CN109370330A - A kind of environmental friendly, anti-corrosive antibacterial interior wall negative ion paint and preparation method thereof - Google Patents
A kind of environmental friendly, anti-corrosive antibacterial interior wall negative ion paint and preparation method thereof Download PDFInfo
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- CN109370330A CN109370330A CN201811310308.0A CN201811310308A CN109370330A CN 109370330 A CN109370330 A CN 109370330A CN 201811310308 A CN201811310308 A CN 201811310308A CN 109370330 A CN109370330 A CN 109370330A
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- interior wall
- negative ion
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D129/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Coating compositions based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Coating compositions based on derivatives of such polymers
- C09D129/02—Homopolymers or copolymers of unsaturated alcohols
- C09D129/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Abstract
The invention discloses a kind of environmental friendly, anti-corrosive antibacterial interior wall negative ion paints of interior wall coating technical field, the coating includes following ingredient: 200-250 parts of polyvinyl alcohol, 150-200 parts of active zeolite powder, 230-260 parts of nano-sized filler, 20-40 parts of preservative, 25-50 parts of mould inhibitor, 80-160 parts of anion part, 50-80 parts of titanium dioxide, 30-65 parts of pigment, 10-20 parts of curing agent, 10-15 parts of thickener, 15-30 parts of film forming agent, 5-10 parts of defoaming agent, 300-500 parts of water, the present invention can launch the anion beneficial to human body, remove the harmful substances such as formaldehyde, improve room air, simultaneously to Escherichia coli, staphylococcus aureus and Mycophyta have good antibacterial action, the quick and sustained release period is long , the growth and breeding of bacterium are effectively prevented, and kill the various bacteriums bred out.
Description
Technical field
The present invention relates to interior wall coating technical field, specially a kind of environmental friendly, anti-corrosive antibacterial interior wall negative ion paint and its
Preparation method.
Background technique
With the development of society, continuous improvement of people's living standards, the requirement that people guarantee the quality to the epipodium of life
Higher and higher, consumer is also increasingly enhanced the house ornamentation consciousness of health, environmental protection.
In use, metope is easy the shadow by Escherichia coli, staphylococcus aureus and Mycophyta to existing coating
It rings and mildew occurs, issue niff, environmental-protecting performance is poor, and long-time service brings lasting harm to the body of people how
The coating that effective antibacterial can be manufactured is the necessary stage in the paint development stage, for this purpose, it is proposed that a kind of environment-friendly type is anti-
Rotten antibacterial interior wall negative ion paint and preparation method thereof.
Summary of the invention
The purpose of the present invention is to provide a kind of environmental friendly, anti-corrosive antibacterial interior wall negative ion paints and preparation method thereof, with solution
Certainly the problems mentioned above in the background art.
To achieve the above object, the invention provides the following technical scheme: a kind of environmental friendly, anti-corrosive antibacterial interior wall anion applies
Material, which includes following ingredient: 200-250 parts of polyvinyl alcohol, 150-200 parts of active zeolite powder, nano-sized filler 230-
260 parts, 20-40 parts of preservative, 25-50 parts of mould inhibitor, 80-160 parts of anion part, 50-80 parts of titanium dioxide, 30-65 parts of pigment,
10-20 parts of curing agent, 10-15 parts of thickener, 15-30 parts of film forming agent, 5-10 parts of defoaming agent, 300-500 parts of water.
Preferably, a kind of environmental friendly, anti-corrosive antibacterial interior wall negative ion paint preparation method, this method comprises the following steps:
S1: preparation A mixed solution: selection 200 parts of polyvinyl alcohol, 150 parts of active zeolite powder, 230 and of nano-sized filler first
300 parts of water, then the raw material of selection is poured into blender and is stirred mixing, blender revolving speed is 1500 revs/min, stirring
Time is 10 minutes, obtains A mixed solution;
S2: preparation B mixed solution: selection 20 parts of preservative, 25 parts of mould inhibitor, 80 parts of anion part, 50 parts of titanium dioxide, face first
30 parts of material, 10 parts of curing agent, 15 parts of film forming agent, 5 parts of defoaming agent and 100 parts of water, then pour into the raw material of selection in dispersion machine,
The degree that turns of dispersion machine is set as 2000 revs/min, and jitter time is 15 minutes, obtains B mixed solution;
S3: it prepares coating: the B mixed solution obtained in S2 being poured into the blender in S1, is mixed again with A mixed solution
It closes, pours into 10 parts of thickener into blender at this time, and by the rotational speed regulation of blender to 2000-3000 revs/min, when stirring
Between be 15-20 minutes;
S4: examine coating: after step S3, whether the viscosity that detection prepares coating is qualified.
