CN109336391A - A kind of rare earth color-change ceramic glaze and preparation method thereof - Google Patents
A kind of rare earth color-change ceramic glaze and preparation method thereof Download PDFInfo
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- CN109336391A CN109336391A CN201811587177.0A CN201811587177A CN109336391A CN 109336391 A CN109336391 A CN 109336391A CN 201811587177 A CN201811587177 A CN 201811587177A CN 109336391 A CN109336391 A CN 109336391A
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- 238000002360 preparation method Methods 0.000 title claims abstract description 40
- 239000000919 ceramic Substances 0.000 title claims abstract description 39
- 229910052761 rare earth metal Inorganic materials 0.000 title claims abstract description 36
- 150000002910 rare earth metals Chemical class 0.000 title claims abstract description 35
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 36
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 claims description 32
- 239000002994 raw material Substances 0.000 claims description 22
- 238000000227 grinding Methods 0.000 claims description 17
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 16
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 claims description 16
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 claims description 16
- 229910052593 corundum Inorganic materials 0.000 claims description 16
- VQCBHWLJZDBHOS-UHFFFAOYSA-N erbium(III) oxide Inorganic materials O=[Er]O[Er]=O VQCBHWLJZDBHOS-UHFFFAOYSA-N 0.000 claims description 16
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 16
- FKTOIHSPIPYAPE-UHFFFAOYSA-N samarium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Sm+3].[Sm+3] FKTOIHSPIPYAPE-UHFFFAOYSA-N 0.000 claims description 16
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 16
- FIXNOXLJNSSSLJ-UHFFFAOYSA-N ytterbium(III) oxide Inorganic materials O=[Yb]O[Yb]=O FIXNOXLJNSSSLJ-UHFFFAOYSA-N 0.000 claims description 16
- 229910052681 coesite Inorganic materials 0.000 claims description 14
- 229910052906 cristobalite Inorganic materials 0.000 claims description 14
- 239000000377 silicon dioxide Substances 0.000 claims description 14
- 229910052682 stishovite Inorganic materials 0.000 claims description 14
- 229910052905 tridymite Inorganic materials 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 12
- 239000005995 Aluminium silicate Substances 0.000 claims description 8
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 8
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 8
- 239000004115 Sodium Silicate Substances 0.000 claims description 8
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 8
- 235000012211 aluminium silicate Nutrition 0.000 claims description 8
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical class [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 claims description 8
- 238000001816 cooling Methods 0.000 claims description 8
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 8
- 239000004571 lime Substances 0.000 claims description 8
- PLDDOISOJJCEMH-UHFFFAOYSA-N neodymium oxide Inorganic materials [O-2].[O-2].[O-2].[Nd+3].[Nd+3] PLDDOISOJJCEMH-UHFFFAOYSA-N 0.000 claims description 8
- 229910052698 phosphorus Inorganic materials 0.000 claims description 8
- 239000011574 phosphorus Substances 0.000 claims description 8
- 238000010298 pulverizing process Methods 0.000 claims description 8
- 239000010453 quartz Substances 0.000 claims description 8
- 235000019795 sodium metasilicate Nutrition 0.000 claims description 8
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 8
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 8
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 8
- 229960001763 zinc sulfate Drugs 0.000 claims description 8
- 229910000368 zinc sulfate Inorganic materials 0.000 claims description 8
- 235000012222 talc Nutrition 0.000 claims description 7
- 238000000498 ball milling Methods 0.000 claims description 2
- 239000000454 talc Substances 0.000 claims description 2
- 229910052623 talc Inorganic materials 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims 2
- 239000003086 colorant Substances 0.000 abstract description 4
- 239000003973 paint Substances 0.000 abstract description 4
- 238000002845 discoloration Methods 0.000 abstract description 3
- 239000011469 building brick Substances 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- 239000011449 brick Substances 0.000 abstract 1
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 14
- 229910052573 porcelain Inorganic materials 0.000 description 5
- 239000000243 solution Substances 0.000 description 3
- 229910052684 Cerium Inorganic materials 0.000 description 2
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 2
- 239000000037 vitreous enamel Substances 0.000 description 2
- 244000283207 Indigofera tinctoria Species 0.000 description 1
- 244000178870 Lavandula angustifolia Species 0.000 description 1
- 235000010663 Lavandula angustifolia Nutrition 0.000 description 1
- 229910052779 Neodymium Inorganic materials 0.000 description 1
- 229910052777 Praseodymium Inorganic materials 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- 244000061458 Solanum melongena Species 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- 229910052769 Ytterbium Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000015895 biscuits Nutrition 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000035622 drinking Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000001102 lavandula vera Substances 0.000 description 1
- 235000018219 lavender Nutrition 0.000 description 1
- 210000001161 mammalian embryo Anatomy 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 description 1
- 229910001404 rare earth metal oxide Inorganic materials 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Structural Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Glass Compositions (AREA)
Abstract
The invention discloses a kind of rare earth color-change ceramic glaze and preparation method thereof, the present invention can be widely applied in the ceramics glaze such as building brick glaze, vase, bottle, decorative craft, it also is used as discoloration glaze paint health brick, preparation process is simple, it is at low cost, performance is stablized, and industrialization production convenient to carry out and popularization and application have very vast market prospect.The present invention shows different colors under the irradiation of different light sources, while further improving glaze paint glossiness, improves intensity and chemical stability, hardness.
