CN109370812A - The low volatilization high-performance water based cleaning agent of one kind and cleaning method - Google Patents
The low volatilization high-performance water based cleaning agent of one kind and cleaning method Download PDFInfo
- Publication number
- CN109370812A CN109370812A CN201811549581.9A CN201811549581A CN109370812A CN 109370812 A CN109370812 A CN 109370812A CN 201811549581 A CN201811549581 A CN 201811549581A CN 109370812 A CN109370812 A CN 109370812A
- Authority
- CN
- China
- Prior art keywords
- surfactant
- agent
- cleaning agent
- cleaning
- water based
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000012459 cleaning agent Substances 0.000 title claims abstract description 71
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 63
- 238000004140 cleaning Methods 0.000 title claims abstract description 46
- 238000000034 method Methods 0.000 title claims abstract description 27
- 239000004094 surface-active agent Substances 0.000 claims abstract description 46
- 230000007797 corrosion Effects 0.000 claims abstract description 24
- 238000005260 corrosion Methods 0.000 claims abstract description 24
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 21
- 239000008367 deionised water Substances 0.000 claims abstract description 18
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 18
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 15
- 239000002888 zwitterionic surfactant Substances 0.000 claims abstract description 13
- 239000003093 cationic surfactant Substances 0.000 claims abstract description 11
- 150000001875 compounds Chemical class 0.000 claims abstract description 5
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 3
- 239000004615 ingredient Substances 0.000 claims description 18
- -1 dodecyl alanine Chemical compound 0.000 claims description 15
- 238000002156 mixing Methods 0.000 claims description 14
- JJWLVOIRVHMVIS-UHFFFAOYSA-N isopropylamine Chemical group CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 claims description 12
- 229920000570 polyether Polymers 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 12
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims description 10
- 235000004279 alanine Nutrition 0.000 claims description 8
- 238000002360 preparation method Methods 0.000 claims description 8
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 7
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical group [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 claims description 6
- CEYYIKYYFSTQRU-UHFFFAOYSA-M trimethyl(tetradecyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCC[N+](C)(C)C CEYYIKYYFSTQRU-UHFFFAOYSA-M 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 150000002191 fatty alcohols Chemical class 0.000 claims description 5
- 229910019142 PO4 Inorganic materials 0.000 claims description 4
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical group OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 4
- 238000005553 drilling Methods 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 4
- 239000008236 heating water Substances 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 4
- 239000010452 phosphate Substances 0.000 claims description 4
- 238000002604 ultrasonography Methods 0.000 claims description 3
- MPNXSZJPSVBLHP-UHFFFAOYSA-N 2-chloro-n-phenylpyridine-3-carboxamide Chemical compound ClC1=NC=CC=C1C(=O)NC1=CC=CC=C1 MPNXSZJPSVBLHP-UHFFFAOYSA-N 0.000 claims description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
- 239000006210 lotion Substances 0.000 claims description 2
- 230000003213 activating effect Effects 0.000 claims 1
- 229920002545 silicone oil Polymers 0.000 claims 1
- 229910000679 solder Inorganic materials 0.000 abstract description 7
- 239000000126 substance Substances 0.000 abstract description 5
- 230000007613 environmental effect Effects 0.000 abstract description 4
- 238000009413 insulation Methods 0.000 abstract description 4
- 239000000843 powder Substances 0.000 abstract description 3
- 239000006260 foam Substances 0.000 abstract description 2
- 238000010926 purge Methods 0.000 abstract description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 11
- 239000000203 mixture Substances 0.000 description 11
- 239000003921 oil Substances 0.000 description 11
- 235000019441 ethanol Nutrition 0.000 description 4
- 238000003466 welding Methods 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000004506 ultrasonic cleaning Methods 0.000 description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000000356 contaminant Substances 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- DDXLVDQZPFLQMZ-UHFFFAOYSA-M dodecyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)C DDXLVDQZPFLQMZ-UHFFFAOYSA-M 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- NECRQCBKTGZNMH-UHFFFAOYSA-N 3,5-dimethylhex-1-yn-3-ol Chemical compound CC(C)CC(C)(O)C#C NECRQCBKTGZNMH-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000005219 brazing Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- ZZVUWRFHKOJYTH-UHFFFAOYSA-N diphenhydramine Chemical compound C=1C=CC=CC=1C(OCCN(C)C)C1=CC=CC=C1 ZZVUWRFHKOJYTH-UHFFFAOYSA-N 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 229940031098 ethanolamine Drugs 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000005213 imbibition Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000010808 liquid waste Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
