CN109355917B - 一种铺地植绒材料及其制备方法 - Google Patents
一种铺地植绒材料及其制备方法 Download PDFInfo
- Publication number
- CN109355917B CN109355917B CN201811037364.1A CN201811037364A CN109355917B CN 109355917 B CN109355917 B CN 109355917B CN 201811037364 A CN201811037364 A CN 201811037364A CN 109355917 B CN109355917 B CN 109355917B
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- Prior art keywords
- flocking
- coating
- layer
- adhesive
- base cloth
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Abstract
本发明提供一种铺地植绒材料及其制备方法,由植绒面料复合底材组成,所述的植绒面料,包括上层绒毛层、中间层粘合剂层、下层基布层;所述底材为高分子材料。所述黏合剂层采用的原料为丙烯酸酯、聚氨酯、环氧树脂中的一种;所述绒毛层,其绒毛材质为聚酰胺纤维、聚酯纤维中的一种或多种混植,纤度为10‑30D,长度为2.0‑4.0mm。本发明铺地植绒材料具有自保洁功能,阻燃达B1级以上,且具有抑菌和抗静电效果。
Description
技术领域
本发明涉及一种铺地植绒材料及其制备方法,属于静电植绒技术领域。
技术背景
随着人们生活水平的提高,在住房内装饰方面的要求越来越高,目前的铺地材料主要是瓷砖、木地板、地毯。瓷砖易使人滑跌,尤其是对老人、儿童以及行动不便的患者具有很大的安全隐患,且脚感坚硬、不舒适,行走会发产生不小的噪音,铺装复杂,施工繁琐,更换困难;而木地板选用天然木材,对室内的干湿度要求较高,容易出现湿胀干缩和翘曲变形、板面开裂等现象,易腐蚀虫蛀,安装保养复杂。铺设地毯是人们很好的选择;市面上普通的簇绒地毯容易藏污纳垢、且不易打理。
较为受欢迎的是静电植绒地毯,但由于目前的静电植绒技术尚不成熟,现有的静电植绒铺地产品质量不高,功能性不强。
因此,设计一种易清洁、耐磨防滑、隔音降噪、阻燃抑菌、抗静电的静电植绒铺地材料成为本领域关注的研发课题之一。
发明内容
针对以上技术问题,本发明提供一种铺地植绒材料及其制备方法,达到以下发明目的:提高铺地植绒材料的阻燃效果、抑菌功能以及抗静电功能。
本发明采用的技术方案是:
一种铺地植绒材料由植绒面料复合底材组成。所述的植绒面料,包括上层绒毛层、中间层粘合剂层、下层基布层。所述绒毛层,其绒毛材质为聚酰胺纤维、聚酯纤维中的一种或多种混植,纤度为10-30D,长度为2.0-4.0mm;
所述黏合剂层为添加麻杆粉、磷酸三苯酯、石墨烯分散液的丙烯酸酯、聚氨酯、环氧树脂中的一种,麻杆粉目数为800-2000目,添加量为0-30wt%,无卤阻燃剂添加量为0-30%,石墨烯分散液浓度为0.001mg/mL-100.0mg/mL;
所述基布层,基布为织物或者无纺布,其材质为棉纤维、麻纤维、聚酯纤维、聚烯烃纤维、玄武岩纤维、碳纤维中的一种或多种混织或混纺,单位面积质量为100-250g/m2。
所述复合底材是在植绒面料背面涂布、流延或贴合高分子材料。
