CN110627455A - High-molecular beneficial daub and preparation method thereof - Google Patents
High-molecular beneficial daub and preparation method thereof Download PDFInfo
- Publication number
- CN110627455A CN110627455A CN201911070007.XA CN201911070007A CN110627455A CN 110627455 A CN110627455 A CN 110627455A CN 201911070007 A CN201911070007 A CN 201911070007A CN 110627455 A CN110627455 A CN 110627455A
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- Prior art keywords
- daub
- high molecular
- silicate fiber
- parts
- cement
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/27—Water resistance, i.e. waterproof or water-repellent materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/28—Fire resistance, i.e. materials resistant to accidental fires or high temperatures
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The invention provides high-molecular easy-care daub which comprises the following components in parts by weight: 20-30 parts of cement, 5-10 parts of aluminum dihydrogen phosphate, 40-50 parts of building fine sand, 0.05-0.2 part of hydroxypropyl methyl cellulose ether, 0.5-1.0 part of silicate fiber and 0.1-0.3 part of lignin fiber, and has excellent fireproof and fireproof performances.
Description
Technical Field
The invention relates to high-molecular easy-care daub and a preparation method thereof, belonging to the technical field of high-molecular easy-care daub.
Background
A high-molecular easy-to-use daub is a non-toxic and tasteless rigid water-proof adhesive material which is made up by mixing several high-molecular materials with silicate cement and powdered sand according to a certain proportion and adopting scientific proportioning and special technological process and integrates the functions of water-proofing, adhesion and leak-stopping into one body.
However, since some polymer materials are contained, which are flammable, their fire-retardant properties are not ideal, and if a fire occurs, the wall is damaged due to softening of the benefical mastic, so there is a high demand for a polymer benefical mastic with excellent fire-retardant properties.
Disclosure of Invention
The present invention provides a solution to the above problems.
The invention is realized by the following steps:
the polymer easy daub is characterized by comprising the following components in parts by weight: 20-30 parts of cement, 5-10 parts of aluminum dihydrogen phosphate, 40-50 parts of building fine sand, 0.05-0.2 part of hydroxypropyl methyl cellulose ether, 0.5-1.0 part of silicate fiber and 0.1-0.3 part of lignin fiber.
As a further improvement, the cement is portland cement. The Portland cement is a main gel material, and can ensure the compressive strength and the tensile bonding strength of the benefited daub.
As a further improvement, the silicate fiber is one or more of aluminum silicate fiber, calcium silicate fiber and magnesium silicate fiber, and is preferably aluminum silicate fiber. The silicate fiber is inorganic mineral fiber, has poor flammability, can improve the fireproof and fireproof performance of the beneficiary daub, and can permeate into capillary pores of silicate cement as the fiber to be crosslinked with the silicate cement, so that the breaking strength, the compressive strength and the tensile bonding strength of the beneficiary daub are improved.
As a further improvement, the building fine sand is 70-140 mesh grade sand. The building fine sand is used as a framework material, and is matched with the silicate cement and the silicate fiber to enhance the compressive strength of the beneficial daub. The selection of 70-140 meshes is very critical, and the sand preparation in the range can ensure the balance of the compressive strength and the binding power of the mortar and good crack resistance.
As a further improvement, the magnesium oxide powder also comprises 3-5 parts of magnesium oxide. The magnesium oxide has high fireproof and insulating properties, and the fireproof and fireproof properties of the beneficiated mortar can be greatly improved by adding the magnesium oxide into the beneficiated mortar. Wherein, the aluminum dihydrogen phosphate is used as the adhesive of the magnesium oxide, so that the magnesium oxide is firmly bonded with other raw materials such as cement, carbonate fiber and the like, and the breaking strength and the seepage pressure resistance of the beneficial daub are improved.
The preparation method of the polymer easy daub comprises the following steps:
s1, weighing cement, construction fine sand, aluminum dihydrogen phosphate and silicate fiber according to the proportion, mixing the weighed cement, aluminum dihydrogen phosphate, silicate fiber and construction fine sand accounting for 45-55% of the weighed construction fine sand, and uniformly stirring in a stirrer to obtain premix A;
s2: weighing hydroxypropyl methyl cellulose ether and lignin fiber according to a proportion, mixing, adding into the premix A in the step S1, and uniformly stirring in a stirrer to obtain premix B;
s3: and (4) adding the residual building fine sand in the step (S1) into the premix B, and uniformly stirring in a stirrer to obtain the high-molecular beneficial daub.
As a further improvement, in the step S1, the stirring time of the stirring is 50 to 80S.
As a further improvement, in the step S2, the stirring time of the stirring is 60 to 120S.
As a further improvement, in the step S3, the stirring time of the stirring is 3-5 min.
As a further improvement, the method also comprises the step of adding magnesium oxide in the step S2, mixing the magnesium oxide with other raw materials and then adding the mixture into a stirrer.
