CN109370330A - A kind of environmental friendly, anti-corrosive antibacterial interior wall negative ion paint and preparation method thereof - Google Patents

A kind of environmental friendly, anti-corrosive antibacterial interior wall negative ion paint and preparation method thereof Download PDF

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Publication number
CN109370330A
CN109370330A CN201811310308.0A CN201811310308A CN109370330A CN 109370330 A CN109370330 A CN 109370330A CN 201811310308 A CN201811310308 A CN 201811310308A CN 109370330 A CN109370330 A CN 109370330A
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parts
interior wall
negative ion
water
mixed solution
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CN201811310308.0A
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朱发明
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Shanghai Haoshi Industrial Co Ltd Shijiazhuang Branch
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Shanghai Haoshi Industrial Co Ltd Shijiazhuang Branch
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Priority to CN201811310308.0A priority Critical patent/CN109370330A/en
Publication of CN109370330A publication Critical patent/CN109370330A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D129/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Coating compositions based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Coating compositions based on derivatives of such polymers
    • C09D129/02Homopolymers or copolymers of unsaturated alcohols
    • C09D129/04Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives

Abstract

The invention discloses a kind of environmental friendly, anti-corrosive antibacterial interior wall negative ion paints of interior wall coating technical field, the coating includes following ingredient: 200-250 parts of polyvinyl alcohol, 150-200 parts of active zeolite powder, 230-260 parts of nano-sized filler, 20-40 parts of preservative, 25-50 parts of mould inhibitor, 80-160 parts of anion part, 50-80 parts of titanium dioxide, 30-65 parts of pigment, 10-20 parts of curing agent, 10-15 parts of thickener, 15-30 parts of film forming agent, 5-10 parts of defoaming agent, 300-500 parts of water, the present invention can launch the anion beneficial to human body, remove the harmful substances such as formaldehyde, improve room air, simultaneously to Escherichia coli, staphylococcus aureus and Mycophyta have good antibacterial action, the quick and sustained release period is long , the growth and breeding of bacterium are effectively prevented, and kill the various bacteriums bred out.

