CN109370170A - 一种高保温可降解地膜材料及其制备方法 - Google Patents

一种高保温可降解地膜材料及其制备方法 Download PDF

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CN109370170A
CN109370170A CN201811253737.9A CN201811253737A CN109370170A CN 109370170 A CN109370170 A CN 109370170A CN 201811253737 A CN201811253737 A CN 201811253737A CN 109370170 A CN109370170 A CN 109370170A
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仲春
王秋波
项衡
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Suzhou Fuhui Material Technology Co Ltd
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Abstract

本发明公开了一种高保温可降解地膜材料及其制备方法,按重量份包括以下组分:聚己二酸/对苯二甲酸丁二酯50~70份;聚碳酸亚丙酯20~50份;聚乳酸2~15份;聚羟基脂肪酸酯10~20份;受阻酚类抗氧剂3~6份;苯乙烯马来酸酐共聚物接枝聚丙烯5~11份;芥酸酰胺0.7~2.3份;木糖醇1~2.5份;乙酰柠檬酸三丁酯0.5~7份;γ‑氨丙基三乙氧基硅烷0.1~0.7份;滑石粉20~40份。本发明制备的高保温可降解地膜材料在具有良好降解能力的同时具有良好的保温效果。

Description

一种高保温可降解地膜材料及其制备方法
技术领域
本发明涉及一种高保温可降解地膜材料及其制备方法。
背景技术
现有的可降解地膜在保温方面有待提高,现有的PBAT生物降解地膜相比PE地膜的保温效果差,而另一种可降解地膜PLA地膜强度高且脆,成膜性差。
鉴于上述问题,有需要研发一种高保温可降解地膜材料。
发明内容
本发明的目的在于提供一种高保温可降解地膜材料及其制备方法,旨在解决上述问题。
为了实现上述目的,本发明的技术方案是设计一种高保温可降解地膜材料,其特征在于,按重量份包括以下组分:
聚己二酸/对苯二甲酸丁二酯 50~70份;
聚碳酸亚丙酯 20~50份;
聚乳酸 2~15份;
聚羟基脂肪酸酯 10~20份;
受阻酚类抗氧剂 3~6份;
苯乙烯马来酸酐共聚物接枝聚丙烯5~11份;
芥酸酰胺 0.7~2.3份;
木糖醇 1~2.5份;
乙酰柠檬酸三丁酯 0.5~7份;
γ-氨丙基三乙氧基硅烷 0.1~0.7份;
滑石粉 20~40份。
一种高保温可降解地膜材料的制备方法,包括以下步骤:
步骤一、将聚己二酸/对苯二甲酸丁二酯、聚碳酸亚丙酯、聚乳酸在75~80℃下干燥7~10h,待冷却至室温后搅拌混合1~2h后备用;
步骤二、向滑石粉加入γ-氨丙基三乙氧基硅烷,搅拌30~45min后待用;
步骤三、向步骤一种的混合物依次加入聚羟基脂肪酸酯、受阻酚类抗氧剂、苯乙烯马来酸酐共聚物接枝聚丙烯、芥酸酰胺、木糖醇、乙酰柠檬酸三丁酯,并在50~60℃下搅拌30~45min;然后加入步骤二中的滑石粉混合物,继续搅拌10~20min后出料;
步骤四、将上述混合好的物料输送进入双螺杆挤出机进行熔融共混,挤出机温度设定150~180℃,螺杆转速50~150rpm,再经过风环冷却造粒获得吹膜母粒,待用;
步骤五、将上述吹膜母粒经多层共挤吹胀成膜,得高保温可降解地膜材料。
本发明的优点和有益效果在于:本发明制备的高保温可降解地膜材料在具有良好降解能力的同时具有良好的保温效果。
具体实施方式
下面结合实施例,对本发明的具体实施方式作进一步描述。以下实施例仅用于更加清楚地说明本发明的技术方案,而不能以此来限制本发明的保护范围。
