CN104650629A - Marine biological mildew resistant paint and preparation method thereof - Google Patents

Marine biological mildew resistant paint and preparation method thereof Download PDF

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Publication number
CN104650629A
CN104650629A CN201310602129.5A CN201310602129A CN104650629A CN 104650629 A CN104650629 A CN 104650629A CN 201310602129 A CN201310602129 A CN 201310602129A CN 104650629 A CN104650629 A CN 104650629A
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China
Prior art keywords
mould
agent
emulsion
preparation
dispersion
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Pending
Application number
CN201310602129.5A
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Chinese (zh)
Inventor
王鑫
李艳妮
陈芬
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Qingdao Hifun Marine Biological Technology Co Ltd
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Qingdao Hifun Marine Biological Technology Co Ltd
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Priority to CN201310602129.5A priority Critical patent/CN104650629A/en
Publication of CN104650629A publication Critical patent/CN104650629A/en
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Abstract

The invention discloses marine biological mildew resistant paint and a preparation method thereof. The paint is prepared from the following components in percentage by weight: 30-60 percent of a base material, 1-5 percent of propylene glycol, 10-35 percent of pigment and filler, 5-10 percent of an auxiliary, 2.0-10 percent of a marine biological bacteriostat and the balance of water. The marine biological mildew resistant paint has relatively strong water resistance, and does not have the phenomenon of peeling off when the coated surface is under a dried air or damp air condition.

