CN109294639B - 一种燃油动力提升剂及其制备方法 - Google Patents

一种燃油动力提升剂及其制备方法 Download PDF

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CN109294639B
CN109294639B CN201811404637.1A CN201811404637A CN109294639B CN 109294639 B CN109294639 B CN 109294639B CN 201811404637 A CN201811404637 A CN 201811404637A CN 109294639 B CN109294639 B CN 109294639B
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林壮
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Abstract

本发明公开了一种燃油动力提升剂及其制备方法，按质量百分比计，其中所述添加剂包括以下组分：轻质溶剂石脑油10‑40％，重质溶剂石脑油0.05‑5％，聚醚胺5‑30％，1,2,4‑三甲苯5‑25％，正丙基苯0.1‑10％，2‑乙基己醇0.1‑10％，二甲苯0.1‑10％，枯烯0.1‑10％，2‑甲基环戊二烯三羰基锰30‑60％，环戊二烯三羰基锰0.01‑5％。本发明所述燃油动力提升剂可以显著提升动力，改善汽油品质，可以防止爆震带来的损害，消除发动机噪音，并能对汽车油路系统的积碳油泥进行清洁与抑制，可最大程度优化发动机性能并降低油耗，且安全环保，不腐蚀、不损伤三元催化器。

Description

一种燃油动力提升剂及其制备方法
技术领域
本发明属于燃油添加剂技术领域，具体涉及一种燃油动力提升剂及其制备方法。
背景技术
汽油爆震是一种燃烧现象，有很多名称，比如“燃料爆震”、“火花爆震”、“积炭爆震”或“砰震”。在出现爆震的情况下，因为压力突然增加，会导致讨厌的噪音和功率损失。另外，爆震还会导致过热，缩短阀门、火花塞以及活塞等发动机部件的使用寿命。
在用新式无铅汽油代替有铅汽油以后，通常会减少辛烷值以节约精炼成本。要防止低辛烷值的无铅汽油出现爆震，则必须降低高压缩发动机的性能，这样会损失功率以及燃料的经济性。无铅汽油所产生的燃烧室沉积物会导致辛烷值要求提高(ORI)。针对常规无铅汽所设计的发动机可能会在使用15,000到20,000英里(24,000到32,000公里)后开始爆震。用户经常不得不转而采用更贵的高价无铅汽油，以防止因为辛烷值要求提高而导致爆震。
一些当代发动机配备了爆震传感器，可以检测因为辛烷值要求提高而增加的爆震。在爆震传感器检测到初期爆震之后，会自动降低发动机的性能，以防止爆震并因此损坏发动机。这样，就会减少输出功率，并提高燃料消耗。高辛烷值汽油可以恢复因为辛烷值要求提高而损失的功率和燃料经济性。
带有催化转化器的当代汽车可以减少排气管的排气量并改善环境。如果尾气中有铅或磷，则会使催化剂中毒。使用无铅汽油，可以解决铅污染催化剂的问题。不过，在尾气中含有少量来自曲轴箱润滑油中的磷。在经过一段时间后，这些磷会堆积在催化剂上，并降低催化剂的转化效率。
经过多年的发展，喷油系统代替了汽化燃油系统。可是喷油嘴容易不充分的燃烧物被弄脏。这些脏物和沉积物会对燃油的喷雾模式产生不利影响，从而增加油耗和排气量。目前发现进气阀沉积物也会对废气的排放量产生不利影响。因此需要采用具有足够防爆震性能(辛烷值)的燃料来防止爆震。并且现在的性能提升剂在油路积碳的去除以及节油率等综合性能总是难以令人满意。
发明内容
针对现有技术存在的问题，本发明提供了一种燃油动力提升剂及其制备方法。
本发明采用以下技术方案：
一种燃油动力提升剂，所述燃油动力提升剂包括质量比为1：3-8的添加剂和航空煤油，按质量百分比计，其中所述添加剂包括以下组分：
Figure BDA0001877069770000021
进一步地，按质量百分比计，其中所述添加剂包括以下组分：
Figure BDA0001877069770000022
进一步地，按质量百分比计，其中所述添加剂包括以下组分：
Figure BDA0001877069770000023
Figure BDA0001877069770000031
进一步地，所述燃油动力提升剂包括质量比为1：4-7的添加剂和(无味)航空煤油。更进一步地，所述燃油动力提升剂包括质量比为1：5-6的添加剂和航空煤油。
进一步地，所述2-甲基环戊二烯三羰基锰的CAS号为12108-13-3；所述环戊二烯三羰基锰的CAS号为12079-65-1。
进一步地，轻质溶剂石脑油是溶剂石脑油(石油)，属于轻质芳烃，CAS号为64742-95-6。重质溶剂石脑油是溶剂石脑油(石油)，属于重质芳烃，CAS号为64742-95-5。1,2,4-三甲苯的CAS号为95-63-6。正丙基苯的CAS号为103-65-1。二甲苯的CAS号为1330-20-7。2-乙基己醇的CAS号为104-76-7。枯烯的CAS号为98-82-8。聚醚胺分子量为1000-3000，例如2000，具体地型号为PEA D2000。
