CN108795592A - A kind of aqua type industrial cleaning agent and preparation method thereof - Google Patents
A kind of aqua type industrial cleaning agent and preparation method thereof Download PDFInfo
- Publication number
- CN108795592A CN108795592A CN201810279657.4A CN201810279657A CN108795592A CN 108795592 A CN108795592 A CN 108795592A CN 201810279657 A CN201810279657 A CN 201810279657A CN 108795592 A CN108795592 A CN 108795592A
- Authority
- CN
- China
- Prior art keywords
- salt
- cleaning agent
- fatty acid
- methyl ester
- surfactant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0026—Low foaming or foam regulating compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/74—Carboxylates or sulfonates esters of polyoxyalkylene glycols
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
The present invention relates to a kind of aqua type industrial cleaning agents, it includes following component（By weight percentage）：N- acylamino acids anion surfactant 0.1 ~ 40%；Fatty acid methyl ester ethoxylate 0.1 ~ 20%；Alkyl glycosides 0.1% ~ 8%；Hydroxypropyl methyl cellulose 0.1% ~ 8%；Auxiliary agent 0.1 ~ 10%；Water 30 ~ 89%.The cleaning agent has the characteristics that formula is simple, safe to use, environmental-friendly, it is small to the irritation of skin, toxicity is low, biological degradability is good, with good stability in use and storage stability, while reducing sewage discharge, reducing environmental protection pressure, it can further promote traditional cleaning, improve cleaning quality.
Description
Technical field
The present invention relates to a kind of aqua type industrial cleaning agents and preparation method thereof, belong to industrial cleaning agent technology of preparing neck
Domain.
Background technology
Industry cleaning link is that the pollution layer or coating that body surface is formed by the effect of physics, chemistry or biology are referred to as
Dirt removes these pollutants or coating and so that it is restored the process of original surface situation and be known as cleaning.Industry cleaning link with it is various
Industrial activity is closely related, does not provide final product, but topical procedure, a technique in many industrial processes
Or special operations.In traditional industry, cleaning regards a simple process or common sense as by people, often not by people
The quality paid attention to, but cleaned determines the performance and quality of final products, especially in current high-tech industry, cleans skill
The effect of art is especially prominent.
The chemistry for being used for removing dirt or biological agent used on industry cleaning link is referred to as industrial cleaning agent.Industrial cleaning agent
It is broadly divided into non-water system industrial cleaning agent and water system industrial cleaning agent.
Non-water system industrial cleaning agent is exactly briefly industrial cleaning agent not soluble in water, that water cannot be added to use；Such as carbon
Hydrogen cleaning agent, white spirit substitute, trichloro ethylene substitute etc. belong to such.Traditional common solvent industry cleaning agent have with
Under several classes：Hydro carbons (petroleum-type)：Such as kerosene, diesel oil, gasoline, environmentally friendly agent for carbon hydrogen detergent；Chlorinated hydrocarbon：Such as trichloro ethylene, two
Chloromethanes and tetrachloro-ethylene etc.；Alkanes：Such as n-hexane, normal heptane；Fluorinated hydrocarbon：Such as freon；Brominated hydrocarbons：As just
N-Propyl Bromide (NPB) etc.；Alcohols：Such as ethyl alcohol, methanol；Ethers：Such as ether, petroleum ether；Ketone：Such as acetone, butanone；
Water system industrial cleaning agent is exactly briefly water-soluble, can be diluted with water the industrial cleaning agent used.Water system industry is clear
Lotion is mainly increased made of the compoundings such as various other chemical agents based on surfactant；Water system industrial cleaning agent is
It is widely used in plastic cement in industry cleaning link, optical glass lens, metal product（Copper, iron, aluminium, steel, zinc, alloy）Etc. a variety of materials it is clear
Wash the various greasy dirts in surface, spot, grease etc..
