrete and structural steelwork Face is protected them in a fire, avoids or reduce loss caused by fire.
Fireproof coating kind is numerous, by its composition can be divided into inorganic type fireproof coating using inorganic salts as base-material with Using natural or artificial resin as the organic type fireproof coating of base-material, can classify water-soluble and solvent by its decentralized medium Type can be divided into intumescent and non-expansion type by its fireproofing mechanism, can be divided into facing type and structural type using function by it.It is several normal Fireproof coating is as follows
Facing expanding fire-proof paint: double fluorine amine-urea-formaldehyde copolymer, titanium dioxide, antimony oxide, pentaerythrite and phosphorus Acid;Melamine pollopas fireproof coating: melamine pollopas, prodan, water, pentaerythrite and polyphosphoric acid amine; Intumescent inorganic fireproof coating: base-material (aluminium hydroxide, phosphoric acid, water), composite flame-retardant agent, alchlor, titanium dioxide, ureaformaldehyde tree Rouge, urea, plasticizer and water;Noninflammability inorganic fireproof coating: potassium silicate, expanded vermiculite, glass powder, titanium dioxide, iron oxide red, Condensation of aluminum phosphate and water.From the above, it can be seen that how much organic coating contains formaldehyde, melamine, fluoride, when burning, these Organic matter will discharge some pernicious gases, seriously affect to human body and environment;Most of raw material is all relatively valuable, can not be again It is raw, cause price higher.
It in engineering construction, generally requires to carry out fire prevention processing to insulation board, uses two methods under normal conditions: is a kind of It is that above-mentioned fireproof coating is sprayed on insulation board, another kind is that nonwoven layer first is arranged on surface when preparing insulation board, so After non-woven fabrics of tearing carry out surface coating again.The fireproof coating of spraying not there is only above-mentioned environmental pollution, disadvantage at high cost, And itself is inconsistent with finishing mucilage property, and interface differs greatly, and is easy to cause the defect at interface, it is hidden in turn result in quality Suffer from.The non-woven fabric compounded fire-retardant one side of plate further increases cost, and easy to fall off, is unfavorable for recycling.
Summary of the invention
It is an object of the invention to overcome deficiency in the prior art, a kind of environmental-protection flame-retardant mortar is provided, it can not only It is effectively fire-retardant, it is easy for construction, and also itself can effectively be combined with finishing mucilage, avoid boundary defect.
A kind of environmental-protection flame-retardant mortar of the invention, by 200-400 mass parts it is general ash, 300-900 mass parts fine sand, The rubber powder of 10-50 mass parts, the wood-fibred of 1-5 mass parts, the cellulose ether of 1-5 mass parts, 20-60 mass parts fire prevention powder, The talcum powder of 2-5 mass parts and the water composition of 300-860 mass parts.
A kind of environmental-protection flame-retardant mortar of the invention, preferably by the general ash of 300-400 mass parts, 700-900 mass parts Fine sand, the rubber powder of 20-40 mass parts, the wood-fibred of 1-5 mass parts, the cellulose ethers of 1-5 mass parts, 20-50 mass parts The water composition of fire prevention powder, the talcum powder of 2-5 mass parts and 300-800 mass parts.
A kind of environmental-protection flame-retardant mortar of the invention, also preferably by the general ash of 300-350 mass parts, 700-800 mass Fine sand, the rubber powder of 20-35 mass parts, the wood-fibred of 1-4 mass parts, the cellulose ether of 1-3 mass parts, 20-35 mass parts of part Fire prevention powder, 2-5 mass parts talcum powder and 500-700 mass parts water composition.
A kind of environmental-protection flame-retardant mortar of the invention, wherein the fine sand is 40-70 mesh or 70-140 mesh.
A kind of method preparing environmental-protection flame-retardant mortar of the invention carries out as steps described below:
(1) by the general ash of 200-400 mass parts, the fine sand of 300-900 mass parts, the rubber powder of 10-50 mass parts, 1-5 mass parts Wood-fibred, the cellulose ether of 1-5 mass parts, the talcum powder of 2-5 mass parts and 20-60 mass parts fire prevention powder sequentially add appearance It in device, is stirred simultaneously, so that whole system is finally uniformly mixed;
(2) water of 300-860 mass parts is added in the uniformly mixed system prepared to step (1), while is stirred so that mixed It closes uniform.