Description

A kind of environmental friendly, anti-corrosive antibacterial interior wall negative ion paint and preparation method thereof
Technical field
The present invention relates to interior wall coating technical field, specially a kind of environmental friendly, anti-corrosive antibacterial interior wall negative ion paint and its Preparation method.
Background technique
With the development of society, continuous improvement of people's living standards, the requirement that people guarantee the quality to the epipodium of life Higher and higher, consumer is also increasingly enhanced the house ornamentation consciousness of health, environmental protection.
In use, metope is easy the shadow by Escherichia coli, staphylococcus aureus and Mycophyta to existing coating It rings and mildew occurs, issue niff, environmental-protecting performance is poor, and long-time service brings lasting harm to the body of people how The coating that effective antibacterial can be manufactured is the necessary stage in the paint development stage, for this purpose, it is proposed that a kind of environment-friendly type is anti- Rotten antibacterial interior wall negative ion paint and preparation method thereof.
Summary of the invention
The purpose of the present invention is to provide a kind of environmental friendly, anti-corrosive antibacterial interior wall negative ion paints and preparation method thereof, with solution Certainly the problems mentioned above in the background art.
To achieve the above object, the invention provides the following technical scheme: a kind of environmental friendly, anti-corrosive antibacterial interior wall anion applies Material, which includes following ingredient: 200-250 parts of polyvinyl alcohol, 150-200 parts of active zeolite powder, nano-sized filler 230- 260 parts, 20-40 parts of preservative, 25-50 parts of mould inhibitor, 80-160 parts of anion part, 50-80 parts of titanium dioxide, 30-65 parts of pigment, 10-20 parts of curing agent, 10-15 parts of thickener, 15-30 parts of film forming agent, 5-10 parts of defoaming agent, 300-500 parts of water.
Preferably, a kind of environmental friendly, anti-corrosive antibacterial interior wall negative ion paint preparation method, this method comprises the following steps:
S1: preparation A mixed solution: selection 200 parts of polyvinyl alcohol, 150 parts of active zeolite powder, 230 and of nano-sized filler first 300 parts of water, then the raw material of selection is poured into blender and is stirred mixing, blender revolving speed is 1500 revs/min, stirring Time is 10 minutes, obtains A mixed solution;
S2: preparation B mixed solution: selection 20 parts of preservative, 25 parts of mould inhibitor, 80 parts of anion part, 50 parts of titanium dioxide, face first 30 parts of material, 10 parts of curing agent, 15 parts of film forming agent, 5 parts of defoaming agent and 100 parts of water, then pour into the raw material of selection in dispersion machine, The degree that turns of dispersion machine is set as 2000 revs/min, and jitter time is 15 minutes, obtains B mixed solution;
S3: it prepares coating: the B mixed solution obtained in S2 being poured into the blender in S1, is mixed again with A mixed solution It closes, pours into 10 parts of thickener into blender at this time, and by the rotational speed regulation of blender to 2000-3000 revs/min, when stirring Between be 15-20 minutes;
S4: examine coating: after step S3, whether the viscosity that detection prepares coating is qualified.
Preferably, the preparation of active zeolite powder be first by active zeolite particle in 80 degrees Celsius of 60- of water, with One or more of mixing of antibacterial metal salts carry out ion exchanges, after the reaction was completed, then drying, pulverize, and activate boiling Stone powder partial size is 0.1-10 microns.
Preferably, nano-sized filler is one of titanium oxide, precipitated calcium carbonate and kaolin or in which a variety of.
Preferably, preservative is by isothiazolinone derivatives, benzimidazole esters, Dao Weixier -75,1,2- benzisoxa The compounding intermixture of thiazoline -3- ketone composition.
Preferably, for titanium dioxide particle diameter at 3-8 microns, water is pure water or deionized water.
Compared with prior art, the beneficial effects of the present invention are: the present invention can launch the anion beneficial to human body, The harmful substances such as formaldehyde are removed, improve room air, while having to Escherichia coli, staphylococcus aureus and Mycophyta good Antibacterial action, the quick and sustained release period is long, effectively prevents the growth and breeding of bacterium, and kills and breed out various thin Bacterium.
Specific embodiment
Below in conjunction with the embodiment of the present invention, technical scheme in the embodiment of the invention is clearly and completely described, Obviously, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based in the present invention Embodiment, every other embodiment obtained by those of ordinary skill in the art without making creative efforts, all Belong to the scope of protection of the invention.