In recent years, some novel cleaning techniques and equipment gradually obtain development and application, as vacuum cleaned, plasma are clear
Wash, UV/ozone cleaning, laser cleaning, Dry ice cleaning etc. are shown up prominently, illustrate good effect and application prospect.Meanwhile
It also begins to be promoted along with the raising of industrial aggregate level, no clean technology, especially in electronics industry and precision machinery
Manufacture field, clean packaging technology can be such that element, silicon chip accomplishes " opening box to use "；The development of solid soldering flux makes circuit board
No clean technology is increasingly widespread；The processing of some precision metallics uses noresidue punching press or drawing oil, in conjunction with lower melanism work together
Processing oil is directly heated and is volatilized by sequence, and realization is free of cleaning, has been applied in shadow mask in colour picture tube production process.
With the continuous improvement of people's environmental consciousness and energy-saving and emission-reduction requirement, the requirement to cleaning product is also gradually increased,
Green multifunctional efficient cleaner starts to attract attention." green " of cleaning agent refers to the basic principle according to Green Chemistry, choosing
With nontoxic, harmless raw material, synthesizing can be biodegradable after the strong detergency of cleaning agent and use；" multi-functional " of cleaning agent
Good cleaning performance can be realized to different types of dirt by referring to it.Water is developed since the sixties in 20th century in the country
Based cleaning agent, kind is up to more than 200 kinds at present, but these cleaning agents can only be directed to a certain specific dirt or cleaning pair mostly
As.For example, by sodium nitrite, pull open powder, sodium tripolyphosphate, turkey red oil, isopropanol, triethanolamine, coco-nut oil fatty acid diethyl
The metal cleaner of alkylolamides, fatty alcohol polyoxyethylene ether, cellosolve, formaldehyde and water composition, in removal metal surface greasy dirt
Anti-rust action is played simultaneously, but its formula is complicated, cleaning object is single, and contain in being formulated and easily lead to body eutrophication
Phosphate builder and sensitization, causing toxicity formaldehyde；Octyl phenol polyoxyethylene ether, borax, sodium tripolyphosphate, sodium phosphate, sodium carbonate, second two
The metal cleaner of four sodium acetate of amine, triethanolamine, carboxymethyl cellulose, benzotriazole, urea and deionized water composition, it is right
The detergency of greasy dirt is up to 90% or more on the metal materials such as steel, copper and aluminium, but the formula of the cleaning agent is excessively complicated, wherein containing
Sodium tripolyphosphate, sodium phosphate etc. can also cause the pollution of environment.
Invention content
In view of the deficiencies in the prior art, the object of the present invention is to provide it is a kind of formula it is simple, safe to use efficiently,
Environmentally protective multifunctional water fundamental mode industrial cleaning agent substitutes the conventional cleans agent such as trichloro ethylene, dichloromethane, white spirit,
While sewage discharge, environmental protection pressure can be reduced, it can further upgrade traditional cleaning, improve cleaning quality.
The purpose of the present invention is by the mildness of N- acylamino acid anion surfactants, high biological degradability and fat
The high efficiency of fatty acid methyl esters alcohol ethoxylate surfactant combines, and provides that a kind of surface-active is excellent, biological degradability
The N- acylamino acid anion surfactants good, irritation is low, critical micelle concentration is small；The present invention also aims to carry
For the preparation method of the surfactant.
In order to achieve the above technical purposes, the present invention provides a kind of technical solutions：
A kind of aqua type industrial cleaning agent, including following mass percent component：
N- acylamino acids anion surfactant 0.1 ~ 40%；
Fatty acid methyl ester ethoxylate surfactant 0.1 ~ 20%；
Alkyl glycosides 0.1% ~ 8%；
Hydroxypropyl methyl cellulose 0.1% ~ 8%；
Auxiliary agent 0.1 ~ 10%；
Water 30 ~ 89%.
Technical scheme of the present invention,
Preferred scheme, including following mass percent component：N- acylamino acids anion surfactant 5 ~ 20%；Fat
Sour methyl ester ethoxylates surfactant 5 ~ 15%；Hydroxypropyl methyl cellulose 1% ~ 5%；Alkyl glycosides 2% ~ 5%；Auxiliary agent 2 ~
8%；Water 40 ~ 70%.
More preferably scheme, the N- acylamino acids anion surfactant and the fatty acid methyl ester ethoxylation
The mass ratio of object surfactant is（0.1~10）:1, more preferably（0.5~2）:1.