In the method, the main materials are fully and uniformly mixed in step S1, then the main materials and the auxiliary materials in step S2 are interacted, and finally the residual fine building sand is added, so that the defect that the binding property of the beneficial daub is poor due to non-uniform mixing and caking of the main materials is avoided, and the binding property and the compressive strength of the beneficial daub are improved. The stirring time of each step is also very critical, the stirring time in the step S1 is 50-80S, the stirring time in the step S2 is 60-120S, if the stirring time is too short, the stirring is not uniform, the bonding property of the beneficiary daub can be reduced, if the stirring time is too long, the main material and the auxiliary material are mixed and then dried and hardened, the interaction between the auxiliary material and the main material in the subsequent steps is not facilitated, and the properties of the beneficiary daub, such as water retention property, bonding property, compressive strength and the like, are difficult to guarantee.
The invention has the beneficial effects that:
1. the high-molecular beneficial daub disclosed by the invention contains a large amount of inorganic materials which are difficult to burn, such as cement, building fine sand, aluminium dihydrogen phosphate, aluminium silicate fiber, magnesium oxide and the like, so that the high-molecular beneficial daub has excellent fireproof and fireproof performances and reaches A level.
2. The high-molecular beneficial daub disclosed by the invention contains silicate fibers, silicate cement, building fine sand, aluminum dihydrogen phosphate and the like in proper proportion, and the synergistic effect is exerted, so that the beneficial daub is high in bonding strength, and can be used for effectively preventing cracks from generating, and preventing hollowing, cracking and alkali whitening.
3. The high molecular beneficial daub contains hydroxypropyl methyl cellulose ether and lignin fiber, so that the beneficial daub has high seepage pressure resistance and can prevent water from permeating from the veneer bonding layer.
4. The high-molecular beneficial daub has good workability, water retention property and sag resistance, can be constructed in a large area, and has high construction efficiency.
5. The high molecular easy daub of the invention is water-resistant, temperature-resistant, freeze-thaw resistant, nontoxic and pollution-free.
6. The high-molecular beneficial daub has high bonding strength and high permeation pressure resistance, and only needs a thin coating when in use, thereby reducing the material consumption and lowering the production cost.
Detailed Description
In order to make the objects, technical solutions and advantages of the embodiments of the present invention more apparent, the technical solutions of the embodiments of the present invention will be clearly and completely described below, and it is apparent that the described embodiments are some embodiments of the present invention, but not all embodiments. All other embodiments, which can be obtained by a person skilled in the art without any inventive step based on the embodiments of the present invention, are within the scope of the present invention. Thus, the following detailed description of embodiments of the invention is not intended to limit the scope of the invention as claimed, but is merely representative of selected embodiments of the invention. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
In the description of the present invention, the terms "first" and "second" are used for descriptive purposes only and are not to be construed as indicating or implying relative importance or implying any number of technical features indicated. Thus, a feature defined as "first" or "second" may explicitly or implicitly include one or more of that feature. In the description of the present invention, "a plurality" means two or more unless specifically defined otherwise.
Example 1
22kg of ordinary portland cement, 8kg of aluminum dihydrogen phosphate, 40kg of 70-140 mesh grade mixed sand, 0.1kg of hydroxypropyl methyl cellulose ether, 3kg of magnesium oxide, 0.2kg of lignin fiber and 0.6kg of aluminum silicate fiber are weighed. And (2) stirring the weighed ordinary portland cement, aluminum dihydrogen phosphate and aluminum silicate fiber and 50% of graded sand by using a dry powder mortar stirrer for 1 minute, slowly adding the weighed hydroxypropyl methyl cellulose ether and magnesium oxide into the stirrer for continuously stirring for 2 minutes, and finally adding the rest 50% of the graded sand into the stirrer for continuously stirring for 4 minutes to obtain the dry powder-shaped polymer beneficial daub which can be packaged and applied.
Example 2
Weighing 30kg of ordinary portland cement, 10kg of aluminum dihydrogen phosphate, 45kg of 70-140 mesh-grade prepared sand, 0.1kg of hydroxypropyl methyl cellulose ether, 4kg of magnesium oxide, 0.2kg of lignin fiber and 0.8kg of magnesium silicate fiber. Firstly, the ordinary portland cement, the aluminum dihydrogen phosphate and the aluminum silicate fiber which are weighed and the graded sand with the proportion of 45 percent are stirred for 80s by a dry powder mortar stirrer, then the weighed hydroxypropyl methyl cellulose ether and the magnesium oxide are slowly added into the stirrer to be continuously stirred for 90s, and finally the rest graded sand with the proportion of 55 percent is added into the stirrer to be continuously stirred for 5min, so that the dry powder-shaped high molecular beneficial daub is obtained and can be packaged and applied.
Example 3
25kg of ordinary portland cement, 5kg of aluminum dihydrogen phosphate, 50kg of 70-140 mesh-grade prepared sand, 0.2kg of hydroxypropyl methyl cellulose ether, 5kg of magnesium oxide, 0.1kg of lignin fiber and 0.8kg of calcium silicate fiber are weighed. Firstly, the ordinary portland cement, the aluminum dihydrogen phosphate and the aluminum silicate fiber which are weighed and the graded sand with the proportion of 45 percent are stirred for 70s by a dry powder mortar stirrer, then the weighed hydroxypropyl methyl cellulose ether and the magnesium oxide are slowly added into the stirrer to be continuously stirred for 100s, and finally the rest graded sand with the proportion of 55 percent is added into the stirrer to be continuously stirred for 3 min, so that the dry powder-shaped high-molecular-benefit daub is obtained and can be packaged and applied.