Description

Marine organisms mould-repellant coating and preparation method thereof
Technical field
of the present invention is a kind of marine organisms mould-repellant coating and preparation method thereof.
Background technology
antibiotic fungus-resisting paint has reduction bacterial reproduction and pathophorous probability, removes the troublesome function to environment disinfected from, can be widely used in various public place and household, office etc.The antibiotic paint of current use generally adopts the organic antibacterial agent of synthetic or organic mould inhibitor, can kill and be attached to bacterium on coated article surface or mould.Shortcoming is that action time is short, and along with organic disintegrate, antibacterial or mildew-proof function fades away, and harmful microorganism can form resistance, and some organism has negative impact to human body and environment.
technical problem to be solved by this invention is to provide a kind of marine organisms mould-repellant coating and preparation method thereof this kind of coating to have the effect of well antibacterial and mildew-resistant simultaneously, harmless to human non-toxic, environmental protection, persistent, synchronous with the work-ing life of coated article.
Summary of the invention
an object of the present invention is to provide a kind of marine organisms mould-repellant coating and preparation method thereof.
marine organisms mould-repellant coating and preparation method thereof, is characterized in that, it is prepared from by following raw material:
base-material 30-60%;
propylene glycol 1-5%;
face, filler 10-35%;
auxiliary agent 5-10%;
marine biological sterilization agent 2.0-10%;
surplus is water.
wherein base-material comprises: silicon sol 30-50%, silicate 20-30%, ethene-vinyl acetate between to for plastic (VAE) emulsion 20-30%, chlorine partial emulsion 20-30%.
wherein face, filler comprise: mica powder 5-10%, calcium carbonate 3-7%, zinc sulfide white 2-5%, talcum powder 5-10%, white clay 5-15%, titanium dioxide 10-20%.
wherein auxiliary agent comprises: Natvosol 30-40%, dispersion agent SN-5040 (poly carboxylic acid sodium, 40%) 20-30%, Manganse Dioxide 5-10%, diethyl phthalate 5-10%, polyethylene oxide 3-7%, polyacrylic ester 2-8%.
marine organisms mould-repellant coating of the present invention, comprises the following steps:
step 1: by base-material: silicon sol 30-50%, silicate 20-30%, ethene-vinyl acetate between to for plastic (VAE) emulsion 20-30%, chlorine partial emulsion 20-30%, face, filler: mica powder 5-10%, calcium carbonate 3-7%, zinc sulfide white 2-5%, talcum powder 5-10%, white clay 5-15%, titanium dioxide 10-20%, polyethylene oxide 3-7%, water per minute in high speed dispersor of polyacrylic ester 2-8% and surplus1000 under the rotating speed turned, high speed dispersion obtains solution A half an hour.
step 2: the solution A of gained in step 1 is put into three-roll grinder grinding2 time, make its granularity be less than the slurry B of 75 μm.
step 3: put into dispersion machine, in dispersion machine by grinding the slurry B obtained in step 2500 turnoften minute rotating speed under add auxiliary agent: Natvosol 30-40%, dispersion agent SN-5040 (poly carboxylic acid sodium, 40%) 20-30%, Manganse Dioxide 5-10%, diethyl phthalate 5-10%, stir30 add marine biological sterilization agent 2.0-10% after minute, last adjusting viscosity, filter through vibratory screening apparatus and be product.
marine organisms mould-repellant coating of the present invention and preparation method thereof, has the effect of good antibacterial and mouldproof, stable performance, harmless to human non-toxic, environmental protection, the advantage of persistent.
Embodiment
embodiment 1
the marine organisms mould-repellant coating of the present embodiment, percentage proportioning is as follows:
marine organisms mould-repellant coating and preparation method thereof, is characterized in that, it is prepared from by following raw material:
base-material 30-60%;
propylene glycol 1-5%;
face, filler 10-35%;
auxiliary agent 5-10%;
marine biological sterilization agent 2.0-10%;
surplus is water.
