CN109399935A - A kind of preparation method of metal oxide ceramic glaze and products thereof - Google Patents
A kind of preparation method of metal oxide ceramic glaze and products thereof Download PDFInfo
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- CN109399935A CN109399935A CN201811625224.6A CN201811625224A CN109399935A CN 109399935 A CN109399935 A CN 109399935A CN 201811625224 A CN201811625224 A CN 201811625224A CN 109399935 A CN109399935 A CN 109399935A
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
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Abstract
The invention discloses a kind of preparation methods of metal oxide ceramic glaze and products thereof, its raw material comprises the following components in parts by weight: its raw material comprises the following components in parts by weight: 3-9 parts of aluminum phosphate, 1-5 parts of magnesia, 2-5 parts of vanadic anhydride, 2-5 parts of copper oxide, 1-5 parts of titanium oxide, 10-15 parts of manganese oxide, 2-6 parts of barium, 2-7 parts of talcum, 3-9 parts of strontium carbonate, red lead 25-35 parts, 17-23 parts of albite, quartzy 17-23 parts and 9-15 parts of soil, specifically take the parts by weight of raw material as follows: 6 parts of aluminum phosphate, 2 parts of magnesia, 2.5 parts of vanadic anhydride, 2.5 parts of copper oxide, 2 parts of titanium oxide, 11.5 parts of manganese oxide, 3.5 parts of barium, 3 parts of talcum, 6 parts of strontium carbonate, 30 parts of red lead, 20 parts of albite, 20 parts of quartz and soil 1 2 parts, which stablizes, durable, applies on metal product, can effectively prevent metal product that oxidation reaction, long service life, good heat conductivity occurs, and will not change in quality using color for a long time, increase aesthetic effect.
Description
Technical field
The present invention relates to ceramic glaze manufacturing method, the preparation method of specifically a kind of metal oxide ceramic glaze and products thereof.
Background technique
Glaze is a kind of silicate, and the glaze applied on ware is generally using quartz, feldspar, clay as raw material, ground plus water
After modulation, be coated on billet surface, the roasting through certain temperature and melt, when the temperature drops, formed ceramic surface the nature of glass
Thin layer.It increases ware by mechanical strength, thermal stability, dielectric strength and the erosion for preventing liquid, gas.There are also increase for glaze
Porcelain is beautiful and convenient for washing the effects of wiping, not being sticky with by dust.
Glaze is the glassy thin layer for being covered on ceramics, enamel surfaces.Such as: 1 tri-coloured glazed pottery of colored glaze, it is prevailing in Tang, it is biscuiting tire
Body is whitewashed, green, brown, blue glaze, and 800 degree of kiln temperature baking are mostly used to do funerary objects at that time, and 2 overglaze colors are color on burned plain device
It draws, then is formed through low temperature baking, because coloured silk invests on glaze, therefore named sees the Song Dynasty earliest, 3 underglaze colours, in colored drawing on green compact, after
Glazing high temperature firing, for lathe work under glaze, never drop-off sees 4 under-glaze red of the Tang Dynasty earliest, color on tire by toner of copper oxide
It draws, high temperature dries white background safflower after glazing, starts from Yuan Dynasty Jing Dezhen, 5 Doucai contrasting colors are applied with blue and white decorative pattern contour line of sketching on green body
After glaze firing, in filling out in contour line with multicolour, then through stove fire twice firing, picture presents blue and white with color ratio on glaze under glaze
Beautiful Xiang Dou, therefore named start from it is bright at year is changed between, 6 hackings, both cracked ice patterns, glaze crack type is with ice crack because of tire, and the glaze coefficient of expansion is not
Together, too early kiln discharge generates in case of cold air, and Song Dynasty brother's kiln is blue and white as main feature, 7, one of underglaze colour kind, with cobalt oxide
It for toner, draws a picture, covers with clear frit, through 1300 degree of high temperature firings, Lan Bai sets each other off, Ming and Qing Dynasties leading porcelain on mold.