Preferably, the preparation of active zeolite powder be first by active zeolite particle in 80 degrees Celsius of 60- of water, with
One or more of mixing of antibacterial metal salts carry out ion exchanges, after the reaction was completed, then drying, pulverize, and activate boiling
Stone powder partial size is 0.1-10 microns.
Preferably, nano-sized filler is one of titanium oxide, precipitated calcium carbonate and kaolin or in which a variety of.
Preferably, preservative is by isothiazolinone derivatives, benzimidazole esters, Dao Weixier -75,1,2- benzisoxa
The compounding intermixture of thiazoline -3- ketone composition.
Preferably, for titanium dioxide particle diameter at 3-8 microns, water is pure water or deionized water.
Compared with prior art, the beneficial effects of the present invention are: the present invention can launch the anion beneficial to human body,
The harmful substances such as formaldehyde are removed, improve room air, while having to Escherichia coli, staphylococcus aureus and Mycophyta good
Antibacterial action, the quick and sustained release period is long, effectively prevents the growth and breeding of bacterium, and kills and breed out various thin
Bacterium.
Specific embodiment
Below in conjunction with the embodiment of the present invention, technical scheme in the embodiment of the invention is clearly and completely described,
Obviously, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based in the present invention
Embodiment, every other embodiment obtained by those of ordinary skill in the art without making creative efforts, all
Belong to the scope of protection of the invention.
Embodiment 1
A kind of environmental friendly, anti-corrosive antibacterial interior wall negative ion paint, the coating include following ingredient: 200 parts of polyvinyl alcohol, activation boiling
150 parts of stone powder, 230 parts of nano-sized filler, 20 parts of preservative, 25 parts of mould inhibitor, 80 parts of anion part, 50 parts of titanium dioxide, face
Expect 30 parts, 10 parts of curing agent, 10 parts of thickener, 15 parts of film forming agent, 5 parts of defoaming agent, 300 parts of water;
A kind of environmental friendly, anti-corrosive antibacterial interior wall negative ion paint preparation method, this method comprises the following steps:
S1: preparation A mixed solution: selection 200 parts of polyvinyl alcohol, 150 parts of active zeolite powder, 230 and of nano-sized filler first
200 parts of water, then the raw material of selection is poured into blender and is stirred mixing, blender revolving speed is 1500 revs/min, stirring
Time is 10 minutes, obtains A mixed solution;
S2: preparation B mixed solution: selection 20 parts of preservative, 25 parts of mould inhibitor, 80 parts of anion part, 50 parts of titanium dioxide, face first
30 parts of material, 10 parts of curing agent, 15 parts of film forming agent, 5 parts of defoaming agent and 100 parts of water, then pour into the raw material of selection in dispersion machine,
The degree that turns of dispersion machine is set as 2000 revs/min, and jitter time is 15 minutes, obtains B mixed solution, is effectively prevented bacterium
It breeds and breeds, and kill the various bacteriums bred out, while launching the anion beneficial to human body, purify air;
S3: it prepares coating: the B mixed solution obtained in S2 being poured into the blender in S1, is mixed again with A mixed solution
It closes, pours into 10 parts of thickener into blender at this time, and by the rotational speed regulation of blender to 2000-3000 revs/min, when stirring
Between be 15-20 minutes, convenient for adequately mixing raw material, improve the uniformity of mixed solution, metope avoided mildew occur;
S4: examine coating: after step S3, whether the viscosity that detection prepares coating is qualified;
The preparation of active zeolite powder is first by active zeolite particle in 80 degrees Celsius of 60- of water, with antibacterial metal salts