一种铺地植绒材料的制备方法,包括基布层处理、涂布粘合剂、多电场植绒、固着、后处理、后整理、复合底材、裁切、包装步骤。
具体步骤如下:
1、基布层处理
将基布选用的织物或无纺布,经轧光处理制成,其作用在于提高光滑度、均匀度、平整度和柔软性,减少涂层胶用量,提高植绒牢度。所述轧光处理工艺:温度50-100℃,压力0.1-0.5MPa,时间:0.1-5秒。
2、涂布粘合剂
将基布引入涂胶台,在基布上涂布粘合剂,涂布厚度为0.5-2mm。所述涂布粘合剂包括一次涂布或多次涂布,涂布方式可以是刮涂,辊涂,喷涂。所述多次涂布粘合剂包括每次涂布粘合剂之后烘干,以便于再次涂布粘合剂,烘干温度为60-120℃,时间为30-90s。
3、多电场植绒
将涂布粘合剂的基布引入静电植绒室,对涂布粘合剂的一面进行静电场植绒。所述多电场植绒包括多次植绒,每次植绒之间的时间间隔为0.5-5s;所述植绒为直流静电场植绒或交流静电场植绒,上述两种静电场可重复或交互使用。所述直流静电场的电压为0.5-4.5万伏;所述交流静电场的电压0.5-4.5万伏,频率为50-100Hz。所述直流静电场和交流静电场:上、下电极间距均为5-20cm;所述多电场植绒:控制植绒时间为10-70s。
4、固着
将植绒之后的材料引入烘箱,进行高温固着,所述高温固着:温度110-160℃,时间3-10min。
5、后处理
将高温固着之后的材料进行冷却、刷绒、吸绒。所述冷却:经冷却辊或冷风冷却至10-50℃;所述刷绒:由辊刷对植绒材料绒毛面进行一次或多次刷绒,目的是刷掉表面的浮绒;所述吸绒:由真空系统对刷掉的浮绒进行真空抽吸,并将浮绒回收。
6、后整理
将步骤5得到的植绒面料表面施加整理液、焙烘、冷却、打卷。所述施加整理液,其方式为刮涂,带液率为50-80%;所述整理液为纳米有机硅或纳米有机氟丙烯酸、脂肪醇硫酸钠、聚氨酯,按照40-150:4-25:5-20的质量比,混合发泡,发泡倍率为3-6倍;所述焙烘为热风烘干,焙烘温度为130-150℃,焙烘时间为3-5min;
7、复合底材
在步骤6得到的植绒面料背面,采用涂布、流延或贴合的工艺复合上底材,底材厚度为2-4mm。
所述涂布工艺:在毯带上涂布高分子材料湿浆,湿浆厚度为1-3mm,再将增强材料平整的铺在湿浆上表面,之后在增强材料表面涂布厚度为1-3mm的高分子材料湿浆;采用的高分子材料为软质聚氯乙烯、乳胶、聚氨酯湿浆中的一种,粘度为1.5-5万cps;所述增强材料为玻璃纤维、碳纤维、玄武岩纤维、聚酰胺纤维的织物或无纺材料中的一种,增强材料厚度为0.2-2mm,单位面积质量为20-80g/m2。
随后将步骤6得到的面料绒毛面朝上平整铺放于高分子材料表面,经轧辊复合,送往烘箱进行高温烘干,冷却辊冷却,完成复合。
所述流延工艺:采用的底材为热塑性聚氨酯(TPU)、硫化热塑性弹性体(TPV)、热塑性橡胶(TPR)、热塑性聚酯弹性体(TPEE)中的一种或多种;
将上述底材熔融、挤出、流延至毯带上,厚度控制在2-5mm,之后将步骤6得到的面料绒毛面朝上平整铺放于底材材料表面,经轧辊复合,送往烘箱进行高温烘干,冷却辊冷却,完成复合。
所述贴合工艺:是将片状高分子材料表面涂布粘合剂,再将步骤6得到的面料绒毛朝上,平整铺放在粘合剂表面,将其放置于热压机中热压4-30min,压力为5-50Mpa,之后取出冷却。所述片状高分子材料指硬质聚氯乙烯或塑胶材料。
8、裁切与包装
将复合底材后的铺地材料按照客户需要的尺寸进行裁切、包装。
本发明带来的有益效果:
1.本发明制作的铺地植绒材料具有自保洁功能,防水、防油、防污、易去污效果可达4级以上,不易脏污,即使脏污清水擦拭即可,维护成本低;