Description
Technical field
The invention belongs to ceramic material fields, and in particular to a kind of rare earth color-change ceramic glaze and preparation method thereof.
Background technique
Different colors can be presented under the irradiation of different light sources in changing colour enamal, also known as " different smooth chatoyance glaze ".Changing colour enamal is with advanced
The white glaze glaze of fine porcelain makees base glaze, is with the mixed rare-earth oxides such as metal oxide, nonmetal oxide and cerium, praseodymium, ytterbium
Glaze slip is made through certain process in color element, imposes on billet surface, under firing temperature appropriate, generates physics and chemistry
Variation generates a kind of new solid solution.
After usual porcelain is burnt out from kiln high temperature, whether blue and white porcelain or high-temperature color vitreous enamel (including white biscuit),
Its glaze face color will not all change, but due to mixed with a variety of rare earth elements such as neodymium, cerium in the glaze for the vitreous enamel that changes colour, through height
The variation of atmosphere when temperature is fired, the oxide in porcelain kiln can selectively absorb the light of certain wavelength, and the light of other wavelength is sent out
It penetrates or transmissive, glaze paint is made to show certain color.Lavender can be presented under sunlight in they, in daylight light
Under source, limpid peaceful Celeste is presented, under incandescent source, and aubergine can be become.Therefore, various with this glaze decorating
The various furnishings vessel such as day dining, tea, drinking utensils and sculpture, vase, the brilliance for all having one kind peculiar, they can be with different
10 multiple colors such as purple, indigo plant, rose, orange are changed in light source irradiation respectively, generate very witty, amazing art effect
Fruit makes original multicoloured porcelain seem more charming.
With the raising of people's quality of life and the transformation of consumption idea, it is desirable that construction material ceramic tile should have practicability,
There is artistry and appreciation again, therefore, the research of changing colour enamal has become a new research direction of ceramic field.From mesh
Come to see, due to being formulated the factors such as unreasonable, discoloration glaze always exists the defects of preparation cost is high, discoloration is uncertain.
Summary of the invention
The purpose of the present invention is to provide a kind of rare earth color-change ceramic glaze and preparation method thereof.
The technical solution used in the present invention is:
A kind of rare earth color-change ceramic glaze, which is characterized in that according to the mass fraction, including the following raw material: 70~100 parts of bases
Plinth glaze, 1~10 part of Nd2O3, 1~5 part of Yb2O3, 1~5 part of Sm2O3, 0.5~3 part of CrO3, 2~6 parts of Fe2O3, 5~15 parts
SiO2, 10~20 parts of Al2O3, 2~10 parts of CeO2, 10~20 parts of CaO；1~10 part of ZnO, 5~15 parts of Er2O3。
Preferably, according to the mass fraction, the base glaze include: 1~10 part of kaolin, 1~10 part of quartz, 5~
10 parts of barium carbonates, 10~25 parts of sodium metasilicate, 5~15 parts of manganese dioxide, 5~15 parts of talcum, 2~10 parts of phosphorus lime, zinc sulfate 4~
10 parts.
The preparation method of above-mentioned rare earth color-change ceramic glaze, which comprises the steps of:
(1) preparation of base glaze: by raw material ball mill wet ball grinding, 100~200 meshes are crossed, 1200 after drying
It is calcined 0.5~1.5 hour at~1300 DEG C, dry pulverization process after cooling crosses 100~200 meshes；
(2) base glaze, Nd the preparation of rare earth color-change ceramic glaze: are weighed2O3、Yb2O3、Sm2O3、CrO3、Fe2O3、
SiO2、Al2O3、CeO2,CaO；ZnO,Er2O3, with ball mill wet ball grinding, crossed after dry 100~200 meshes to get.
Preferably, the mass ratio of the wet ball grinding, glaze and water be 10:1~3, Ball-milling Time be 20~50min,
Revolving speed is 500~800r/min.