Embodiment 1
A kind of environmental friendly, anti-corrosive antibacterial interior wall negative ion paint, the coating include following ingredient: 200 parts of polyvinyl alcohol, activation boiling 150 parts of stone powder, 230 parts of nano-sized filler, 20 parts of preservative, 25 parts of mould inhibitor, 80 parts of anion part, 50 parts of titanium dioxide, face Expect 30 parts, 10 parts of curing agent, 10 parts of thickener, 15 parts of film forming agent, 5 parts of defoaming agent, 300 parts of water;
A kind of environmental friendly, anti-corrosive antibacterial interior wall negative ion paint preparation method, this method comprises the following steps:
S1: preparation A mixed solution: selection 200 parts of polyvinyl alcohol, 150 parts of active zeolite powder, 230 and of nano-sized filler first 200 parts of water, then the raw material of selection is poured into blender and is stirred mixing, blender revolving speed is 1500 revs/min, stirring Time is 10 minutes, obtains A mixed solution;
S2: preparation B mixed solution: selection 20 parts of preservative, 25 parts of mould inhibitor, 80 parts of anion part, 50 parts of titanium dioxide, face first 30 parts of material, 10 parts of curing agent, 15 parts of film forming agent, 5 parts of defoaming agent and 100 parts of water, then pour into the raw material of selection in dispersion machine, The degree that turns of dispersion machine is set as 2000 revs/min, and jitter time is 15 minutes, obtains B mixed solution, is effectively prevented bacterium It breeds and breeds, and kill the various bacteriums bred out, while launching the anion beneficial to human body, purify air;
S3: it prepares coating: the B mixed solution obtained in S2 being poured into the blender in S1, is mixed again with A mixed solution It closes, pours into 10 parts of thickener into blender at this time, and by the rotational speed regulation of blender to 2000-3000 revs/min, when stirring Between be 15-20 minutes, convenient for adequately mixing raw material, improve the uniformity of mixed solution, metope avoided mildew occur;
S4: examine coating: after step S3, whether the viscosity that detection prepares coating is qualified;
The preparation of active zeolite powder is first by active zeolite particle in 80 degrees Celsius of 60- of water, with antibacterial metal salts One or more mixing carries out ion exchanges, after the reaction was completed, then drying, pulverizes, and active zeolite powder diameter is 0.1-10 microns, active zeolite powder is added in interior wall coating with 0.5%-10% (weight) and is mixed, and becomes antibiotic paint, to big Enterobacteria, staphylococcus aureus and Mycophyta have good antibacterial action, and the quick and sustained release period is long;
Nano-sized filler is one of titanium oxide, precipitated calcium carbonate and kaolin or in which a variety of, and preservative is by isothiazole The compounding intermixture that quinoline ketone derivatives, benzimidazole esters, Dao Weixier -75,1,2-benzisothiazolin-3-one form, titanium For white powder particle diameter at 3-8 microns, water is pure water or deionized water, effectively improves the wear-resisting and corrosion resistance of the coating;
Embodiment 2
A kind of environmental friendly, anti-corrosive antibacterial interior wall negative ion paint, the coating include following ingredient: 230 parts of polyvinyl alcohol, activation boiling 200 parts of stone powder, 245 parts of nano-sized filler, 30 parts of preservative, 35 parts of mould inhibitor, 120 parts of anion part, 65 parts of titanium dioxide, face Expect 50 parts, 15 parts of curing agent, 13 parts of thickener, 23 parts of film forming agent, 7 parts of defoaming agent, 400 parts of water;
A kind of environmental friendly, anti-corrosive antibacterial interior wall negative ion paint preparation method, this method comprises the following steps:
S1: preparation A mixed solution: selection 230 parts of polyvinyl alcohol, 200 parts of active zeolite powder, 245 and of nano-sized filler first 270 parts of water, then the raw material of selection is poured into blender and is stirred mixing, blender revolving speed is 1500 revs/min, stirring Time is 10 minutes, obtains A mixed solution;
S2: preparation B mixed solution: first selection 30 parts of preservative, 35 parts of mould inhibitor, 120 parts of anion part, 65 parts of titanium dioxide, 50 parts of pigment, 15 parts of curing agent, 23 parts of film forming agent, 7 parts of defoaming agent and 130 parts of water, then pour into dispersion machine for the raw material of selection In, the degree that turns of dispersion machine is set as 2000 revs/min, and jitter time is 15 minutes, obtains B mixed solution, is effectively prevented thin The growth and breeding of bacterium, and the various bacteriums bred out are killed, while launching the anion beneficial to human body, purify air;