A kind of method preparing environmental-protection flame-retardant mortar of the invention, the step (1) preferably 300-400 mass parts The fiber of general ash, the fine sand of 700-900 mass parts, the rubber powder of 20-40 mass parts, the wood-fibred of 1-5 mass parts, 1-5 mass parts The fire prevention powder of plain ether, the talcum powder of 2-5 mass parts and 20-50 mass parts;The step (2) preferably 300-800 mass parts Water.
A kind of method preparing environmental-protection flame-retardant mortar of the invention, the step (1) is also preferably by 300-350 mass Part general ash, the fine sand of 700-800 mass parts, the rubber powder of 20-35 mass parts, the wood-fibred of 1-4 mass parts, 1-3 mass parts Cellulose ether, the talcum powder of 2-5 mass parts, 20-35 mass parts fire prevention powder;The also preferable 500-700 mass of step (2) The water of part.
A kind of method preparing environmental-protection flame-retardant mortar of the invention, wherein the fine sand is 40-70 mesh or 70-140 mesh.
When using a kind of environmental-protection flame-retardant mortar of the invention, the environmental-protection flame-retardant mortar stirred evenly is directly applied It overlays on insulation board.
The each component used in the present invention selects common material in building engineering field.Wherein general ash is ordinary silicon Acid salt cement, according to GB175-2007, by Portland clinker, the mixing material of 5%-20% and proper amount of gypsum is levigate is made Hydraulic cementing materials, such as development cement plant, open new cement plant or the cement plant Ji Dong, select label PO42.5 and Two kinds of PSB32.5;Fine sand selects the common fine sand of building engineering field, such as rising sun Sha Chang, Xia Cang sand factory or Dingxing Sha Chang 40-70 mesh and 70-140 mesh, preferred 70-100 mesh;Rubber powder is redispersible type rubber powder, and this rubber powder is some to be gathered in one The spheric granules of the 80~100mm risen, these particles are water-soluble, and form the stable dispersion more bigger than original emulsion particle Liquid can form a film after this dispersion liquid desiccation;Select styrene-butadiene copolymer, versatic acid ethylene copolymer or second One Methane Carboxylic Acid copolymer of alkene, for example, Wa Ke company, Germany 5044 or three-dimensional chemical company swf-04, swf-05;It is wooden fine Dimension is to prepare fiber by raw material of timber, plays the role of hydrophobic and increases pulling force, such as 300mm, the moral of three-dimensional chemical company The zzc500 of Guo Wake company;Cellulose ether selects alkyl ethers or cellulose hydroxyalkyl ether, such as three-dimensional chemical industry public affairs The cellulose ether hpmc100000 of department, Luzhou north company cellulose ether HK-100000S;Fire prevention powder, i.e., rise in the present invention To the effect of fire retardant, it is fire-retardant to can choose common inorganic salts fire retardant, organic fire-retardant or organic and inorganic mixing Agent considers, preferably inorganic additive flame retardant that common main component is hydroxide from the fit angle of environmental protection and material component Aluminium, magnesium hydroxide, shepardite, antimony oxide, zinc borate fire retardant, such as the FH- of Tianjin security protection fire retardant Co., Ltd 07 fabric coating flame-retardant additive.
Environmental-protection flame-retardant mortar of the invention, can be effectively fire-retardant, using the technique coated after being mixed with water, cost It is low, it is easy to operate;Its property is close with finishing mucilage, and cohesive force is larger, can favorably avoid boundary defect.
Specific embodiment
Technical solution of the present invention is further illustrated combined with specific embodiments below.
(1) by general ash, the fine sand of 500 mass parts, the rubber powder of 30 mass parts, the wood-fibred of 3 mass parts, 2 of 300 mass parts The fire prevention powder of the cellulose ether of mass parts, the talcum powder of 4 mass parts and 40 mass parts sequentially adds in container, while being stirred It mixes, so that whole system is finally uniformly mixed;
(2) water of 500 mass parts is added in the uniformly mixed system prepared to step (1), while is stirred so as to mix It is even.
Wherein general ash selects the PSB32.5 in development cement plant.
The 40-70 mesh of fine sand selection rising sun sand factory.
Rubber powder selects the 5044 of Wa Ke company, Germany.
Cellulose ether is selected from the cellulose ether hpmc100000 of three-dimensional chemical company.