实施例1:
高保温可降解地膜材料,按重量份包括以下组分:聚己二酸/对苯二甲酸丁二酯 50份;聚碳酸亚丙酯 20份;聚乳酸 2份;聚羟基脂肪酸酯 10份;受阻酚类抗氧剂 3份;苯乙烯马来酸酐共聚物接枝聚丙烯 5份;芥酸酰胺 0.7份;木糖醇 1份;乙酰柠檬酸三丁酯 0.5份;γ-氨丙基三乙氧基硅烷 0.1份。滑石粉 20份。
制备方法,包括以下步骤:
步骤一、将聚己二酸/对苯二甲酸丁二酯、聚碳酸亚丙酯、聚乳酸在75~80℃下干燥7~10h,待冷却至室温后搅拌混合1~2h后备用;
步骤二、向滑石粉加入γ-氨丙基三乙氧基硅烷,搅拌30~45min后待用;
步骤三、向步骤一种的混合物依次加入聚羟基脂肪酸酯、受阻酚类抗氧剂、苯乙烯马来酸酐共聚物接枝聚丙烯、芥酸酰胺、木糖醇、乙酰柠檬酸三丁酯,并在50~60℃下搅拌30~45min;然后加入步骤二中的滑石粉混合物,继续搅拌10~20min后出料;
步骤四、将上述混合好的物料输送进入双螺杆挤出机进行熔融共混,挤出机温度设定150~180℃,螺杆转速50~150rpm,再经过风环冷却造粒获得吹膜母粒,待用;
步骤五、将上述吹膜母粒经多层共挤吹胀成膜,得高保温可降解地膜材料。
实施例2:
高保温可降解地膜材料,按重量份包括以下组分:聚己二酸/对苯二甲酸丁二酯 70份;聚碳酸亚丙酯 50份;聚乳酸 15份;聚羟基脂肪酸酯 20份;受阻酚类抗氧剂 6份;苯乙烯马来酸酐共聚物接枝聚丙烯 11份;芥酸酰胺 2.3份;木糖醇 2.5份;乙酰柠檬酸三丁酯 7份;γ-氨丙基三乙氧基硅烷 0.7份;滑石粉 40份。
制备方法,包括以下步骤:
步骤一、将聚己二酸/对苯二甲酸丁二酯、聚碳酸亚丙酯、聚乳酸在75~80℃下干燥7~10h,待冷却至室温后搅拌混合1~2h后备用;
步骤二、向滑石粉加入γ-氨丙基三乙氧基硅烷,搅拌30~45min后待用;
步骤三、向步骤一种的混合物依次加入聚羟基脂肪酸酯、受阻酚类抗氧剂、苯乙烯马来酸酐共聚物接枝聚丙烯、芥酸酰胺、木糖醇、乙酰柠檬酸三丁酯,并在50~60℃下搅拌30~45min;然后加入步骤二中的滑石粉混合物,继续搅拌10~20min后出料;
步骤四、将上述混合好的物料输送进入双螺杆挤出机进行熔融共混,挤出机温度设定150~180℃,螺杆转速50~150rpm,再经过风环冷却造粒获得吹膜母粒,待用;
步骤五、将上述吹膜母粒经多层共挤吹胀成膜,得高保温可降解地膜材料。
实施例3:
高保温可降解地膜材料,按重量份包括以下组分:聚己二酸/对苯二甲酸丁二酯 65份;聚碳酸亚丙酯 37份;聚乳酸 11份;聚羟基脂肪酸酯 13份;受阻酚类抗氧剂 4.1份;苯乙烯马来酸酐共聚物接枝聚丙烯 7.3份;芥酸酰胺 1.7份;木糖醇 2.1份;乙酰柠檬酸三丁酯6.1份;γ-氨丙基三乙氧基硅烷 0.55份;滑石粉 33份。
制备方法,包括以下步骤:
步骤一、将聚己二酸/对苯二甲酸丁二酯、聚碳酸亚丙酯、聚乳酸在75~80℃下干燥7~10h,待冷却至室温后搅拌混合1~2h后备用;
步骤二、向滑石粉加入γ-氨丙基三乙氧基硅烷,搅拌30~45min后待用;
步骤三、向步骤一种的混合物依次加入聚羟基脂肪酸酯、受阻酚类抗氧剂、苯乙烯马来酸酐共聚物接枝聚丙烯、芥酸酰胺、木糖醇、乙酰柠檬酸三丁酯,并在50~60℃下搅拌30~45min;然后加入步骤二中的滑石粉混合物,继续搅拌10~20min后出料;
步骤四、将上述混合好的物料输送进入双螺杆挤出机进行熔融共混,挤出机温度设定150~180℃,螺杆转速50~150rpm,再经过风环冷却造粒获得吹膜母粒,待用;
步骤五、将上述吹膜母粒经多层共挤吹胀成膜,得高保温可降解地膜材料。
表1 实施例1~3的性能对比(采用膜材料厚度为15μm)
以上所述仅是本发明的优选实施方式,应当指出,对于本技术领域的普通技术人员来说,在不脱离本发明技术原理的前提下,还可以做出若干改进和润饰,这些改进和润饰也应视为本发明的保护范围。