Preferred scheme, N- acylamino acid anion surfactants include lauroyl glutamate salt, lauroyl
Base glycinate, lauroyl sarcosine salt, lauroyl alanine salt, lauroyl lysine salt, myristoyl paddy ammonia
Hydrochlorate, myristoyl glycinate, myristoy sarcosine salt, myristoyl alanine salt, myristoyl rely ammonia
Hydrochlorate, cocoyl glutamate, cocoyl glycinate, cocoyl sarcosine salt, cocoyl alanine salt, cocounut oil
Acyl-lysine salt, palmityl glutamate, palmityl glycinate, palmitoyl sarcosine salt, the third ammonia of palmityl
Hydrochlorate, palmityl lysine salt, stearyl glutamate, stearyl glycinate, stearyl sarcosine salt, tristearin
At least one of acylalaninies salt, stearyl lysine salt.Preferred scheme, N- acylamino acid anionic surfaces are lived
Property agent is mainly the sodium salt of N- acylamino acids, sylvite etc..
Preferred scheme, fatty acid methyl ester ethoxylate surfactant include lauroyl aminocarbonyl propyl fatty acid methyl
Ester ethoxylate, cocamidopropyl propyl amide fatty acid methyl ester ethoxylate, dodecanamide propyl hydroxyl sulfo methyl ester second
At least one of oxygroup compound, cocamidopropyl propyl amide hydroxyl sulfo methyl ester ethoxylate.
More preferably scheme, product pH are 5 ~ 8.
The advantages of N- acyl amino hydrochlorates is by the mildness of amino acid surfactant, high biological degradability and nonionic
The high efficiency of surfactant combines, and can reach preferable interface performance using small amount.Can be used for cosmetics,
In the household chemicals such as detergent and industry cleaning link agent prescription.Its application method and other daily chemical products raw materials and industry are former
Expect similar.It or typical chelate surfactant class corrosion inhibiter, amido bond and carboxyl in molecular structure can be
Metal surface forms the chelating type absorption of five-membered ring structure, has inoxidizability, can be used as corrosion inhibiter and oil-soluble antirust agent, example
Such as N- acyl sarcosinates are added in gold plating solution, metal surface can be increased, are reduced damaged.
Fatty acid methyl ester ethoxylate is a kind of novel nonionic surfactant, physico-chemical parameter such as surface
Power, critical micelle concentration, wetting power, cloud point etc. are suitable with alcohol ether, but have some performances to be better than alcohol ether, very such as water-soluble speed
Soon, it is easy to be made into fluid product；Belong to low bubble product, antifoaming speed is fast, is easy to rinse, and is especially suitable for industry cleaning link；Grease is increased
Molten ability is strong, particularly suitable for hard surface cleaning；It is small to the irritation of skin, toxicity is low, irritation and alkyl glycosides or ammonia
Base acids surfactant is equal or slightly lower；Biological degradability is good, environmentally safe.
Aqua type industrial cleaning agent has the characteristics that easy to use and environmental-friendly, is a kind of liquid of colourless homogeneous transparent
Body, pH value have good stability in use and storage stability, wash rear noresidue close to neutrality.In addition, the product is free of phenol
And chlorine, it is harmless to the human body, destruction will not be generated to atmospheric ozone layer after volatilization.
In order to achieve the above technical purposes, include following mass percent component the present invention provides one kind：N- acyl group ammonia
Base acid anion surfactant 0.1 ~ 40%；Fatty acid methyl ester ethoxylate surfactant 0.1 ~ 20%；Alkyl glycosides
0.1%~8%；Hydroxypropyl methyl cellulose 0.1% ~ 8%；Auxiliary agent 0.1 ~ 10%；Water 30 ~ 89%.