wherein base-material comprises: silicon sol 30-50%, silicate 20-30%, ethene-vinyl acetate between to for plastic (VAE) emulsion 20-30%, chlorine partial emulsion 20-30%.
wherein face, filler comprise: mica powder 5-10%, calcium carbonate 3-7%, zinc sulfide white 2-5%, talcum powder 5-10%, white clay 5-15%, titanium dioxide 10-20%.
wherein auxiliary agent comprises: Natvosol 30-40%, dispersion agent SN-5040 (poly carboxylic acid sodium, 40%) 20-30%, Manganse Dioxide 5-10%, diethyl phthalate 5-10%, polyethylene oxide 3-7%, polyacrylic ester 2-8%.
embodiment 2
present embodiments provide a kind of preparation method for the marine organisms mould-repellant coating described in embodiment 1, comprise the following steps:
step 1: by base-material: silicon sol 30-50%, silicate 20-30%, ethene-vinyl acetate between to for plastic (VAE) emulsion 20-30%, chlorine partial emulsion 20-30%, face, filler: mica powder 5-10%, calcium carbonate 3-7%, zinc sulfide white 2-5%, talcum powder 5-10%, white clay 5-15%, titanium dioxide 10-20%, polyethylene oxide 3-7%, water per minute in high speed dispersor of polyacrylic ester 2-8% and surplus1000 under the rotating speed turned, high speed dispersion obtains solution A half an hour.
step 2: the solution A of gained in step 1 is put into three-roll grinder grinding2 time, make its granularity be less than the slurry B of 75 μm.
step 3: put into dispersion machine, in dispersion machine by grinding the slurry B obtained in step 2500 turnoften minute rotating speed under add auxiliary agent: Natvosol 30-40%, dispersion agent SN-5040 (poly carboxylic acid sodium, 40%) 20-30%, Manganse Dioxide 5-10%, diethyl phthalate 5-10%, stir30 add marine biological sterilization agent 2.0-10% after minute, last adjusting viscosity, filter through vibratory screening apparatus and be product.
embodiment 3
the marine organisms mould-repellant coating of the present embodiment, percentage proportioning is as follows:
marine organisms mould-repellant coating and preparation method thereof, is characterized in that, it is prepared from by following raw material:
base-material 30-60%;
propylene glycol 1-5%;
face, filler 10-35%;
auxiliary agent 5-10%;
marine biological sterilization agent 2.0-10%;
surplus is water.
wherein base-material comprises: silicon sol 30-50%, silicate 20-30%, ethene-vinyl acetate between to for plastic (VAE) emulsion 20-30%, chlorine partial emulsion 20-30%.
wherein face, filler comprise: mica powder 5-10%, calcium carbonate 3-7%, zinc sulfide white 2-5%, talcum powder 5-10%, white clay 5-15%, titanium dioxide 10-20%.
wherein auxiliary agent comprises: Natvosol 30-40%, dispersion agent SN-5040 (poly carboxylic acid sodium, 40%) 20-30%, Manganse Dioxide 5-10%, diethyl phthalate 5-10%, polyethylene oxide 3-7%, polyacrylic ester 2-8%.
present embodiments provide a kind of preparation method for the marine organisms mould-repellant coating described in embodiment 1, comprise the following steps:
step 1: by base-material: silicon sol 30-50%, silicate 20-30%, ethene-vinyl acetate between to for plastic (VAE) emulsion 20-30%, chlorine partial emulsion 20-30%, face, filler: mica powder 5-10%, calcium carbonate 3-7%, zinc sulfide white 2-5%, talcum powder 5-10%, white clay 5-15%, titanium dioxide 10-20%, polyethylene oxide 3-7%, water per minute in high speed dispersor of polyacrylic ester 2-8% and surplus1000 under the rotating speed turned, high speed dispersion obtains solution A half an hour.
step 2: the solution A of gained in step 1 is put into three-roll grinder grinding2 time, make its granularity be less than the slurry B of 75 μm.
step 3: put into dispersion machine, in dispersion machine by grinding the slurry B obtained in step 2500 turnoften minute rotating speed under add auxiliary agent: Natvosol 30-40%, dispersion agent SN-5040 (poly carboxylic acid sodium, 40%) 20-30%, Manganse Dioxide 5-10%, diethyl phthalate 5-10%, stir30 add marine biological sterilization agent 2.0-10% after minute, last adjusting viscosity, filter through vibratory screening apparatus and be product.
marine organisms mould-repellant coating of the present invention and preparation method thereof, has the effect of good antibacterial and mouldproof, stable performance, harmless to human non-toxic, environmental protection, the advantage of persistent.
 