- C11D3/3738—Alkoxylated silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C11D2111/14—
-
- C11D2111/44—
-
- C11D2111/46—
Abstract
The present invention provides a kind of low volatilization high-performance water based cleaning agent and cleaning methods, are made of the raw material of following mass percent: surfactant 6% ~ 12%；Corrosion inhibiter 0% ~ 0.1%;Defoaming agent 0% ~ 0.05%；Surplus is deionized water；Surfactant is that nonionic surfactant, zwitterionic surfactant, Gemini nonionic surface active agent and cationic surfactant compound, and wherein nonionic surfactant and Gemini nonionic surface active agent account for the 50% ~ 69% of total weight；Zwitterionic surfactant accounts for the 10% ~ 25% of total weight；Cationic surfactant accounts for the 15% ~ 35% of total weight.Cleaning agent matching purge technique of the present invention can strongly remove the surface residue of colophony type scaling powder postwelding, and solder joint keeps bright, and surface insulation performance is good；Compared with conventional clean agent, the complete low volatility of the present invention, safety and environmental protection will not generate public hazards substance；Almost without foam generation in cleaning process, cleaning process is easy to operate.
Description
Technical field
The invention belongs to cleaning agent for electronic industry manufacturing field, it is related to a kind of low volatilization high-performance water based cleaning agent and clearly
Process is washed, is cleaned especially suitable for electronic component pin and its postwelding on surface.
Background technique
With the development of electronic industry, higher and higher to the requirement of Quality of electronic products.After the completion of welding, brazing flux residual
Object or other external contaminants not only influence product appearance, but also product reliability can be made to be deteriorated, and cause short circuit, corrosion etc.
Cause electric fault.
The cleaning agent of traditional ODS substance containing freon one kind has grease rosin and other resins clear well
Wash effect.But such cleaning agent contains the substance for destroying ozone layer, the in process of production improper use of halogen and its compound
Harm can be brought to staff's body and environment, with the raising of safety and environmental consciousness, ODS is gradually disabled.
Currently used halogen-free cleaning agent is mainly by alcohols, ketone, alkanes, and the low lightning such as lipid is low-boiling
Solvent composition, residue is less after cleaning but its higher cost for such cleaning agent, and toxic, inflammable and explosive, volatility is big, this
Outside, the alcohol of low-carbon class blushing can occur because of the surface that water imbibition is strong and occurs cleaning.
Nowadays the cleaning agent of domestic research and development is various in style, and " water base " bright spot the most can be divided into half water according to the content of water
Based cleaning agent and aqueous cleaning agent, wherein aqueous cleaning agent can also be divided into according to acid-base property alkaline cleaner, neutral cleaners,
Alkaline cleaner.It is able to satisfy cleaning requirement although being substantially all, on the one hand, kind of most of cleaning agents to solder and scaling powder
Class dependence is strong, and clean range is limited, and stability is poor, volatile and to human health.On the other hand, most of cleaning agents
Preparation method is cumbersome, and some need introduces other ancillary equipments, and the complicated component of cleaning agent, and butt welding point can generate corrosion,
A large amount of bubbles can be generated in cleaning process, be not used to full-automatic cleaning and ultrasonic cleaning.
Summary of the invention
The present invention is directed to the above-mentioned deficiency of the prior art, and the purpose of the present invention is to provide a kind of low volatilization is high-property water-based
Cleaning agent and cleaning process；The aqueous cleaning agent preparation method is simple, low volatility, highly-safe, cleaning effect in cleaning process
Fruit is preferable, will not corrode cleaned part etc..
To achieve the above object, the invention provides the following technical scheme: a kind of low volatilization high-performance water based cleaning agent, special
Sign is: it is made of the raw material of following mass percent:
Surfactant: 6% ~ 12%；
Corrosion inhibiter: 0% ~ 0. 1%;
Defoaming agent: 0% ~ 0.05%；
Surplus is deionized water；The sum of each Ingredients Weight is 100%.
Further feature is: the surfactant is nonionic surfactant, zwitterionic surfactant, double
Component nonionic surface active agent and cationic surfactant compound, wherein nonionic surfactant and Gemini
Nonionic surface active agent accounts for the 50% ~ 69% of total weight；Zwitterionic surfactant accounts for the 10% ~ 25% of total weight；Sun from
Sub- surfactant accounts for the 15% ~ 35% of total weight.