One or more mixing carries out ion exchanges, after the reaction was completed, then drying, pulverizes, and active zeolite powder diameter is
0.1-10 microns, active zeolite powder is added in interior wall coating with 0.5%-10% (weight) and is mixed, and becomes antibiotic paint, to big
Enterobacteria, staphylococcus aureus and Mycophyta have good antibacterial action, and the quick and sustained release period is long;
Nano-sized filler is one of titanium oxide, precipitated calcium carbonate and kaolin or in which a variety of, and preservative is by isothiazole
The compounding intermixture that quinoline ketone derivatives, benzimidazole esters, Dao Weixier -75,1,2-benzisothiazolin-3-one form, titanium
For white powder particle diameter at 3-8 microns, water is pure water or deionized water, effectively improves the wear-resisting and corrosion resistance of the coating;
Embodiment 2
A kind of environmental friendly, anti-corrosive antibacterial interior wall negative ion paint, the coating include following ingredient: 230 parts of polyvinyl alcohol, activation boiling
200 parts of stone powder, 245 parts of nano-sized filler, 30 parts of preservative, 35 parts of mould inhibitor, 120 parts of anion part, 65 parts of titanium dioxide, face
Expect 50 parts, 15 parts of curing agent, 13 parts of thickener, 23 parts of film forming agent, 7 parts of defoaming agent, 400 parts of water;
A kind of environmental friendly, anti-corrosive antibacterial interior wall negative ion paint preparation method, this method comprises the following steps:
S1: preparation A mixed solution: selection 230 parts of polyvinyl alcohol, 200 parts of active zeolite powder, 245 and of nano-sized filler first
270 parts of water, then the raw material of selection is poured into blender and is stirred mixing, blender revolving speed is 1500 revs/min, stirring
Time is 10 minutes, obtains A mixed solution;
S2: preparation B mixed solution: first selection 30 parts of preservative, 35 parts of mould inhibitor, 120 parts of anion part, 65 parts of titanium dioxide,
50 parts of pigment, 15 parts of curing agent, 23 parts of film forming agent, 7 parts of defoaming agent and 130 parts of water, then pour into dispersion machine for the raw material of selection
In, the degree that turns of dispersion machine is set as 2000 revs/min, and jitter time is 15 minutes, obtains B mixed solution, is effectively prevented thin
The growth and breeding of bacterium, and the various bacteriums bred out are killed, while launching the anion beneficial to human body, purify air;
S3: it prepares coating: the B mixed solution obtained in S2 being poured into the blender in S1, is mixed again with A mixed solution
It closes, pours into 10 parts of thickener into blender at this time, and by the rotational speed regulation of blender to 2000-3000 revs/min, when stirring
Between be 15-20 minutes, convenient for adequately mixing raw material, improve the uniformity of mixed solution, metope avoided mildew occur;
S4: examine coating: after step S3, whether the viscosity that detection prepares coating is qualified;
The preparation of active zeolite powder is first by active zeolite particle in 80 degrees Celsius of 60- of water, with antibacterial metal salts
One or more mixing carries out ion exchanges, after the reaction was completed, then drying, pulverizes, and active zeolite powder diameter is
0.1-10 microns, active zeolite powder is added in interior wall coating with 0.5%-10% (weight) and is mixed, and becomes antibiotic paint, to big
Enterobacteria, staphylococcus aureus and Mycophyta have good antibacterial action, and the quick and sustained release period is long;
Nano-sized filler is one of titanium oxide, precipitated calcium carbonate and kaolin or in which a variety of, and preservative is by isothiazole
The compounding intermixture that quinoline ketone derivatives, benzimidazole esters, Dao Weixier -75,1,2-benzisothiazolin-3-one form, titanium
For white powder particle diameter at 3-8 microns, water is pure water or deionized water, effectively improves the wear-resisting and corrosion resistance of the coating;