A kind of preparation method of rare earth color-change ceramic includes the following steps: above-mentioned rare earth color-change ceramic glaze imposing on embryo
20~50min is fired in body surface face at 900~1100 DEG C.
The beneficial effects of the present invention are:
(1) present invention can be widely applied in the ceramics glaze such as building brick glaze, vase, bottle, decorative craft, system
Standby simple process and low cost, performance are stablized, and industrialization production convenient to carry out and popularization and application have very vast market prospect.
(2) present invention shows different colors under the irradiation of different light sources, while further improving glaze paint glossiness, improves
Intensity and chemical stability, hardness.
Specific embodiment
The present invention is further illustrated combined with specific embodiments below.
Embodiment 1
Raw material: 100 parts of base glazes, 1 part of Nd2O3, 5 parts of Yb2O3, 1 part of Sm2O3, 3 parts of CrO3, 2 parts of Fe2O3, 15 parts of SiO2、
10 parts of Al2O3, 10 parts of CeO2, 10 parts of CaO；10 parts of ZnO, 5 parts of Er2O3。
Base glaze raw material: 1 part of kaolin, 10 parts of quartz, 5 parts of barium carbonates, 25 parts of sodium metasilicate, 5 parts of manganese dioxide, talcums
15 parts, 2 parts of phosphorus lime, 10 parts of zinc sulfate.
Preparation method:
(1) preparation of base glaze: raw material ball mill wet ball grinding sieves with 100 mesh sieve, and forges at 1300 DEG C after dry
It burns 0.5 hour, dry pulverization process after cooling crosses 200 meshes；
(2) base glaze, Nd the preparation of rare earth color-change ceramic glaze: are weighed2O3、Yb2O3、Sm2O3、CrO3、Fe2O3、
SiO2、Al2O3、CeO2、CaO、ZnO、Er2O3, with ball mill wet ball grinding, sieved with 100 mesh sieve after dry to get.
The preparation of rare earth color-change ceramic: rare earth color-change ceramic glaze is imposed on into idiosome surface, fires 40min at 900 DEG C.
Embodiment 2
Raw material: 70 parts of base glazes, 10 parts of Nd2O3, 1 part of Yb2O3, 5 parts of Sm2O3, 0.5 part of CrO3, 6 parts of Fe2O3, 5 parts
SiO2, 20 parts of Al2O3, 2 parts of CeO2, 20 parts of CaO, 1 part of ZnO, 15 parts of Er2O3。
Base glaze raw material: 10 parts of kaolin, 1 part of quartz, 10 parts of barium carbonates, 10 parts of sodium metasilicate, 15 parts of manganese dioxide, cunnings
5 parts of stone, 10 parts of phosphorus lime, 4 parts of zinc sulfate.
Preparation method:
(1) preparation of base glaze: by raw material ball mill wet ball grinding, 200 meshes is crossed, are forged at 1200 DEG C after dry
It burns 1.5 hours, dry pulverization process after cooling sieves with 100 mesh sieve；
(2) base glaze, Nd the preparation of rare earth color-change ceramic glaze: are weighed2O3、Yb2O3、Sm2O3、CrO3、Fe2O3、
SiO2、Al2O3、CeO2、CaO、ZnO、Er2O3, with ball mill wet ball grinding, crossed after dry 200 meshes to get.
The preparation of rare earth color-change ceramic: rare earth color-change ceramic glaze is imposed on into idiosome surface, is fired at 1000 DEG C
40min。
Embodiment 3
Raw material: 80 parts of base glazes, 7 parts of Nd2O3, 3 parts of Yb2O3, 2 parts of Sm2O3, 1 part of CrO3, 3 parts of Fe2O3, 8 parts of SiO2、15
Part Al2O3, 7 parts of CeO2, 15 parts of CaO；4 parts of ZnO, 8 parts of Er2O3。
Base glaze raw material: 7 parts of kaolin, 4 parts of quartz, 7 parts of barium carbonates, 18 parts of sodium metasilicate, 12 parts of manganese dioxide, talcums
11 parts, 7 parts of phosphorus lime, 7 parts of zinc sulfate.
Preparation method:
(1) preparation of base glaze: by raw material ball mill wet ball grinding, 200 meshes is crossed, are forged at 1200 DEG C after dry
It burns 0.5 hour, dry pulverization process after cooling sieves with 100 mesh sieve；
(2) base glaze, Nd the preparation of rare earth color-change ceramic glaze: are weighed2O3、Yb2O3、Sm2O3、CrO3、Fe2O3、
SiO2、Al2O3、CeO2、CaO、ZnO、Er2O3, with ball mill wet ball grinding, sieved with 100 mesh sieve after dry to get.