The nonionic surfactant is triethanolamine, fatty alcohol polyoxyethylene ether, polysorbas20, alkylphenol-polyethenoxy
Any one of 9 ethers or any two be each greater than 0% mass percent mix, or wantonly three kinds be each greater than 0% quality
It is mixed than mixing or four kinds with the mass percent for being each greater than 0%；
The zwitterionic surfactant is: dodecyl alanine, TX-10 phosphate (nonylphenol polyoxyethylene ether phosphorus
Acid esters) one or both of be each greater than 0% mass percent mixing,
The Gemini nonionic surface active agent is by any in Surfynol420, Surfynol440, Surfynol465
Kind or any two be each greater than 0% mass percent mixing or three kinds be each greater than 0% mass percent mixing；
The cationic surfactant is hexadecyltrimethylammonium chloride, tetradecyl trimethyl ammonium chloride, dodecyl
Any one of trimethyl ammonium chloride or any two mixed with the mass percent for being each greater than 0%, or wantonly three kinds with each arrogant
Mass ratio in 0% mixes.
The corrosion inhibiter is isopropylamine.
The defoaming agent is polyether modified silicon oil.
The aqueous cleaning agent is alkaline species cleaning agent, and PH is 9.5 ~ 11.5.
Mass percent between nonionic surfactant and Gemini nonionic surface active agent is 1:1.
The nonionic surfactant, Gemini nonionic surface active agent, zwitterionic surfactant and sun
The weight ratio of ionic surface active agent is 3:3:2:2.
A kind of preparation method of low volatilization high-performance water based cleaning agent, which comprises the following steps:
It is former that each ingredient is measured respectively according to ingredient contained by aqueous cleaning agent as claimed in claim 1 to 7 and content ratio
Material, with the method for heating water bath, maintains the temperature at 30 ± 5 DEG C, and deionized water is added in the reaction kettle with blender and opens
Begin stirring, then be separately added into surfactant, corrosion inhibiter and defoaming agent, continues stirring until and stop stirring and quiet after being thoroughly mixed
It sets.
A kind of low volatilization high-performance water based cleaning agent cleaning method, which comprises the steps of:
1) part to be cleaned is at 80 DEG C+35 ~ 50min is impregnated in 2 DEG C of water；
2) configured cleaning agent and part to be cleaned are placed in supersonic wave cleaning machine, adjustment is initially 60 DEG C -65 DEG C, ultrasound
25 ~ 40min is cleaned, selected ultrasonic drilling machine power is adjusted between 100 ~ 800W according to the size and number of cleaning part；
3) after completing step 2, cleaning part is placed in 5 ~ 8min of rinsing in 55 DEG C -65 DEG C of deionized water；
4) taking out after dry 2 h of 0.5h-of drying box that the cleaning part that rinsing is completed is placed in 75 DEG C -85 DEG C, cleaning is completed.
Compared with the existing technology, low volatilization high-performance water based cleaning agent of the invention and cleaning process have following beneficial
Effect:
1, the aqueous cleaning agent preparation method that the present invention obtains is simple, low in cost；
2, the aqueous cleaning agent that obtains of the present invention in the process of cleaning low bubble, low volatility, it is highly-safe, will not corrode it is cleaned
Part；
3, aqueous cleaning agent of the invention washes rear surface noresidue, and solder joint is bright, and surface insulation performance is good；
4, aqueous cleaning agent of the invention is suitable for automation cleaning and ultrasonic cleaning, cleaning effect are significant.
5, the postwelding that aqueous cleaning agent of the invention is suitable for various soft pricker solders cleans, and will not corrode solder joint.
Aqueous cleaning agent in the present invention is for current electronic component pin and its cleaning of the postwelding on surface, welding
The a large amount of residues and external contaminant generated in the process, corrosivity is big, influences appearance.Cleaning agent matching purge technique of the present invention
The surface residue of colophony type scaling powder postwelding can be strongly removed, solder joint keeps bright, and surface insulation performance is good；It is clear with tradition
Lotion is compared, and the complete low volatility of the present invention, safety and environmental protection will not generate public hazards substance.Its is at low cost, and preparation method letter
It is single, almost without foam generation in cleaning process, it is suitable for full-automatic cleaning and ultrasonic cleaning, cleaning process is easy to operate.