Technical scheme of the present invention, the key component of rinse product be N- acylamino acids anion surfactant and
Fatty acid methyl ester ethoxylate nonionic surfactant, many experiments, which show that the two is used cooperatively, can make micellar aggregates behavior
It changes, viscoplasticity, the thixotropy that micelle volume viscosity can be made to increase, system can be remarkably reinforced improve network structure
Stability.Good shear shinning is all had to different ratio system, foam, which more enriches soft and smooth, careful exquisiteness, bullet
Property, and lather quickness is fast, assigns the good use feeling of product, avoids stimulation of the alkaline surfactant to skin.Together
When, alkyl glycosides is also introduced in formula, and alkyl glycosides not only plays its nonionic surfactant function, in addition also rises
To thickening power.On the one hand, consistency is moderate, and has extraordinary stability, on the other hand, reaction can in the process generated
Component is disperseed rapidly, the third aspect, alkyl glycosides utilize its special molecular structure, make it is intermolecular associated well, have
There is good thickening power and improve the resistant to shearing ability of system, makes the product being prepared that there is extraordinary stability.Its
Secondary, the hydroxypropyl methyl cellulose in formula makes production process become more light, easy, has the function of defoaming suds,
Product can be reduced and generate ice crystal during low temperature and freezing/heating, stable product viscosity can be still maintained after defrosting,
Hydroxypropyl methyl cellulose has ideal acid burdening compatibility, can be with acyl amino hydrochlorate, alkyl in cleaning agent formula
Various ingredients compatibility including glucosides etc. improves and enriches the performance of its product.
Preferred scheme, cleaning agent include following mass percent component：N- acylamino acids anion surfactant 5
~20%；Fatty acid methyl ester ethoxylate surfactant 5 ~ 15%；Hydroxypropyl methyl cellulose 1% ~ 5%；Alkyl glycosides 2% ~
5%；Auxiliary agent 2 ~ 8%；Water 40 ~ 70%.
More preferably scheme, the N- acylamino acids anion surfactant and the fatty acid methyl ester ethoxylation
The mass ratio of object surfactant is（0.1~10）:1, more it is selected as（0.5~2）:1.
Preferred scheme, N- acylamino acid anion surfactants include lauroyl glutamate salt, lauroyl
Base glycinate, lauroyl sarcosine salt, lauroyl alanine salt, lauroyl lysine salt, myristoyl paddy ammonia
Hydrochlorate, myristoyl glycinate, myristoy sarcosine salt, myristoyl alanine salt, myristoyl rely ammonia
Hydrochlorate, cocoyl glutamate, cocoyl glycinate, cocoyl sarcosine salt, cocoyl alanine salt, cocounut oil
Acyl-lysine salt, palmityl glutamate, palmityl glycinate, palmitoyl sarcosine salt, the third ammonia of palmityl
Hydrochlorate, palmityl lysine salt, stearyl glutamate, stearyl glycinate, stearyl sarcosine salt, tristearin
At least one of acylalaninies salt, stearyl lysine salt.Preferred scheme, N- acylamino acid anionic surfaces are lived
Property agent is mainly sodium salt, sylvite or triethanolamine salt of N- acylamino acids etc..
Preferred scheme, fatty acid methyl ester ethoxylate surfactant include lauroyl aminocarbonyl propyl fatty acid methyl
Ester ethoxylate, cocamidopropyl propyl amide fatty acid methyl ester ethoxylate, dodecanamide propyl hydroxyl sulfo methyl ester second
At least one of oxygroup compound, cocamidopropyl propyl amide hydroxyl sulfo methyl ester ethoxylate.
More preferably scheme, cleaning agent pH are 5 ~ 8.
The present invention also provides the systems of the aqua type cleaning agent of the anion surfactant of acylamino acid containing N-
Preparation Method, this method is that N- acyl amino acid surfactants are added in water, and after being warming up to 70 ~ 90 DEG C, fatty acid methyl is added
Ester alcohol ethoxylate surfactant, alkyl glycosides and hydroxypropyl methyl cellulose, constant temperature stir 20 ~ 40 minutes, it is cooled to 40 ~
50 DEG C, be added auxiliary agent, stir evenly, be down to room temperature to get.
The each component in product formula in technical solution of the present invention is conventional commercial product.
Compared with the prior art, the advantageous effects that technical scheme of the present invention is brought：
1）The cleaning agent of the present invention has height temperature stability, overcomes traditional industrial cleaning agent because being coagulated in low temperature
Gluey phenomenon, and easily there is metachromatism in high temperature, the defect that can not be used.