The chemical property of metal is more active, and being easy to react with other substances (oxidant) such as oxygen becomes metal ion
And be depleted, this process is known as getting rusty.Such as iron generates red rust, copper generates patina, aluminium generates white rust.
Existing metal product needs to prevent metal from oxidation hair occurs by smearing antioxidizing paint and answer, antioxidizing paint needs
Feeding is wanted to operate, operating process is time-consuming and laborious, and to be able to maintain the metal anti-oxidation time limit short for antioxidizing paint, uses for a long time,
Formation part is fallen or breakage, and it is overall beautiful to influence metal product.
Summary of the invention
The purpose of the present invention is to provide a kind of preparation methods of metal oxide ceramic glaze and products thereof, to solve above-mentioned back
The problem of being proposed in scape technology.
To achieve the above object, the invention provides the following technical scheme:
A kind of preparation method of metal oxide ceramic glaze and products thereof, raw material comprise the following components in parts by weight: its raw material packet
Include the component of following parts by weight: 3-9 parts of aluminum phosphate, 1-5 parts of magnesia, 2-5 parts of vanadic anhydride, 2-5 parts of copper oxide, titanium oxide
1-5 parts, 10-15 parts of manganese oxide, 2-6 parts of barium, 2-7 parts of talcum, 3-9 parts of strontium carbonate, red lead 25-35 parts, 17-23 parts of albite,
Quartzy 17-23 parts and 9-15 parts of soil, specifically take the parts by weight of raw material as follows: 6 parts of aluminum phosphate, 2 parts of magnesia, vanadic anhydride
2.5 parts, 2.5 parts of copper oxide, 2 parts of titanium oxide, 11.5 parts of manganese oxide, 3.5 parts of barium, 3 parts of talcum, 6 parts of strontium carbonate, 30 parts of red lead,
12 parts of 20 parts of albite, 20 parts of quartz and soil.
A kind of preparation method of the preparation method of metal oxide ceramic glaze and products thereof, the specific steps of which are as follows:
(1) by 6 parts of aluminum phosphate, 2 parts of magnesia, 2.5 parts of vanadic anhydride, 2.5 parts of copper oxide, 2 parts of titanium oxide, manganese oxide 11.5
20 parts of part, 3.5 parts of barium, 3 parts of talcum, 6 parts of strontium carbonate, 30 parts of red lead, 20 parts of albite and quartz are put into inside reactor tank, and
Gained mixed-powder is reacted into 5-10h under the conditions of 400-500 °C of temperature, reactor tank upper surface is equipped with blender, stirring
Device revolving speed is that mixing time is 10-20min, speed of agitator 600-900r/min, obtains raw material A for 6 parts of aluminum phosphate, magnesia
2 parts, 2.5 parts of vanadic anhydride, 2.5 parts of copper oxide, 2 parts of titanium oxide, 11.5 parts of manganese oxide, 3.5 parts of barium, 3 parts of talcum, strontium carbonate
20 parts of 6 parts, 30 parts of red lead, 20 parts of albite and quartz are put into inside reactor tank, and by gained mixed-powder in 400-500 °C
Temperature under the conditions of react 5-10h, reactor tank upper surface is equipped with blender, and agitator speed is that mixing time is 10-
20min, speed of agitator 600-900r/min, obtains raw material A；
(2) raw material A is put into ball grinder interior, is crushed, crushed 350-400 mesh, obtain raw material B；
(3) ball grinder interior is put by native 12 parts, is crushed, crushed 350-400 mesh, obtains raw material C；
(4) raw material B and raw material C are put into inside agitator tank, mixing time 20-30min, speed of agitator 600-900r/
Min obtains ceramic glaze after the completion of stirring.
Compared with prior art, durable the beneficial effects of the present invention are: the ceramic glaze chemical property is stablized, application
On metal product, it can effectively prevent metal product that oxidation reaction, long service life, good heat conductivity, and long-time occurs
It will not be changed in quality using color, increase aesthetic effect.