Specific embodiment
Below with reference to specific embodiment, the present invention is described in detail.
A kind of low volatilization high-performance water based cleaning agent, which is characterized in that be made of the raw material of following mass percent:
Surfactant: 6% ~ 12%；
Corrosion inhibiter: 0% ~ 0. 1%;
Defoaming agent: 0% ~ 0.05%；
Surplus is deionized water；The sum of each Ingredients Weight is 100%.
Further feature is: the surfactant is nonionic surfactant, zwitterionic surfactant, double
Component nonionic surface active agent and cationic surfactant compound, wherein nonionic surfactant and Gemini
Nonionic surface active agent accounts for the 50% ~ 69% of total weight；Zwitterionic surfactant accounts for the 10% ~ 25% of total weight；Sun from
Sub- surfactant accounts for the 15% ~ 35% of total weight.Between nonionic surfactant and Gemini nonionic surface active agent
To be each greater than 0% mass percent mixing, most preferably 1:1.
The nonionic surfactant is triethanolamine, fatty alcohol polyoxyethylene ether, polysorbas20, alkylphenol-polyethenoxy
Any one of 9 ethers or any two be each greater than 0% mass percent mix, or wantonly three kinds be each greater than 0% quality
It is mixed than mixing or four kinds with the mass percent for being each greater than 0%；
The zwitterionic surfactant is: dodecyl alanine, TX-10 phosphate (nonylphenol polyoxyethylene ether phosphorus
Acid esters) one or both of be each greater than 0% mass percent mixing,
The Gemini nonionic surface active agent is by any in Surfynol420, Surfynol440, Surfynol465
Kind or any two be each greater than 0% mass percent mixing or three kinds be each greater than 0% mass percent mixing.
Surfynol medicine series are US Air gasification chemical products, and Chinese name can be U.S.'s air 104, can also directly use this
English name.
The cationic surfactant is hexadecyltrimethylammonium chloride, tetradecyl trimethyl ammonium chloride, 12
Any one of alkyl trimethyl ammonium chloride or any two mixed with the mass percent for being each greater than 0%, or wantonly three kinds with each
It is mixed from the mass ratio greater than 0%.
The corrosion inhibiter is isopropylamine.
The defoaming agent is polyether modified silicon oil.
The aqueous cleaning agent is alkaline species cleaning agent, and PH is 9.5 ~ 11.5.
The nonionic surfactant, Gemini nonionic surface active agent, zwitterionic surfactant and sun
The weight ratio of ionic surface active agent is 3:3:2:2.
A kind of preparation method of low volatilization high-performance water based cleaning agent, which comprises the following steps:
It is former that each ingredient is measured respectively according to ingredient contained by aqueous cleaning agent as claimed in claim 1 to 7 and content ratio
Material, with the method for heating water bath, maintains the temperature at 30 ± 5 DEG C, and deionized water is added in the reaction kettle with blender and opens
Begin stirring, then be separately added into surfactant, corrosion inhibiter and defoaming agent, continues stirring until and stop stirring and quiet after being thoroughly mixed
It sets.
A kind of low volatilization high-performance water based cleaning agent cleaning method, which comprises the steps of:
1) part to be cleaned is at 80 DEG C+35 ~ 50min is impregnated in 2 DEG C of water；
2) configured cleaning agent and part to be cleaned are placed in supersonic wave cleaning machine, adjustment is initially 60 DEG C -65 DEG C, ultrasound
25 ~ 40min is cleaned, selected ultrasonic drilling machine power is adjusted between 100 ~ 800W according to the size and number of cleaning part；
3) after completing step 2, cleaning part is placed in 5 ~ 8min of rinsing in 55 DEG C -65 DEG C of deionized water；
4) taking out after dry 2 h of 0.5h-of drying box that the cleaning part that rinsing is completed is placed in 75 DEG C -85 DEG C, cleaning is completed.
Compared with the existing technology, low volatilization high-performance water based cleaning agent of the invention and cleaning process have following beneficial
Effect:
The corrosion inhibiter is isopropylamine；
The defoaming agent is polyether modified silicon oil.
The aqueous cleaning agent is alkaline species cleaning agent, and PH is 9.5 ~ 11.5.
Preferably, the nonionic surfactant, Gemini nonionic surface active agent, amphoteric ion surface-active
The weight ratio of agent and cationic surfactant is 3:3:2:2.