The preparation of rare earth color-change ceramic: rare earth color-change ceramic glaze is imposed on into idiosome surface, is fired at 1100 DEG C
50min。
Embodiment 4
Raw material: 90 parts of base glazes, 6 parts of Nd2O3, 4 parts of Yb2O3, 2 parts of Sm2O3, 2 parts of CrO3, 5 parts of Fe2O3, 11 parts of SiO2、
14 parts of Al2O3, 4 parts of CeO2, 16 parts of CaO, 6 parts of ZnO, 13 parts of Er2O3。
Base glaze raw material: 8 parts of kaolin, 8 parts of quartz, 6 parts of barium carbonates, 22 parts of sodium metasilicate, 13 parts of manganese dioxide, talcums
11 parts, 9 parts of phosphorus lime, 5 parts of zinc sulfate.
Preparation method:
(1) preparation of base glaze: by raw material ball mill wet ball grinding, 200 meshes is crossed, are forged at 1300 DEG C after dry
It burns 1.5 hours, dry pulverization process after cooling crosses 200 meshes；
(2) base glaze, Nd the preparation of rare earth color-change ceramic glaze: are weighed2O3、Yb2O3、Sm2O3、CrO3、Fe2O3、
SiO2、Al2O3、CeO2、CaO、ZnO、Er2O3, with ball mill wet ball grinding, crossed after dry 200 meshes to get.
The preparation of rare earth color-change ceramic: rare earth color-change ceramic glaze is imposed on into idiosome surface, fires 20min at 900 DEG C.
Embodiment 5
Raw material: 70 parts of base glazes, 10 parts of Nd2O3, 5 parts of Yb2O3, 2 parts of Sm2O3, 1 part of CrO3, 6 parts of Fe2O3, 14 parts of SiO2、
11 parts of Al2O3, 3 parts of CeO2, 10 parts of CaO；6 parts of ZnO, 7 parts of Er2O3。
Base glaze raw material: 4 parts of kaolin, 5 parts of quartz, 9 parts of barium carbonates, 17 parts of sodium metasilicate, 13 parts of manganese dioxide, talcums
12 parts, 7 parts of phosphorus lime, 8 parts of zinc sulfate.
Preparation method:
(1) preparation of base glaze: by raw material ball mill wet ball grinding, 200 meshes is crossed, are forged at 1200 DEG C after dry
It burns 1 hour, dry pulverization process after cooling crosses 200 meshes；
(2) base glaze, Nd the preparation of rare earth color-change ceramic glaze: are weighed2O3、Yb2O3、Sm2O3、CrO3、Fe2O3、
SiO2、Al2O3、CeO2、CaO、ZnO、Er2O3, with ball mill wet ball grinding, sieved with 100 mesh sieve after dry to get.
The preparation of rare earth color-change ceramic: rare earth color-change ceramic glaze is imposed on into idiosome surface, is fired at 1100 DEG C
20min。
Embodiment 6
Raw material: 80 parts of base glazes, 6 parts of Nd2O3, 3 parts of Yb2O3, 2 parts of Sm2O3, 2 parts of CrO3, 4 parts of Fe2O3, 8 parts of SiO2、13
Part Al2O3, 8 parts of CeO2, 12 parts of CaO, 7 parts of ZnO, 14 parts of Er2O3。
Base glaze raw material: 6 parts of kaolin, 3 parts of quartz, 7 parts of barium carbonates, 18 parts of sodium metasilicate, 12 parts of manganese dioxide, talcums
8 parts, 7 parts of phosphorus lime, 7 parts of zinc sulfate.
Preparation method:
(1) preparation of base glaze: by raw material ball mill wet ball grinding, 200 meshes is crossed, are forged at 1300 DEG C after dry
It burns 1.5 hours, dry pulverization process after cooling sieves with 100 mesh sieve；
(2) base glaze, Nd the preparation of rare earth color-change ceramic glaze: are weighed2O3、Yb2O3、Sm2O3、CrO3、Fe2O3、
SiO2、Al2O3、CeO2,CaO；ZnO,Er2O3, with ball mill wet ball grinding, sieved with 100 mesh sieve after dry to get.
The preparation of rare earth color-change ceramic: rare earth color-change ceramic glaze is imposed on into idiosome surface, fires 50min at 900 DEG C.
Above-described embodiment is merely illustrative of the technical solution of the present invention and is not intended to limit it, all without departing from the present invention
Any modification of spirit and scope or equivalent replacement should all cover the range in technical solution of the present invention.