2.本发明制作的铺地植绒材料阻燃达B1级以上,安全性能高;
3.本发明制作的铺地植绒材料抑菌效果好,大肠杆菌、金黄色葡萄球菌、白色念珠球菌有效抑制率可达99.5%以上;
4.本发明制作的铺地植绒材料抗静电效果好,抗静电性能≤2kV;
5.本发明制作的铺地植绒材料结实耐磨,正常使用寿命10年以上。
具体实施方式
实施例1
一种铺地植绒材料由植绒面料复合底材组成。所述的植绒面料,包括上层绒毛层、中间层粘合剂层、下层基布层。所述绒毛层,其绒毛材质为聚酰胺66,纤度为10D,长度为2mm;
所述黏合剂层为含有汉麻杆粉的水性丙烯酸酯;所述汉麻杆粉:粒径为800目,添加量为10wt%,粘度为2.0万cps;
所述基布层,基布为聚丙烯无纺布,单位面积质量为100g/m2。
所述复合底材是在植绒面料背面涂布高分子材料。
一种铺地植绒材料及其制备方法,包括基布层处理、涂布粘合剂、多电场植绒、固着、后处理、后整理、复合底材、裁切、包装步骤。
具体步骤如下:
1.基布层处理
将无纺布经轧光处理,所述轧光处理工艺:温度50℃,压力0.5MPa,时间:5秒;
2.涂布粘合剂
将基布引入涂胶台,在基布上涂布粘合剂,涂布厚度为0.5mm。
所述涂布粘合剂采用一次涂布,涂布方式为刮涂。
烘干温度为80℃,时间为50s。
3.多电场植绒
将涂布粘合剂的基布引入静电植绒室,对涂布粘合剂的一面进行静电场植绒。
所述静电场植绒为六次植绒,依次为两次直流静电场、四次交流静电场;
记直流静电场为M,交流静电场为N,M、N的数目均为大于0的整数,采用MMNNNN式静电场。
所述两次直流静电场电压分别是1.2万伏、1.6万伏,上、下电极间距为8cm;
所述四次交流静电场电压分别是1.6万伏、2.0万伏、2.8万伏、3.5万伏,频率均为50Hz,上、下电极间距均为8cm;
上述六次植绒,控制单次植绒时间为10s,六次植绒间隔时间分别为1s、1s、1s、1.5s、2s。
4.固着
将植绒之后的材料引入烘箱,进行高温固着,所述高温固着:温度110℃,时间10min。
5.后处理
将高温固着之后的材料进行冷却、刷绒、吸绒。所述冷却:经冷却辊冷却至10℃;所述刷绒:由辊刷对植绒材料绒毛面进行三次刷绒,目的是刷掉表面的浮绒;所述吸绒:由真空系统对刷掉的浮绒进行真空抽吸,并将浮绒回收。
6.后整理
将步骤5得到的植绒面料表面施加整理液、焙烘、冷却、打卷。所述施加整理液,其方式为刮涂,带液率为50%;所述整理液为纳米有机氟丙烯酸、脂肪醇硫酸钠、聚氨酯的混合溶液发泡,发泡倍率为5倍;组分浓度分别为100g/L,15g/L,10g/L;所述焙烘为热风烘干,焙烘温度为130℃,焙烘时间为5min。
7.复合底材
在步骤6得到的面料背面,采用涂布的工艺复合上底材,底材厚度为2mm。
所述涂布工艺:在毯带上涂布高分子材料湿浆,湿浆厚度为1mm,再将增强材料平整的铺在湿浆上表面,之后在增强材料表面涂布高分子材料湿浆,涂布厚度为1mm;
所述高分子材料为软质聚氯乙烯,粘度为1.5万cps;所述增强材料为玻璃纤维无纺材料(以下简称玻纤),增强材料厚度为0.5mm,单位面积质量为50g/m2。
随后将步骤6得到的面料绒毛面朝上平整铺放于高分子材料表面,经轧辊复合,送往烘箱进行高温烘干,冷却辊冷却,完成复合。
8.裁切与包装
将复合底材后的铺地材料按照客户需要的尺寸进行裁切、包装。
本实施例带来的有益效果:
1.本发明制作的铺地植绒材料具有自保洁功能,防水、防油、防污、易去污效果可达4级以上,不易脏污,即使脏污清水擦拭即可,维护成本低;
2.本发明制作的铺地植绒材料阻燃达B1级以上,安全性能高;