Surfactant of the invention, selectable specific mass percent are as follows: 6%, 6.5%, 7%, 7.5%, 8%,
8.5%, 9%, 9.5%, 10%, 10.5%, 11%, 11.5%, 12% etc., needs of the invention can be met；Corrosion inhibiter of the invention,
Selectable specific mass percent are as follows: 0%, 0.001%, 0.002%, 0.005%, 0.01%, 0.02%, 0.03%, 0.04%,
0.05%, 0.06%, 0.07%, 0.08%, 0.09%, 0.1% etc., needs of the invention can be met;Defoaming agent of the invention,
Selectable specific mass percent are as follows: 0%, 0.001%, 0.002%, 0.005%, 0.008%, 0.01%, 0.015%,
0.018%, 0.02%, 0.025%, 0.03%, 0.035%, 0.04%, 0.045%, 0.05% etc., needs of the invention can be met.Certain
When containing measurement zero of component, then it represents that do not use this component in this single proportion.
A kind of preparation method of low volatilization high-performance water based cleaning agent, according to contained by any aqueous cleaning agent in front
Ingredient and content ratio measure each component materials respectively, with the method for heating water bath, maintain the temperature at 30 ± 5 DEG C, in band
There is addition deionized water in the reaction kettle of blender to start to stir, then be separately added into surfactant, corrosion inhibiter and defoaming agent, holds
Continuous stirring stops stirring and standing to after being thoroughly mixed.
A kind of low volatilization high-performance water based cleaning agent cleaning method, which comprises the steps of:
1) part to be cleaned impregnates 35 ~ 50min in 80 DEG C ± 2 DEG C of constant temperature of water；
2) configured cleaning agent and part to be cleaned are put into reaction kettle, are placed in the ultrasonic wave that initial water temperature is 60 DEG C -65 DEG C
30 ~ 45min is cleaned in cleaning machine, selected ultrasonic drilling machine power can be adjusted between 100 ~ 800W according to the size and number of cleaning part
Section；
3) after completing step 2, cleaning part is placed in 5 ~ 8min of rinsing in 55 DEG C -65 DEG C of deionized water；
4) it has finally been cleaned being taken out after dry 2 h of 0.5h-of drying box that the cleaning part that rinsing is completed is placed in 75 DEG C -85 DEG C
At.
Case study on implementation 1
Low volatilization high-performance water based cleaning agent ingredient composition is as follows: its weight accounting 6% of surfactant, wherein polysorbas20:
Surfynol420: dodecyl alanine: hexadecyltrimethylammonium chloride=3:3:2:2, corrosion inhibiter 0.01% are isopropyl
Amine, defoaming agent 0.01% are polyether modified silicon oil, and surplus is deionized water.
Case study on implementation 2
Low volatilization high-performance water based cleaning agent ingredient composition is as follows: its weight accounting 7% of surfactant, wherein alkyl phenol polyoxy
9 ether of ethylene: Surfynol420: fatty alcohol polyoxyethylene ether: hexadecyltrimethylammonium chloride=3:3:2:2, corrosion inhibiter
0.02%, it is isopropylamine, defoaming agent 0.02% is polyether modified silicon oil, and surplus is deionized water.
Case study on implementation 3
Low volatilization high-performance water based cleaning agent ingredient composition is as follows: its weight accounting 9% of surfactant, wherein polysorbas20: three second
Hydramine: Surfyonl104:TX-10 phosphate: hexadecyltrimethylammonium chloride=2.5:2:2:1.5:2, corrosion inhibiter 0.05%,
For isopropylamine, defoaming agent 0.04% is polyether modified silicon oil, and surplus is deionized water.
Case study on implementation 4
Low volatilization high-performance water based cleaning agent ingredient composition is as follows: its weight accounting 8% of surfactant, wherein alkyl phenol polyoxy
9 ether of ethylene: polysorbas20: triethanolamine: dodecyl alanine: SurfyonlSE-F: tetradecyl trimethyl ammonium chloride=
15:10:25:25:10:15, corrosion inhibiter 0.02% are isopropylamine, and defoaming agent 0.025% is polyether modified silicon oil, and surplus is to go
Ionized water.