Claims (5)
1. a kind of rare earth color-change ceramic glaze, which is characterized in that according to the mass fraction, including the following raw material: 70~100 parts of bases
Glaze, 1~10 part of Nd2O3, 1~5 part of Yb2O3, 1~5 part of Sm2O3, 0.5~3 part of CrO3, 2~6 parts of Fe2O3, 5~15 parts of SiO2、
10~20 parts of Al2O3, 2~10 parts of CeO2, 10~20 parts of CaO；1~10 part of ZnO, 5~15 parts of Er2O3。
2. a kind of rare earth color-change ceramic glaze according to claim 1, which is characterized in that according to the mass fraction, described
Base glaze includes: 1~10 part of kaolin, 1~10 part of quartz, 5~10 parts of barium carbonates, 10~25 parts of sodium metasilicate, 5~15 part two
Manganese oxide, 5~15 parts of talcum, 2~10 parts of phosphorus lime, 4~10 parts of zinc sulfate.
3. the preparation method of rare earth color-change ceramic glaze according to claim 1 or 2, which is characterized in that including walking as follows
It is rapid:
(1) preparation of base glaze: by raw material ball mill wet ball grinding, crossing 100~200 meshes, it is dry after 1200~
It is calcined 0.5~1.5 hour at 1300 DEG C, dry pulverization process after cooling crosses 100~200 meshes；
(2) base glaze, Nd the preparation of rare earth color-change ceramic glaze: are weighed2O3、Yb2O3、Sm2O3、CrO3、Fe2O3、SiO2、
Al2O3、CeO2,CaO；ZnO,Er2O3, with ball mill wet ball grinding, crossed after dry 100~200 meshes to get.
4. the preparation method of rare earth color-change ceramic glaze according to claim 3, which is characterized in that the wet process ball
The mass ratio of mill, glaze and water is 10:1~3, and Ball-milling Time is 20~50min, revolving speed is 500~800r/min.
5. a kind of preparation method of rare earth color-change ceramic, which comprises the steps of: will be described in claims 1 or 2
Rare earth color-change ceramic glaze impose on idiosome surface, at 900~1100 DEG C fire 20~50min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811587177.0A CN109336391A (en) | 2018-12-25 | 2018-12-25 | A kind of rare earth color-change ceramic glaze and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811587177.0A CN109336391A (en) | 2018-12-25 | 2018-12-25 | A kind of rare earth color-change ceramic glaze and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
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| CN109336391A true CN109336391A (en) | 2019-02-15 |
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ID=65297124
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|---|---|---|---|
| CN201811587177.0A Pending CN109336391A (en) | 2018-12-25 | 2018-12-25 | A kind of rare earth color-change ceramic glaze and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109336391A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110436936A (en) * | 2019-08-09 | 2019-11-12 | 东莞市唯美陶瓷工业园有限公司 | A kind of photochromic Ceramic Tiles of decorative pattern and preparation method thereof |
| CN114907101A (en) * | 2021-02-08 | 2022-08-16 | Oppo广东移动通信有限公司 | Shell assembly, preparation method and electronic equipment |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103693994A (en) * | 2013-12-23 | 2014-04-02 | 宾阳县明翔新材料科技有限公司 | Color-changing glaze tile and production method thereof |
| CN103693992A (en) * | 2013-12-23 | 2014-04-02 | 宾阳县明翔新材料科技有限公司 | Color-changing glaze ceramic and production method thereof |
| CN103693991A (en) * | 2013-12-23 | 2014-04-02 | 宾阳县明翔新材料科技有限公司 | Color-changing glaze and preparation method thereof |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103693994A (en) * | 2013-12-23 | 2014-04-02 | 宾阳县明翔新材料科技有限公司 | Color-changing glaze tile and production method thereof |
| CN103693992A (en) * | 2013-12-23 | 2014-04-02 | 宾阳县明翔新材料科技有限公司 | Color-changing glaze ceramic and production method thereof |
| CN103693991A (en) * | 2013-12-23 | 2014-04-02 | 宾阳县明翔新材料科技有限公司 | Color-changing glaze and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110436936A (en) * | 2019-08-09 | 2019-11-12 | 东莞市唯美陶瓷工业园有限公司 | A kind of photochromic Ceramic Tiles of decorative pattern and preparation method thereof |
| CN110436936B (en) * | 2019-08-09 | 2022-01-11 | 东莞市唯美陶瓷工业园有限公司 | Photochromic ceramic tile with decorative patterns and preparation method thereof |
| CN114907101A (en) * | 2021-02-08 | 2022-08-16 | Oppo广东移动通信有限公司 | Shell assembly, preparation method and electronic equipment |
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