Claims (5)

1.一种高保温可降解地膜材料,其特征在于,按重量份包括以下组分:
聚己二酸/对苯二甲酸丁二酯 50~70份;
聚碳酸亚丙酯 20~50份;
聚乳酸 2~15份;
聚羟基脂肪酸酯 10~20份;
受阻酚类抗氧剂 3~6份;
苯乙烯马来酸酐共聚物接枝聚丙烯5~11份;
芥酸酰胺 0.7~2.3份;
木糖醇 1~2.5份;
乙酰柠檬酸三丁酯 0.5~7份;
γ-氨丙基三乙氧基硅烷 0.1~0.7份;
滑石粉 20~40份。
2.根据权利要求1所述的一种高保温可降解地膜材料,其特征在于,按重量份包括以下组分:
聚己二酸/对苯二甲酸丁二酯 50份;
聚碳酸亚丙酯 20份;
聚乳酸 2份;
聚羟基脂肪酸酯 10份;
受阻酚类抗氧剂 3份;
苯乙烯马来酸酐共聚物接枝聚丙烯 5份;
芥酸酰胺 0.7份;
木糖醇 1份;
乙酰柠檬酸三丁酯 0.5份;
γ-氨丙基三乙氧基硅烷 0.1份;
滑石粉 20份。
3.根据权利要求1所述的一种高保温可降解地膜材料,其特征在于,按重量份包括以下组分:
聚己二酸/对苯二甲酸丁二酯 70份;
聚碳酸亚丙酯 50份;
聚乳酸 15份;
聚羟基脂肪酸酯 20份;
受阻酚类抗氧剂 6份;
苯乙烯马来酸酐共聚物接枝聚丙烯 11份;
芥酸酰胺 2.3份;
木糖醇 2.5份;
乙酰柠檬酸三丁酯 7份;
γ-氨丙基三乙氧基硅烷 0.7份;
滑石粉 40份。
4.根据权利要求1所述的一种高保温可降解地膜材料,其特征在于,按重量份包括以下组分:
聚己二酸/对苯二甲酸丁二酯 65份;
聚碳酸亚丙酯 37份;
聚乳酸 11份;
聚羟基脂肪酸酯 13份;
受阻酚类抗氧剂 4.1份;
苯乙烯马来酸酐共聚物接枝聚丙烯 7.3份;
芥酸酰胺 1.7份;
木糖醇 2.1份;
乙酰柠檬酸三丁酯 6.1份;
γ-氨丙基三乙氧基硅烷 0.55份;
滑石粉 33份。
5.根据权利要求1~4所述的一种高保温可降解地膜材料的制备方法,其特征在于,包括以下步骤:
步骤一、将聚己二酸/对苯二甲酸丁二酯、聚碳酸亚丙酯、聚乳酸在75~80℃下干燥7~10h,待冷却至室温后搅拌混合1~2h后备用;
步骤二、向滑石粉加入γ-氨丙基三乙氧基硅烷,搅拌30~45min后待用;
步骤三、向步骤一种的混合物依次加入聚羟基脂肪酸酯、受阻酚类抗氧剂、苯乙烯马来酸酐共聚物接枝聚丙烯、芥酸酰胺、木糖醇、乙酰柠檬酸三丁酯,并在50~60℃下搅拌30~45min;然后加入步骤二中的滑石粉混合物,继续搅拌10~20min后出料;
步骤四、将上述混合好的物料输送进入双螺杆挤出机进行熔融共混,挤出机温度设定150~180℃,螺杆转速50~150rpm,再经过风环冷却造粒获得吹膜母粒,待用;
步骤五、将上述吹膜母粒经多层共挤吹胀成膜,得高保温可降解地膜材料。
CN201811253737.9A 2018-10-26 2018-10-26 一种高保温可降解地膜材料及其制备方法 Pending CN109370170A (zh)

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