Case study on implementation 5
Low volatilization high-performance water based cleaning agent ingredient composition is as follows: its weight accounting 6.5% of surfactant, wherein polysorbas20: ten
Dialkyl amido propionic acid: tetradecyl trimethyl ammonium chloride: Surfyonl465=5:3:1:1, corrosion inhibiter 0.03% are isopropylamine,
Defoaming agent 0.035% is polyether modified silicon oil, and surplus is deionized water.
Case study on implementation 6
Low volatilization high-performance water based cleaning agent ingredient composition is as follows: its weight accounting 9.5% of surfactant, polysorbas20: three ethyl alcohol
Amine: dodecyl alanine: Surfyonl465: tetradecyl trimethyl ammonium chloride=22:20:24:18:16, corrosion inhibiter
0.06%, it is isopropylamine, defoaming agent 0.04% is polyether modified silicon oil, and surplus is deionized water.
Case study on implementation 7
Low volatilization high-performance water based cleaning agent ingredient composition is as follows: its weight accounting 10.5% of surfactant, wherein three ethyl alcohol
Amine: dodecyl alanine: Surfyonl465: dodecyl trimethyl ammonium chloride=4:3:1:2, corrosion inhibiter 0.08% are
Isopropylamine, defoaming agent 0.04% are polyether modified silicon oil, and surplus is deionized water.
Case study on implementation 8
Low volatilization high-performance water based cleaning agent ingredient composition is as follows: its weight accounting 10% of surfactant, wherein polysorbas20: three
Ethanol amine: fatty alcohol polyoxyethylene ether: dodecyl alanine: Surfyonl465: dodecyl trimethyl ammonium chloride=
20:15:16:23:11:15, corrosion inhibiter 0.09%, be isopropylamine, defoaming agent 0.04%, be polyether modified silicon oil, surplus be go from
Sub- water.
The cleaning agent being configured to using the above case study on implementation, the basic noresidue in surface after cleaning, solder joint is bright, beautiful,
Surface insulation performance is good, and butt welding point will not generate corrosion, wash rear waste liquid can directly when general liquid waste processing, and will not to work people
Member and the Nature generate harm, noresidue truly, the aqueous cleaning agent of safety and environmental protection.
Finally, it should be noted that technical side the above examples are only used to illustrate the technical scheme of the present invention and are not limiting
Case, although applicant describes the invention in detail referring to preferred embodiment, those skilled in the art should be managed
Solution, modification or equivalent replacement of the technical solution of the present invention are made for those, without departing from the objective and range of the technical program,
It is intended to be within the scope of the claims of the invention.
Claims (10)
1. a kind of low volatilization high-performance water based cleaning agent, it is characterised in that: be made of the raw material of following mass percent:
Surfactant: 6% ~ 12%；
Corrosion inhibiter: 0% ~ 0. 1%;
Defoaming agent: 0% ~ 0.05%；
Surplus is deionized water；The sum of each Ingredients Weight is 100%.
2. low volatilization high-performance water based cleaning agent according to claim 1, it is characterised in that: the surfactant is non-
Ionic surface active agent, zwitterionic surfactant, Gemini nonionic surface active agent and cationic surfactant
It compounds, wherein nonionic surfactant and Gemini nonionic surface active agent account for the 50% ~ 69% of total weight；Both sexes
Ionic surface active agent accounts for the 10% ~ 25% of total weight；Cationic surfactant accounts for the 15% ~ 35% of total weight.
3. low volatilization high-performance water based cleaning agent according to claim 2, it is characterised in that: the non-ionic surface active
Agent is triethanolamine, fatty alcohol polyoxyethylene ether, polysorbas20, any one of 9 ether of alkylphenol-polyethenoxy or any two with each
From the mass percent mixing greater than 0%, or wantonly three kinds, to be each greater than, 0% mass ratio is mixed or four kinds to be each greater than 0%
Mass percent mixing；
The zwitterionic surfactant is: dodecyl alanine, one or both of TX-10 phosphate is with respective
Mass percent mixing greater than 0%；
The Gemini nonionic surface active agent is by any in Surfynol420, Surfynol440, Surfynol465
Kind or any two be each greater than 0% mass percent mixing or three kinds be each greater than 0% mass percent mixing；
The cationic surfactant is hexadecyltrimethylammonium chloride, tetradecyl trimethyl ammonium chloride, dodecyl
Any one of trimethyl ammonium chloride or any two mixed with the mass percent for being each greater than 0%, or wantonly three kinds with each arrogant
Mass ratio in 0% mixes.