Powder of preventing fires selects the FH-07 fabric coating flame-retardant additive of Tianjin security protection fire retardant Co., Ltd.

Claims (9)

1. a kind of environmental-protection flame-retardant mortar, which is characterized in that by the general grey, 300-900 mass parts thin of 200-400 mass parts The fire prevention of sand, the rubber powder of 10-50 mass parts, the wood-fibred of 1-5 mass parts, the cellulose ether of 1-5 mass parts, 20-60 mass parts The water of powder, the talcum powder of 2-5 mass parts and 300-860 mass parts forms.
2. a kind of environmental-protection flame-retardant mortar according to claim 1, which is characterized in that by 300-400 mass parts it is general ash, The fine sand of 700-900 mass parts, the rubber powder of 20-40 mass parts, the wood-fibred of 1-5 mass parts, 1-5 mass parts cellulose ether, The water composition of the fire prevention powder of 20-50 mass parts, the talcum powder of 2-5 mass parts and 300-800 mass parts.
3. a kind of environmental-protection flame-retardant mortar according to claim 1, which is characterized in that by 300-350 mass parts it is general ash, The fine sand of 700-800 mass parts, the rubber powder of 20-35 mass parts, the wood-fibred of 1-4 mass parts, 1-3 mass parts cellulose ether, The water composition of the fire prevention powder of 20-35 mass parts, the talcum powder of 2-5 mass parts and 500-700 mass parts.
4. a kind of environmental-protection flame-retardant mortar described in one of -3 according to claim 1, which is characterized in that the general ash is ordinary silicon Acid salt cement;The fine sand is 40-70 mesh or 70-140 mesh;The rubber powder is redispersible type rubber powder;The cellulose ether For alkyl ethers or cellulose hydroxyalkyl ether;The fire prevention powder is inorganic additive flame retardant.
5. a kind of method for preparing environmental-protection flame-retardant mortar, which is characterized in that carry out as steps described below:
(1) by the general ash of 200-400 mass parts, the fine sand of 300-900 mass parts, the rubber powder of 10-50 mass parts, 1-5 mass parts Wood-fibred, the cellulose ether of 1-5 mass parts, the talcum powder of 2-5 mass parts and 20-60 mass parts fire prevention powder sequentially add appearance It in device, is stirred simultaneously, so that whole system is finally uniformly mixed;
(2) water of 300-860 mass parts is added in the uniformly mixed system prepared to step (1), while is stirred so that mixed It closes uniform.
6. a kind of method for preparing environmental-protection flame-retardant mortar according to claim 5, which is characterized in that the step (1) The wood of the middle general ash for selecting 300-400 mass parts, the fine sand of 700-900 mass parts, the rubber powder of 20-40 mass parts, 1-5 mass parts Fiber, the cellulose ether of 1-5 mass parts, the talcum powder of 2-5 mass parts and 20-50 mass parts fire prevention powder;In the step (2) Select the water of 300-800 mass parts.
7. a kind of method for preparing environmental-protection flame-retardant mortar according to claim 5, which is characterized in that the step (1) The wood of the middle general ash for selecting 300-350 mass parts, the fine sand of 700-800 mass parts, the rubber powder of 20-35 mass parts, 1-4 mass parts Fiber, the cellulose ether of 1-3 mass parts, the talcum powder of 2-5 mass parts, 20-35 mass parts fire prevention powder;In the step (2) Select the water of 500-700 mass parts.
8. a kind of method for preparing environmental-protection flame-retardant mortar according to one of claim 5-7, which is characterized in that described general Ash is ordinary portland cement;The fine sand is 40-70 mesh or 70-140 mesh;The rubber powder is redispersible type rubber powder;Institute Stating cellulose ether is alkyl ethers or cellulose hydroxyalkyl ether;The fire prevention powder is inorganic additive flame retardant.
9. application of a kind of environmental-protection flame-retardant mortar in insulation board fire resistant coating as described in one of claim 1-3.
CN201710776891.3A 2017-09-01 2017-09-01 A kind of environmental-protection flame-retardant mortar and its preparation method and application Pending CN109422505A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110627455A (en) * 2019-11-05 2019-12-31 厦门高辰新材料有限公司 High-molecular beneficial daub and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110627455A (en) * 2019-11-05 2019-12-31 厦门高辰新材料有限公司 High-molecular beneficial daub and preparation method thereof

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Application publication date: 20190305