embodiment 4
the marine organisms mould-repellant coating of the present embodiment, percentage proportioning is as follows:
marine organisms mould-repellant coating and preparation method thereof, is characterized in that, it is prepared from by following raw material:
base-material 30%;
propylene glycol 1%;
face, filler 10%;
auxiliary agent 5%;
marine biological sterilization agent 2.0%;
surplus is water.
wherein base-material comprises: silicon sol 30%, silicate 20%, ethene-vinyl acetate between to for plastic (VAE) emulsion 20%, chlorine partial emulsion 20%.
wherein face, filler comprise: mica powder 5%, calcium carbonate 3%, zinc sulfide white 2%, talcum powder 5%, white clay 5%, titanium dioxide 10%.
wherein auxiliary agent comprises: Natvosol 30%, dispersion agent SN-5040 (poly carboxylic acid sodium, 40%) 20%, Manganse Dioxide 5%, diethyl phthalate 5%, polyethylene oxide 3%, polyacrylic ester 2%.
present embodiments provide a kind of preparation method for the marine organisms mould-repellant coating described in embodiment 1, comprise the following steps:
step 1: by base-material: silicon sol 30%, silicate 20%, ethene-vinyl acetate between to for plastic (VAE) emulsion 20%, chlorine partial emulsion 20%, face, filler: mica powder 5%, calcium carbonate 3%, zinc sulfide white 2%, talcum powder 5%, white clay 5%, titanium dioxide 10%, polyethylene oxide 3%, water per minute in high speed dispersor of polyacrylic ester 2% and surplus1000 under the rotating speed turned, high speed dispersion obtains solution A half an hour.
step 2: the solution A of gained in step 1 is put into three-roll grinder grinding2 time, make its granularity be less than the slurry B of 75 μm.
step 3: put into dispersion machine, in dispersion machine by grinding the slurry B obtained in step 2500 turnoften minute rotating speed under add auxiliary agent: Natvosol 30%, dispersion agent SN-5040 (poly carboxylic acid sodium, 40%) 20%, Manganse Dioxide 5%, diethyl phthalate 5%, stir30 add marine biological sterilization agent 2.0% after minute, last adjusting viscosity, filter through vibratory screening apparatus and be product.
embodiment 5
the marine organisms mould-repellant coating of the present embodiment, percentage proportioning is as follows:
marine organisms mould-repellant coating and preparation method thereof, is characterized in that, it is prepared from by following raw material:
base-material 60%;
propylene glycol 5%;
face, filler 35%;
auxiliary agent 10%;
marine biological sterilization agent 10%;
surplus is water.
wherein base-material comprises: silicon sol 50%, silicate 30%, ethene-vinyl acetate between to for plastic (VAE) emulsion 30%, chlorine partial emulsion 30%.
wherein face, filler comprise: mica powder 10%, calcium carbonate 7%, zinc sulfide white 5%, talcum powder 10%, white clay 15%, titanium dioxide 20%.
wherein auxiliary agent comprises: Natvosol 40%, dispersion agent SN-5040 (poly carboxylic acid sodium, 40%) 30%, Manganse Dioxide 10%, diethyl phthalate 10%, polyethylene oxide 7%, polyacrylic ester 8%.
present embodiments provide a kind of preparation method for the marine organisms mould-repellant coating described in embodiment 1, comprise the following steps:
step 1: by base-material: silicon sol 50%, silicate 30%, ethene-vinyl acetate between to for plastic (VAE) emulsion 30%, chlorine partial emulsion 30%, face, filler: mica powder 10%, calcium carbonate 7%, zinc sulfide white 5%, talcum powder 10%, white clay 15%, titanium dioxide 20%, polyethylene oxide 7%, water per minute in high speed dispersor of polyacrylic ester 8% and surplus1000 under the rotating speed turned, high speed dispersion obtains solution A half an hour.
step 2: the solution A of gained in step 1 is put into three-roll grinder grinding2 time, make its granularity be less than the slurry B of 75 μm.
step 3: put into dispersion machine, in dispersion machine by grinding the slurry B obtained in step 2500 turnoften minute rotating speed under add auxiliary agent: Natvosol 40%, dispersion agent SN-5040 (poly carboxylic acid sodium, 40%) 30%, Manganse Dioxide 10%, diethyl phthalate 10%, stir30 add marine biological sterilization agent 10% after minute, propylene glycol 5%, last adjusting viscosity, filter through vibratory screening apparatus and be product.
embodiment 6
the marine organisms mould-repellant coating of the present embodiment, percentage proportioning is as follows:
marine organisms mould-repellant coating and preparation method thereof, is characterized in that, it is prepared from by following raw material:
base-material 40%;
propylene glycol 3%;
face, filler 15%;
auxiliary agent 6%;
marine biological sterilization agent 3%;
surplus is water.
wherein base-material comprises: silicon sol 30%, silicate 22%, ethene-vinyl acetate between to for plastic (VAE) emulsion 20%, chlorine partial emulsion 23%.
wherein face, filler comprise: mica powder 5%, calcium carbonate 3%, zinc sulfide white 3%, talcum powder 5%, white clay 7%, titanium dioxide 12%.
wherein auxiliary agent comprises: Natvosol 30%, dispersion agent SN-5040 (poly carboxylic acid sodium, 40%) 25%, Manganse Dioxide 6%, diethyl phthalate 6%, polyethylene oxide 4%, polyacrylic ester 3%.
present embodiments provide a kind of preparation method for the marine organisms mould-repellant coating described in embodiment 1, comprise the following steps:
step 1: by base-material: silicon sol 30%, silicate 22%, ethene-vinyl acetate between to for plastic (VAE) emulsion 20%, chlorine partial emulsion 23%, face, filler: mica powder 5%, calcium carbonate 3%, zinc sulfide white 3%, talcum powder 5%, white clay 7%, water per minute in high speed dispersor of titanium dioxide 12% and surplus1000 under the rotating speed turned, high speed dispersion obtains solution A half an hour.
step 2: the solution A of gained in step 1 is put into three-roll grinder grinding2 time, make its granularity be less than the slurry B of 75 μm.
step 3: put into dispersion machine, in dispersion machine by grinding the slurry B obtained in step 2500 turnoften minute rotating speed under add auxiliary agent: Natvosol 30%, dispersion agent SN-5040 (poly carboxylic acid sodium, 40%) 25%, Manganse Dioxide 6%, diethyl phthalate 6%, polyethylene oxide 4%, polyacrylic ester 3%, last adjusting viscosity adds marine biological sterilization agent 3%, propylene glycol 3%; Filter through vibratory screening apparatus and be product.