3.本发明制作的铺地植绒材料抑菌效果好,大肠杆菌、金黄色葡萄球菌、白色念珠球菌有效抑制率可达99.9%以上;
4.本发明制作的铺地植绒材料抗静电效果好,抗静电性能≤2kV;
5.本发明制作的铺地植绒材料结实耐磨,正常使用寿命10年以上。
实施例2
一种铺地植绒材料由植绒面料复合底材组成。所述的植绒面料,包括上层绒毛层、中间层粘合剂层、下层基布层。所述绒毛层,其绒毛材质为阻燃聚酰胺66,纤度为20D,长度为4mm;
所述黏合剂层为添加无卤阻燃剂的阻燃水性丙烯酸酯,粘度为3万cps,所述无卤阻燃剂为磷酸三苯酯,添加量为10wt%;
所述基布层,基布为玄武岩纤维织物,单位面积质量为150g/m2。
所述复合底材是在植绒面料背面涂布高分子材料。
一种铺地植绒材料及其制备方法,包括基布层处理、涂布粘合剂、多电场植绒、固着、后处理、后整理、复合底材、裁切、包装步骤。
具体步骤如下:
1.基布层处理
将玄武岩纤维织物经轧光处理制成,其作用在于提高光滑度、均匀度、平整度和柔软性,减少涂层胶用量,提高植绒牢度。所述轧光处理工艺:温度80℃,压力0.3MPa,时间:2秒。
2.涂布粘合剂
将基布引入涂胶台,在基布上涂布粘合剂,涂布厚度为2mm。所述涂布粘合剂采用两次涂布,涂布方式采用刮涂。第一次涂布粘合剂厚度为0.5mm,烘干温度为80℃,烘干时间为20s,第二次涂布粘合剂厚度为1.5mm。
3.多电场植绒
将涂布粘合剂的基布引入静电植绒室,对涂布粘合剂的一面进行静电场植绒。
所述静电场植绒为六次植绒,依次为两次直流静电场、四次交流静电场;
记直流静电场为M,交流静电场为N,M、N的数目均为大于0的整数,采用MMNNNN式静电场。
所述两次直流静电场:电压分别是1.2万伏、1.6万伏,上、下电极间距为8cm;
所述四次交流静电场:电压分别是1.6万伏、2.0万伏、2.8万伏、3.5万伏,频率均为50Hz,上、下电极间距均为8cm;
上述六次植绒:控制单次植绒时间为10s,六次植绒间隔时间分别为1s、1s、1s、1.5s、2s。
4.固着
将植绒之后的材料引入烘箱,进行高温固着,所述高温固着:温度160℃,时间5min。
5.后处理
将高温固着之后的材料进行冷却、刷绒、吸绒。
所述冷却:经冷却辊冷却至30度;所述刷绒:由辊刷对植绒材料绒毛面进行三次刷绒,目的是刷掉表面的浮绒;所述吸绒:由真空系统对刷掉的浮绒进行真空抽吸,并将浮绒回收。
6.后整理
将步骤5得到的植绒面料表面施加整理液、焙烘、冷却、打卷。
所述施加整理液,其方式为刮涂,带液率为70%;
所述整理液为纳米有机氟丙烯酸、脂肪醇硫酸钠、聚氨酯的混合溶液发泡,浓度分别为90g/L,20g/L,10g/L;发泡倍率为4倍;
所述焙烘为热风烘干,焙烘温度为140℃,焙烘时间为4min。
7.复合底材
在步骤6得到的面料背面复合一层底材,底材厚度为3mm。
所述复合底材,采用发泡聚氯乙烯湿浆,粘度为2.2万cps;所述涂布工艺包括:在毯带上涂布高分子材料,厚度为1.5mm,随后将步骤6得到的面料绒毛面朝上平整铺放于高分子材料表面,经轧辊复合,送往烘箱进行高温烘干发泡,冷却辊冷却,完成复合。
8.裁切与包装
将复合底材后的铺地材料按照客户需要的尺寸进行裁切、包装。
本实施例带来的有益效果:
1.本发明制作的铺地植绒材料具有自保洁功能,防水、防油、防污、易去污效果可达4级以上,不易脏污,即使脏污清水擦拭即可,维护成本低;
2.本发明制作的铺地植绒材料阻燃达A级,安全性能高;
3.本发明制作的铺地植绒材料抑菌效果好,大肠杆菌、金黄色葡萄球菌、白色念珠球菌有效抑制率可达99.5%以上;