Embodiment 3
A kind of environmental friendly, anti-corrosive antibacterial interior wall negative ion paint, the coating include following ingredient: 250 parts of polyvinyl alcohol, activation boiling
200 parts of stone powder, 260 parts of nano-sized filler, 40 parts of preservative, 50 parts of mould inhibitor, 160 parts of anion part, 80 parts of titanium dioxide, face
Expect 65 parts, 20 parts of curing agent, 15 parts of thickener, 30 parts of film forming agent, 10 parts of defoaming agent, 500 parts of water;
A kind of environmental friendly, anti-corrosive antibacterial interior wall negative ion paint preparation method, this method comprises the following steps:
S1: preparation A mixed solution: selection 250 parts of polyvinyl alcohol, 200 parts of active zeolite powder, 260 and of nano-sized filler first
350 parts of water, then the raw material of selection is poured into blender and is stirred mixing, blender revolving speed is 1500 revs/min, stirring
Time is 10 minutes, obtains A mixed solution;
S2: preparation B mixed solution: first selection 40 parts of preservative, 50 parts of mould inhibitor, 160 parts of anion part, 80 parts of titanium dioxide,
65 parts of pigment, 20 parts of curing agent, 30 parts of film forming agent, 10 parts of defoaming agent and 150 parts of water, then pour into dispersion machine for the raw material of selection
In, the degree that turns of dispersion machine is set as 2000 revs/min, and jitter time is 15 minutes, obtains B mixed solution, is effectively prevented thin
The growth and breeding of bacterium, and the various bacteriums bred out are killed, while launching the anion beneficial to human body, purify air;
S3: it prepares coating: the B mixed solution obtained in S2 being poured into the blender in S1, is mixed again with A mixed solution
It closes, pours into 10 parts of thickener into blender at this time, and by the rotational speed regulation of blender to 2000-3000 revs/min, when stirring
Between be 15-20 minutes, convenient for adequately mixing raw material, improve the uniformity of mixed solution, metope avoided mildew occur;
S4: examine coating: after step S3, whether the viscosity that detection prepares coating is qualified;
The preparation of active zeolite powder is first by active zeolite particle in 80 degrees Celsius of 60- of water, with antibacterial metal salts
One or more mixing carries out ion exchanges, after the reaction was completed, then drying, pulverizes, and active zeolite powder diameter is
0.1-10 microns, active zeolite powder is added in interior wall coating with 0.5%-10% (weight) and is mixed, and becomes antibiotic paint, to big
Enterobacteria, staphylococcus aureus and Mycophyta have good antibacterial action, and the quick and sustained release period is long;
Nano-sized filler is one of titanium oxide, precipitated calcium carbonate and kaolin or in which a variety of, and preservative is by isothiazole
The compounding intermixture that quinoline ketone derivatives, benzimidazole esters, Dao Weixier -75,1,2-benzisothiazolin-3-one form, titanium
For white powder particle diameter at 3-8 microns, water is pure water or deionized water, effectively improves the wear-resisting and corrosion resistance of the coating.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding
And modification, the scope of the present invention is defined by the appended.
Claims (6)
1. a kind of environmental friendly, anti-corrosive antibacterial interior wall negative ion paint, it is characterised in that: the coating includes following ingredient: polyvinyl alcohol
200-250 parts, 150-200 parts of active zeolite powder, 230-260 parts of nano-sized filler, 20-40 parts of preservative, mould inhibitor 25-50
Part, 80-160 parts of anion part, 50-80 parts of titanium dioxide, 30-65 parts of pigment, 10-20 parts of curing agent, 10-15 parts of thickener, at
15-30 parts of film, 5-10 parts of defoaming agent, 300-500 parts of water.