Claims (7)

1. marine organisms mould-repellant coating and preparation method thereof, is characterized in that, it is prepared from by following raw material:
base-material 30-60%;
propylene glycol 1-5%;
Face, filler 10-35%;
Auxiliary agent 5-10%;
Marine biological sterilization agent 2.0-10%;
Surplus is water.
2. marine organisms mould-repellant coating according to claim 1, wherein comprises raw material as follows:
Base-material comprises: silicon sol 30-50%, silicate 20-30%, ethene-vinyl acetate between to for plastic (VAE) emulsion 20-30%, chlorine partial emulsion 20-30%.
3. face, filler comprise: mica powder 5-10%, calcium carbonate 3-7%, zinc sulfide white 2-5%, talcum powder 5-10%, white clay 5-15%, titanium dioxide 10-20%.
4. auxiliary agent comprises: Natvosol 30-40%, dispersion agent SN-5040 (poly carboxylic acid sodium, 40%) 20-30%, Manganse Dioxide 5-10%, diethyl phthalate 5-10%, polyethylene oxide 3-7%, polyacrylic ester 2-8%.
5. marine organisms mould-repellant coating according to claim 1 and 2, wherein preparation method and step as follows:
Step 1: by base-material: silicon sol 30-50%, silicate 20-30%, ethene-vinyl acetate between to for plastic (VAE) emulsion 20-30%, chlorine partial emulsion 20-30%, face, filler: mica powder 5-10%, calcium carbonate 3-7%, zinc sulfide white 2-5%, talcum powder 5-10%, white clay 5-15%, titanium dioxide 10-20%, polyethylene oxide 3-7%, under the rotating speed of water per minute 1000 turns in high speed dispersor of polyacrylic ester 2-8% and surplus, high speed dispersion obtains solution A half an hour.
6. step 2: the solution A of gained in step 1 is put into three-roll grinder and grinds 2 times, makes its granularity be less than the slurry B of 75 μm.
7. step 3: put into dispersion machine by grinding the slurry B obtained in step 2, auxiliary agent is added under the rotating speed of 500 rpms: Natvosol 30-40% in dispersion machine, dispersion agent SN-5040 (poly carboxylic acid sodium, 40%) 20-30%, Manganse Dioxide 5-10%, diethyl phthalate 5-10%, stir and add marine biological sterilization agent 2.0-10% after 30 minutes, last adjusting viscosity, filters through vibratory screening apparatus and is product.
CN201310602129.5A 2013-11-26 2013-11-26 Marine biological mildew resistant paint and preparation method thereof Pending CN104650629A (en)

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Application Number Priority Date Filing Date Title
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CN104650629A true CN104650629A (en) 2015-05-27

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108610801A (en) * 2017-05-25 2018-10-02 太仓安托建筑材料有限公司 A kind of inner wall mold-proof paint
CN111087859A (en) * 2019-12-24 2020-05-01 江西省颐冠涂料有限公司 Nanoscale anti-mildew coating
CN111117377A (en) * 2019-12-24 2020-05-08 江西省颐冠涂料有限公司 Super-hydrophilic self-cleaning coating and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5761066A (en) * 1980-10-01 1982-04-13 Nippon Oil & Fats Co Ltd Mildewproofing paint composition
CN101210143A (en) * 2006-12-31 2008-07-02 北京金源化学集团有限公司 Environment-friendly type long-acting mildew-resisting paint and preparing method thereof
CN101705038A (en) * 2009-11-19 2010-05-12 黄宏亭 Dirt-resistant self-cleaning outer wall paint
CN102367397A (en) * 2010-10-11 2012-03-07 青岛海芬海洋生物科技有限公司 Marine organism antibiosis floor cleaning agent
CN102511507A (en) * 2011-12-16 2012-06-27 青岛海芬海洋生物科技有限公司 Marine bios sterilization solution

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5761066A (en) * 1980-10-01 1982-04-13 Nippon Oil & Fats Co Ltd Mildewproofing paint composition
CN101210143A (en) * 2006-12-31 2008-07-02 北京金源化学集团有限公司 Environment-friendly type long-acting mildew-resisting paint and preparing method thereof
CN101705038A (en) * 2009-11-19 2010-05-12 黄宏亭 Dirt-resistant self-cleaning outer wall paint
CN102367397A (en) * 2010-10-11 2012-03-07 青岛海芬海洋生物科技有限公司 Marine organism antibiosis floor cleaning agent
CN102511507A (en) * 2011-12-16 2012-06-27 青岛海芬海洋生物科技有限公司 Marine bios sterilization solution

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108610801A (en) * 2017-05-25 2018-10-02 太仓安托建筑材料有限公司 A kind of inner wall mold-proof paint
CN111087859A (en) * 2019-12-24 2020-05-01 江西省颐冠涂料有限公司 Nanoscale anti-mildew coating
CN111117377A (en) * 2019-12-24 2020-05-08 江西省颐冠涂料有限公司 Super-hydrophilic self-cleaning coating and preparation method thereof

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