4. low volatilization high-performance water based cleaning agent according to claim 1, it is characterised in that: the corrosion inhibiter is isopropyl
Amine.
5. low volatilization high-performance water based cleaning agent according to claim 1, it is characterised in that: the defoaming agent changes for polyethers
Property silicone oil.
6. low volatilization high-performance water based cleaning agent ccording to any one of claims 1 to 5, it is characterised in that: described water base clear
Lotion is alkaline species cleaning agent, and PH is 9.5 ~ 11.5.
7. according to any low volatilization high-performance water based cleaning agent of claim 2-3, it is characterised in that: non-ionic surface
Mass percent between activating agent and Gemini nonionic surface active agent is 1:1.
8. according to any low volatilization high-performance water based cleaning agent of claim 2-3, it is characterised in that: the nonionic
Surfactant, Gemini nonionic surface active agent, zwitterionic surfactant and cationic surfactant weight
Amount is than being 3:3:2:2.
9. a kind of preparation method of low volatilization high-performance water based cleaning agent, which comprises the following steps:
It is former that each ingredient is measured respectively according to ingredient contained by aqueous cleaning agent as claimed in claim 1 to 7 and content ratio
Material, with the method for heating water bath, maintains the temperature at 30 ± 5 DEG C, and deionized water is added in the reaction kettle with blender and opens
Begin stirring, then be separately added into surfactant, corrosion inhibiter and defoaming agent, continues stirring until and stop stirring and quiet after being thoroughly mixed
It sets.
10. a kind of low volatilization high-performance water based cleaning agent cleaning method, which comprises the steps of:
1) part to be cleaned is at 80 DEG C+35 ~ 50min is impregnated in 2 DEG C of water；
2) configured cleaning agent and part to be cleaned are placed in supersonic wave cleaning machine, adjustment is initially 60 DEG C -65 DEG C, ultrasound
25 ~ 40min is cleaned, selected ultrasonic drilling machine power is adjusted between 100 ~ 800W according to the size and number of cleaning part；
3) after completing step 2, cleaning part is placed in 5 ~ 8min of rinsing in 55 DEG C -65 DEG C of deionized water；
4) taking out after dry 2 h of 0.5h-of drying box that the cleaning part that rinsing is completed is placed in 75 DEG C -85 DEG C, cleaning is completed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811549581.9A CN109370812B (en) | 2018-12-18 | 2018-12-18 | Low-volatility high-performance water-based cleaning agent and cleaning method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811549581.9A CN109370812B (en) | 2018-12-18 | 2018-12-18 | Low-volatility high-performance water-based cleaning agent and cleaning method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109370812A true CN109370812A (en) | 2019-02-22 |
| CN109370812B CN109370812B (en) | 2021-03-23 |
Family
ID=65374678
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811549581.9A Active CN109370812B (en) | 2018-12-18 | 2018-12-18 | Low-volatility high-performance water-based cleaning agent and cleaning method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109370812B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110471262A (en) * | 2019-08-28 | 2019-11-19 | 华璞微电子科技(宁波)有限公司 | A kind of colored filter developer composition |
| CN111234944A (en) * | 2020-03-04 | 2020-06-05 | 上海极标化工有限公司 | Neutral cleaning agent for train |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101921672A (en) * | 2009-06-10 | 2010-12-22 | 陆平 | Wool detergent |
| CN102816660A (en) * | 2012-09-11 | 2012-12-12 | 广东普赛特电子科技股份有限公司 | Nano water-based cleaning agent and preparing method thereof |
| CN106833993A (en) * | 2016-12-27 | 2017-06-13 | 东莞市先飞电子材料有限公司 | A kind of aqueous cleaning agent and preparation method thereof |
| CN107312662A (en) * | 2017-07-03 | 2017-11-03 | 中山翰华锡业有限公司 | A kind of scolding tin residue environment-friendlywater-based water-based cleaning agent and its preparation and application method |
-
2018
- 2018-12-18 CN CN201811549581.9A patent/CN109370812B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101921672A (en) * | 2009-06-10 | 2010-12-22 | 陆平 | Wool detergent |
| CN102816660A (en) * | 2012-09-11 | 2012-12-12 | 广东普赛特电子科技股份有限公司 | Nano water-based cleaning agent and preparing method thereof |