2）Synergistic function is apparent between the various surfactants of cleaning agent of the present invention, and cleaning capacity is obviously improved.
3）Low bubble is stablized during the cleaning agent use of the present invention, and foam characteristic is suppressed.
4）The cleaning agent pH partial neutrals of the present invention, and the surfactant used and other components are mild, low stimulation, peace
Quan Xinggao, and reduce irritation.
5）The cleaning agent of the present invention belongs to from thickened systems, low without in addition addition thickener, product cost.
6）The cleaning agent preparation method of the present invention is simple, raw material sources are wide, at low cost, meets demand of industrial production.
Specific implementation mode
Here is the non-limiting example of the cleaning agent of the present invention.These embodiments be only given in order to illustrate mesh
, it can not be interpreted as limitation of the invention, because without departing from the spirit and scope of the present invention, it can be to this
Invention carries out many changes.In these embodiments, unless stated otherwise, all concentration is all weight percent.
A kind of aqua type cleaning agent containing acyl amino acids surfactant, preparation method are as follows：
N- acyl amino acid surfactants are added in water, after being warming up to 70 ~ 90 DEG C, fatty acid methyl ester ethoxylate is added
Surfactant, alkyl glycosides and hydroxypropyl methyl cellulose, constant temperature stir 20 ~ 40 minutes, are cooled to 40 ~ 50 DEG C, addition helps
Agent stirs evenly, be down to room temperature to get.
Embodiment 1
Cleaning agent includes following mass percent component：N- sodium lauroyl glutamates surfactant 10%；Lauroyl amido third
Base fatty acid methyl ester ethoxylate surfactant 10%；Hydroxypropyl methyl cellulose 5%；Alkyl glycosides 5%；Auxiliary agent 2%；Water
68%。
It is in a liquid state under the formulation product normal temperature and pressure, pH 5.0 ~ 5.5, good fluidity, viscosity is smaller, and toxicity is low, volatility
It is weak, remain in material surface less after cleaning, detergency is up to 92%.
Embodiment 2
Cleaning agent includes following mass percent component：N- sodium lauroyl glutamates surfactant 15%；Lauroyl amido third
Base fatty acid methyl ester ethoxylate surfactant 10%；Hydroxypropyl methyl cellulose 5%；Alkyl glycosides 5%；Auxiliary agent 2%；Water
63%。
It is in a liquid state under the formulation product normal temperature and pressure, pH 5.0 ~ 5.5, good fluidity, viscosity is slightly higher compared with embodiment 1, toxicity
It is low, volatility is weak, remains in material surface less after cleaning, detergency is up to 94%.
Embodiment 3
Cleaning agent includes following mass percent component：N- cocounut oil acyl glycine potassium surfactant 10%；Cocamidopropyl
Fatty acid methyl ester ethoxylate surfactant 10%；Hydroxypropyl methyl cellulose 5%；Alkyl glycosides 5%；Auxiliary agent 2%；Water
68%。
It is in a liquid state under the formulation product normal temperature and pressure, pH 7.0 ~ 8.0, good fluidity, low temperature（0℃~5℃）Under the conditions of produce
Product are not precipitated, and viscosity is smaller, and toxicity is low, volatility is weak, remain in material surface less after cleaning, and detergency is up to 95%.
Embodiment 4
Cleaning agent includes following mass percent component：N- lauroyl glycine potassium surfactant 5%；N- nutmeg acyl paddy ammonia
Sour sodium 5%；Cocamidopropyl fatty acid methyl ester ethoxylate surfactant 10%；Hydroxypropyl methyl cellulose 5%；Alkane
Base glucosides 5%；Auxiliary agent 2%；Water 68%.
It is in a liquid state under the formulation product normal temperature and pressure, pH 6.0 ~ 7.0, good fluidity, low temperature（0℃~5℃）Under the conditions of produce
Product are not precipitated, and viscosity is smaller, and product is from thickening, and toxicity is low, volatility is weak, and less, decontamination is remained in material surface after cleaning
Power is up to 95%.