2. a kind of environmental friendly, anti-corrosive antibacterial interior wall negative ion paint preparation method, it is characterised in that: this method comprises the following steps:
S1: preparation A mixed solution: selection 200 parts of polyvinyl alcohol, 150 parts of active zeolite powder, 230 and of nano-sized filler first
300 parts of water, then the raw material of selection is poured into blender and is stirred mixing, blender revolving speed is 1500 revs/min, stirring
Time is 10 minutes, obtains A mixed solution;
S2: preparation B mixed solution: selection 20 parts of preservative, 25 parts of mould inhibitor, 80 parts of anion part, 50 parts of titanium dioxide, face first
30 parts of material, 10 parts of curing agent, 15 parts of film forming agent, 5 parts of defoaming agent and 100 parts of water, then pour into the raw material of selection in dispersion machine,
The degree that turns of dispersion machine is set as 2000 revs/min, and jitter time is 15 minutes, obtains B mixed solution;
S3: it prepares coating: the B mixed solution obtained in S2 being poured into the blender in S1, is mixed again with A mixed solution
It closes, pours into 10 parts of thickener into blender at this time, and by the rotational speed regulation of blender to 2000-3000 revs/min, when stirring
Between be 15-20 minutes;
S4: examine coating: after step S3, whether the viscosity that detection prepares coating is qualified.
3. a kind of environmental friendly, anti-corrosive antibacterial interior wall negative ion paint according to claim 1, it is characterised in that: active zeolite
The preparation of powder is to mix first by active zeolite particle in 80 degrees Celsius of 60- of water with the one or more of antibacterial metal salts
It closes and carries out ion exchange, after the reaction was completed, then drying, pulverize, and active zeolite powder diameter is 0.1-10 microns.
4. a kind of environmental friendly, anti-corrosive antibacterial interior wall negative ion paint according to claim 1, it is characterised in that: nanoscale is filled out
Material is one of titanium oxide, precipitated calcium carbonate and kaolin or in which a variety of.
5. a kind of environmental friendly, anti-corrosive antibacterial interior wall negative ion paint according to claim 1, it is characterised in that: preservative is
It is mixed by the compounding that isothiazolinone derivatives, benzimidazole esters, Dao Weixier -75,1,2-benzisothiazolin-3-one form
Mixture.
6. a kind of environmental friendly, anti-corrosive antibacterial interior wall negative ion paint according to claim 1, it is characterised in that: titanium dioxide
For grain diameter at 3-8 microns, water is pure water or deionized water.
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CN201811310308.0A CN109370330A (en) | 2018-11-06 | 2018-11-06 | A kind of environmental friendly, anti-corrosive antibacterial interior wall negative ion paint and preparation method thereof |
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CN201811310308.0A CN109370330A (en) | 2018-11-06 | 2018-11-06 | A kind of environmental friendly, anti-corrosive antibacterial interior wall negative ion paint and preparation method thereof |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111363426A (en) * | 2020-05-11 | 2020-07-03 | 江西清大高端技术服务有限公司 | Efficient and environment-friendly negative oxygen ion concentrated solution and preparation method thereof |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1424366A (en) * | 2001-12-11 | 2003-06-18 | 中国科学院光电技术研究所 | Internal-wall coating and preparation thereof |
CN103351746A (en) * | 2013-06-21 | 2013-10-16 | 天长市开林化工有限公司 | Preparation method of antibacterial environmentally-friendly interior wall coating |
CN107936660A (en) * | 2017-11-10 | 2018-04-20 | 清远市思晴新材料科技有限公司 | A kind of environmental friendly, anti-corrosive antibacterial interior wall negative ion paint |
-
2018
- 2018-11-06 CN CN201811310308.0A patent/CN109370330A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1424366A (en) * | 2001-12-11 | 2003-06-18 | 中国科学院光电技术研究所 | Internal-wall coating and preparation thereof |
CN103351746A (en) * | 2013-06-21 | 2013-10-16 | 天长市开林化工有限公司 | Preparation method of antibacterial environmentally-friendly interior wall coating |
CN107936660A (en) * | 2017-11-10 | 2018-04-20 | 清远市思晴新材料科技有限公司 | A kind of environmental friendly, anti-corrosive antibacterial interior wall negative ion paint |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111363426A (en) * | 2020-05-11 | 2020-07-03 | 江西清大高端技术服务有限公司 | Efficient and environment-friendly negative oxygen ion concentrated solution and preparation method thereof |
CN111363426B (en) * | 2020-05-11 | 2022-03-04 | 江西清大高端技术服务有限公司 | Environment-friendly negative oxygen ion concentrated solution and preparation method thereof |
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Application publication date: 20190222 |