Specific embodiment
Below in conjunction with the embodiment of the present invention, technical scheme in the embodiment of the invention is clearly and completely described,
Obviously, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based in the present invention
Embodiment, every other embodiment obtained by those of ordinary skill in the art without making creative efforts, all
Belong to the scope of protection of the invention.
Embodiment 1
In the embodiment of the present invention, a kind of metal oxide ceramic glaze specifically takes the parts by weight of raw material as follows: specifically taking the weight of raw material
Part is as follows: 3 parts of aluminum phosphate, 1 part of magnesia, 2 parts of vanadic anhydride, 2 parts of copper oxide, 1 part of titanium oxide, 10 parts of manganese oxide, barium 2
9 parts of part, 2 parts of talcum, 3 parts of strontium carbonate, 25 parts of red lead, 17 parts of albite, 17 parts of quartz and soil；
A kind of preparation method of metal oxide ceramic glaze, the specific steps of which are as follows:
(1) 3 parts of aluminum phosphate, 1 part of magnesia, 2 parts of vanadic anhydride, 2 parts of copper oxide, 1 part of titanium oxide, 10 parts of manganese oxide, barium 2
17 parts of part, 2 parts of talcum, 3 parts of strontium carbonate, 25 parts of red lead, 17 parts of albite and quartz, put into inside reactor tank, and by gained
Mixed-powder reacts 5h under the conditions of 400 DEG C of temperature, and reactor tank upper surface is equipped with blender, when agitator speed is stirring
Between be 10min, speed of agitator 600r/min obtains raw material A；
(2) raw material A is put into ball grinder interior, is crushed, crushed 350 meshes, obtain raw material B；
(3) ball grinder interior is put by native 9 parts, is crushed, crushed 350 meshes, obtains raw material C；
(4) raw material B and raw material C are put into inside agitator tank, mixing time 20min, speed of agitator 600r/min, is stirred
Ceramic glaze is obtained after the completion.
Embodiment 2
In the embodiment of the present invention, a kind of metal oxide ceramic glaze specifically takes the parts by weight of raw material as follows: specifically taking the weight of raw material
Part is as follows: 4 parts of aluminum phosphate, 2 parts of magnesia, 3 parts of vanadic anhydride, 3 parts of copper oxide, 4 parts of titanium oxide, 11 parts of manganese oxide, barium 3
10 parts of part, 3 parts of talcum, 4 parts of strontium carbonate, 26 parts of red lead, 18 parts of albite, 18 parts of quartz and soil；
A kind of preparation method of metal oxide ceramic glaze, the specific steps of which are as follows:
(1) 4 parts of aluminum phosphate, 2 parts of magnesia, 3 parts of vanadic anhydride, 3 parts of copper oxide, 4 parts of titanium oxide, 11 parts of manganese oxide, barium 3
18 parts of part, 3 parts of talcum, 4 parts of strontium carbonate, 26 parts of red lead, 18 parts of albite and quartz, put into inside reactor tank, and by gained
Mixed-powder reacts 7h under the conditions of 420 DEG C of temperature, and reactor tank upper surface is equipped with blender, when agitator speed is stirring
Between be 14min, speed of agitator 700r/min obtains raw material A；
(2) raw material A is put into ball grinder interior, is crushed, crushed 360 meshes, obtain raw material B；
(3) ball grinder interior is put by native 10 parts, is crushed, crushed 360 meshes, obtains raw material C；
(4) raw material B and raw material C are put into inside agitator tank, mixing time 24min, speed of agitator 700r/min, is stirred
Ceramic glaze is obtained after the completion.