Embodiment 5
Cleaning agent includes following mass percent component：N- sodium lauroyl sarcosines surfactant 20%；Cocamidopropyl
Fatty acid methyl ester ethoxylate surfactant 10%；Hydroxypropyl methyl cellulose 5%；Alkyl glycosides 5%；Auxiliary agent 2%；Water
68%。
It is in a liquid state under the formulation product normal temperature and pressure, pH 7.0 ~ 8.0, good fluidity, low temperature（0℃~5℃）Under the conditions of produce
Product are not precipitated, and viscosity is smaller, and toxicity is low, volatility is weak, remain less, tool corrosion inhibition, decontamination after cleaning in material surface
Power is up to 96%.
Comparative example 1
Octyl phenol polyoxyethylene ether, borax, sodium tripolyphosphate, sodium phosphate, sodium carbonate, ethylenediaminetetraacetic acid sodium, triethanolamine, carboxylic
The metal cleaner of methylcellulose, benzotriazole, urea and deionized water composition, on the metal materials such as steel, copper and aluminium
For the detergency of greasy dirt up to 90%, the formula of the cleaning agent is excessively complicated, wherein the sodium tripolyphosphate contained, sodium phosphate etc. can also be made
At the pollution of environment.
Comparative example 2
By sodium nitrite, pull open powder, sodium tripolyphosphate, turkey red oil, isopropanol, triethanolamine, coco-nut oil fatty acid diethanol acyl
The metal cleaner of amine, fatty alcohol polyoxyethylene ether, cellosolve, formaldehyde and water composition, while removing metal surface greasy dirt
Anti-rust action is played, formula is complicated, cleaning object is single, and contains the phosphate builder for easily leading to body eutrophication in being formulated
With sensitization, causing toxicity formaldehyde, detergency 90%.
Following table is the performance comparison sheet of above-described embodiment and comparative example：
| Scheme | Irritation | Toxicity | Safety and environmental protection performance | Detergency（%） |
| Embodiment 1 | PH5.0 ~ 5.5, it is mild non-stimulated | It is nontoxic | Biological degradation rate 100%, safety and environmental protection | 92 |
| Embodiment 2 | PH5.0 ~ 5.5, it is mild non-stimulated | It is nontoxic | Biological degradation rate 100%, safety and environmental protection | 94 |
| Embodiment 3 | PH7.0 ~ 8.0, it is mild non-stimulated | It is nontoxic | Biological degradation rate 100%, safety and environmental protection | 95 |
| Embodiment 4 | PH6.0 ~ 7.0, it is mild non-stimulated | It is nontoxic | Biological degradation rate 100%, safety and environmental protection | 95 |
| Embodiment 5 | PH7.0 ~ 8.0, it is mild non-stimulated | It is nontoxic | Biological degradation rate 100%, safety and environmental protection | 96 |
| Comparative example 1 | It is irritant | It is toxic | It is phosphorous, body eutrophication is easily caused, environment is polluted | 90 |
| Comparative example 2 | It is irritant | It is toxic | Phosphorous and formaldehyde pollutes environment | 90 |
From table, it will be seen that cleaning agent cleaning capacity of the present invention is obviously improved, pH partial neutrals, and the surface used is lived
Property agent and other components are mild, and low stimulation is safe.
Claims (8)
1. a kind of aqua type industrial cleaning agent, which is characterized in that it includes following quality component：
N- acylamino acids anion surfactant 0.1 ~ 40%；
Fatty acid methyl ester ethoxylate surfactant 0.1 ~ 20%；
Alkyl glycosides 0.1% ~ 8%；
Hydroxypropyl methyl cellulose 0.1% ~ 8%；
Auxiliary agent 0.1 ~ 10%；
Water 30 ~ 89%.
2. a kind of aqua type industrial cleaning agent according to claim 1, which is characterized in that be made of following mass parts：
N- acylamino acids anion surfactant 5 ~ 20%；
Fatty acid methyl ester ethoxylate surfactant 5 ~ 15%；
Alkyl glycosides 2% ~ 5%；
Hydroxypropyl methyl cellulose 1% ~ 5%；
Auxiliary agent 2 ~ 8%；
Water 40 ~ 70%.