The application method of the high-molecular easy daub comprises the following steps:
the proportion of the high molecular beneficial daub and water is 1:0.20-0.25, the high molecular beneficial daub and the water are uniformly stirred, and the high molecular beneficial daub can be used without a dough-like object. When the ceramic tile is pasted, the stirred polymer beneficial daub is smeared on the back of the ceramic tile and then is pressed on the wall surface forcibly, or the polymer beneficial daub is smeared on the wall surface by using a tooth-shaped scraper blade to be uniformly distributed, and then the ceramic tile is pressed on the polymer beneficial daub forcibly.
The method is characterized by carrying out detection according to DB 35/T516 plus 2018 general technical conditions for high-molecular beneficial daub, carrying out a fire resistance test according to a building material incombustibility test method GB8624-2012, and the detection results are shown in the following table 1:
TABLE 1
The data in table 1 show that the beneficial daub reaches grade A, is a non-combustible material, has excellent fire resistance and fire resistance, and simultaneously has the advantages of standard folding strength, compressive strength, coating permeation resistance and tensile bonding strength, and wide application prospect.
The above description is only a preferred embodiment of the present invention, and is not intended to limit the present invention, and various modifications and changes may be made by those skilled in the art. Any modification, equivalent replacement, or improvement made without departing from the spirit and principle of the present invention shall fall within the protection scope of the present invention.
Claims (10)
1. The polymer easy daub is characterized by comprising the following components in parts by weight: 20-30 parts of cement, 5-10 parts of aluminum dihydrogen phosphate, 40-50 parts of building fine sand, 0.05-0.2 part of hydroxypropyl methyl cellulose ether, 0.5-1.0 part of silicate fiber and 0.1-0.3 part of lignin fiber.
2. The high molecular beneficial daub as claimed in claim 1, wherein the cement is portland cement.
3. The high molecular beneficial daub according to claim 1, wherein the silicate fiber is one or more of aluminum silicate fiber, calcium silicate fiber and magnesium silicate fiber.
4. The high molecular beneficial daub as claimed in claim 1, wherein the fine building sand is 70-140 mesh grade sand.
5. The high molecular beneficial daub as claimed in claim 1, further comprising 3-5 parts of magnesium oxide.
6. A method for preparing the high molecular beneficial daub as claimed in any one of claims 1 to 5, wherein: the method comprises the following steps:
s1, weighing cement, construction fine sand, aluminum dihydrogen phosphate and silicate fiber according to the proportion, mixing the weighed cement, aluminum dihydrogen phosphate, silicate fiber and construction fine sand accounting for 45-55% of the weighed construction fine sand, and uniformly stirring in a stirrer to obtain premix A;
s2: weighing hydroxypropyl methyl cellulose ether and lignin fiber according to a proportion, mixing, adding into the premix A in the step S1, and uniformly stirring in a stirrer to obtain premix B;
s3: and (4) adding the residual building fine sand in the step (S1) into the premix B, and uniformly stirring in a stirrer to obtain the high-molecular beneficial daub.
7. The method for preparing high molecular beneficial daub as claimed in claim 6, wherein: in the step S1, the stirring time is 50 to 80 seconds.
8. The method for preparing high molecular beneficial daub as claimed in claim 6, wherein: in the step S2, the stirring time is 60 to 120 seconds.
9. The method for preparing high molecular beneficial daub according to claim 6, wherein in the step S3, the stirring time is 3-5 min.
10. The method for preparing high molecular beneficial daub as claimed in claim 6, further comprising adding magnesium oxide in step S2, mixing with other raw materials, and adding into a blender.
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CN201911070007.XA CN110627455A (en) | 2019-11-05 | 2019-11-05 | High-molecular beneficial daub and preparation method thereof |
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CN111363416A (en) * | 2020-05-21 | 2020-07-03 | 天津市宏越新材料有限公司 | Intumescent steel structure fireproof coating and preparation method and application thereof |
CN112142417A (en) * | 2020-11-24 | 2020-12-29 | 佛山市建通混凝土制品有限公司 | Plastering anti-crack waterproof mortar and preparation method thereof |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN111363416A (en) * | 2020-05-21 | 2020-07-03 | 天津市宏越新材料有限公司 | Intumescent steel structure fireproof coating and preparation method and application thereof |
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CN112142417A (en) * | 2020-11-24 | 2020-12-29 | 佛山市建通混凝土制品有限公司 | Plastering anti-crack waterproof mortar and preparation method thereof |
CN112142417B (en) * | 2020-11-24 | 2021-03-23 | 佛山市建通混凝土制品有限公司 | Plastering anti-crack waterproof mortar and preparation method thereof |
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