| CN106833993A (en) * | 2016-12-27 | 2017-06-13 | 东莞市先飞电子材料有限公司 | A kind of aqueous cleaning agent and preparation method thereof |
| CN107312662A (en) * | 2017-07-03 | 2017-11-03 | 中山翰华锡业有限公司 | A kind of scolding tin residue environment-friendlywater-based water-based cleaning agent and its preparation and application method |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110471262A (en) * | 2019-08-28 | 2019-11-19 | 华璞微电子科技(宁波)有限公司 | A kind of colored filter developer composition |
| CN111234944A (en) * | 2020-03-04 | 2020-06-05 | 上海极标化工有限公司 | Neutral cleaning agent for train |
Also Published As
| Publication number | Publication date |
|---|---|
| CN109370812B (en) | 2021-03-23 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109554716A (en) | A kind of solder aqueous cleaning agent and cleaning method | |
| CN105296177B (en) | A kind of multifunctional meter surface cleaning agent and preparation method thereof | |
| CN109370809A (en) | The low bubble high-efficiency water-base cleaning agent of one kind and cleaning method | |
| CN104263566B (en) | A kind of stain removal bactericidal multifunctional cleaning cream and preparation method thereof | |
| CN109370796A (en) | A kind of high-density packages aqueous cleaning agent and cleaning method | |
| CN109370808A (en) | A kind of soft type aqueous cleaning agent and cleaning method | |
| CN105331471A (en) | Environment-friendly neutral water-based cleaning agent, preparation method and application | |
| CN109370812A (en) | The low volatilization high-performance water based cleaning agent of one kind and cleaning method | |
| CN106148028A (en) | A kind of compositions with high-efficiency cleaning function | |
| CN106893642A (en) | A kind of aqueous cleaning agent and application thereof | |
| CN105950312B (en) | A kind of garden stuff pesticide residue cleaning agent and preparation method thereof | |
| CN107312662A (en) | A kind of scolding tin residue environment-friendlywater-based water-based cleaning agent and its preparation and application method | |
| CN109837145A (en) | A kind of aqueous fluxes in electronic industry cleaning agent and preparation method thereof | |
| CN109456850A (en) | A kind of alkalescent composite multifunction aqueous cleaning agent and cleaning method | |
| CN106753928A (en) | A kind of aqueous cleaning agent | |
| EP3511401A1 (en) | Multiuse, high-efficiency and environment-friendly cleaning solution and preparation method therefor | |
| CN104818160B (en) | A kind of kitchen duplicate removal finish and preparation method thereof | |
| CN108795592A (en) | A kind of aqua type industrial cleaning agent and preparation method thereof | |
| CN109370811A (en) | A kind of Electronic Assemblies aqueous cleaning agent and cleaning method | |
| CN109401859A (en) | A kind of colophony type scaling powder aqueous cleaning agent and cleaning method | |
| CN109055024A (en) | A kind of multi-functional cleaning solution | |
| CN108301008A (en) | A kind of high-efficiency environment friendly Degreasant composition and preparation method thereof and application method | |
| KR20100041898A (en) | Insulating detergent for electric machine | |
| JPH07109493A (en) | Detergent composition | |
| CN111979055A (en) | Preparation method of cleaning agent for hard and brittle material wafer |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20220623 Address after: 230000 room 091, 6 / F, building 1, Internet Industrial Park, 17 Huayuan Avenue, Baohe Economic Development Zone, Hefei City, Anhui Province Patentee after: Anhui keyiguo Network Technology Co.,Ltd. Address before: No. 69 lijiatuo Chongqing District of Banan City Road 400054 red Patentee before: Chongqing University of Technology Effective date of registration: 20220623 Address after: 245000 room 306, building 8, Ping'an yuan new village, Tunxi District, Huangshan City, Anhui Province Patentee after: He Ying Address before: 230000 room 091, 6 / F, building 1, Internet Industrial Park, 17 Huayuan Avenue, Baohe Economic Development Zone, Hefei City, Anhui Province Patentee before: Anhui keyiguo Network Technology Co.,Ltd. |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20230718 Address after: Room 217, No. 12 Science Research Road, Science City, High tech Industrial Development Zone, Guangzhou, Guangdong Province, 510700 Patentee after: Guangzhou Kai rock new Mstar Technology Ltd. Address before: 245000 room 306, building 8, Ping'an yuan new village, Tunxi District, Huangshan City, Anhui Province Patentee before: He Ying |