S3: it prepares coating: the B mixed solution obtained in S2 being poured into the blender in S1, is mixed again with A mixed solution It closes, pours into 10 parts of thickener into blender at this time, and by the rotational speed regulation of blender to 2000-3000 revs/min, when stirring Between be 15-20 minutes, convenient for adequately mixing raw material, improve the uniformity of mixed solution, metope avoided mildew occur;
S4: examine coating: after step S3, whether the viscosity that detection prepares coating is qualified;
The preparation of active zeolite powder is first by active zeolite particle in 80 degrees Celsius of 60- of water, with antibacterial metal salts One or more mixing carries out ion exchanges, after the reaction was completed, then drying, pulverizes, and active zeolite powder diameter is 0.1-10 microns, active zeolite powder is added in interior wall coating with 0.5%-10% (weight) and is mixed, and becomes antibiotic paint, to big Enterobacteria, staphylococcus aureus and Mycophyta have good antibacterial action, and the quick and sustained release period is long;
Nano-sized filler is one of titanium oxide, precipitated calcium carbonate and kaolin or in which a variety of, and preservative is by isothiazole The compounding intermixture that quinoline ketone derivatives, benzimidazole esters, Dao Weixier -75,1,2-benzisothiazolin-3-one form, titanium For white powder particle diameter at 3-8 microns, water is pure water or deionized water, effectively improves the wear-resisting and corrosion resistance of the coating;
Embodiment 3
A kind of environmental friendly, anti-corrosive antibacterial interior wall negative ion paint, the coating include following ingredient: 250 parts of polyvinyl alcohol, activation boiling 200 parts of stone powder, 260 parts of nano-sized filler, 40 parts of preservative, 50 parts of mould inhibitor, 160 parts of anion part, 80 parts of titanium dioxide, face Expect 65 parts, 20 parts of curing agent, 15 parts of thickener, 30 parts of film forming agent, 10 parts of defoaming agent, 500 parts of water;
A kind of environmental friendly, anti-corrosive antibacterial interior wall negative ion paint preparation method, this method comprises the following steps:
S1: preparation A mixed solution: selection 250 parts of polyvinyl alcohol, 200 parts of active zeolite powder, 260 and of nano-sized filler first 350 parts of water, then the raw material of selection is poured into blender and is stirred mixing, blender revolving speed is 1500 revs/min, stirring Time is 10 minutes, obtains A mixed solution;
S2: preparation B mixed solution: first selection 40 parts of preservative, 50 parts of mould inhibitor, 160 parts of anion part, 80 parts of titanium dioxide, 65 parts of pigment, 20 parts of curing agent, 30 parts of film forming agent, 10 parts of defoaming agent and 150 parts of water, then pour into dispersion machine for the raw material of selection In, the degree that turns of dispersion machine is set as 2000 revs/min, and jitter time is 15 minutes, obtains B mixed solution, is effectively prevented thin The growth and breeding of bacterium, and the various bacteriums bred out are killed, while launching the anion beneficial to human body, purify air;
S3: it prepares coating: the B mixed solution obtained in S2 being poured into the blender in S1, is mixed again with A mixed solution It closes, pours into 10 parts of thickener into blender at this time, and by the rotational speed regulation of blender to 2000-3000 revs/min, when stirring Between be 15-20 minutes, convenient for adequately mixing raw material, improve the uniformity of mixed solution, metope avoided mildew occur;
S4: examine coating: after step S3, whether the viscosity that detection prepares coating is qualified;
The preparation of active zeolite powder is first by active zeolite particle in 80 degrees Celsius of 60- of water, with antibacterial metal salts One or more mixing carries out ion exchanges, after the reaction was completed, then drying, pulverizes, and active zeolite powder diameter is 0.1-10 microns, active zeolite powder is added in interior wall coating with 0.5%-10% (weight) and is mixed, and becomes antibiotic paint, to big Enterobacteria, staphylococcus aureus and Mycophyta have good antibacterial action, and the quick and sustained release period is long;
Nano-sized filler is one of titanium oxide, precipitated calcium carbonate and kaolin or in which a variety of, and preservative is by isothiazole The compounding intermixture that quinoline ketone derivatives, benzimidazole esters, Dao Weixier -75,1,2-benzisothiazolin-3-one form, titanium For white powder particle diameter at 3-8 microns, water is pure water or deionized water, effectively improves the wear-resisting and corrosion resistance of the coating.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding And modification, the scope of the present invention is defined by the appended.