Embodiment 3
In the embodiment of the present invention, a kind of metal oxide ceramic glaze specifically takes the parts by weight of raw material as follows: specifically taking the weight of raw material
Part is as follows: 4.5 parts of aluminum phosphate, 4 parts of magnesia, 4 parts of vanadic anhydride, 4 parts of copper oxide, 4 parts of titanium oxide, 14 parts of manganese oxide, barium 5
13 parts of part, 6 parts of talcum, 8 parts of strontium carbonate, 30 parts of red lead, the long 21 stone parts of sodium, 21 parts of quartz and soil；
A kind of preparation method of metal oxide ceramic glaze, the specific steps of which are as follows:
(1) 4.5 parts of aluminum phosphate, 4 parts of magnesia, 4 parts of vanadic anhydride, 4 parts of copper oxide, 4 parts of titanium oxide, 14 parts of manganese oxide, barium 5
21 parts of part, 6 parts of talcum, 8 parts of strontium carbonate, 30 parts of red lead, the long 21 stone parts of sodium and quartz, put into inside reactor tank, and by gained
Mixed-powder reacts 10h under the conditions of 400 DEG C of temperature, and reactor tank upper surface is equipped with blender, and agitator speed is stirring
Time is 18min, and speed of agitator 800r/min obtains raw material A；
(2) raw material A is put into ball grinder interior, is crushed, crushed 380 meshes, obtain raw material B；
(3) ball grinder interior is put by native 13 parts, is crushed, crushed 380 meshes, obtains raw material C；
(4) raw material B and raw material C are put into inside agitator tank, mixing time 28min, speed of agitator 800r/min, is stirred
Ceramic glaze is obtained after the completion.
Embodiment 4
In the embodiment of the present invention, a kind of metal oxide ceramic glaze specifically takes the parts by weight of raw material as follows: specifically taking the weight of raw material
Part is as follows: 5 parts of aluminum phosphate, 5 parts of magnesia, 5 parts of vanadic anhydride, 5 parts of copper oxide, 5 parts of titanium oxide, 15 parts of manganese oxide, barium 6
15 parts of part, 7 parts of talcum, 9 parts of strontium carbonate, 35 parts of red lead, 23 parts of albite, 23 parts of quartz and soil；
A kind of preparation method of metal oxide ceramic glaze, the specific steps of which are as follows:
(1) 5 parts of aluminum phosphate, 5 parts of magnesia, 5 parts of vanadic anhydride, 5 parts of copper oxide, 5 parts of titanium oxide, 15 parts of manganese oxide, barium 6
23 parts of part, 7 parts of talcum, 9 parts of strontium carbonate, 35 parts of red lead, 23 parts of albite and quartz, put into inside reactor tank, and by gained
Mixed-powder reacts 10h under the conditions of 500 DEG C of temperature, and reactor tank upper surface is equipped with blender, and agitator speed is stirring
Time is 30min, and speed of agitator 900r/min obtains raw material A；
(2) raw material A is put into ball grinder interior, is crushed, crushed 400 meshes, obtain raw material B；
(3) ball grinder interior is put by native 15 parts, is crushed, crushed 400 meshes, obtains raw material C；
(4) raw material B and raw material C are put into inside agitator tank, mixing time 30min, speed of agitator 900r/min, is stirred
Ceramic glaze is obtained after the completion.
Embodiment 5
In the embodiment of the present invention, a kind of metal oxide ceramic glaze specifically takes the parts by weight of raw material as follows: specifically taking the weight of raw material
Part is as follows: 8 parts of aluminum phosphate, 4.5 parts of magnesia, 4.5 parts of vanadic anhydride, 4.5 parts of copper oxide, 3.6 parts of titanium oxide, manganese oxide
10.7 parts, 5.5 parts of barium, 6.5 parts of talcum, 4.8 parts of strontium carbonate, 32 parts of red lead, 18.5 parts of albite, 22.5 parts of quartz and soil 10.5
Part；
A kind of preparation method of metal oxide ceramic glaze, the specific steps of which are as follows:
(1) 8 parts of aluminum phosphate, 4.5 parts of magnesia, 4.5 parts of vanadic anhydride, 4.5 parts of copper oxide, 3.6 parts of titanium oxide, manganese oxide
22.5 parts of 10.7 parts, 5.5 parts of barium, 6.5 parts of talcum, 4.8 parts of strontium carbonate, 32 parts of red lead, 18.5 parts of albite and quartz, put into
Inside reactor tank, and gained mixed-powder is reacted into 8.5h under the conditions of 480 DEG C of temperature, reactor tank upper surface is equipped with stirring
Device, agitator speed are that mixing time is 17min, and speed of agitator 865r/min obtains raw material A；
(2) raw material A is put into ball grinder interior, is crushed, crushed 365 meshes, obtain raw material B；
(3) ball grinder interior is put by native 10.5 parts, is crushed, crushed 365 meshes, obtains raw material C；
(4) raw material B and raw material C are put into inside agitator tank, mixing time 27.5min, speed of agitator 865r/min is stirred
Ceramic glaze is obtained after the completion of mixing
Although the present invention is described in detail referring to the foregoing embodiments, for those skilled in the art, according to
It is so possible to modify the technical solutions described in the foregoing embodiments, or part of technical characteristic is equally replaced
It changes, all within the spirits and principles of the present invention, any modification, equivalent replacement, improvement and so on should be included in the present invention
Protection scope within.