3. a kind of aqua type industrial cleaning agent according to claim 1, which is characterized in that N- acyl amino acid anion tables
Face activating agent and the mass ratio of the fatty acid methyl ester ethoxylate surfactant are（0.1~10）:1, more preferably（0.5
~2）:1.
4. a kind of aqua type industrial cleaning agent according to claim 1, which is characterized in that N- acylamino acids used are cloudy
Ionic surface active agent includes lauroyl glutamate, lauroyl glycinate, Hamposyl L salt, lauroyl alanine
Salt, lauroyl lysine salt, myristoyl glutamate, myristoyl glycine salt, myristoyl-N-methylaminoacetic acid salt, myristoyl
Alanine salt, myristoyl lysine salt, cocounut oil acyl glutamate, cocounut oil acyl glycinate, cocoyl sarcosine salt, cocounut oil acyl
Alanine salt, cocounut oil acyl lysine salt, palmityl glutamate, palmityl glycinate, palmitoyl sarcosine salt, palmityl third
Propylhomoserin salt, palmitoyllysines salt, stearoyl-glutamic acid salt, stearoylglycine salt, Hamposyl S salt, the third ammonia of stearoyl
It is one or more in hydrochlorate, stearoyl lysine salt.
5. a kind of aqua type industrial cleaning agent according to claim 1, which is characterized in that N- acylamino acids used are cloudy
Ionic surface active agent is the sodium salt of N- acylamino acids or the sylvite of N- acylamino acids.
6. a kind of aqua type industrial cleaning agent according to claim 1, which is characterized in that fatty acid methyl ester ethoxy used
Glycolylate surfactant includes lauroyl aminocarbonyl propyl fatty acid methyl ester ethoxylate, cocamidopropyl propyl amide fatty acid methyl ester
Ethoxylate, dodecanamide propyl hydroxyl sulfo methyl ester ethoxylate, cocamidopropyl propyl amide hydroxyl sulfo-fatty acid first
It is one or more in ester ethoxylate.
7. a kind of aqua type industrial cleaning agent according to claim 1, which is characterized in that its pH value is maintained at 5 ~ 8.
8. the preparation method of above-mentioned aqua type cleaning agent, which is characterized in that N- acyl amino acid anion tables are first added in water
After being warming up to 70 ~ 90 DEG C, fatty acid methyl ester ethoxylate surfactant, alkyl glycosides and hydroxypropyl is added in face activating agent
Methylcellulose, constant temperature stir 20 ~ 40 minutes, are cooled to 40 ~ 50 DEG C, and auxiliary agent is added, stirs evenly, is down to room temperature.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2017107267854 | 2017-08-23 | ||
| CN201710726785 | 2017-08-23 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108795592A true CN108795592A (en) | 2018-11-13 |
Family
ID=64094733
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810279657.4A Pending CN108795592A (en) | 2017-08-23 | 2018-04-01 | A kind of aqua type industrial cleaning agent and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108795592A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110638679A (en) * | 2019-10-29 | 2020-01-03 | 广州市娇兰化妆品有限公司 | Amino acid cleansing cream compounded by amino acid potassium salt and amino acid sodium salt and preparation method thereof |
| CN111101231A (en) * | 2019-12-27 | 2020-05-05 | 宁夏宁东泰和新材有限公司 | Spandex easy to degrade and preparation method thereof |
| CN111909802A (en) * | 2020-09-14 | 2020-11-10 | 上海毅诺生物科技有限公司 | Alkaline multi-surface cleaning agent |
| CN114806527A (en) * | 2022-05-07 | 2022-07-29 | 大庆瑞雪石油科技开发有限公司 | Nonylphenol polyoxyethylene ether sodium oxalate ternary viscous micelle dirt degrading agent |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1121107A (en) * | 1994-09-20 | 1996-04-24 | 花王株式会社 | Aqueous liquid cleansing composition |
| CN103045401A (en) * | 2013-01-19 | 2013-04-17 | 重庆暄洁环保产业（集团）股份有限公司 | Water-base oil dirt cleaning agent and preparation method thereof |
| CN103966035A (en) * | 2013-01-30 | 2014-08-06 | 石家庄菠莉亚日用化工有限公司 | Environment-friendly water-saving super-concentrated cleaning agent and preparation method thereof |