Claims (6)

1. a kind of environmental friendly, anti-corrosive antibacterial interior wall negative ion paint, it is characterised in that: the coating includes following ingredient: polyvinyl alcohol 200-250 parts, 150-200 parts of active zeolite powder, 230-260 parts of nano-sized filler, 20-40 parts of preservative, mould inhibitor 25-50 Part, 80-160 parts of anion part, 50-80 parts of titanium dioxide, 30-65 parts of pigment, 10-20 parts of curing agent, 10-15 parts of thickener, at 15-30 parts of film, 5-10 parts of defoaming agent, 300-500 parts of water.
2. a kind of environmental friendly, anti-corrosive antibacterial interior wall negative ion paint preparation method, it is characterised in that: this method comprises the following steps:
S1: preparation A mixed solution: selection 200 parts of polyvinyl alcohol, 150 parts of active zeolite powder, 230 and of nano-sized filler first 300 parts of water, then the raw material of selection is poured into blender and is stirred mixing, blender revolving speed is 1500 revs/min, stirring Time is 10 minutes, obtains A mixed solution;
S2: preparation B mixed solution: selection 20 parts of preservative, 25 parts of mould inhibitor, 80 parts of anion part, 50 parts of titanium dioxide, face first 30 parts of material, 10 parts of curing agent, 15 parts of film forming agent, 5 parts of defoaming agent and 100 parts of water, then pour into the raw material of selection in dispersion machine, The degree that turns of dispersion machine is set as 2000 revs/min, and jitter time is 15 minutes, obtains B mixed solution;
S3: it prepares coating: the B mixed solution obtained in S2 being poured into the blender in S1, is mixed again with A mixed solution It closes, pours into 10 parts of thickener into blender at this time, and by the rotational speed regulation of blender to 2000-3000 revs/min, when stirring Between be 15-20 minutes;
S4: examine coating: after step S3, whether the viscosity that detection prepares coating is qualified.
3. a kind of environmental friendly, anti-corrosive antibacterial interior wall negative ion paint according to claim 1, it is characterised in that: active zeolite The preparation of powder is to mix first by active zeolite particle in 80 degrees Celsius of 60- of water with the one or more of antibacterial metal salts It closes and carries out ion exchange, after the reaction was completed, then drying, pulverize, and active zeolite powder diameter is 0.1-10 microns.
4. a kind of environmental friendly, anti-corrosive antibacterial interior wall negative ion paint according to claim 1, it is characterised in that: nanoscale is filled out Material is one of titanium oxide, precipitated calcium carbonate and kaolin or in which a variety of.
5. a kind of environmental friendly, anti-corrosive antibacterial interior wall negative ion paint according to claim 1, it is characterised in that: preservative is It is mixed by the compounding that isothiazolinone derivatives, benzimidazole esters, Dao Weixier -75,1,2-benzisothiazolin-3-one form Mixture.
6. a kind of environmental friendly, anti-corrosive antibacterial interior wall negative ion paint according to claim 1, it is characterised in that: titanium dioxide For grain diameter at 3-8 microns, water is pure water or deionized water.
CN201811310308.0A 2018-11-06 2018-11-06 A kind of environmental friendly, anti-corrosive antibacterial interior wall negative ion paint and preparation method thereof Pending CN109370330A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111363426A (en) * 2020-05-11 2020-07-03 江西清大高端技术服务有限公司 Efficient and environment-friendly negative oxygen ion concentrated solution and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1424366A (en) * 2001-12-11 2003-06-18 中国科学院光电技术研究所 Internal-wall coating and preparation thereof
CN103351746A (en) * 2013-06-21 2013-10-16 天长市开林化工有限公司 Preparation method of antibacterial environmentally-friendly interior wall coating
CN107936660A (en) * 2017-11-10 2018-04-20 清远市思晴新材料科技有限公司 A kind of environmental friendly, anti-corrosive antibacterial interior wall negative ion paint

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1424366A (en) * 2001-12-11 2003-06-18 中国科学院光电技术研究所 Internal-wall coating and preparation thereof
CN103351746A (en) * 2013-06-21 2013-10-16 天长市开林化工有限公司 Preparation method of antibacterial environmentally-friendly interior wall coating
CN107936660A (en) * 2017-11-10 2018-04-20 清远市思晴新材料科技有限公司 A kind of environmental friendly, anti-corrosive antibacterial interior wall negative ion paint

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111363426A (en) * 2020-05-11 2020-07-03 江西清大高端技术服务有限公司 Efficient and environment-friendly negative oxygen ion concentrated solution and preparation method thereof
CN111363426B (en) * 2020-05-11 2022-03-04 江西清大高端技术服务有限公司 Environment-friendly negative oxygen ion concentrated solution and preparation method thereof

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Application publication date: 20190222