4.本发明制作的铺地植绒材料抗静电效果好,抗静电性能≤1.5kV;
5.本发明制作的铺地植绒材料结实耐磨,正常使用寿命10年以上。
本产品还具有轻量化的优点,单位面积重量为1.0kg/m2
实施例3
一种铺地植绒材料由植绒面料复合底材组成。所述的植绒面料,包括上层绒毛层、中间层粘合剂层、下层基布层。所述绒毛层,其绒毛材质为聚酰胺66,纤度为30D,长度为2.0mm;
所述黏合剂层为加入石墨烯分散液的水性丙烯酸酯,添加量为10wt%,粘度为3万cps,所述石墨烯分散液为N-甲基吡咯烷酮,浓度为50mg/mL;
所述基布层,基布为碳纤维织物,单位面积质量为250g/m2。
所述复合底材是在植绒面料背面涂布高分子材料。
一种铺地植绒材料及其制备方法,包括基布层处理、涂布粘合剂、多电场植绒、固着、后处理、后整理、复合底材、裁切、包装步骤。
具体步骤如下:
1.基布层处理
将碳纤维织物经轧光处理制成,其作用在于提高均匀度、平整度和柔软性,减少涂层胶用量,提高植绒牢度。所述轧光处理工艺:温度100℃,压力0.5MPa,时间:1.5秒。
2.涂布粘合剂
将基布引入涂胶台,在基布上涂布粘合剂,涂布厚度为2mm。
所述涂布粘合剂采用两次涂布,涂布方式采用刮涂。第一次涂布粘合剂厚度为0.5mm,烘干温度为80℃,烘干时间为20s,第二次涂布粘合剂厚度为1.5mm。
3.多电场植绒
将涂布粘合剂的基布引入静电植绒室,对涂布粘合剂的一面进行静电场植绒。
所述静电场植绒为六次植绒,记直流静电场为M,交流静电场为N,M、N的数目均为大于0的整数,采用MMNNNN式静电场。所述两次直流静电场电压分别是1.0万伏、1.4万伏,上、下电极间距为8cm;所述四次交流静电场电压分别是1.4万伏、1.8万伏、2.2万伏、3.0万伏,频率均为50Hz,上、下电极间距均为8cm;控制单次植绒时间为10s,六次植绒间隔时间分别为1s、1s、1s、1.5s、2s。
4.固着
将植绒之后的材料引入烘箱,进行高温固着,所述高温固着:温度140℃,时间6min。
5.后处理
将高温固着之后的材料进行冷却、刷绒、吸绒。所述冷却:经冷风冷却至20℃;所述刷绒:由辊刷对植绒材料绒毛面进行两次刷绒,目的是刷掉表面的浮绒;所述吸绒:由真空系统对刷掉的浮绒进行真空抽吸,并将浮绒回收。
6.后整理
将步骤5得到的植绒面料表面施加整理液、焙烘、冷却、打卷。
所述施加整理液,其方式为刮涂,带液率为70%;
所述整理液为纳米有机氟丙烯酸、脂肪醇硫酸钠、聚氨酯的混合溶液发泡,浓度分别为120g/L,4g/L,15g/L;发泡倍率为5倍;
所述焙烘为热风烘干,焙烘温度为140℃,焙烘时间为3min。
7.复合底材
将步骤6得到的面料背面复合底材,底材厚度为2mm。
所述涂布高分子材料工艺,底材为加有亲油性石墨烯的聚氯乙烯湿浆,石墨烯添加量为5wt%,粘度为5万cps;所述涂布工艺包括:在毯带上涂布湿浆,厚度为2mm,随后将步骤6得到的面料绒毛面朝上平整铺放于湿浆表面,经轧辊复合,送往烘箱进行高温烘干,冷却辊冷却,完成复合。
8.裁切与包装
将复合底材后的铺地材料按照客户需要的尺寸进行裁切、包装。
本实施例带来的有益效果是:
1.本发明制作的铺地植绒材料具有自保洁功能,防水、防油、防污、易去污效果可达4级以上,不易脏污,即使脏污清水擦拭即可,维护成本低;
2.本发明制作的铺地植绒材料阻燃达A级,安全性能高;
3.本发明制作的铺地植绒材料抑菌效果好,大肠杆菌、金黄色葡萄球菌、白色念珠球菌有效抑制率可达99.5%以上;