-
2018
- 2018-04-01 CN CN201810279657.4A patent/CN108795592A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1121107A (en) * | 1994-09-20 | 1996-04-24 | 花王株式会社 | Aqueous liquid cleansing composition |
| CN103045401A (en) * | 2013-01-19 | 2013-04-17 | 重庆暄洁环保产业（集团）股份有限公司 | Water-base oil dirt cleaning agent and preparation method thereof |
| CN103966035A (en) * | 2013-01-30 | 2014-08-06 | 石家庄菠莉亚日用化工有限公司 | Environment-friendly water-saving super-concentrated cleaning agent and preparation method thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110638679A (en) * | 2019-10-29 | 2020-01-03 | 广州市娇兰化妆品有限公司 | Amino acid cleansing cream compounded by amino acid potassium salt and amino acid sodium salt and preparation method thereof |
| CN110638679B (en) * | 2019-10-29 | 2022-08-16 | 广州市娇兰化妆品有限公司 | Amino acid cleansing cream compounded by amino acid potassium salt and amino acid sodium salt and preparation method thereof |
| CN111101231A (en) * | 2019-12-27 | 2020-05-05 | 宁夏宁东泰和新材有限公司 | Spandex easy to degrade and preparation method thereof |
| CN111909802A (en) * | 2020-09-14 | 2020-11-10 | 上海毅诺生物科技有限公司 | Alkaline multi-surface cleaning agent |
| CN114806527A (en) * | 2022-05-07 | 2022-07-29 | 大庆瑞雪石油科技开发有限公司 | Nonylphenol polyoxyethylene ether sodium oxalate ternary viscous micelle dirt degrading agent |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108795592A (en) | A kind of aqua type industrial cleaning agent and preparation method thereof | |
| CN105331471B (en) | Environmentally protective neutrality aqueous cleaning agent and preparation method and application | |
| CN100497571C (en) | Solar energy silicon crystal chip cleaning agent | |
| CN109628947A (en) | A kind of environment-friendly type neutral cleaners and the preparation method and application thereof | |
| CN105040013A (en) | Environment-friendly and efficient cleaning process for metal parts | |
| CN105567459B (en) | A kind of green alkaline cleaning solution and preparation method | |
| CN109576084A (en) | A kind of glass cleaner of cover-plate glass and preparation method thereof | |
| CN106048632A (en) | Neutral non-phosphorus degreasing agent and preparation method thereof | |
| CN105297042A (en) | Metal material cleaning agent and use method thereof | |
| CN103469237A (en) | Metal oil contamination cleaner | |
| CN103668258A (en) | Surface treating agent for copper and copper alloys | |
| CN105297044B (en) | A kind of aqueous stainless steel cleaner | |
| CN104593791A (en) | Cleaning solution for high-zinc copper alloy cold-rolled pipes | |
| CN109267076A (en) | A kind of alkaline defatting agent and method improving titanium tube surface hydrophilicity | |
| CN111549351B (en) | High-cleaning-ability environment-friendly metal surface oil stain cleaning agent and preparation method thereof | |
| CA3129654C (en) | High foaming liquid alkaline cleaner concentrate composition | |
| CN1339578A (en) | Cleaning agent for metal equipment | |
| CN108301008A (en) | A kind of high-efficiency environment friendly Degreasant composition and preparation method thereof and application method | |
| CN104804881A (en) | Cleaning liquid for display screen of computer | |
| CN108641826A (en) | A kind of turbine greasy filth scavenger and turbine flushing liquor | |
| CN115197786A (en) | Scrubbing-free vehicle cleaning liquid and preparation method thereof | |
| CN112574831A (en) | Synthetic method of environment-friendly industrial cleaning agent | |
| CN106318670A (en) | Water-reducible cleaning agent for integrated circuit board scaling powder | |
| JPH0226670B2 (en) | ||
| CN111979058A (en) | Special cleaning agent for aviation operation |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20181113 |
|
| WD01 | Invention patent application deemed withdrawn after publication |