Claims (3)
1. a kind of metal oxide ceramic glaze, which is characterized in that its raw material comprises the following components in parts by weight: 3-9 parts of aluminum phosphate, oxygen
Change magnesium 1-5 parts, 2-5 parts of vanadic anhydride, 2-5 parts of copper oxide, 1-5 parts of titanium oxide, 10-15 parts of manganese oxide, 2-6 parts of barium, talcum
9-15 parts of 2-7 parts, 3-9 parts of strontium carbonate, red lead 25-35 parts, 17-23 parts of albite, 17-23 parts of quartz and soil.
2. a kind of metal oxide ceramic glaze according to claim 1, which is characterized in that specifically take the parts by weight of raw material such as
Under: 6 parts of aluminum phosphate, 2 parts of magnesia, 2.5 parts of vanadic anhydride, 2.5 parts of copper oxide, 2 parts of titanium oxide, 11.5 parts of manganese oxide, barium
12 parts of 3.5 parts, 3 parts of talcum, 6 parts of strontium carbonate, 30 parts of red lead, 20 parts of albite, 20 parts of quartz and soil.
3. a kind of a kind of preparation method of metal oxide ceramic glaze as described in claim 1 or 2 is any, which is characterized in that its
Specific step is as follows:
(1) by 6 parts of aluminum phosphate, 2 parts of magnesia, 2.5 parts of vanadic anhydride, 2.5 parts of copper oxide, 2 parts of titanium oxide, manganese oxide 11.5
20 parts of part, 3.5 parts of barium, 3 parts of talcum, 6 parts of strontium carbonate, 30 parts of red lead, 20 parts of albite and quartz are put into inside reactor tank, and
Gained mixed-powder is reacted into 5-10h under the conditions of 400-500 °C of temperature, reactor tank upper surface is equipped with blender, stirring
Device revolving speed is that mixing time is 10-20min, and speed of agitator 600-900r/min obtains raw material A；
(2) raw material A is put into ball grinder interior, is crushed, crushed 350-400 mesh, obtain raw material B；
(3) ball grinder interior is put by native 12 parts, is crushed, crushed 350-400 mesh, obtains raw material C；
(4) raw material B and raw material C are put into inside agitator tank, mixing time 20-30min, speed of agitator 600-900r/
Min obtains ceramic glaze after the completion of stirring.
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| CN201811625224.6A CN109399935A (en) | 2018-12-28 | 2018-12-28 | A kind of preparation method of metal oxide ceramic glaze and products thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN116082030A (en) * | 2022-12-26 | 2023-05-09 | 广西产研院新型功能材料研究所有限公司 | Aluminum phosphate ceramic produced by using unpurified wet-process phosphoric acid, and method and application thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN116082030A (en) * | 2022-12-26 | 2023-05-09 | 广西产研院新型功能材料研究所有限公司 | Aluminum phosphate ceramic produced by using unpurified wet-process phosphoric acid, and method and application thereof |
| CN116082030B (en) * | 2022-12-26 | 2024-06-07 | 广西产研院新型功能材料研究所有限公司 | Aluminum phosphate ceramic produced by using unpurified wet-process phosphoric acid, and method and application thereof |
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