4.本发明制作的铺地植绒材料抗静电效果好,抗静电指标u30为0.3kV,且具有永久抗静电效果;
5.本发明制作的铺地植绒材料结实耐磨,正常使用寿命10年以上。
最后应该说明的是:以上所述仅为本发明的优选实施例而已,并不用于限制本发明,尽管参照前述实施例对本发明进行了详细说明,对于本领域的技术人员来说,其依然可以对前述各实施例所记载的技术方案进行修改,或者对其中部分技术特征进行等同替换。凡在本发明的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。
Claims (1)
1.一种铺地植绒材料的制备方法,其特征在于:包括基布层处理、涂布粘合剂、多电场植绒、固着、后处理、后整理、复合底材、裁切、包装步骤;
所述的植绒面料,包括上层绒毛层、中间层粘合剂层、下层基布层,所述绒毛层,其绒毛材质为聚酰胺66,纤度为30D,长度为2.0mm;所述黏合剂层为加入石墨烯分散液的水性丙烯酸酯,添加量为10wt%,粘度为3万cps,所述石墨烯分散液为N-甲基吡咯烷酮,浓度为50mg/mL;所述基布层,基布为碳纤维织物,单位面积质量为250g/m2;所述复合底材是在植绒面料背面涂布高分子材料;
所述基布层处理:将碳纤维织物经轧光处理制成,其作用在于提高均匀度、平整度和柔软性,减少涂层胶用量,提高植绒牢度;所述轧光处理工艺:温度100℃,压力0.5MPa ,时间:1 .5秒;
所述涂布粘合剂:将基布引入涂胶台,在基布上涂布粘合剂,涂布厚度为2mm; 所述涂布粘合剂采用两次涂布,涂布方式采用刮涂,第一次涂布粘合剂厚度为0.5mm,烘干温度为80℃,烘干时间为20s,第二次涂布粘合剂厚度为1 .5mm;
所述多电场植绒:将涂布粘合剂的基布引入静电植绒室,对涂布粘合剂的一面进行静电场植绒;所述静电场植绒为六次植绒,记直流静电场为M,交流静电场为N,采用MMNNNN式静电场;所述两次直流静电场电压分别是1 .0万伏、1 .4万伏,上、下电极间距为8cm;所述四次交流静电场电压分别是1 .4万伏、1 .8万伏、2 .2万伏、3 .0万伏,频率均为50Hz,上、下电极间距均为8cm;控制单次植绒时间为10s,六次植绒间隔时间分别为1s、1s、1s、1 .5s、2s;
所述固着:将植绒之后的材料引入烘箱,进行高温固着,所述高温固着:温度140℃,时间6min;
所述后处理:将高温固着之后的材料进行冷却、刷绒、吸绒,所述冷却:经冷风冷却至20℃;所述刷绒:由辊刷对植绒材料绒毛面进行两次刷绒,目的是刷掉表面的浮绒;所述吸绒:由真空系统对刷掉的浮绒进行真空抽吸,并将浮绒回收;
所述后整理:将后处理步骤得到的植绒面料表面施加整理液、焙烘、冷却、打卷;所述施加整理液,其方式为刮涂,带液率为70%;
所述整理液为纳米有机氟丙烯酸、脂肪醇硫酸钠、聚氨酯的混合溶液发泡,浓度分别为120g/L,4g/L,15g/L;发泡倍率为5倍;所述焙烘为热风烘干,焙烘温度为140℃,焙烘时间为3min;
所述复合底材:将后整理步骤得到的面料背面复合底材,底材厚度为2mm;
所述涂布高分子材料工艺,底材为加有亲油性石墨烯的聚氯乙烯湿浆,石墨烯添加量为5wt% ,粘度为5万cps;所述涂布工艺包括:在毯带上涂布湿浆,厚度为2mm,随后将后整理步骤得到的面料绒毛面朝上平整铺放于湿浆表面,经轧辊复合,送往烘箱进行高温烘干,冷却辊冷却,完成复合;
所述裁切与包装:将复合底材后的铺地材料按照客户需要的尺寸进行裁切、包装。
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