一种燃油动力提升剂的制备方法，包括以下步骤：
(1)将所述添加剂中的成分按配比搅拌均匀(使用防爆电机)，即得所述添加剂；
(2)将所述添加剂和航空煤油按配比搅拌均匀(使用防爆电机)，即得所述燃油动力提升剂。
所述燃油动力提升剂的运动粘度(40℃mm2/S，GB/T265)为1～8，例如3.16；闭口闪点(℃，GB/T261)≥40，例如100；机械杂质(质量数，％，GB/T511)≤0.01；铜片腐蚀(50℃，3小时，GB/T5096)级≤1b；水份(％，GB/T260)≤0.03；标准密度(20℃；g/cm3，GB/T1884)：0.70～0.90，例如0.8263。低温性测试：浊点(℃，GB/T6986)＜-35，倾点(℃，GB/T3535)＜-50，凝点(℃，GB/T510)＜-50。
本发明所述燃油动力提升剂可以用于汽油，每60-75升汽油每次使用325mL。本发明所述燃油动力提升剂可用于各类汽油发动机，例如缸内直喷、涡轮增压发动机。
本发明所述燃油动力提升剂可以显著提升动力，改善汽油品质。可以防止爆震带来的损害，消除发动机噪音，并能对汽车油路系统的积碳油泥进行清洁与抑制，可最大程度优化发动机性能并降低油耗，且安全环保，不腐蚀、不损伤三元催化器，增加无铅汽油辛烷值，保持喷油嘴清净性及清除积碳作用，减少对高辛烷值组分的依赖，减少爆震和发动机异响，降低发动机启动时间，减少气门阀座磨损，提高驾驶性能。
本发明的有益效果：
(1)本发明的燃油动力提升剂可以提升辛烷值，改善汽油品质减少噪音产生；
(2)本发明的燃油动力提升剂的制备方法简便，成本低，适合大规模工业生产应用；
(3)本发明的燃油动力提升剂可以增强抗爆性，防止辛烷值要求提高(ORI)而引起的爆震；
(4)本发明的燃油动力提升剂可以使燃油充分燃烧，恢复燃烧功率，增强发动机动力，提升燃油经济性，减少尾气排放；
(5)本发明的燃油动力提升剂可以有效清洁并抑制喷油嘴、进气门和燃油室等部件积碳油泥；
(6)本发明的燃油动力提升剂可以消除怠速不稳，加速不畅，油耗高等现象。
具体实施方式
为了更好的解释本发明，现结合以下具体实施例做进一步说明，但是本发明不限于具体实施例。
按照表1配制燃油动力提升剂中的添加剂。
表1：各实施例中添加剂的组分(质量％)。
Figure BDA0001877069770000041
Figure BDA0001877069770000051
实施例1的燃油动力提升剂包括质量比为1：3的实施例1添加剂和航空煤油。实施例2的燃油动力提升剂包括质量比为1：4的实施例2添加剂和航空煤油。实施例3的燃油动力提升剂包括质量比为1：5的实施例3添加剂和航空煤油。实施例4的燃油动力提升剂包括质量比为1：6的实施例4添加剂和航空煤油。实施例5的燃油动力提升剂包括质量比为1：7的实施例5添加剂和航空煤油。
进气阀沉积物(IVD)测试，不使用本发明的燃油动力提升剂时进气阀门平均沉积物数量为65mg，而使用了本发明的燃油动力提升剂时进气阀门平均沉积物数量为26mg(22次检测的平均值)。可见使用了本发明的燃油动力提升剂时进气阀沉积物降低了50％以上。此外，使用了本发明的燃油动力提升剂时辛烷值要求提高降低了近50％，其能够以高效方式清洁进气阀以及进气口喷油嘴沉积物，同时不会导致燃烧室聚集有害的沉积物。根据排气量检测的结果：使用本发明的燃油动力提升剂可以显著降低氮氧化物(NOx)和一氧化碳的排放量。22辆试验车累积行驶100,000英里(160,000公里)，参与试验的车型包括福特、本田、丰田。按照要求定期使用本发明的燃油动力提升剂后，汽车排气管所排放的与烟雾相关的氮氧化物数量减少20％，并减少排气管排放的一氧化碳数量。
以上所述仅为本发明的具体实施例，并非因此限制本发明的专利范围，凡是利用本发明作的等效变换，或直接或间接运用在其它相关的技术领域，均同理包括在本发明的专利保护范围之中。

Claims (4)

1.一种汽油动力提升剂，其特征在于，所述汽油动力提升剂包括质量比为1：4-7的添加剂和航空煤油，
按质量百分比计，其中所述添加剂包括以下组分：
Figure FDA0002959095820000011
其中轻质溶剂石脑油的CAS号为64742-95-6，重质溶剂石脑油的CAS号为64742-95-5。
2.根据权利要求1所述的汽油动力提升剂，其特征在于，按质量百分比计，其中所述添加剂包括以下组分：
Figure FDA0002959095820000012
3.根据权利要求1或2所述的汽油动力提升剂，其特征在于，所述2-甲基环戊二烯三羰基锰的CAS号为12108-13-3；所述环戊二烯三羰基锰的CAS号为12079-65-1。
4.一种根据权利要求1-3中任一项所述的汽油动力提升剂的制备方法，其特征在于，包括以下步骤：
(1)将所述添加剂中的成分按配比搅拌均匀，即得所述添加剂；
(2)将所述添加剂和航空煤油按配比搅拌均匀，即得所述汽油动力提升剂。
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